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At least 73 records · Page 4

Enhanced visible-light-assisted peroxymonosulfate activation on cobalt-doped mesoporous iron oxide for orange II degradation

Sulfate radical-based advanced oxidation processes (SR-AOP) attracted a lot of attention due to their capability and adaptability in wastewater treatment. Although heterogeneous cobalt-based catalysts have been extensively studied and have emerged superior for peroxymonosulfate (PMS) activation, leaching of cobalt is still a major concern. Herein, we report a photo-assisted PMS activation approach using cobalt doped mesoporous iron oxide with exceptional activity and stability up to 7 cycles with very low cobalt leaching (0.5 ppm). The highest activity was obtained by 1 mol % cobalt doped mesoporous iron oxide. Orange II dye was completely degraded by the reactive oxygen species (ROS) generated under visible light irradiation within 1 min. ROS were evaluated using two distinct techniques (Fluorescence probes and Electron Paramagnetic Resonance (EPR). ROS quenching experiments were also used to highlight the dominant pathway. This study correlates the structural and electronic changes induced with cobalt doping to the exceptional activity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effective removal of trace-level toxic metals from flue gas desulfurization wastewater using SiO 2 supported hydrogel sorbent

Flue gas desulfurization (FGD) wastewater generated from coal-fired power plants contain potentially harmful heavy metal pollutants that pose a threat to public health and clean water. In this work, we present a water stable polyethylenimine-n,n’-methylenebisacrylamide (PEI-MBAA) functionalized SiO 2 solid sorbent material (PMS-1.2/1/4) and investigate its metal adsorption kinetics, selectivity, regenerability, and space velocity. The kinetic studies of six of the toxic heavy metals (As, Cd, Cr, Pb, Se, and Hg) prepared with single elements in Milli-Q water showed the effect of chemical bonding and intraparticle mass transfer resistance on the sorption process. The selectivity studies demonstrated the significant adsorption efficiency toward trace-level heavy metals (Se, Cd, U, Al, etc.) from authentic industrial FGD wastewater. Through five consecutive adsorption–desorption cycles with the FGD (uptake)-citrate (release)-based buffer pair, the sorbent showed high heavy metal removal ability and good reusability. The maximum flow rate for the removal of Se from industrial FGD wastewater was determined to be as high as 8 bed volumes/minute of the sorbent bed. Finally, the results demonstrate the PMS-1.2/1.4 sorbent is a promising candidate for the removal of heavy metals from practical aqueous solutions.

36 MATERIALS SCIENCE↗

Existence of tidal tails for the globular cluster NGC 5824

Context: Several dynamically cold streams have been associated with certain globular clusters (GCs) based on orbital energies and angular momenta. Some of these streams are surprisingly far apart from their progenitors and one such pair is Triangulum and NGC 5824. Triangulum can be considered as a piece of the leading tail of NGC 5824 since the cluster’s future orbit matches well with the stream’s track. The existence of the leading tail of NGC 5824 is the motivation behind the search for its trailing tail. Aims: Our goal is to confirm the connection between Triangulum and NGC 5824. We also search for the trailing tail of the cluster. Methods: The selection of member stars of Triangulum is made through various cuts in metallicity, proper motions (PMs), radial velocity and a color–magnitude diagram (CMD). The selected members are compared in phase space to a mock stream that models the disruption of NGC 5824. We then try to detect the trailing tail of the cluster based on a modified matched-filter technique. Stars are assigned weights using their color differences from the cluster’s locus in the CMD. These weights are further scaled, based on the stars’ departures from expected PMs of the model stream. Results: A total of 26 member stars for Triangulum are obtained, 16 of which are newly identified. These members are consistent with the mock stream in the phase space, and their metalicity and position on the CMD are in good agreement with NGC 5824. By applying the matched filter, a tenuous trailing tail of the cluster is detected, spanning ~50° long on sky. The signature matches well with the mock stream’s trajectory. Conclusions: Our results support that the Triangulum stream acts as a part of the leading tail for NGC 5824. On the trailing side, we detected a 50° tail extending from the cluster. The existence of both leading and trailing tails for the GC NGC 5824 is verified.

79 ASTRONOMY AND ASTROPHYSICS↗

Magneto-Structural Combined Dimensional and Topology Optimization of Interior Permanent Magnet Synchronous Machine Rotors

A magneto-structural combined dimensional and topology optimization approach for interior permanent magnet synchronous machine (IPMSM) rotor design is proposed using the Solid Isotropic Material Penalization (SIMP) density-based topology optimization method. This method optimizes the location and dimensions of the permanent magnets (PMs) embedded in the rotor, while simultaneously optimizing the lamination flux barriers using topology optimization.To allow for the location and dimensions of the PMs to change while retaining the same number of mesh elements and connectivity, the mesh must be deformed. Mesh deformation is accomplished using a Laplace smoothing technique. To increase the range of PM displacement and size changes, the non-PM areas of the rotor design domain are divided into sub-regions along whose boundaries the mesh nodes are redistributed also using a Laplace smoothing algorithm. Three examples of IPMSM rotor optimizations are presented to demonstrate the proposed approach.

33 ADVANCED PROPULSION SYSTEMS↗

Rotor Magnet Fault Analysis in Permanent Magnet AC Machines Under Load Conditions - All Electric Transportation Systems

This paper studies the performance of a Permanent Magnet (PM) alternating-current (AC) machine when subjected to faults under load conditions. The effect of varying load torques, and unbalances are found to be potential causes of rotor faults, inducing physical magnet defects or broken rotor-PMs. The consequent and immediate impact on the machine quantities is observed through anomalous change in torque-speed characteristics and other vital signatures such as machine back-EMF/flux and motor current signatures (MCS). The present research study develops and illustrates a method to diagnose physical magnet defects (fault) in PMAC machines by estimating the machine torque/back-EMF constant, Ke. The constant Ke is a measure of magnet strength exhibiting the health of rotor PMs, indicative of faults. Advanced research studies and investigations are carried out to establish motor approximations and signature-based analysis as significant viable tools for diagnosing machine faults even under load conditions.

alternating current↗

Plasma mirror focal spot quality for glass and aluminum mirrors for laser pulses up to 20 ps

High-intensity short-pulse lasers are being pushed further as applications continue to demand higher laser intensities. Uses such as radiography and laser-driven particle acceleration require these higher intensities to produce the necessary x-ray and particle fluxes. Achieving these intensities, however, is limited by the damage threshold of costly optics and the complexity of target chambers. This is evidenced by the Advanced Radiographic Capability (ARC) short-pulse laser at the National Ignition Facility (NIF) at the Lawrence Livermore National Laboratory, producing four high-energy ≈1 kJ laser pulses at 30 ps pulse duration, being limited to an intensity of 10 18 W/cm 2 by the large focal spot size of ≈100 µm. Due to the setup complexity of NIF, changing the location of the final focusing parabola in order to improve the focal spot size is not an option. Therefore, this leads to the possible use of disposable ellipsoidal plasma mirrors (PMs) placed within the chamber, close to the target in an attempt to refocus the four ARC beams. However, the behavior of PMs at these relatively long pulse durations (tens of picoseconds) is not well characterized. The results from the COMET laser at the Jupiter Laser Facility carried out at 0.5 to 20 ps pulse durations on flat mirrors are presented as a necessary first step towards focusing curved mirrors. The findings show defocusing at longer pulse durations and higher intensities, with less degradation when using aluminum coated mirrors.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The Principle of Maximum Conformality Correctly Resolves the Renormalization-Scheme-Dependence Problem

In this paper, we clarify a serious misinterpretation and consequent misuse of the Principle of Maximum Conformality (PMC), which also can serve as a mini-review of PMC. In a recently published article, P. M. Stevenson has claimed that “the PMC is ineffective and does nothing to resolve the renormalization-scheme-dependence problem”, concluding incorrectly that the success of PMC predictions is due to the PMC being a “laborious, ad hoc, and back-door” version of the Principle of Minimal Sensitivity (PMS). We show that such conclusions are incorrect, deriving from a misinterpretation of the PMC and an overestimation of the applicability of the PMS. The purpose of the PMC is to achieve precise fixed-order pQCD predictions, free from conventional renormalization schemes and scale ambiguities. We demonstrate that the PMC predictions satisfy all the self-consistency conditions of the renormalization group and standard renormalization-group invariance; the PMC predictions are thus independent of any initial choice of renormalization scheme and scale. The scheme independence of the PMC is also ensured by commensurate scale relations, which relate different observables to each other. Moreover, in the Abelian limit, the PMC dovetails into the well-known Gell-Mann–Low framework, a method universally revered for its precision in QED calculations. Due to the elimination of factorially divergent renormalon terms, the PMC series not only attains a convergence behavior far superior to that of its conventional counterparts but also deftly curtails any residual scale dependence caused by the unknown higher-order terms. This refined convergence, coupled with its robust suppression of residual uncertainties, furnishes a sound and reliable foundation for estimating the contributions from unknown higher-order terms. Anchored in the bedrock of standard renormalization-group invariance, the PMC simultaneously eradicates the factorial divergences and eliminates superfluous systematic errors, which inversely provides a good foundation for achieving high-precision pQCD predictions. Consequently, owing to its rigorous theoretical underpinnings, the PMC is eminently applicable to virtually all high-energy hadronic processes.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The Sejong Open Cluster Survey (SOS). VII. A Photometric Study of the Young Open Cluster IC 1590

Young open clusters are ideal laboratories to understand the star formation process. We present deep UBVI and Hα photometry for the young open cluster IC 1590 in the center of the H ii region NGC 281. Early-type members are selected from UBV photometric diagrams, and low-mass pre-main-sequence (PMS) members are identified by using Hα photometry. In addition, the published X-ray source list and Gaia astrometric data are also used to isolate probable members. A total of 408 stars are selected as members. The mean reddening obtained from early-type members is ⟨E(B – V)⟩ = 0.40 ± 0.06 (s.d.). We confirm the abnormal extinction law for the intracluster medium. The distance modulus to the cluster determined from the zero-age main-sequence fitting method is 12.3 ± 0.2 mag (d = 2.88 ± 0.28 kpc), which is consistent with the distance d=2.70{sub -0.20}{sup +0.24} kpc from the recent Gaia parallaxes. We also estimate the ages and masses of individual members by means of stellar evolutionary models. The mode of the age of PMS stars is about 0.8 Myr. The initial mass function of IC 1590 is derived. It appears to be a steeper shape (Γ = -1.49 ± 0.14) than that of the Salpeter/Kroupa initial mass function for the high-mass regime (m > 1 M {sub ⊙}). The signature of mass segregation is detected from the difference in the slopes of the initial mass functions for the inner ([[Formula]]) and outer regions of this cluster. We finally discuss the star formation history in NGC 281.

47 OTHER INSTRUMENTATION↗

Infrared studies of star formation

Infrared observations at wavelengths of a few microns to 1 mm are reviewed which pertain to the problem of star formation. The data considered include observations of large gas and dust clouds within which stars may be forming and detailed studies of individual objects within these clouds. Stages of star formation are outlined, the IR luminosity of forming stars is examined, and criteria for selecting interstellar regions for IR studies are discussed along with the importance of dust in the IR energy distributions of star-formation regions. Detailed results, including IR maps, are evaluated for the Orion Molecular Cloud 1 (OMC-1), W3, OMC-2, Mon R2, RCW 57, M17, CRL 2591, and NGC 7538. Some general properties of star-formation regions are summarized, and observational techniques for IR astronomy are described. It is noted that the discovery of possible pre-main-sequence (PMS) objects in the densest central portions of larger clouds supports the generally accepted premise of gravitational collapse as the driving mechanism for the star-formation process and that the observed properties of possible PMS objects agree qualitatively with the predictions of detailed models based on gravitational collapse.

Werner, M. W.↗

Data base management system analysis and performance testing with respect to NASA requirements

Several candidate Data Base Management Systems (DBM's) that could support the NASA End-to-End Data System's Integrated Data Base Management System (IDBMS) Project, later rescoped and renamed the Packet Management System (PMS) were evaluated. The candidate DBMS systems which had to run on the Digital Equipment Corporation VAX 11/780 computer system were ORACLE, SEED and RIM. Oracle and RIM are both based on the relational data base model while SEED employs a CODASYL network approach. A single data base application which managed stratospheric temperature profiles was studied. The primary reasons for using this application were an insufficient volume of available PMS-like data, a mandate to use actual rather than simulated data, and the abundance of available temperature profile data.

Martin, E. A.↗

A search for weak H-alpha emission line pre-main-sequence stars

A spectroscopic survey of 177 stars brighter than about 12.5 in R near four dark clouds in an effort to find pre-main-sequence (PMS) stars with weak H-alpha emission is reported. A number of such stars have been found previously in X-ray images of star formation clouds. Six new candidate PMS stars with EW (H-alpha) between 0.4 and 4.2 A, in addition to four X-ray discovered stars, are found in the L1551 and L1529 clouds in the Taurus-Auriga complex. The total number of pre-main-sequence stars in these clouds appears to be about two times the number of strong emission line T Tauri stars.

Feigelson, E. D.↗

High-sensitivity IRAS observations of the Chamaeleon I dark cloud

Very sensitive IRAS observations of a region of 0.8 sq deg in the Chamaeleon I cloud have revealed 70 compact sources. Hot sources are field stars; warm sources are associated with pre-main-sequence (PMS) stars in the cloud center; others may be in an even earlier phase of gravitational collapse. Cool sources, detected only at the long wavelengths, surround the main cloud and appear to be associated with small globules. Only a small fraction (less than 20 percent) of the total luminosity of the known PMS objects is emitted in the IRAS bands. This has important implications for the classification of the newly discovered embedded objects.

Baud, B.↗

X-ray Activity in Pre-main Sequence Stars

X-ray findings and their interpretation with respect to winds and surface activity of pre-main sequence stars are summarized. Some recent optical and radio observations supporting the X-ray evidence for giant flares on PMS stars are discussed. The unusual properties of PMS/T Tauri stars were for many years primarily attributed to their strong winds. Numerous lines of evidence are outlined herein indicating that PMS stars also have enhanced surface activity, including extremely strong individual flares.

Feigelson, E. D.↗

Specifications Physiological Monitoring System

The operation of a physiological monitoring system (PMS) is described. Specifications were established for performance, design, interface, and test requirements. The PMS is a compact, microprocessor-based system, which can be worn in a pack on the body or may be mounted on a Spacelab rack or other appropriate structure. It consists of two modules, the Data Control Unit (DCU) and the Remote Control/Display Unit (RCDU). Its purpose is to collect and distribute data from physiological experiments in the Spacelab and in the Orbiter.

Source record↗

Radio continuum emission from premain sequence stars and associated structures

VLA 6 cm (4860 MHz with 100 MHz total bandwidth) C-array observations of regions of recent star formation containing premain sequence (PMS) stars, Herbig-Haro objects, and stellar jets, are presented. Three PMS stars, HL Tau, XZ Tau and FS Tau, were definitely (6-sigma) detected and FS Tau B is possibly (5-sigma) detected. The mass loss rates implied for spherically-symmetric stellar winds with outflow velocities of 200 km/s are in the range 1-2 x 10 to the -8th solar masses/yr. HL Tau shows extended structure including a 3-sigma detection of emission possibly associated with the jet from this star. No Herbig-Haro objects were detected at a typical 3-sigma rms level of 0.12 mJy/beam.

Brown, A.↗

Chromospheric and transition region structure of the Herbig emission stars HR 5999 and BN Ori

The IUE spectra of HR 5999 and BN Ori were analyzed, showing strong emission lines of C II, C IV, O I, and Si IV (also Mg II in HR 5999), indicating the presence of chromospheres and transition regions around these high mass premain sequence (PMS) stars. Infrared, optical, and ultraviolet observations show that BN Ori has a spectral type of FO-2 IIIe, a bolometric luminosity of 36 L, age 1.5 million yr, and mass 2 to 2.5 solar mass. As HR 5999 fades, the ratio of total to selective absorption increases indicating the appearance of larger grains or changes in grain alignment. Emission measure distributions are used to investigate the atmospheric structure of the stars. As HR 5999 fades the emission measure distribution rises systematically and the inferred transition region pressures increase. The transition region and chromospheric radiative losses are large and imply input mechanical energy fluxes similar to those of lower mass PMS stars.

Brown, A.↗

An electronic scanner of pressure for wind tunnel models

An electronic scanner of pressure (ESOP) has been developed by NASA Ames Research Center for installation in wind tunnel models. An ESOP system consists of up to 20 pressure modules (PMs), each with 48 pressure transducers and a heater, an analog-to-digital (A/D) converter module, a microprocessor, a data controller, a monitor unit, a control and processing unit, and a heater controller. The PMs and the A/D converter module are sized to be installed in the models tested in the Ames Aerodynamics Division wind tunnels. A unique feature of the pressure module is the lack of moving parts such as a pneumatic switch used in other systems for in situ calibrations. This paper describes the ESOP system and the results of the initial testing of the system. The initial results indicate the system meets the original design goal of 0.15 percent accuracy.

Kauffman, Ronald C.↗