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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Final results of the search for new Milky Way satellites in the Hyper Suprime-Cam Subaru Strategic Program survey: Discovery of two more candidates

Abstract We present the final results of our search for new Milky Way (MW) satellites using the data from the Hyper Suprime-Cam (HSC) Subaru Strategic Program (SSP) survey over ∼1140 deg2. In addition to three candidates that we have already reported, we have identified two new MW satellite candidates in the constellations of Sextans, at a heliocentric distance of D⊙ ≃ 126 kpc, and Virgo, at D⊙ ≃ 151 kpc, named Sextans II and Virgo III, respectively. Their luminosities (Sext II: MV ≃ −3.9 mag; Vir III: MV ≃ −2.7 mag) and half-light radii (Sext II: rh ≃ 154 pc; Vir III: rh ≃ 44 pc) place them in the region of size–luminosity space of ultra-faint dwarf galaxies (UFDs). Including four previously known satellites, there are a total of nine satellites in the HSC-SSP footprint. This discovery rate of UFDs is much higher than that predicted from the recent models for the expected population of MW satellites in the framework of cold dark matter models, thereby suggesting that we encounter a too many satellites problem. Possible solutions to settle this tension are also discussed.

Homma, Daisuke↗
DOE OSTI2026

Arabidopsis lipins mediate lipid droplet biogenesis to protect cells from lipotoxicity

Lipin proteins, a family of phosphatidic acid phosphatases (PAHs), are key regulators of lipid metabolism, storage, and homeostasis across eukaryotes. While Arabidopsis (Arabidopsis thaliana) lipins function in lipid biosynthesis and gene regulation, their roles in lipid droplet (LD) biogenesis and lipid homeostasis remain largely unknown. Here, we show that double knockout of two PAH genes (PAH1/2) results in impaired LD biogenesis, accelerated triacylglycerol (TAG) hydrolysis, and lipid imbalance. pah1/2 mutant leaves exhibited a marked reduction in TAG levels and a significant decrease in LD size, while the rates of TAG and diacylglycerol (DAG) synthesis remained largely unchanged. In seeds, PAH1/2 disruption minimally affected TAG content but significantly reduced LD size. Fatty acid feeding experiments demonstrated impaired LD formation and increased lipotoxicity in pah1/2 leaves and seedlings. Furthermore, knockout of PAH1/2 in mutants with enhanced fatty acid flux through phosphatidylcholine (PC) led to severe reductions in leaf TAG levels, despite increases in TAG synthesis rates, indicating accelerated TAG turnover. Phosphatidic acid, free fatty acids, and PC accumulated, leading to massive proliferation of endoplasmic reticulum membranes and severe growth and developmental defects. These findings demonstrate evolutionarily conserved roles for PAH1/2 in LD biogenesis, membrane lipid homeostasis, and cellular protection against lipotoxicity, particularly under conditions of elevated fatty acid flux.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Spatial String Tension and Its Effects on Screening Correlators in a Thermal QCD Plasma

We calculate the spatial Wilson line correlator for 2 +1 flavor QCD using highly improved staggered quark discretization for fermions and in quenched QCD for a wide range of temperatures, from the chiral crossover temperature 𝑇 pc ≃ 156 MeV or the deconfinement temperature ≃300 MeV, respectively, up to 2 GeV. Extracting the spatial string tension for different lattice cutoffs and by performing a continuum extrapolation of this observable, we show that the soft (magnetic) gluons interact nonperturbatively even at temperatures ≳1 GeV. We provide incriminating evidences to demonstrate that dimensionally reduced effective theories can describe these soft quark and gluon quasi-particles for both quenched and 2 +1 flavor QCD, at temperatures 𝑇 ≳ 5⁢𝑇 pc . We also show for the first time the imprints of the nonperturbative pseudopotential in the properties of mesonic screening masses for temperatures ranging from 0.8 to 164 GeV in the quark-gluon plasma.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Study of the decay J / ψ → ϕ π 0 η

Based on ( 10.09 ± 0.04 ) × 10 9 J / ψ events collected with the BESIII detector operating at the BEPCII collider, a partial wave analysis of the decay J / ψ → ϕ π 0 η is performed. We observe for the first time two new structures on the ϕ η invariant mass distribution, with significances exceeding 27 σ and 13 σ ; the first with J PC = 1 + − , mass M = ( 1908 ± 6 ( stat ) − 4 + 8 ( sys ) ) MeV / c 2 , and width Γ = ( 175 ± 13 ( stat ) − 16 + 7 ( sys ) ) MeV , the second with J PC = 1 − − , mass M = ( 1992 ± 12 ( stat ) − 6 + 15 ( sys ) ) MeV / c 2 , and width Γ = ( 132 ± 22 ( stat ) − 4 + 17 ( sys ) ) MeV . These measurements provide important input for the strangeonium spectrum. In addition, the f 0 ( 980 ) − a 0 ( 980 ) 0 mixing signal in J / ψ → ϕ f 0 ( 980 ) → ϕ a 0 ( 980 ) 0 and the corresponding electromagnetic decay J / ψ → ϕ a 0 ( 980 ) 0 are measured with improved precision, providing crucial information to understand the nature of a 0 ( 980 ) 0 and f 0 ( 980 ) . Published by the American Physical Society 2024

Ablikim, M.↗
DOE OSTI2024

Thermal Stability of the Dot-in-Well Gain Medium for Photonic Crystal Surface Emitting Lasers

Self-assembled quantum dots (QDs) embedded in InGaAs quantum wells (QWs) are used as active regions for photonic-crystal surface-emitting lasers (PCSELs). An epitaxial regrowth method is developed to fabricate the dot-in-well (DWELL) PCSELs. Here, the epitaxial regrowth starts with the growth of a partial laser structure containing bottom cladding, waveguide, active region, and the photonic crystal (PC) layer. The PC layer is patterned to realize the cavity. Subsequently a top cladding layer is regrown to complete the laser structure. During the regrowth of the top cladding layer, the partial laser structure is subjected to high growth temperatures in excess of 600 °C resulting in an unintentional annealing of the active region. This annealing of the active region can alter the QDs by changing their size resulting in a blue shift in photoluminescence (PL) and narrowing PL emission. This effect results in the misaligning of the gain peak and the cavity resonance, resulting in sub-optimal lasing performance. DWELL active regions are known to have better thermal stability compared to both QDs and QWs and could be an ideal candidate for regrown PCSELs. We successfully demonstrate an optically-pumped epitaxially-regrown DWELL PCSEL with an emission wavelength of 1230 nm operating at room temperature. Furthermore, the DWELL active region shows excellent emission wavelength stability and intensity despite the high temperature regrowth process.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2024

Impact of Sugarcane Cultivation on C Cycling in Southeastern United States Following Conversion From Grazed Pastures

ABSTRACT The expansion of sugarcane, a tropical high‐yielding feedstock, will likely reshape the Southeastern United States (SE US) bioenergy landscape. However, the sustainability of sugarcane, particularly as it displaces grazed pastures, is highly uncertain. Here, we investigated how pasture conversion to sugarcane in subtropical Florida impacts net ecosystem CO 2 exchange (NEE) and net ecosystem carbon (C) balance (NECB). Measurements were made over three full growth cycles (> 3 years) in sugarcane—plant cane, PC; first ratoon cane, FRC; second ratoon cane, SRC—and in improved (IM) and semi‐native (SN) pastures, which make up ca. 37% of agricultural land in the region. Immediately following conversion, PC was a stronger net source of CO 2 than pastures, indicating the importance of CO 2 losses related to land disturbance. Sugarcane, however, shifted to a strong net sink of CO 2 after first regrowth, and overall sugarcane was a stronger net CO 2 sink than pastures. Both stand age and low water availability during cane emergence and tillering substantially decreased its potential gross CO 2 uptake. Accounting for all C gains and removals (i.e., NECB), greater frequency of burn events and repeated harvest increased removals and overall made sugarcane a stronger C source relative to pastures despite substantial C inputs from the previous land use and a stronger CO 2 sink strength. Time since conversion substantially reduced C losses from sugarcane, and the NECB of SRC was similar to that of IM pasture but lower than that of SN pasture, indicating a rapid shift in the NECB of cane. We conclude that the C‐balance implications following conversion will depend on the proportion of IM versus SN pastures converted to sugarcane. Furthermore, our findings suggest that no‐burn harvest management strategies will be critical to the development of a sustainable bioenergy landscape in SE US.

Gomez‐Casanovas, Nuria↗
DOE OSTI2024

Capacity Fade of Graphite/NMC811: Influence of Particle Morphology, Electrolyte, and Charge Voltage

LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) is an important Li-ion battery cathode material; however, there is a tradeoff between delivered capacity and capacity retention. As the charge potential increases the capacity rises but at the expense of capacity retention. The decrease in capacity retention has been ascribed to several factors including particle cracking, surface reconstruction, transition metal dissolution, and electrolyte reactivity. The present study compares 4.1 and 4.3 V charging limits in commercially relevant graphite/NMC811 pouch cells for single crystal (SC) and polycrystalline (PC) NMC811 with ethylene carbonate (EC)-containing or EC-free electrolytes. The electrochemistry is rationalized through analysis of electrochemical impedance spectroscopy, positive electrode X-ray photoelectron spectroscopy, soft X-ray absorption spectroscopy, X-ray diffraction, and negative electrode mapping by X-ray fluorescence. Graphite/SC-NMC811 cells show high-capacity retention at 4.1 V but exhibit degradation at 4.3 V charging potentials. The EC-free electrolyte cells led to higher capacity fade, especially when charged to 4.3 V. Cathode dissolution and deposition on the negative electrode from PC-NMC811 cells was higher than for samples from SC-NMC811 cells. This study reveals the impact of material type, charge voltage, and electrolyte composition on the reactions at the positive electrode, their influence on the negative electrode, and evolution with cycle number.

36 MATERIALS SCIENCE↗
DOE OSTI2024

HWO Pupil Chopping Wavefront Sensing and Control FY24 Mini-Project Writeup

This document is a summary of work completed in June through July 2024 to assess the feasibility of implementing non-coronagraphic pupil chopping (PC) for Habitable Worlds Observatory (HWO) primary mirror segment stabilization with an on- and/or off-axis Natural Guide Star (NGS) or Laser Guide Star (LGS). This work considers three different PC configurations: (1) a non-common path (NCP) continuous low-order Deformable Mirror (DM), (2) using the telescope’s primary mirror (M1) segment(s), and (3) using a NCP low-order segmented DM. We show that option 2 likely needs a LGS for guiding, while options 1 and 3 may be able to guide on NGSs. We also separately evaluate spectral bandwidth limitations in the absence of photon noise, showing that the technique is limited to Δλ/λ ≲ 25% in a standard imaging configuration but Δλ/λ ≲ 150% when using a NCP Wynne corrector.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2026

ASU’s DAC polymer-enhanced cyanobacterial bioproductivity (AUDACity)

ASU’s DAC polymer-enhanced cyanobacterial bioproductivity (AUDACity) project aims to demonstrate a novel, scalable method for removing carbon dioxide (CO 2 ) directly from ambient air and delivering it to cyanobacterial cultures to produce commodity biofuel, mid-value protein for supplements, and high value phycocyanin (PC), a natural blue colorant (Figure A). This approach uses low-cost, reusable anion exchange polymers embedded in modular mesh packets, which capture CO 2 during drying cycles when exposed to ambient air, and release concentrated CO 2 into aqueous cultivation systems. The project addresses a critical challenge in energy research needed for developing sustainable, economically viable methods of Direct Air Capture (DAC) that can be integrated with bio-based systems for fuel and chemical production. AUDACity contributes to scientific understanding by integrating materials chemistry, cyanobacterial biology, and system engineering to create a distributed CO 2 delivery platform. Key insights have emerged around the design of biocompatible sorbents, optimization of CO 2 capture-release cycles, and durability of packet-based delivery systems under outdoor conditions. Notably, the team has synthesized and tested a range of polymer sorbents, identified mechanisms of material degradation and fouling, and advanced both lab- and pilot-scale cultivation systems to evaluate performance. From a technical and economic standpoint, AUDACity shows promise for achieving cost-effective CO 2 capture and delivery into aqueous media and biofuel production. Preliminary techno-economic analysis (TEA) indicates that the DAC system based on current performance can reach $\$$680/tonne CO 2 delivered into aqueous solution; with reasonable improvements to sorbent lifetime, sorbent capacity, reducing water uptake the approach could reach $\$$66/tonne by avoiding the need for energy-intensive sorbent regeneration and CO 2 compression, making it more feasible for decentralized deployment. With these costs for CO 2 and by extracting and selling high-value PC ($\$$50/kg) and mid-value protein supplement ($\$$6/kg), the remaining biomass can be hydrothermally treated into biofuel for $\$$2.50/gallon, and would support a small first-of-a-kind biorefinery capable of producing 500 barrels per day of biofuel. The project offers meaningful public benefits by advancing carbon removal technologies that are low-energy, modular, and adaptable to non-arable land and brackish water use. It aligns with national goals to develop advanced biotechnology and supports future pathways for bio-based fuels and products. By enabling direct coupling of CO 2 transfer into aqueous medium and biological carbon utilization, AUDACity lays the groundwork for effective algae cultivation without wasteful CO 2 delivery and is a promising and innovative solution for low-carbon fuel and bioproduct generation contributing to a vigorous bioeconomy.

09 BIOMASS FUELS↗
DOE OSTI2026

Transformational Molecular Layer Deposition Tailor-Made Size-Sieving Sorbents for Post-Combustion CO 2 Capture

This report summarizes the carbon capture research and development conducted by The State University of New York at Buffalo (UB), University of South Carolina (USC), GTI Energy (GTI), and Rensselaer Polytechnic Institute (RPI) for U.S. Department of Energy (DOE) project DE-FE0031730 titled “Transformational Molecular Layer Deposition Tailor-made Size-Sieving Sorbents for Post-Combustion CO 2 capture.” The objective of this project was to develop a transformational molecular layer deposition (MLD) tailor-made size-sieving sorbent integrated with a pressure swing adsorption (PSA) cycle schedule that can be installed in new or retrofitted into existing pulverized coal (PC) power plants for CO 2 capture with a cost of electricity at least 30% lower than a supercritical PC power with CO 2 capture, or approximately $\$$30 per tonne of CO 2 captured, and with it being ready for demonstration by 2030.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2026

An absolute recoil-carbon polarimeter for polarized light-ions at the BNL Booster

We describe a recoil-carbon polarimeter for the BNL Booster synchrotron capable of measuring the transverse polarization of both the polarized proton beam and the polarized 3 He ion beam throughout the acceleration cycle. The instrument addresses a critical gap in the BNL polarized beam program: no independent polarization measurement currently exists in the injector chain between the 200 MeV Linac polarimeter and the AGS. The proposed new polarimeter will provide continuous, absolute polarization measurements at the Booster stage, supplying additional anchor points for the polarization transmission through the accelerator chain. The polarimeter 9 is based on elastic pC and 3 He C scattering from a thin internal carbon target, with detection of the recoil 12 C nucleus in a fixed six-station silicon detector ring. A single detector geometry provides continuous kinematic coverage from injection to extraction for both beam species without mechanical adjustment. For pC scattering, the available data and the Bonin parametrization provide a well-established basis for estimating the analyzing power and figure of merit over the Booster energy range; for 3 He C the sole experimental anchor is a measurement at 443 MeV, and the Booster polarimeter itself is identified as the instrument to map the analyzing power across the remainder of the acceleration ramp by a ramp-and-return calibration that anchors the absolute 3 He polarization scale to a few percent. Provision for future deuteron polarimetry is incorporated in the chamber design without modification to the existing geometry. With appropriate detector upgrades, the same recoil-carbon technique can be extended to deuteron beams, for which analyzing power data are already available, and, with future analyzing-power measurements, also to 6 Li and 7 Li beams, making the polarimeter a versatile instrument for the full range of light polarized ion species anticipated at BNL.

43 PARTICLE ACCELERATORS↗
DOE OSTI2024

Eridanus III and DELVE 1: Carbon-rich Primordial Star Clusters or the Smallest Dwarf Galaxies?

We present spectroscopy of the ultra-faint Milky Way satellites Eridanus III (Eri III) and DELVE 1. We identify eight member stars in each satellite and place non-constraining upper limits on their velocity and metallicity dispersions. The brightest star in each object is very metal-poor, at [Fe/H] = -3.1 for Eri III and [Fe/H] = -2.8 for DELVE 1. Both of these stars exhibit large overabundances of carbon and very low abundances of the neutron-capture elements Ba and Sr, and we classify them as CEMP-no stars. Because their metallicities are well below those of the Milky Way globular cluster population, and because no CEMP-no stars have been identified in globular clusters, these chemical abundances could suggest that Eri III and DELVE 1 are dwarf galaxies. On the other hand, the two systems have half-light radii of 8 pc and 6 pc, respectively, which is more compact than any known ultra-faint dwarfs. We conclude that Eri III and DELVE 1 are either the smallest dwarf galaxies yet discovered, or they are representatives of a new class of star clusters that underwent chemical evolution distinct from that of ordinary globular clusters. In the latter scenario, such objects are likely the most primordial star clusters surviving today. These possibilities can be distinguished by future measurements of carbon and/or iron abundances for larger samples of stars or improved stellar kinematics for the two systems.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

GD-1 Stellar Stream and Cocoon in the DESI Early Data Release

We present ∼115 new spectroscopically identified members of the GD-1 tidal stream observed with the 5000-fiber Dark Energy Spectroscopic Instrument (DESI). We confirm the existence of a “cocoon,” which is a broad (FWHM ∼ 2:932 ∼ 460 pc) and kinematically hot (velocity dispersion, σ ∼ 5–8 km s −1 ) component that surrounds a narrower (FWHM ∼ 0:353 ∼ 55 pc) and colder [(σ = 3.09 ± 0.76 km s −1 )] thin stream component (based on a median per star velocity precision of 2.7 km s −1 ). The cocoon extends over at least a 30 ∘ segment of the stream observed by DESI. The thin and cocoon components have similar mean values of [Fe/H]: −2.54 ± 0.04 dex and −2.47 ± 0.06 dex, suggestive of a common origin. The data are consistent with the following scenarios for the origin of the cocoon. The progenitor of the GD-1 stream was an accreted globular cluster (GC) and: (a) the cocoon was produced by pre-accretion tidal stripping of the GC while it was still inside its parent dwarf galaxy; (b) the cocoon comprises debris from the parent dwarf galaxy; (c) an initially thin GC tidal stream was heated by impacts from dark subhalos in the Milky Way; (d) an initially thin GC stream was heated by a massive Sagittarius dwarf galaxy; or a combination of some of these. Future DESI spectroscopy and detailed modeling may enable us to distinguish between these possible origins.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

The SAGA Survey. VI. The Size–Mass Relation for Low-mass Galaxies Across Environments

We investigate how Milky Way (MW)–like environments influence the sizes and structural properties of low mass galaxies by comparing satellites of MW analogs from the Satellites Around Galactic Analogs (SAGA) Survey with two control samples: an environmentally agnostic population from the SAGA background sample and isolated galaxies from the Sloan Digital Sky Survey NASA-Sloan Atlas. All sizes and structural parameters are measured uniformly using pysersic to ensure consistency across samples. We find the half-light sizes of SAGA satellites are systematically larger than those of isolated galaxies, with the magnitude of the offset ranging from 0.05 to 0.12 dex (10%–24%) depending on the comparison sample and completeness cuts. This corresponds to physical size differences between 85 and 200 pc at log 10 (M$_{{\star}}$/M ⊙ ) = 7.5 and 220–960 pc at log 10 (M$_{{\star}}$/M ⊙ ) = 10. This offset persists among star-forming galaxies, suggesting that environment can influence the structure of low-mass galaxies even before it impacts quenching. The intrinsic scatter in the size–mass relation is lower for SAGA satellites than isolated galaxies, and the Sérsic index distributions of satellites and isolated galaxies are similar. In comparison to star-forming satellites, quenched SAGA satellites have a slightly shallower size–mass relation and rounder morphologies at low mass, suggesting that quenching is accompanied by structural transformation and that the processes responsible differ between low- and high-mass satellites. Our results show that environmental processes can imprint measurable structural differences on satellites in MW-mass halos.

Asali, Yasmeen [Yale Univ., New Haven, CT (United ↗
DOE OSTI2024

Self–Healing and Stretchable Molecular Ferroelectrics with High Expandability

The interplay between crystal ordering and stretchability is frequently encountered in contemporary materials science, particularly in the case of ferroelectrics. The inherent dilemma arises when these materials need to withstand repetitive mechanical deformations or stretching without sacrificing their crystal integrity, all while retaining their remarkable ferroelectric properties and even exhibiting self-healing capabilities. This complexity further presents a significant challenge in the design and engineering of mechanically rigid molecular ferroelectric crystals, particularly for applications where both precise crystalline structure and mechanical adaptability are crucial. In this study, the humidity-controlled expansion and contraction, dissolution, and recrystallization of a self-assembled molecular ferroelectric-in-hydrogel framework are reported. Self-healing ferroelectric-in-hydrogel networks exhibit a recyclable humidity-tailored ionic conductivity from 2.86 × 10 –6 to 1.36 × 10 –5 S cm –1 , facilitating the stretchable piezoelectric sensing. Additionally, the dynamic bond reforming interactions are observed, leading to the tailoring of Young's modulus from 452 to 170 MPa, maintaining ferroelectricity under a strain of 20% with a piezoelectric coefficient of 15.7 pC N –1 . Upon lattice contraction, the molecular contacts undergo reforming, leading to the restoration of stretchable ferroelectrics/piezoelectrics and paving the way for stretchable bioelectronics for full-body motion monitoring. The capabilities highlighted here open avenues for stretchable and self-healing ferroelectric-in-hydrogel bioelectronic technologies.

36 MATERIALS SCIENCE↗
DOE OSTI2024

4.6 V Moisture‐Tolerant Electrolytes for Lithium‐Ion Batteries

Abstract Commercial LiPF 6 ‐based electrolytes face limitations in oxidation stability (4.2 V) and water tolerance (10 ppm). While replacing LiPF 6 with lithium bis(trifluoromethane)sulfonimide (LiTFSI) improves water tolerance, it induces Al current collector corrosion above 3.7 V vs. Li/Li + . To address this, lithium cyano(trifluoromethanesulfonyl)imide (LiCTFSI) is proposed here as a non‐corrosive, moisture‐tolerant alternative. The 2.0 M LiCTFSI/propylene carbonate (PC)‐fluoroethylene carbonate (FEC) (7:3 by volume) electrolyte enables LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811) cathodes to reach 210 mAh g −1 (2.8‐4.6 V) with a cycle life of 500. Full cells with NCM811||graphite (2.0 mAh cm −2 ) show 77.8% capacity retention after 500 cycles. Even with 2000 ppm moisture in the electrolyte, full cells maintain high cycling stability, reducing the need for costly dry rooms. The electrolyte’s low freezing point and high thermal stability enable the operation from ‐20 °C to 60 °C, delivering 168 mAh g −1 at ‐20 °C and retaining 94% capacity after 100 cycles at 60 °C. In contrast, cells with commercial LiPF 6 electrolyte deliver 71 mAh g −1 at ‐20°C and retain 52.7% after 100 cycles at 60 °C. This novel salt offers a cost‐effective solution for developing robust, high‐performance batteries suitable for extreme conditions.

Zhang, Nan↗
DOE OSTI2025

Anion Vacancies Coupling with Heterostructures Enable Advanced Aerogel Cathode for Ultrafast Aqueous Zinc‐Ion Storage

As a potential cathode material, manganese-based sulfide has recently attracted increasing interest due to its many advantages in aqueous zinc-ion storage. Unfortunately, some challenges such as sluggish kinetics, unstable structure, and controversial phase transition mechanism during the energy storage process hinder its practical application. Herein, inspired by density functional theory (DFT) calculations, a novel 3D sulfur vacancy-rich and heterostructured MnS/MXene aerogel is designed, and used as a cathode for aqueous Zn-ion batteries/hybrid capacitors (ZIBs/ZICs) for the first time. Thanks to the synergistic modification strategy of sulfur vacancies and heterostructures, the as-constructed MnS/MXene//Zn ZIBs exhibit significantly enhanced electrochemical properties, especially outstanding rate capability and cyclic stability. More encouragingly, the as-assembled MnS/MXene//porous carbon (PC) ZICs exhibit an ultrahigh energy density, a high power density, and a splendid cycling lifespan. Most notably, systematic kinetic analyses, ex situ characterizations, and DFT calculations illustrate that MnS/MXene first irreversibly converts into MnO x @ZnMnO 3 /MXene, and then undergoes a reversible conversion from MnO x @ZnMnO 3 /MXene to MnOOH@ZnMn 2 O 4 /MXene, accompanied by the co-insertion/extraction of H + and Zn 2+ . Further, the synergistic modification strategy of sulfur vacancies and heterostructures and the thorough mechanistic study proposed in this work offer valuable guidance for designing and exploiting high-performance cathodes in aqueous zinc-based energy storage devices.

25 ENERGY STORAGE↗
DOE OSTI2026

The Influence of Mesoscale Particle Structure on the Electrode Degradation and Resultant Electrochemistry of Lithium Ion Cells With Nickel Rich Lithium Nickel Manganese Cobalt Oxide Positive Electrodes

Nickel-rich lithium nickel manganese cobalt oxide, NMC (LiNi x Mn y Co z O 2 ), materials are desirable positive electrodes in lithium ion batteries, providing high capacity and energy density. The mesoscale structure of NMC materials is commonly a polycrystalline aggregate, providing opportunity for short lithium ion transport distance of the small primary particles, yet facile material handling due to the larger secondary particles. On (de)lithiation the NMC unit cell changes volume, where the anisotropic strain can result in secondary particle fracture. This secondary particle fracture process during cycling has been associated with several degradation modes of NMC materials in LIBs. In this work, a milling process was determined whereby the secondary particles could be pre-fractured with retention of the parent primary particle crystallographic structure, crystallite size, and morphology, providing the ability to unambiguously determine the influence of NMC secondary particle size and mesostructure on resultant functional behavior. The bulk and interfacial properties and electrochemistry of as-received commercially obtained polycrystal NMC811 (LiNi 0.8 Mn 0.1 Co 0.1 O 2 , PC NMC) and its milled MPC NMC counterpart were compared. The smaller secondary particle size, higher surface area MPC NMC was found to result in 1) greater cathode tortuosity, 2) reduced surface Ni on the cycled MPC cathodes consistent with surface reconstruction, and 3) increased Ni deposition on the anodes from cathode-anode crosstalk. These factors manifested in unfavorable electrochemical behavior of MPC with lower functional capacity at both 1C and C/10 rates and higher impedance over extended moderate voltage (dis)charge cycling.

36 MATERIALS SCIENCE↗