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At least 73 records · Page 4

Quantifying the role of land-atmosphere feedbacks in mediating near-surface temperature persistence

Weather persistence from month to month is an important source of predictability on the intraseasonal time-scale. Persistence in the lower troposphere is thought to be mainly due to dynamical feedbacks between the atmosphere and physical variables at or below the surface. Many recent improvements of dynamical seasonal forecasting models have been due to better initialisations and representations of the lower boundary. While many physical mechanisms that mediate persistence are well-understood, they have not previously been considered simultaneously in a causal framework. Here we use linear methods that are widely used in the field of causal inference in statistics to identify mediators between persistent near-surface temperature anomalies from one month to the next. The variables considered are soil temperature and soil moisture at four levels, and snow depth. In Northern Europe, the high persistence of temperature in summer is shown to be mediated mainly by soil temperature anomalies. The high persistence in winter is mediated by snow depth and soil moisture in addition to soil temperature. The annual cycles of persistence are also investigated for the mid- and high latitudes of the Northern Hemisphere, confirming the important role of soil temperature in summer. Snow depth is an important mediator when, and where, its interannual variability is large: in winter at midlatitudes and in spring and autumn at high latitudes. The novel contribution of this study is the introduction of a linear causal methodology and a holistic approach that allows quantification and comparison of the different roles of soil variables and snow depth in mediating near-surface temperature persistence.

Meteorology & Atmospheric Sciences↗

Reverse-zoonoses of 2009 H1N1 pandemic influenza A viruses and evolution in United States swine results in viruses with zoonotic potential

The 2009 H1N1 pandemic (pdm09) lineage of influenza A virus (IAV) crosses interspecies barriers with frequent human-to-swine spillovers each year. These spillovers reassort and drift within swine populations, leading to genetically and antigenically novel IAV that represent a zoonotic threat. We quantified interspecies transmission of the pdm09 lineage, persistence in swine, and identified how evolution in swine impacted zoonotic risk. Human and swine pdm09 case counts between 2010 and 2020 were correlated and human pdm09 burden and circulation directly impacted the detection of pdm09 in pigs. However, there was a relative absence of pdm09 circulation in humans during the 2020–21 season that was not reflected in swine. During the 2020–21 season, most swine pdm09 detections originated from human-to-swine spillovers from the 2018–19 and 2019–20 seasons that persisted in swine. We identified contemporary swine pdm09 representatives of each persistent spillover and quantified cross-reactivity between human seasonal H1 vaccine strains and the swine strains using a panel of monovalent ferret antisera in hemagglutination inhibition (HI) assays. The swine pdm09s had variable antigenic reactivity to vaccine antisera, but each swine pdm09 clade exhibited significant reduction in cross-reactivity to one or more of the human seasonal vaccine strains. Further supporting zoonotic risk, we showed phylogenetic evidence for 17 swine-to-human transmission events of pdm09 from 2010 to 2021, 11 of which were not previously classified as variants, with each of the zoonotic cases associated with persistent circulation of pdm09 in pigs. These data demonstrate that reverse-zoonoses and evolution of pdm09 in swine results in viruses that are capable of zoonotic transmission and represent a potential pandemic threat.

60 APPLIED LIFE SCIENCES↗

Risk Evaluation for CO2 Geosequestration in the Knox Supergroup, Illinois Basin Final Report

This report describes a process and provides seed information for identifying and evaluating risks pertinent to a hypothetical carbon dioxide (CO2) capture and sequestration (CCS) project. In the envisioned project, the target sequestration reservoir rock is the Potosi Formation of the Knox Supergroup. The Potosi is identified as a potential target formation because (1) at least locally, it contains vuggy to cavernous layers that have very high porosity, and (2) it is present in areas where the deeper Mt. Simon Sandstone (a known potential reservoir unit) is absent or nonporous. The key report content is discussed in Section 3.3, which describes two lists of Features, Events, and Processes (FEPs) that should be considered during the design stage of such a project. These lists primarily highlight risk elements particular to the establishment of the Potosi as the target formation in general. The lists are consciously incomplete with respect to risk elements that would be relevant for essentially all CCS projects regardless of location or geology. In addition, other risk elements specific to a particular future project site would have to be identified. Sources for the FEPs and scenarios listed here include the iconic Quintessa FEPs list developed for the International Energy Agency Greenhouse Gas (IEAGHG) Programme; previous risk evaluation projects executed by Schlumberger Carbon Services; and new input solicited from experts currently working on aspects of CCS in the Knox geology. The projects used as sources of risk information are primarily those that have targeted carbonate reservoir rocks similar in age, stratigraphy, and mineralogy to the Knox-Potosi. Risks of using the Potosi Formation as the target sequestration reservoir for a CCS project include uncertainties about the levels of porosity and permeability of that rock unit; the lateral consistency and continuity of those properties; and the ability of the project team to identify suitable (i.e., persistently porous and permeable) injection depths within the overall formation. Less direct implications include the vertical position of the Potosi within the rock column and the absence of a laterally extensive shale caprock immediately overlying the Potosi. Based on modeling work done partly in association with this risk report, risks that should also be evaluated include the ability of available methods to predict and track the development of a CO2 plume as it migrates away from the injection point(s). The geologic and hydrodynamic uncertainties present risks that are compounded at the stage of acquiring necessary drilling and injection permits. It is anticipated that, in the future, a regional geologic study or CO2-emitter request may identify a small specific area as a prospective CCS project site. At that point, the FEPs lists provided in this report should be evaluated by experts for their relative levels of risk. A procedure for this evaluation is provided. The higher-risk FEPs should then be used to write project-specific scenarios that may themselves be evaluated for risk. Then, actions to reduce and to manage risk can be described and undertaken. The FEPs lists provided as Appendix 2 should not be considered complete, as potentially the most important risks are ones that have not yet been thought of. But these lists are intended to include the most important risk elements pertinent to a Potosi-target CCS project, and they provide a good starting point for diligent risk identification, evaluation, and management.

Hnottavange-Telleen, Ken↗

Risk Evaluation for CO 2 Geosequestration in the Knox Supergroup, Illinois Basin (Final Report)

This report describes a process and provides seed information for identifying and evaluating risks pertinent to a hypothetical carbon dioxide (CO 2 ) capture and sequestration (CCS) project. In the envisioned project, the target sequestration reservoir rock is the Potosi Formation of the Knox Supergroup. The Potosi is identified as a potential target formation because (1) at least locally, it contains vuggy to cavernous layers that have very high porosity, and (2) it is present in areas where the deeper Mt. Simon Sandstone (a known potential reservoir unit) is absent or nonporous. The key report content is discussed in Section 3.3, which describes two lists of Features, Events, and Processes (FEPs) that should be considered during the design stage of such a project. These lists primarily highlight risk elements particular to the establishment of the Potosi as the target formation in general. The lists are consciously incomplete with respect to risk elements that would be relevant for essentially all CCS projects regardless of location or geology. In addition, other risk elements specific to a particular future project site would have to be identified. Sources for the FEPs and scenarios listed here include the iconic Quintessa FEPs list developed for the International Energy Agency Greenhouse Gas (IEAGHG) Programme; previous risk evaluation projects executed by Schlumberger Carbon Services; and new input solicited from experts currently working on aspects of CCS in the Knox geology. The projects used as sources of risk information are primarily those that have targeted carbonate reservoir rocks similar in age, stratigraphy, and mineralogy to the Knox-Potosi. Risks of using the Potosi Formation as the target sequestration reservoir for a CCS project include uncertainties about the levels of porosity and permeability of that rock unit; the lateral consistency and continuity of those properties; and the ability of the project team to identify suitable (i.e., persistently porous and permeable) injection depths within the overall formation. Less direct implications include the vertical position of the Potosi within the rock column and the absence of a laterally extensive shale caprock immediately overlying the Potosi. Based on modeling work done partly in association with this risk report, risks that should also be evaluated include the ability of available methods to predict and track the development of a CO 2 plume as it migrates away from the injection point(s). The geologic and hydrodynamic uncertainties present risks that are compounded at the stage of acquiring necessary drilling and injection permits. It is anticipated that, in the future, a regional geologic study or CO 2 -emitter request may identify a small specific area as a prospective CCS project site. At that point, the FEPs lists provided in this report should be evaluated by experts for their relative levels of risk. A procedure for this evaluation is provided. The higher-risk FEPs should then be used to write project-specific scenarios that may themselves be evaluated for risk. Then, actions to reduce and to manage risk can be described and undertaken. The FEPs lists provided as Appendix 2 should not be considered complete, as potentially the most important risks are ones that have not yet been thought of. But these lists are intended to include the most important risk elements pertinent to a Potosi-target CCS project, and they provide a good starting point for diligent risk identification, evaluation, and management.

54 ENVIRONMENTAL SCIENCES↗

ACOUSTIC WAVES GENERATED BY IMPULSIVE DISTURBANCES IN A GRAVITATIONALLY STRATIFIED MEDIUM

Even though it is well-known from observations of the Sun that three-minute period chromospheric oscillations persist in the internetwork quiet regions and sunspot umbrae, until now their origin and persistence has defied clear explanation. Here we provide a clear and simple explanation for it with a demonstration of how such oscillations at the chromosphere's cutoff frequency naturally arise in a gravitationally stratified medium when it is disturbed. The largest-wavenumber vertical components of a chromospheric disturbance produce the highest-frequency wave packets, which propagate out of the disturbed region at group speeds that are close to the sound speed. Meanwhile, the smallest-wavenumber components develop into wave packets of frequencies close to the acoustic cutoff frequency that propagate at group speeds that are much lower than the sound speed. Because of their low propagation speed, these low-frequency wave packets linger in the disturbed region and nearby, and thus, are the ones that an observer would identify as the persistent, chromospheric three-minute oscillations. We emphasize that we can account for the power of the persistent chromospheric oscillations as coming from the repeated occurrence of disturbances with length scales greater than twice the pressure scale height in the upper photosphere.

79 ASTRONOMY AND ASTROPHYSICS↗

Adaptive Scalpel Scanning Probe Microscopy for Enhanced Volumetric Sensing in Tomographic Analysis

Controlling nanoscale tip‐induced material removal is crucial for achieving atomic‐level precision in tomographic sensing with atomic force microscopy (AFM). While advances have enabled volumetric probing of conductive features with nanometer accuracy in solid‐state devices, materials, and photovoltaics, limitations in spatial resolution and volumetric sensitivity persist. This work identifies and addresses in‐plane and vertical tip‐sample junction leakage as sources of parasitic contrast in tomographic AFM, hindering real‐space 3D reconstructions. Novel strategies are proposed to overcome these limitations. First, the contrast mechanisms analyzing nanosized conductive features are explored when confining current collection purely to in‐plane transport, thus allowing reconstruction with a reduction in the overestimation of the lateral dimensions. Furthermore, an adaptive tip‐sample biasing scheme is demonstrated for the mitigation of a class of artefacts induced by the high electric field inside the thin oxide when volumetrically reduced. This significantly enhances vertical sensitivity by approaching the intrinsic limits set by quantum tunneling processes, allowing detailed depth analysis in thin dielectrics. The effectiveness of these methods is showcased in tomographic reconstructions of conductive filaments in valence change memory, highlighting the potential for application in nanoelectronics devices and bulk materials and unlocking new limits for tomographic AFM.

36 MATERIALS SCIENCE↗

Disorder-induced proximate quantum spin ice phase in Pr2Sn2O7

We report a comprehensive bulk characterization and neutron scattering investigation of single-crystalline Pr2Sn2O7, a magnetic pyrochlore synthesized via a flux-growth method. Unpolarized neutron diffuse scattering reveals the emergence of spin-ice correlations below T ∼ 1 K, evidenced by the development of anisotropic pinch-point features that are consistent with quantum-spin-ice (QSI) behavior. A.C. susceptibility measurements indicate a progressive slowing of spin dynamics in this regime, culminating in complete spin freezing below Tf ≈ 0.15 K. Inelastic neutron scattering at T = 0.5 K reveals a broad spectrum of quasi-elastic magnetic excitations, with intensity in the low-energy range [0, 0.2] meV significantly suppressed below Tf. Meanwhile, an incipient (100)-type magnetic order begins to nucleate, and a gapped excitation centered at ℏω = 0.23 meV persists. We further identify two distinct dynamical timescales above Tf , a slow component τ_slow ∼ 10^−5 s and a fast component τ_fast ∼ 10^−10 s, in quantitative agreement with theoretical predictions for QSI systems. Taken together, these results indicate that Pr2Sn2O7 enters a disorder-induced spin-frozen phase below Tf , lying in close proximity to a U(1) quantum spin liquid

Luo, Yi [ORNL] (ORCID:000900048710428X)↗

Contribution of sewage to occurrence of phosphodiesterase-5 inhibitors in natural water

Phosphodiesterase-5 inhibitors (PDE-5i, such as Sildenafil, Tadalafil and Vardenafil, mainly prescribed to treat erectile dysfunction) and their generic drug equivalents have been widely marketed and consumed in Korea. From the concentrations detected in wastewater, we could deduce that relatively large amounts of PDE-5i were consumed without a legal prescription. Thus, PDE-5i’s presence in the environment via sewage is unavoidable, and their environmental fate within a sewage treatment plant (STP) should be evaluated. In this study, we investigated the occurrence of three PDE-5i analogs in the influent and effluent of two STPs and the receiving water bodies. The PDE-5i concentration in total reached 62 ± 12 (STP#1) and 88 ± 37 ng L -1 (STP#2) in the sewage influent; about 70% of it was Sildenafil in both STPs. However, they were hardly removed by the STPs as the removal efficiency of the STPs was less than 10% ± 5%. Therefore, the pharmaceuticals were detected in the receiving water (lower than 7 ng L -1 as a total amount) and the concentration slightly increased downstream of the STPs. A simple mass balance model applied for the compounds in the STP effluent and receiving water bodies also confirmed that the discharged PDE-5i were quite persistent. Lastly, we identified temporal and regional patterns in the consumption of the drugs from daily variations of PDE-5i in the influent to these two STPs. For instance, the levels of PDE-5i in the sewage significantly increased on weekends (from Friday to Saturday), and especially in the area where adult-entertainment businesses are common. We estimated that the amount of PDE-5i consumption in this area was 31% higher than that in the area with fewer nightlife spots. Considering that they are pharmaceutically active and resistant to treatment processes within an STP, it is advised that a regular monitoring and management program for PDE-5i should be developed to prevent the discharge of the pharmaceuticals into the water environment.

54 ENVIRONMENTAL SCIENCES↗

Restoration Strategy for Active Distribution Systems Considering Endogenous Uncertainty in Cold Load Pickup

Cold load pickup (CLPU) phenomenon is identified as the persistent power inrush upon a sudden load pickup after an outage. Under the active distribution system (ADS) paradigm, where distributed energy resources (DERs) are extensively installed, the decreased outage duration can induce a strong interdependence between CLPU pattern and load pickup decisions. In this paper, we propose a novel modelling technique to tractably capture the decision-dependent uncertainty (DDU) inherent in the CLPU process. Subsequently, a two-stage stochastic decision-dependent service restoration (SDDSR) model is constructed, where first stage searches for the optimal switching sequences to decide step-wise network topology, and the second stage optimizes the detailed generation schedule of DERs as well as the energization of switchable loads. Further, to tackle the computational burdens introduced by mixed-integer recourse, the progressive hedging algorithm (PHA) is utilized to decompose the original model into scenario-wise subproblems that can be solved in parallel. The numerical test on modified IEEE 123-node test feeders has verified the efficiency of our proposed SDDSR model and provided fresh insights into the monetary and secure values of DDU quantification.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Evaluation of survival estimates generated from tracking downstream migrating juvenile sea lamprey ( Petromyzon marinus ) with a miniature acoustic telemetry tag

Fish that undertake juvenile migration pass through habitats that vary in mortality risk. The ability to identify regions of persistently low survival would improve fishery management. We conducted a field study combined with predictive modeling of survival in downstream migrating juvenile sea lamprey using a new micro-acoustic telemetry tag designed for implantation into small, slender-bodied fishes. Detection data were collected from eight receivers placed across a coastal riverine–wetland–lake complex. Juvenile sea lamprey initiated downstream movement near nautical twilight, stopped frequently, and were more likely to move during high river discharge. Estimated survival was highest in the riverine reach, declined through the river–wetland complex, and dropped precipitously in the drowned rivermouth lake. However, the high transmission rate and resulting short battery life of the microtransmitters (as configured) likely resulted in missed detections in the lower reaches. Simulation analyses suggested survival estimation could be improved by increasing the number of tagged lamprey and staggering release locations. We offer practical recommendations for the use of this new transmitter in field studies with small anguilliform fish.

59 BASIC BIOLOGICAL SCIENCES↗

Interim Results from a Study of the Impacts of Tin(II) Based Mercury Treatment in a Small Stream Ecosystem: Tims Branch, Savannah River Site

Mercury (Hg) has been identified as a 'persistent, bioaccumulative and toxic' pollutant with widespread impacts throughout North America and the world (EPA. 1997a, 1997b, 1998a, 1998b, 2000). Although most of the mercury in the environment is inorganic Hg, a small proportion of total Hg is transformed through the actions of aquatic microbes into methylmercury (MeHg). In contrast to virtually all other metals, MeHg biomagnifies or becomes increasingly concentrated as it is transferred through aquatic food chains so that the consumption of mercury contaminated fish is the primary route of this toxin to humans. For this reason, the ambient water quality criterion (AWQC) for mercury is based on a fish tissue endpoint rather than an aqueous Hg concentration, as the tissue concentration (e.g., < 0.3 μg/g fillet) is considered to be a more consistent indicator of exposure and risk (EPA, 2001).

54 ENVIRONMENTAL SCIENCES↗

Thermal aging effects on crosslinked polyethylene cable insulation with decabromodiphenyl ether flame retardant alternative

Decabromodiphenyl ether (decaBDE) has been extensively used as a flame retardant in several applications, including nuclear electrical cable insulation. However, decaBDE has been identified as a persistent, bioaccumulative and toxic (PBT) substance, leading to regulatory scrutiny. The Environmental Protection Agency (EPA) published a regulation on January 6, 2021, aimed at phasing out the manufacturing, processing, and distribution of decaBDE. This rule set a compliance deadline of March 8, 2021, for the manufacture and processing of decaBDE, and an extended deadline of January 6, 2023, for specific applications including wire and cable insulation in nuclear power generation facilities. In response to such regulations, RSCC, a major supplier of safety-related electrical cables and associated products to the U.S. nuclear industry updated the formula of their crosslinked polyethylene (XLPE) insulation to replace the historically used decaBDE flame retardant with an acceptable alternative. This change from the previous decaBDE-containing XLPE prompted interest in comparative performance of the two material formulations, especially with respect to characteristics relevant to safety-related function such as thermal and radiation resistance. RSCC graciously provided samples of wire insulated with the decaBDE-containing XLPE formulation and corresponding wire insulated with XLPE of the new formulation, containing a decaBDE alternative. In this work we compare characteristics of the two formulations and a previously produced commercial version of the RSCC decaBDE-containing XLPE insulation subjected to thermal aging at 150 °C and 165 °C. The comparison was focused on mechanical durability, thermal stability in the oxidative environment, and chemical structures. Briefly, • Tensile elongation at break (EAB) results showed loss of mechanical elasticity with longer aging time, as expected. Aging time dependence of EAB did not differ between the decaBDE-containing and decaBDE-alternative samples. • Subtle differences between the two materials can be detected from Fourier-transform infrared spectroscopy (FTIR) absorbance spectra in the range below 1700 cm -1 , are assumed to be related to decomposition of flame retardant additives during thermal aging. • The oxidation induction time (OIT) data seemed to show that the unaged decaBDE-containing XLPE material is more thermally stable than the unaged decaBDE-alternative material, but the discrepancy in OIT decreased with aging time and the OIT values of the two materials became similar starting with the 4 th day of aging at 165 °C. This thermal aging investigation confirmed that the mechanical durability, a key property monitored for cable qualification, was not significantly affected by the modification of the formulation with a decaBDE alternative flame-retardant system in the investigated thermal aging conditions. Further studies on the same sets of materials exposed to thermal and gamma radiation aging would further inform comparison of the materials safety-related function.

36 MATERIALS SCIENCE↗

Consideration of Decabromodiphenyl Ether Flame Retardant in Thermal and Radiation Aging of Crosslinked Polyethylene Cable Insulation

Decabromodiphenyl ether (decaBDE) has been used as a flame-retardant additive in nuclear-grade electrical cable insulation. However, decaBDE has been identified as a persistent, bioaccumulative and toxic (PBT) substance, leading to regulatory scrutiny. On January 6, 2021, the Environmental Protection Agency (EPA) published a final rule to phase out decaBDE. The 2021 rule set a two-year compliance deadline for “processing and distribution in commerce of decaBDE for use in wire and cable insulation in nuclear power generation facilities.” In recognition of industry concerns following a sudden discontinuation of decaBDE-containing Class 1E wire and cable essential for nuclear power operations and the time needed for qualifying the individual components using the alternative insulation technology, an extended compliance deadline was set in the finalized amendments to the 2021 rule as published by the Environmental Appeals Board on November 12, 2024. The 2024 rule set the compliance deadline for processing and distributing decaBDE-containing wire and cable insulation until the end of the service life of these materials. Since decaBDE has long been relied upon as the flame retardant in one of the most common cross-linked polyethylene (XLPE) nuclear cable insulation formulations, RSCC Firewall III insulation, questions have naturally arisen regarding whether changes in cable performance might be expected for XLPE containing a decaBDE alternative, especially for safety-related cables that must perform their safety function in a design basis event such as a loss of coolant accident.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Advective forecasts of VAS imagery for use in anticipating convective destabilization

Wind field forecasts, based on data from the Visible Atmospheric Sounder (VAS) instrument on board the most recent GOES satellite, are described. The forecasts were used to generate a series of water vapor images for the Central U.S. according to an isentropic prediction scheme. The ability of VAS imagery to detect regions of mesoscale convective instability was contrasted with data from a 9-12 hr advective forecast and the results are discussed. It is shown that the VAS imagery was free from masking by convective outflows and lends itself to repeated applications for updating throughout the day. The incorporation of surface data into the VAS forecast is recommended in order to identify areas of persistent moisture convergence. Some examples of the VAS imagery are provided.

Petersen, R. A.↗

Radiation physics and modelling for off-nadir satellite-sensing of non-Lambertian surfaces

The primary objective of this paper is to provide a deeper understanding of the physics of satellite remote-sensing when off-nadir observations are considered. Emphasis is placed on the analysis and modeling of atmospheric effects and the radiative transfer of non-Lambertian surface reflectance characteristics from ground-level to satellite locations. The relative importance of spectral, spatial, angular, and temporal reflectance characteristics for satellite-sensed identification of vegetation types in the visible and near-infrared wavelength regions is evaluated. The highest identification value is attributed to angular reflectance signatures. Using radiative transfer calculations to evaluate the atmospheric effects on angular reflectance distributions of vegetation surfaces, atmosphere-invariant angular reflectance features such as the 'hot spot' and the 'persistent valley' are identified. A new atmospheric correction formalism for complete angular reflectance distributions is described. A sample calculation demonstrates that a highly non-Lambertian measured surface reflectance distribution can be retrieved from simulated satellite data in the visible and near infrared to within about 20 percent accuracy for almost all view directions up to 60 deg off-nadir. Thus the high value of angular surface reflectance characteristics (the 'angular signature') for satellite-sensed feature identification is confirmed, which provides a scientific basis for future off-nadir satellite observations.

Gerstl, S. A.↗

White dwarfs in Be star binary systems

An evaluation is made of possible reasons for the persistent inability to identify white dwarf stars in the Be binary systems. It is noted that many Be stars exhibiting large optical enhancements may be Be + WD and Be + He systems, and that observations of pulsations in the H-alpha emission, as well as observation of time delays between enhancements of optical line and continuum, can identify such systems.

Apparao, K. M. V.↗

Multiple flow regimes in the Northern Hemisphere winter. I - Methodology and hemispheric regimes. II - Sectorial regimes and preferred transitions

Multivariate pdfs in the phase space of large-scale atmospheric motions are examined in order to identify recurrent and persistent flow patterns. The extent to which intraseasonal variablity can be described and understood in terms of multiple flow regimes is clarified. It is shown that the synoptically intriguing and statistically significant inhomogeneities exhibited by the 2D phase plane on the periphery of the distribution are due to the existence of persistent and recurrent anomaly patterns. It is argued that these inhomgeneities are obscured when PDFs are examined in a smaller-dimensional subspace than dynamically desired. A synoptic characterization of onsets and breaks for the flow regimes is given by compositing. In situ evolutions of anomaly patterns, slow westward shifts of high-latitude anomaly centers, and successive downstream increase of anomaly magnitudes are the typical signatures of such events.

Kimoto, Masahide↗

Effect of marine stratocumulus in TOMS ozone

The algorithm used to correct total O3 from the total ozone mapping spectrometer (TOMS) for cloud effects is based on the measured reflectivity, a climatological cloud top height, and an assumed tropospheric O3 column amount below clouds. In regions of persistent subtropical marine stratocumulus it is assumed that this introduces a positive error into total O3 because these clouds are lower than the assumed mean cloud height used in the algorithm. This appears to be confirmed by high correlation between Nimbus 7 TOMS total O3 and reflectivity data for typical regimes of persistent stratus, as identified by the international satellite cloud climatology project (ISCCP) observations. The TOMS total O3 overestimate has been computed using Nimbus 7/solar backscattered ultraviolet total O3 derived using temperature humidity infrared radiometer (THIR) data for years 1979-1984. A functional relationship between the THIR/non-THIR total O3 difference and reflectivity is used with TOMS reflectivity to modify Nimbus 7 TOMS O3 data for selected regions and periods. The correction diminishes or eliminates a number of apparent O3 maxima, with reductions of up to 20 Dobson units (DU) in total O3 on daily maps and approximately 5 DU on monthly mean O3 maps. Significant correlation between corrected TOMS O3 and reflectivity data remains because low-altitude O3 is retrieved more efficiently over a high-albedo surface. It is also possible that dynamical influences leading to stratocumulus formation bring O3-enriched air into the area. These results imply that although good arguments can be made for the use of TOMS total O3 as a proxy for tropospheric O3 in the tropics, caution must be exercised in the use of daily and even monthly O3 maps in the vicinity of clouds. Further research into the TOMS algorithm in cloudy regions is required to derive reliable estimates of tropospheric O3.

Thompson, A. M.↗