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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS2018

Retrieval of H2O Abundance in Titan's Stratosphere: A (Re)Analysis of CIRS/Cassini and PACS/Herschel Observations

Since its first measurement 20 years ago by the Infrared Space Observatory (ISO), the water (H2O) mole fraction in Titan’s stratosphere remains uncertain due to large differences between the determinations from available measurements. More particularly, the recent measurements made from the Herschel observatory (PACS (Photodetector Array Camera and Spectrometer) and HIFI (Heterodyne Instrument for the Far Infrared)) estimated the H2O mole fraction to be 0.023 parts per billion at 12.1 millibars. A mixing ratio of 0.14 parts per billion at 10.7 millibars was, however, retrieved from nadir spatially-resolved observations of Cassini/CIRS (Composite Infrared Spectrometer). At the same pressure level (10.7 millibars), this makes a difference of a factor of 5.5 between PACS and CIRS measurements, and this has notably prevented current models from fully constraining the oxygen flux flowing into Titan’s atmosphere. In this work, we try to understand the differences between the H2O mole fractions estimated from Herschel/PACS and Cassini/CIRS observations. The strategy for this is to 1) analyse recent disc-averaged observations of CIRS to investigate if the observation geometry could explain the previous observed differences, and 2) (re)analyse the three types of observation with the same retrieval scheme to assess if previous differences in retrieval codes/methodology could be responsible for the previous discrepancies. With this analysis, we show that using the same retrieval method better reconcile the previous measurements of these instruments. However, the addition of the disc-averaged CIRS observations, instead of confirming the consistency between the different datasets, reveals discrepancies between one of the CIRS disc-averaged set of observations and PACS measurements. This raises new questions regarding the possibility of latitudinal variations of H2O, which could be triggered by seasonal changes of the meridional circulation. As it has already been shown for nitriles and hydrocarbons, this circulation could potentially impact the latitudinal distribution of H2O through the subsidence or up- welling of air rich in H2O. The possible influence of spatial/time variations of the OH/H2O input flux in Titan’s atmosphere is also discussed. The analysis of more observations will be needed in future work to address the questions arising from this work and to improve the understanding of the sources of H2O in Titan’s atmosphere.

Bauduin, S.↗
NASA NTRS2013

Herschel Observations of the Debris Disc Around HIP 92043

Context: Typical debris discs are composed of particles ranging from several micron sized dust grains to kilometer-sized asteroidal bodies, and their infrared emission peaks at wavelengths 60-100 microns. Recent Herschel DUNES (Dust Around Nearby Stars) observations have identified several debris discs around nearby Sun-like stars (F, G and K spectral type) with significant excess emission only at 160 microns. Aims: We observed HIP 92043 (110 Her, HD 173667) at far-infrared and sub-millimetre wavelengths with Herschel PACS (Photodetector Array Camera and Spectrometer) and SPIRE (Spectral and Photometric Imaging Receiver).Identification of the presence of excess emission from HIP 92043 and the origin and physical properties of any excess was undertaken through analysis of its spectral energy distribution (SED) and the PACS images. Methods: The PACS and SPIRE images were produced using the HIPE (Herschel Interactive Processing Environment) photProject map maker routine. Fluxes were measured using aperture photometry. A stellar photosphere model was scaled to optical and near infrared photometry and subtracted from the far-infared and sub-mm fluxes to determine the presence of excess emission. Source radial profiles were fitted using a 2D Gaussian and compared to a PSF (Point Spread Function) model based on Herschel observations of alpha Boo to check for extended emission. Results: Clear excess emission from HIP 92043 was observed at 70 and 100 microns. Marginal excess was observed at 160 and 250 microns.Analysis of the images reveals that the source is extended at 160 microns. A fit to the source SED is inconsistent with a photosphere and single temperature black body. Conclusions: The excess emission from HIP 92043 is consistent with the presence of an unresolved circumstellar debris disc at 70and 100 microns, with low probability of background contamination. The extended 160 micron emission may be interpreted as an additional cold component to the debris disc or as the result of background contamination along the line of sight. The nature of the 160 micron excess cannot be determined absolutely from the available data, but we favour a debris disc interpretation, drawing parallels with previously identified cold disc sources in the DUNES sample.

debris discs↗
NASA NTRS2018

Maps of Tethys' Thermophysical Properties

On 11th April 2015 Cassini's Composite Infrared Spectrometer (CIRS) made a series of observations of Tethys’ daytime anti-Saturn hemisphere over a nine-hour time period. During this time the sub-spacecraft position was remarkably stable (0.3° S to 3.9° S; 153.2° W to 221.8° W), and so these observations provide unprecedented coverage of diurnal temperature variations on Tethys’ anti-Saturn hemisphere. In 2012 a thermal anomaly was discovered at low latitudes on Tethys’ leading hemisphere; it appears cooler during the day and warmer at night than its surroundings (Howett et al., 2012) and is spatially correlated with a decrease in the IR3/UV3 visible color ratio (Schenk et al., 2011). The cause of this anomaly is believed to be surface alteration by high-energy electrons, which preferentially bombard low-latitudes of Tethys’ leading hemisphere (Schenk et al., 2011; Howett et al., 2012; Paranicas et al. 2014; Schaible et al., 2017). The thermal anomaly was quickly dubbed “Pac-Man” due to its resemblance to the 1980s video game icon. We use these daytime 2015 CIRS data, along with two sets of nighttime CIRS observations of Tethys (from 27 June 2007 and 17 August 2015) to make maps of bolometric Bond albedo and thermal inertia variations across the anti-Saturn hemisphere of Tethys (including the edge of its Pac-Man region). These maps confirm the presence of the Pac-Man thermal anomaly and show that while Tethys’ bolometric Bond albedo varies negligibly outside and inside the anomaly (0.69 plus or minus 0.02 inside, compared to 0.71 plus or minus 0.04 outside) the thermal inertia varies dramatically (29 plus or minus 10 J m−2 K−1 s−1/2 inside, compared to 9 plus or minus 4 J m−2 K−1 s−1/2 outside). These thermal inertias are in keeping with previously published values: 25 plus or minus 3 J m−2 K−1 s−1/2 inside, and 5 ± 1 J m−2 K−1 s−1/2 outside the anomaly (Howett et al., 2012). A detailed analysis shows that on smaller spatial-scales the bolometric Bond albedo does vary: increasing to a peak value at 180° W. For longitudes between approximately 100° W and approximately 160° W the thermal inertia increases from northern to southern latitudes, while the reverse is true for bolometric Bond albedo. The thermal inertia on Tethys generally increases towards the center of its leading hemisphere but also displays other notable small-scale variations. These thermal inertia and bolometric Bond albedo variations are perhaps due to differences in competing surface modification by E ring grains and high-energy electrons which both bombard Tethys’ leading hemisphere (but in different ways). A comparison between the observed temperatures and our best thermal model fits shows notable discrepancies in the morning warming curve, which may provide evidence of regional variations in surface roughness effects, perhaps again due to variations in surface alteration mechanisms.

Howett, C. J. A.↗
DOE OSTI2022

Simultaneous Control of Pore‐Space Partition and Charge Distribution in Multi‐Modular Metal–Organic Frameworks

Abstract We report here a strategy for making anionic pacs type porous materials by combining pore space partition with charge reallocation. The method uses the first negatively charged pore partition ligand (2,5,8‐tri‐(4‐pyridyl)‐1,3,4,6,7,9‐hexaazaphenalene, H‐tph) that simultaneously enables pore partition and charge reallocation. Over two dozen anionic pacs materials have been made to demonstrate their excellent chemical stability and a high degree of tunability. Notably, Ni 3 ‐bdt‐tph (bdt=1,4‐benzeneditetrazolate) exhibits month‐long water stability, while CoV‐bdt‐tph sets a new benchmark for C 2 H 2 storage capacity under ambient conditions for ionic MOFs. In addition to tunable in‐framework modules, we show feasibility to tune the type and concentration of extra‐framework counter cations and their influence on both stability and capability to separate industrial C 3 H 8 /C 3 H 6 and C 6 H 6 /C 6 H 12 mixtures.

Hong, Anh N.↗
DOE OSTI2022

Simultaneous Control of Pore-Space Partition and Charge Distribution in Multi-Modular Metal–Organic Frameworks

Here we report here a strategy for making anionic pacs type porous materials by combining pore space partition with charge reallocation. The method uses the first negatively charged pore partition ligand (2,5,8-tri-(4-pyridyl)-1,3,4,6,7,9-hexaazaphenalene, H-tph) that simultaneously enables pore partition and charge reallocation. Over two dozen anionic pacs materials have been made to demonstrate their excellent chemical stability and a high degree of tunability. Notably, Ni 3 -bdt-tph (bdt=1,4-benzeneditetrazolate) exhibits month-long water stability, while CoV-bdt-tph sets a new benchmark for C 2 H 2 storage capacity under ambient conditions for ionic MOFs. In addition to tunable in-framework modules, we show feasibility to tune the type and concentration of extra-framework counter cations and their influence on both stability and capability to separate industrial C 3 H 8 /C 3 H 6 and C 6 H 6 /C 6 H 12 mixtures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Comparison of effectiveness and energy use of airborne pathogen mitigation measures to meet clean air targets in a prototypical office building

Organizations such as ASHRAE and the Centers for Disease Control and Prevention (CDC) have proposed guidelines for controlling infectious aerosols in buildings, which can be met through measures such as modified operation of the heating, ventilation, and air-conditioning (HVAC) system or incorporating air-cleaning technologies. However, more research is needed to understand the trade-offs between health, energy, and comfort aspects when designing measures for these guidelines. To address this gap, this paper presents an analysis using new models for air-cleaning technologies, including in-duct and in-room germicidal ultraviolet (GUV) systems and portable air cleaners (PACs). These models are incorporated into an existing prototypical office building model and six measures are designed to meet ASHRAE Standard 241 and CDC clean air targets: MERV 13 HVAC filtration, maximum outdoor air supplied to the building, PACs, and in-duct, upper-room, and whole-room GUV. The measures are simulated for an office building in a cool and humid climate compared against a baseline simulation using MERV 8 filtration. The results show that all measures, except for the maximum outdoor air case, can meet the ASHRAE 241 standard without significant impacts on energy or comfort. The HVAC system measures were not able to meet the CDC target with the default system sizing and lead to significant energy increases, while the in-room measures were able to meet the CDC target with small impacts on energy consumption. Finally, this paper consolidates the simulation findings and provides practical guidance for building operators to meet clean air targets while limiting energy and comfort impacts.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2026

Analysis of strategies to meet ASHRAE S241 infectious aerosol control targets by space type and region using EnergyPlus™ simulations

Professional organizations, such as ASHRAE, have recently proposed new voluntary standards for controlling infectious aerosols. Specifically, ASHRAE Standard 241 (S241) defines equivalent clean air targets for a range of space types that can be met through combinations of mitigation measures. This paper seeks to inform the selection of measures by space type and climate zone through building simulations that quantify the impacts of increased outdoor air ventilation; increasing filtration and/or adding germicidal ultraviolet (GUV) in the central heating, ventilation, and air-conditioning (HVAC) systems; or using portable air cleaners (PACs), upper room GUV, or whole room GUV approaches to increase equivalent clean air delivery. The measures are assessed individually and in practical combinations for their ability to meet S241 in four space types (offices, classrooms, dining areas, and healthcare waiting rooms) using prototype buildings modeled using EnergyPlus. The mitigation measures are compared holistically against baseline building operations using metrics for equivalent clean air, energy, and comfort. The results in this study show that single measures can meet S241 for offices with minimal impacts on energy and comfort, while either upper room GUV systems or combinations of measures such as MERV 13 HVAC filtration with PACs are needed to meet S241 for classrooms. The dining area and healthcare waiting room targets cannot be met in this study when assuming design occupancy and MS2 as the challenge agent, even when combining multiple measures together. This paper provides valuable considerations when designing measures to meet S241 for a range of spaces and scenarios.

GUV↗
DOE OSTI2026

Influence of overhead HVAC and aerosol control strategies on coarse mode particle dispersion and exposure in a full-scale room experiment

Coarse mode respiratory aerosols can carry viral loads over long distances and have very different dynamics than submicron particles, but experimental studies under realistic conditions remain limited. Here, to study the differential impacts on exposure under different mixing conditions, we co-released 7–10 µm particles and carbon dioxide (CO 2 )—which served as an indicator of gas and submicron particle dynamics—in a 158 m 3 room at LBNL's FLEXLAB facility with an overhead heating, ventilation, and air conditioning (HVAC) system. The room was arranged as a distanced meeting then a classroom with eight heated manikins and a researcher. Spatial variability was measured using 16 particle counters and 22–26 CO 2 sensors throughout the space. Conditions included: HVAC off or supply air at 1000-1060 m 3 h -1 at neutral, cooling, or heating temperatures; with and without 20% outdoor air; and added HVAC filtration, portable air cleaners (PACs), or a physical barrier between the speaker and occupants. We found that good mixing via neutral or cooling supply air or use of PACs under heating lowered coarse particle exposure at some locations, but increased exposure for one-quarter to two-thirds of manikins compared to poor mixing under heating. A physical barrier reduced direct transfer of coarse particles during heating, but less during cooling. High spatial variability shows that a single measurement cannot represent occupant exposure. Instantaneous air mixing assumptions overstate the effectiveness of ventilation, HVAC filtration, and upper-room germicidal ultraviolet disinfection for coarse particles, as relatively few particles reach the return grille or upper room under most conditions.

Air mixing↗
DOE OSTI2023

Simultaneous Control of Flexibility and Rigidity in Pore-Space-Partitioned Metal–Organic Frameworks

Flexi-MOFs are typically limited to low-connected (< 9) frameworks. Here we report a platform-wide approach capable of creating a family of high-connected materials (collectively called CPM-220) that integrate exceptional framework flexibility with high rigidity. We show that the multi-module nature of the pore-space-partitioned pacs (partitioned acs net) platform allows us to introduce flexibility as well as to simultaneously impose high rigidity in a tunable module-specific fashion. The inter-modular synergy has remarkable macro-morphological and sub-nanometer structural impacts. A prominent manifestation at both length scales is the retention of X-ray-quality single crystallinity despite huge hexagonal c-axial contraction (≈ 30%) and harsh sample treatment such as degassing and sorption cycles. CPM-220 sets multiple precedents and benchmarks on the pacs platform in both structural and sorption properties. Furthermore, they possess exceptionally high benzene/cyclohexane selectivity, unusual C 3 H 6 and C 3 H 8 isotherms, and promising separation performance for small gas molecules such as C 2 H 2 /CO 2 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Laboratory Testing of Portable Air Cleaner Products for Energy Efficiency and Clean Air Performance at Various Fan Settings [Slides]

This document contains the results of a product review and laboratory testing experiment of portable air cleaning devices (PACs). Thirty-four commercially available PACs were reviewed, and from those, 7 products were purchased and underwent AHAM AC-7 clean air delivery rate (CADR) testing. The following research questions were explored: 1) What is the relationship between clean air delivery rate (CADR) and energy across a range of products and what is the general decrement in CADR as a result of operating at lower fan speeds? 2) How might the multiple units at lower power compare to fewer, larger units at full power in terms of energy efficiency and total cost? 3) How do the measured CADR, power, and efficiency compare to the manufacturer specs? 4) Are there product attributes that can be identified that might contribute to better CADR/W performance?

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS1980

An industrial application of the JPL ACTS with energy recovery

The JPL Activated Carbon Treatment System (ACTS) uses sewage solids derived from municipal wastewater treatment systems as a source of organic material for powdered activated carbons (PAC). The PAC is used for the COD removal from wastewater and as a filter aid in the recovery of additional sewage solids.

Humphrey, M. F.↗
NASA NTRS1983

An advanced control system for a next generation transport aircraft

The use of modern control theory to develop a high-authority stability and control system for the next generation transport aircraft is described with examples taken from work performed on an advanced pitch active control system (PACS). The PACS was configured to have short-period and phugoid modes frequency and damping characteristics within the shaded S-plane areas, column force gradients with set bounds and with constant slope, and a blended normal-acceleration/pitch rate time history response to a step command. Details of the control law, feedback loop, and modal control syntheses are explored, as are compensation for the feedback gain, the deletion of the velocity signal, and the feed-forward compensation. Scheduling of the primary and secondary gains are discussed, together with control law mechanization, flying qualities analyses, and application on the L-1011 aircraft.

Rising, J. J.↗
NASA NTRS1984

L-1011 testing with relaxed static stability

Wind tunnel and flight tests indicate that fuel savings of 2 percent can be achieved by center of gravity (C.G.) management for an L-1011 with the current wing configuration. The normal c.b. location is at 25 percent mean aerodynamic center (MAC). The maximum fuel saving occurs for a C.G. location of 35 percent MAC. However, flight at 35 percent requires that the C.G. range be extended aft of the 35-percent point. Flight at C.G. locations aft or 35 percent requires a pitch active control system (PACS) so that handling qualities are not significantly degraded. The development of this PACS is discussed.

Rising, J. J.↗
NASA NTRS1992

A magma ocean and the Earth's internal water budget

There are lines of evidence which relate bounds on the primordial water content of the Earth's mantle to a magma ocean and the accompanying Earth accretion process. We assume initially (before a magma ocean could form) that as the Earth accreted, it grew from volatile- (H2O, CO2, NH3, CH4, SO2, plus noble) gas-rich planetesimals, which accreted to form an initial 'primitive accretion core' (PAC). The PAC retained the initial complement of planetesimal gaseous components. Shock wave experiments in which both solid, and more recently, the gaseous components of materials such as serpentine and the Murchison meteorite have demonstrated that planetesimal infall velocities of less than 0.5 km/sec, induce shock pressures of less than 0.5 GPa and result in virtually complete retention of planetary gases.

Ahrens, Thomas J.↗
NASA NTRS1995

STS-73 Flight Day 3

On this third day of the STS-73 sixteen day mission, the crew, Cmdr. Kenneth Bowersox, Pilot Kent Rominger, Payload Specialists Albert Sacco and Fred Leslie, and Mission Specialists Kathryn Thornton, Catherine 'Cady' Coleman, and Michael Lopez-Alegria are shown performing several of the spaceborne experiments onboard the United States Microgravity Lab-2 (USML-2). The experiments shown include the Surface Tension Driven Convection Experiment (STDCE), the Drop Physics Module (DPM) experiment, and the High-Packed Digital Television (HI-PAC) demonstration. The HI-PAC allows the digitization of up to six video downlink signals from the Spacelab experiments and other cameras onboard the Shuttle, where previously only one downlink was allowed.

Source record↗
NASA NTRS1995

STS-73 Post Flight Presentation

The post flight presentation of the STS-73 Space Shuttle's United States Microgravity Lab. (USML) mission was presented by the flight crew, Cmdr. Kenneth Bowersox, Pilot Kent Rominger, Payload Specialists Albert Sacco and Fred Gregory, and Mission Specialists Kathryn Thornton, Catherine 'Cady' Collman, and Michael Lopez-Alegria, using color video and slides. Film footage includes the prelaunch and launch activities, the USML and Middeck experiments (Advanced Protein Crystallization Facility (APCF), the Astroculture(tm) (ASC) hardware and experiment, the Commercial Generic Bioprocessing Apparatus (CGBA), the Crystal Growth Furnace (CGF), the Drop Physics Module (DPM), the Geophysical Fluid Flow Cell (GFFC), the Glovebox (GBX), the Zeolite Crystal Growth (ZCG) experiment, the Surface Tension Driven Convection Experiment (STDCE), the Protein Crystal Growth (PCG) experiment, three Measuring Microgravity experiments (the Space Acceleration Measurement System (SAMS), the Three Dimensional Microgravity Accelerometer (3DMA), and the Orbital Acceleration Research Experiment (OARE)), and the High-Packed Digital Television (HI-PAC) demonstration system), pre-return flight systems checkout, reentry, and space shuttle landing. The USML experiments were monitored via the HI-PAC system downlink. Earth views included mostly geographical locations (Mediterranean Sea; Turkey; Lake Powell, Arizona/Utah area; San Francisco Bay; Baltimore, Maryland; Washington, DC; India; Tibet; China; Bhutan; Philadelphia; and the Himalayas).

Source record↗
NASA NTRS1996

Contamination control engineering design guidelines for the aerospace community

Thermal control surfaces, solar arrays, and optical devices may be adversely affected by a small quantity of molecular and/or particulate contamination. What is rarely discussed is how one: (1) quantifies the level of contamination that must be maintained in order for the system to function properly, and (2) enforces contamination control to ensure compliance with requirements. This document is designed to address these specific issues and is intended to serve as a handbook on contamination control for the reader, illustrating process and methodology while providing direction to more detailed references when needed. The effects of molecular contamination on reflecting and transmitting surfaces are examined and quantified in accordance with MIL STD 1246C. The generation, transportation, and deposition of molecular contamination is reviewed and specific examples are worked to illustrate the process a design engineer can use to estimate end of life cleanliness levels required by solar arrays, thermal control surfaces, and optical surfaces. A similar process is used to describe the effect of particulate contamination as related to percent area coverage (PAC) and bi-directional reflectance distribution function (BRDF). Relationships between PAC and surface cleanliness, which include the effects of submicron sized particles, are developed and BRDF is related to specific sensor design parameters such as Point Source Transmittance (PST). The pros and cons of various methods of preventing, monitoring, and cleaning surfaces are examined and discussed.

Tribble, A. C.↗
NASA NTRS1996

Analysis of Cumulus Solar Irradiance Reflectance (CSIR) Events

Clouds are extremely important with regard to the transfer of solar radiation at the earth's surface. This study investigates Cumulus Solar Irradiance Reflection (CSIR) using ground-based pyranometers. CSIR events are short-term increases in solar radiation observed at the surface as a result of reflection off the sides of convective clouds. When sun-cloud observer geometry is favorable, these occurrences produce characteristic spikes in the pyranometer traces and solar irradiance values may exceed expected clear-sky values. Ultraviolet CSIR events were investigated during the summer of 1995 using Yankee Environmental Systems UVA-1 and UVB-1 pyranometers. Observed data were compared to clear-sky curves which were generated using a third degree polynomial best-fit line technique. Periods during which the observed data exceeded this clear-sky curve were identified as CSIR events. The magnitude of a CSIR event was determined by two different quantitative calculations. The MAC (magnitude above clear-sky) is an absolute measure of the difference between the observed and clear-sky irradiances. Maximum MAC values of 3.4 Wm(exp -2) and 0.069 Wm(exp -2) were observed at the UV-A and UV-B wavelengths, respectively. The second calculation determined the percentage above clear-sky (PAC) which indicated the relative magnitude of a CSIR event. Maximum UV-A and UV-B PAC magnitudes of 10.1% and 7.8%, respectively, were observed during the study. Also of interest was the duration of the CSIR events which is a function of sun-cloud-sensor geometry and the speed of cloud propagation over the measuring site. In both the UV-A and UV-B wavelengths, significant CSIR durations of up to 30 minutes were observed.

Laird, John L.↗