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At least 73 records · Page 4

Reflection High-Energy Electron Diffraction Beam-Induced Structural and Property Changes on WO3 Thin Films

Reduction of transition metal oxides can greatly change their physical and chemical properties. Using deposition of WO3 as a case study, we demonstrate that reflection high-energy electron diffraction (RHEED), a surface-sensitive tool widely used to monitor thin-film deposition processes, can significantly affect the cation valence and physical properties of the films through electron-beam induced sample reduction. The RHEED beam is found to increase film smoothness during epitaxial growth of WO3, as well as change the electronic properties of the film through preferential removal of surface oxygen.

Environmental Molecular Sciences Laboratory↗

Optimized mirror shape tuning using beam weightings based on distance, angle of incidence, reflectivity, and power

For glancing-incidence optical systems, such as short-wavelength optics used for nano-focusing, incorporating physical factors in the calculations used for shape optimization can improve performance. Wavefront metrology, including the measurement of a mirror's shape or slope, is routinely used as input for mirror figure optimization on mirrors that can be bent, actuated, positioned, or aligned. Modeling shows that when the incident power distribution, distance from focus, angle of incidence, and the spatially varying reflectivity are included in the optimization, higher Strehl ratios can be achieved. Following the works of Maréchal and Mahajan, optimization of the Strehl ratio (for peak intensity with a coherently illuminated system) occurs when the expectation value of the phase error's variance is minimized. We describe an optimization procedure based on regression analysis that incorporates these physical parameters. This approach is suitable for coherently illuminated systems of nearly diffraction-limited quality. Mathematically, this work is an enhancement of the methods commonly applied for ex situ alignment based on uniform weighting of all points on the surface (or a sub-region of the surface). It follows a similar approach to the optimization of apodized and non-uniformly illuminated optical systems. Significantly, it reaches a different conclusion than a more recent approach based on minimization of focal plane ray errors.

47 OTHER INSTRUMENTATION↗

Measurement and models of bent KAP(001) crystal integrated reflectivity and resolution (invited)

The Advanced Light Source beamline-9.3.1 x-rays are used to calibrate the rocking curve of bent potassium acid phthalate (KAP) crystals in the 2.3-4.5 keV photon-energy range. Crystals are bent on a cylindrically convex substrate with a radius of curvature ranging from 2 to 9 in. and also including the flat case to observe the effect of bending on the KAP spectrometric properties. As the bending radius increases, the crystal reflectivity converges to the mosaic crystal response. The X-ray Oriented Programs (XOP) multi-lamellar model of bent crystals is used to model the rocking curve of these crystals and the calibration data confirm that a single model is adequate to reproduce simultaneously all measured integrated reflectivities and rocking-curve FWHM for multiple radii of curvature in both 1st and 2nd order of diffraction.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Porous Nanomaterials for Ultrabroadband Omnidirectional Anti‐Reflection Surfaces with Applications in High Concentration Photovoltaics

Materials for nanoporous coatings that exploit optimized chemistries and self‐assembly processes offer capabilities to reach ≈98% transmission efficiency and negligible scattering losses over the broad wavelength range of the solar spectrum from 350 nm to 1.5 µm, on both flat and curved glass substrates. These nanomaterial anti‐reflection coatings also offer wide acceptance angles, up to ±40°, for both s‐ and p‐polarization states of incident light. Carefully controlled bilayer films have allowed for the fabrication of dual‐sided, gradient index profiles on plano‐convex lens elements. In concentration photovoltaics platforms, the resultant enhancements in the photovoltaics efficiencies are ≈8%, as defined by experimental measurements on systems that use microscale triple‐junction solar cells. These materials and their applications in technologies that require control over interface reflections have the potential for broad utility in imaging systems, photolithography, light‐emitting diodes, and display technologies.

Yao, Yuan↗

Reflection-asymmetric nuclear deformations within the Density Functional Theory

Within the nuclear density functional theory (DFT) we study the effect of reflection-asymmetric shapes on ground-state binding energies and binding energy differences. To this end, we developed the new DFT solver AXIALHFB that uses an approximate second-order gradient to solve the Hartree-Fock-Bogoliubov equations of superconducting DFT with the quasi-local Skyrme energy density functionals. Illustrative calculations are carried out for even-even isotopes of radium and thorium.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Inversion of vegetation canopy reflectance models for estimating agronomic variables. III - Estimation using only canopy reflectance data as illustrated by the suits model. IV - Total inversion of the SAIL model

The possibility of estimating agronomic and spectral parameters for a vegetation canopy from the canopy reflectance (CR) data in the infrared region is investigated for a set of solar/view directions. It is shown that such an estimation is possible, in principle, for the Suits (1972) model for a homogeneous canopy. The technique is then applied to a more complex model, the SAIL (scattering by arbitrarily inclined leaves) model which explicitly includes the leaf angle distribution in the computation of the canopy reflectance. It is concluded that, given the expected accuracy of CR measurements and the accuracy of the SAIL model in representing CR in the infrared region, the agronomic parameters, leaf area index, and leaf angle distribution can be estimated fairly accurately using ancillary data on spectral parameters.

Goel, N. S.↗

A test of the Suits vegetative-canopy reflectance model with LARS soybean-canopy reflectance data

The Suits vegetative-canopy reflectance model is tested with an extensive set of field reflectance measurements made by the Laboratory for Application of Remote Sensing (LARS) for soybean canopies. The model is tested for the full hemisphere of observer directions as well as the nadir direction. The results show moderate agreement for the visible channels of the Landsat MSS and poor agreement in the near-infrared channel of Landsat MSS. An analysis of errors is given.

Chance, J. E.↗

Estimation of leaf area index from bidirectional spectral reflectance data by inverting a canopy reflectance model

A technique for estimating the leaf area index from bidirectional canopy reflectance (CR) data, in the infrared region, e.g., in band 4 of a Thematic Mapper (TM), is described. It involves inversion of a CR model which accurately represents the reflectance from the canopy. A method for remotely collecting this CR data using an aircraft based TM is described. The bidirectional CR's, for a black spruce (picea mariana) canopy, for 7 solar/view directions, as measured using this technique, are given. A very preliminary analysis of the data from a point of view of estimating LAI by inversion of a CR model is given. This analysis suggests that for an acceptably accurate estimation of LAI, one will require bidirectional CR's for many more than 7 solar/view directions.

Goel, N. S.↗

Colors of reflection nebulae. III - Ultraviolet scattering by small particles in reflection nebulae associated with 17, 20, and 23 Tauri

New surface brightness measurements in the reflection nebulae associated with the Pleiades stars 17, 20, and 23 Tau have been carried out with the IUE satellite. Each nebula was observed at two angular offsets south of the respective illuminating star. At the larger offsets (40, 40, and 60 arcsec respectively) each nebula exhibits a flux distribution which rises much more steeply with decreasing wavelengths than the corresponding stellar spectrum. At the smaller offsets (20 arcsec) the nebular spectra are more similar to those of the stars and fail to show the steep rise at wavelengths less than 2200 A. Independent observations of interstellar absorption lines as well as theoretical arguments by several previous authors lead to a model wherein the reflection nebulosity near the Pleiades stars is caused by a thin sheet of interstellar matter in front of the stars, at an approximate distance of a few x 10 to the -2nd pc. In the context of such a model the nebular spectra obtained near 17, 20, and 23 Tau can be understood only if the phase-function asymmetry of scattering declines with decreasing wavelengths throughout the spectral range. This result indicates that the role of scattering in the UV by particles in the 10 to the -6th cm size range appears more important than is generally recognized by current models.

Witt, A. N.↗

Estimation of shortwave hemispherical reflectance (albedo) from bidirectionally reflected radiance data

An equation for estimating albedo from bidirectional reflectance data is proposed. The estimates of albedo are found to be greater than values obtained with simultaneous pyranometer measurements. Particular attention is given to potential sources of systematic errors including extrapolation of bidirectional reflectance data out to a view zenith angle of 90 deg, the use of inappropriate weighting coefficients in the numerator of the albedo equation, surface shadowing caused by the A-frame instrumentation used to measure the incoming and outgoing radiation fluxes, errors in estimates of the denominator of the proposed albedo equation, and a 'hot spot' contribution in bidirectional data measured by a modular multiband radiometer.

Starks, Patrick J.↗