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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Separation of surface and bulk minority-carrier lifetimes in silicon

A photoexcitation technique is suggested which is direct and convenient, requiring little special equipment. No change in the dimensions of the crystal sample is necessary. Although related to the technique of interposing a filter between the light source and the sample, it differs in that the filter is part of the crystal itself. Basically, one of the electrodes is split into two electrodes, one collecting charge from carriers excited in the bulk. This phenomenon in which the carriers follow very closely the electric field lines has been used in position-sensitive semiconductor radiation detectors (Norbeck and Carlson, 1963) but has not been applied to lifetime measurements. In a sense, the split electrode creates a sample without a surface.

Carroll, K. A.↗
NASA NTRS1974

Possible H2/+/ ultraviolet spectrum of Jupiter

An ultraviolet spectral probe for a hydrogen-rich planetary atmosphere, such as that of Jupiter, is suggested, utilizing discrete lines in the H2(+) 2p pi u - /s sigma g electronic transition. For the Jovian atmosphere, the dominant mechanism for exciting H2(+) to its 2p pi u state appears to be photoexcitation, principally through absorption of the solar Lyman-alpha line. The critical role of corrections to the Born-Oppenheimer approximation in the use of an H2(+) probe is discussed.

Wu, F.-M.↗
NASA NTRS1975

OSO-7 results on coronal emission near 304 A

The spectral composition and spatial distribution of equatorial coronal emission near 304 A is examined. Spectral scans indicate that the predominant line is from Si XI. Comparisons of observations with calculations of intensity changes with altitude indicate that collisional excitation is important near the sun but that photoexcitation becomes dominant beyond about 1.3 solar radii from the solar center. Observed and calculated intensities are in approximate agreement for abundances and electron densities that are within the range of observed values.

Nakada, M. P.↗
NASA NTRS1976

Post sunset behavior of the 6300 A atomic oxygen airglow emission

A theoretical model of the 6300 A OI airglow emission was developed based on the assumptions that both the charged and neutral portions of the Earth's upper atmosphere are in steady state conditions of diffusive equilibrium. Intensities of 6300 A OI emission line were calculated using electron density true height profiles from a standard C-4 ionosonde and exospheric temperatures derived from Fabry-Perot interferometer measurements of the Doppler broadened 6300 A emission line shape as inputs to the model. Reaction rate coefficient values, production mechanism efficiencies, solar radiation fluxes, absorption cross sections, and models of the neutral atmosphere were varied parametrically to establish a set of acceptable inputs which will consistently predict 6300 A emission intensities that closely agree with intensities observed during the post-sunset twilight period by an airglow observatory consisting of a Fabry-Perot interferometer and a turret photometer. Emission intensities that can only result from the dissociative recombination of molecular oxygen ions were observed during the latter portion of the observational period. Theoretical calculations indicate that contamination of the 6300 A OI emission should be on the order of or less than 3 percent; however, these results are very sensitive to the wavelengths of the individual lines and their intensities relative to the 6300 A OI intensity. This combination of a model atmosphere, production mechanism efficiencies, and quenching coefficient values was used when the dissociative photoexcitation and direct impact excitation processes were contributing to the intensity to establish best estimates of solar radiation fluxes in the Schumann--Runge continuum and associated absorption cross sections. Results show that the Jacchia 1971 model of the upper atmosphere combined with the Ackerman recommended solar radiation fluxes and associated absorption cross sections produces theoretically calculated intensities that more closely agree with the observed intensities than all the other combinations.

Smith, R. E.↗
NASA NTRS1976

Coronal temperatures and temperature gradients from OSO-7 spectroheliograms

Temperatures and temperature gradients for the outer corona are obtained from brightness gradients of EUV lines that were measured with the spectroheliograph on OSO-7. Brightness gradients show considerable deviations from isothermal model calculations that include collisional excitation and photoexcitation. A negative temperature gradient that gives both positive and negative ion-abundance gradients appears to be able to account for the discrepancy. For the 284-A of Fe XV, perhaps the strongest line from the outer corona, measurements during 1972 appear to be consistent with a temperature near 2.3 million K near the equator at about 1.3 solar radii from the solar center and with temperature-gradient values near -0.7 that extend from as low as 1.2 to about 1.8 solar radii. Temperatures from strong lines of Fe XIV and Fe XVI indicate that variations of about 200,000 K exist along lines of sight where emission is appreciable. There appears to be some agreement between these results and temperature measurements from ion abundances in the solar wind and the Doppler width of the 5303-A line.

Nakada, M. P.↗
NASA NTRS1978

Solar photolysis of water

A cyclic process is described for the solar photolysis of water, including a first stage in which water is reduced in the presence of a Eu(+2) photooxidizable reagent producing hydrogen and spent oxidized Eu(+3) reagent. The spent reagent Eu(+3) is reduced by means of a transition metal ligand complex reductant, RuL(+3) in a photoexcited state, such as a ruthenium pyridyl complex. Due to competing reactions between the photolysis and regeneration products, the photooxidation reaction must be separated from the regeneration in space and time by supporting the reagent and/or the reductant on solid supports and utilizing pH, wavelength and flow control to maximize hydrogen and oxygen production.

Ryason, P. R.↗
NASA NTRS1978

Emission lines of H2 in the extreme-ultraviolet solar spectrum

A sunspot EUV spectrum covering the wavelength range from 1175 to 1714 A with high spatial and spectral resolution is examined which contains about 200 lines not previously reported in solar spectra. Many of the lines are identified as transitions in the Lyman bands of H2. It is shown that the H2 lines are photoexcited not only by H L-alpha, as reported previously, but also by the strong transition-region lines of C II, Si IV, and O IV. The line intensities are analyzed as far as is possible at present, and differences between the quiet chromosphere and the sunspot chromosphere are deduced. The polarization of the observed lines is briefly discussed, the importance of the H L-alpha fluorescence mechanism for the excitation of the H2 Lyman bands is demonstrated, and it is concluded that the H2 lines could also be observable in stars of spectral type later than the sun.

Jordan, C.↗
NASA NTRS1980

Modeling of a solar-pumped iodine laser

The direct conversion in space of solar radiation into laser radiation for power transmission to earth, satellites, or deep space probes shows promise as a reasonably simple technology and may have cost advantage in deployment and greater reliability compared to other methods of space power generation and transmission. The main candidates for solar pumping are the gas dynamic, photochemical, and direct photoexcited lasers. Here consideration is given to the photochemical reaction of alkyliodides which predominantly excite the I(2P1/2) state which then lases at 1.315 microns. The iodine ground state is eventually lost to reconstituting the gas or in the formation of molecular iodine. The rates at which the gas is required to be recycled through the laser system are modest. The side exposure at 100-fold solar concentration of a 100-m long tube with a 1 sq m cross section is estimated to provide 20 kW of continuous laser output. Scaling laws and optimum operating conditions of this system are discussed.

Wilson, J. W.↗
NASA NTRS1981

GaAs-oxide interface states - Gigantic photoionization via Auger-like process

Spectral and transient responses of photostimulated current in MOS structures were employed for the study of GaAs-anodic oxide interface states. Discrete deep traps at 0.7 and 0.85 eV below the conduction band were found with concentrations of 5 x 10 to the 12th/sq cm and 7 x 10 to the 11th/sq cm, respectively. These traps coincide with interface states induced on clean GaAs surfaces by oxygen and/or metal adatoms (submonolayer coverage). In contrast to surfaces with low oxygen coverage, the GaAs-thick oxide interfaces exhibited a high density (about 10 to the 14th/sq cm) of shallow donors and acceptors. Photoexcitation of these donor-acceptor pairs led to a gigantic photoionization of deep interface states with rates 1000 times greater than direct transitions into the conduction band. The gigantic photoionization is explained on the basis of energy transfer from excited donor-acceptor pairs to deep states.

Lagowski, J.↗
NASA NTRS1983

Optical characteristics of young quasars as sources of the cosmic X-ray background

The sources which dominate the thermal cosmic X-ray background cannot have X-ray spectra similar to the power laws measured for bright active galactic nuclei. The optical consequences of this disparity are pursued by considering a standard model for the photoexcitation and heating of the line emitting gas surrounding a central source (e.g., such as a quasar). The optical line emission to be associated with compact young quasar sources having the same X-ray spectrum as the X-ray background is found to be substantially different from that characteristic of typical quasars. Implications on quasar source counts and the identification of such new objects are discussed.

Boldt, E.↗
NASA NTRS1984

Optical characteristics of young quasars as sources of the cosmic X-ray background

The sources which dominate the thermal cosmic X-ray background cannot have X-ray spectra similar to the power laws measured for bright active galactic nuclei. The optical consequences of this disparity are pursued by considering a standard model for the photoexcitation and heating of the line-emitting gas surrounding a central source (e.g., such as a quasar). The optical line emission to be associated with compact young quasar sources having the same X-ray spectrum as the X-ray background is found to be substantially different from that characteristic of typical quasars. Implications on quasar source counts and the identification of such new objects are discussed.

Boldt, E.↗
NASA NTRS1984

Study of the sulphur-containing molecules in the EUV region. IV - The dissociation processes of SO2 in the 760 A region

The fluoresence throughout the VUV and violet regions has been observed from photoexcitation of SO2, and the absolute fluorescence cross sections of the VUV emissions have been measured at selected atomic emission lines and in the synchrotron radiation continuum from 550 to 760 A. Emissions from the O I 1304 A and several S I lines account for the fluorescence observed in the VUV region, while the fluorescence observed in the UV and violet regions is due to excited SO and, also, possibly to excited SO2(+) and SO(+). Structure in the VUV fluorescence excitation function is attributed to predissociation of Rydberg states. The VUV fluorescence resulting from an O2 elimination process, SO2 + h times nu yielding metastable S + O2, has been observed in the present work although the threshold for this process has not been determined. The threshold corresponding to the total dissociation process, SO2 + h times nu yielding metastable S + 2O, has been measured and found to agree reasonably with the expected value calculated from thermochemical data. The processes for the formation of S(+) are also discussed.

Wu, C. Y. R.↗
NASA NTRS1984

Variable ultraviolet emission in SY Muscae

The results of continued IUE monitoring of the symbiotic variable SY Muscae, following an earlier report of a radical enhancement in UV emission from the star, are reported. Over the course of one year, the prominent emission lines of N V, O V, C IV, and He II appear to be gradually decreasing in absolute intensity. This appears to coincide with a steady decline in electron density in the emission line forming region. The data are consistent with a sudden ejection event in which material expelled from the surface of a hot subdwarf has exposed the underlying UV continuum of the star. A number of strong emission lines that are photoexcited by the intense radiation field of the secondary also exhibit broad pedestal emission that suggests turbulent velocities of about 150-300 km/s in an expanding shell or possibly in an accretion disk.

Michalitsianos, A. G.↗
NASA NTRS1985

Population mechanisms for the He(+) n = 3 levels determined from measurements of the solar 1640 A emission

The 1640 A line profile is analyzed using solar data obtained by the NRL slit spectrograph on Skylab. Data from coronal hole regions, quiet sun regions, active regions, prominence regions, and flare regions are presented. The relative densities of 3s, 3p, and 3d levels are determined from the data, and the dominant population mechanisms for these levels are inferred using a rate equation model for the He(+) ion. The relative importance of collisional excitation, radiative recombination, and photoexcitation is determined for each of the solar regions.

Seely, J. F.↗
NASA NTRS1985

Comprehensive solar cell modeling and correlation studies

Modeling and correlation studies of solar cells was discussed. Recursive relationships were used to generate solutions at a number of mesh points within the emitter region. Photoexcited hole concentration and built-in electric field were calculated as a function of position. Simulated and experimentally determined I-V curves were shown to have good fit.

Lamorte, M. L.↗
NASA NTRS1985

Native hole trap in bulk GaAs and its association with the double-charge state of the arsenic antisite defect

A dominant hole trap has been identified in p-type bulk GaAs employing deep level transient and photocapacitance spectroscopies. The trap is present at a concentration up to about 4 x 10 to the 16th per cu cm, and it has two charge states with energies 0.54 + or - 0.02 and 0.77 + or - 0.02 eV above the top of the valence band (at 77 K). From the upper level the trap can be photoexcited to a persistent metastable state just as the dominant midgap level, EL2. Impurity analysis and the photoionization characteristics rule out association of the trap with impurities Fe, Cu, or Mn. Taking into consideration theoretical results, it appears most likely that the two charge states of the trap are the single and double donor levels of the arsenic antisite As(Ga) defect.

Lagowski, J.↗
NASA NTRS1986

Measurement of HO2 chemical kinetics with a new detection method

Reaction rate constants of HO2+O3 were measured at various temperatures using a newly developed HO2 detection method. HO2 was detected by the OH(A-X) emission produced from photodissociative excitation of HO2 at 147 nm. In order to examine the possible interference of other emitting species with the HO2 detection, the photoexcitation processes of all the chemical species existing in the discharge flow tube were also investigated. The results are summarized.

Lee, Long C.↗
NASA NTRS1986

CF2 and CFCl fluorescence from VUV excitation of C2F3Cl

The photoexcitation process of C2F3Cl molecule was investigated in the 106 to 230 nm region using synchrotron radiation as a light source. Photoabsorption and fluorescence cross sections were measured and used to determine the fluorescence quantum yield. Fluorescence yield starts to appear at 170 nm and increases to about 2% at 155 nm. The fluorescence spectra were dispersed to identify the emitting species. At the excitation wavelength of 155 nm, the emission system is CFCl (Hermitian conjugate of A - Hermitian conjugate of X), and at 123.9 nm, both the CF2 (Hermitian conjugate of A - Hermitian conjugate of X) and CFCl (Hermitian conjugate of A - Hermitian conjugate of X) systems are observed. The dissociation processes that produced these excited species are discussed.

Nee, J. B.↗