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At least 73 records · Page 4

Coupling AFEX and steam-exploded sugarcane residue pellets with a room temperature CIIII-activation step lowered enzyme dosage requirements for sugar conversion

In this study, the potential integration of steam explosion (StEx) and ammonia fiber expansion (AFEX) with existing sugar/ethanol mills to form decentralized pre-processing depots was explored. Both StEx and AFEX pretreatment facilitated the production of sugarcane bagasse (SCB) and cane leaf matter (CLM) pellets with significantly higher bulk density, mechanical durability, and hydrophobicity relative to their untreated biomass pellet controls. However, ethanol production from standalone StEx and AFEX-treated SCB and CLM pellets required enzyme dosages greater than 21 mg/g glucan to achieve enzymatic hydrolysis sugar yields of 75% and ethanol titres greater than 40 g.L -1 . Coupling AFEX-treated SCB or CLM pellets with a room temperature CIII I -activation step using liquid ammonia lowered enzyme dosage requirements by more than 50% without affecting ethanol titers and production yields (greater than300 L per Mg residual dry matter raw dry biomass (RDM)). In contrast, treating StEx-treated pellets with CIIII-activation using liquid ammonia did not result in similar enzyme dosage reductions, due to pseudo-lignin formation, leading to enzyme deactivation and/or lignin blockage that retarded enzymatic hydrolysis at low enzyme dosages. A gross energy conversion assessment revealed that low enzyme dosage (3-4 mg enzyme/g RDM) ethanol and electricity co-production from AFEX and CIII I -activated SCB and CLM can recover up to 73% of the energy in the untreated biomass, compared to 54% recovered by StEx and CIII I -activation. The results from this work suggest that StEx or AFEX based pre-processing depots can produce dense and mechanically durable biomass pellets. The AFEX-treated pellets can be easily upgraded using a room temperature CIII I -activation step at the biorefinery to significantly reduce bioconversion enzymes.

42 ENGINEERING↗

The effectiveness of D 2 pellet injection in reducing intra-ELM and inter-ELM tungsten divertor erosion rates in DIII-D during the Metal Rings Campaign

Abstract Edge localized modes (ELMs) in H-mode plasmas erode plasma-facing components (PFCs) and lead to impurities in the core, reducing confinement. This study analyzes D 2 pellet injection on the DIII-D fusion experiment used as an ELM mitigation technique applied during the 2016 tungsten Metal Rings Campaign to reduce W erosion during ELMs. The 400.9 nm photon wavelength line emission intensity of tungsten atoms (WI) filterscope channels and Langmuir probes were used to infer the gross erosion rate of tungsten-coated tiles installed in the divertor of DIII-D. D 2 mass injection rates ranging from 34 to 41 arbitrary units (A.U.) and no D 2 injection resulted in a similar total W erosion rate during ELMs (intra-ELM). On average, results show a 29% increase in the total gross W erosion rate with intermediate mass injection rates (∼13–23 A.U.) compared to the no pellets and the highest injection rate cases. On average, the fast D 2 mass injection rate cases had 15% less erosion in the inter-ELM phase than the case with no pellets. Generally, higher D 2 mass injection rates increased the ELM frequency, and the highest injection rates reduced the average erosion per ELM and fractional carbon impurities at the top of the pedestal by nearly 40% when compared to the no-pellet case. As expected, a higher D 2 pellet injection rate led to a higher plasma density and lower plasma temperature in the divertor. Additionally, an increasing divertor inter-ELM plasma electron density directly correlated to more frequent pellet injection and a decrease in both the average gross intra-ELM W erosion and the total gross intra-ELM W erosion rate. Simulations of intra-ELM erosion using the ‘free-streaming plus recycling model’ (FSRM) underestimate W erosion during pellet injection by about 30% on average. The discrepancies between the experimental measurements and the FSRM intra-ELM W erosion predictions are postulated to be due to C/W material mixing. A simple analytic mixed-material model is presented and results in better agreement with the experimental data. These results highlight the importance of incorporating the effects of a mixed-material layer in the analysis of PFC erosion.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Interaction of SPI pellets with plasma on JET and associated disruptions

Abstract The presented data refer to the Shattered Pellet Injector (SPI) experiments carried out at JET in 2019–2020. This paper is a full journal version of the data originally presented as posters at TMPDM_2020 and EPS_2021. This paper presents various aspects of the interaction of pellets with plasma and associated disruptions. The experiment was performed with I p = (1.1–3.1) MA plasmas and mainly with Ne + D 2 pellet composition, but also with Ar pellets. The Current Quench (CQ) time, τ 80−20 , is the key characteristic of mitigation effectiveness. A pellet with a high content of Ne or Ar can reduce the CQ duration below the upper required JET threshold. Plasmas with high (thermal + internal poloidal magnetic) pre-disruptive plasma energy require a high content of Ne pellets to obtain a short CQ duration. Pellets with a small amount of Ne (and accordingly large amount of D), instead of causing a mitigated CQ, create the conditions for a ‘cold’ Vertical Displacement Events (VDE). The SPI was applied to plasma with different status: mainly to normal (‘healthy’) plasma, i.e. not prone to disruption, post-disruptive and VDE plasma. This study shows that SPI effectiveness in terms of CQ duration and, accordingly, EM loads does not depend on the state of the plasma, whether it is ‘healthy’ or post-disruptive plasma. SPI has been shown to reduce the axisymmetric vertical vessel reaction forces by about (30–40) % compared to unmitigated disruptions. On JET, the VDE, whether ‘hot’ or ‘cold’, always creates the conditions for a toroidal asymmetry in the plasma, so the VDE on the JET is referred to as Asymmetric VDE (AVDE). The interrupting of VDE and prevention of AVDE with SPI has been demonstrated. Thus, the effectiveness of disruption mitigation using SPI has been confirmed.

Gerasimov, S. N. (ORCID:0009000237937211)↗

Recent progress in shattered pellet injection technology in support of the ITER disruption mitigation system*

Shattered pellet injection (SPI) has been selected as the baseline technology for the disruption mitigation (DM) system for ITER. Typical SPI utilizes cryogenic cooling to desublimate low pressure (<100 mbar) gases onto a cold zone within a pipe gun barrel, forming a cylindrical pellet. Pellets are dislodged from the barrel and accelerated using either a gas driven mechanical punch or high-pressure light-gas delivered by a fast-opening valve. SPI technology developed at Oak Ridge National Laboratory is currently deployed and operational on DIII-D, JET, and KSTAR. These SPI systems are used in experiments for physics scaling to ITER thermal mitigation and runaway electron dissipation/avoidance. The pellet sizes used for these machines are in the range of 4 to 12.5 mm in diameter with length to diameter ratios (L/D) of ~1.5. The current plan for ITER SPI is to utilize pellets that are 28.5 mm in diameter with an L/D of ~2. Furthermore, the large pellet sizes, high steady-state magnetic fields, and limitations of operating in a radiation environment render much of the current technology unusable. In addition to technology improvements, a deeper understanding of pellet material properties, formation, and release is being developed for implementation in future SPI designs, specifically ITER.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Solid state NMR Investigation of Structural Differences in Pelletized DEB Samples

Upon hydrogenation of DEB pellets, which are composed of 75% virgin DEB and 25% of nanometer scale Pd catalysts on activated carbon, the uptake rate is strong, and the hydrogenation process is fast. However, the last batch of DEB pellets from KCNSC uptakes 10 times slower than traditional DEB pellets after ~ 50% consumption. In addition, the last batch of DEB getter pellets also became partially molten/wet during the hydrogenation process. This molten/wet phase during hydrogenation has only been observed with DPB and never with DEB formulation. DRIFT (diffuse reflection infrared Fourier transform) and XRD (x-ray diffraction) confirm that the questionable batch of DEB pellets from KCNSC are truly 100% DEB and not a mixture of DEB and DPB. So, there must be something different in the composition (like concentration and distribution of Pd) or interaction between the DEB molecules with the surrounding environment (activated carbon spreading medium). The possibility of some chemical contamination in the processing of this batch of questionable DEB getter pellets also comes to mind. Due to the ability of NMR to detect intermolecular interaction and sensitivity to small chemical concentration, NMR investigation was requested for this questionable batch of DEB getter pellets from KCNSC.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

How does pelleting alter the enzymatic digestibility of corn stover?

Pelleting of lignocellulosic biomass facilitates its transportation, storage and handling and offers opportunities to improve the enzymatic digestibility of pelleted biomass. Here, we report the impact of pelleting on the enzymatic digestibility of corn stover prior to pretreatment and associated substrate characteristics. Pelleting almost doubles the digestibility of unpretreated corn stover, from 8.2 to 15.5% glucan conversion, at 5% solid loading using 1 FPU Cellic CTec2 per g solids. Compositional analysis indicates that loose and pelleted corn stover have similar non-dissolvable compositions, although their extractives are slightly different. Enzymatic hydrolysis of washed corn stover after size reduction to normalize particle sizes and removal of extractives confirms that pelleting improves corn stover digestibility. Such differences may be explained by the decreased particle size, increased specific surface area, improved cellulose accessibility, and reduction of the polymer length of cellulose induced by pelleting. These findings help to design processing schemes for sustainable and efficient use of lignocellulose.

Chen, Xueli↗

Assessing Edge Localized Mode (ELM) Mitigation by Pellet Triggering in Smallest-Possible Affordable Robust Compact (SPARC) Low-Collisionality Discharges

Simulations of pellet edge-localized mode (ELM) triggering with the M3D-C1 code confirmed experimentally observed pellet mass thresholds in low-collisionality DIII-D discharges and predicted extremely large thresholds in ITER. The linear (static) and nonlinear (dynamic) workflows developed in this previous work are now applied to the SPARC tokamak. Multiple synthetic equilibria for the high-performance H-mode scenario are tested for MHD stability without pellets using the linear workflow and ELITE simulations; a stable one is identified. Pellets of various mass are injected along an inboard, near-midplane trajectory in the M3D-C1 simulation. No pellet mass threshold for ELM triggering can be found for realistic pellet masses, concluding that fueling from this injection location would not trigger ELMs. A poloidal scan of possible injection locations shows very high thresholds on the high-field side and reasonable thresholds on the low-field-side (LFS). Based on results of this work the location for a LFS injection was finalized in the SPARC design. For this LFS injection the pellet mass threshold is determined using the linear workflow, aligning well with the poloidal scan.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A centrifuge CO2 pellet cleaning system

An advanced turbine/CO2 pellet accelerator is being evaluated as a depaint technology at Oak Ridge National Laboratory (ORNL). The program, sponsored by Warner Robins Air Logistics Center (ALC), Robins Air Force Base, Georgia, has developed a robot-compatible apparatus that efficiently accelerates pellets of dry ice with a high-speed rotating wheel. In comparison to the more conventional compressed air 'sandblast' pellet accelerators, the turbine system can achieve higher pellet speeds, has precise speed control, and is more than ten times as efficient. A preliminary study of the apparatus as a depaint technology has been undertaken. Depaint rates of military epoxy/urethane paint systems on 2024 and 7075 aluminum panels as a function of pellet speed and throughput have been measured. In addition, methods of enhancing the strip rate by combining infra-red heat lamps with pellet blasting and by combining the use of environmentally benign solvents with the pellet blasting have also been studied. The design and operation of the apparatus will be discussed along with data obtained from the depaint studies.

Foster, C. A.↗

Effect of pelleting on the enzymatic digestibility of corn stover

Pelleting of lignocellulosic biomass to improve its transportation, storage and handling impacts subsequent processing and conversion. Here, this work reports the role of high moisture pelleting in the enzymatic digestibility of corn stover prior to pretreatment, together with associated substrate characteristics. Pelleting increases the digestibility of unpretreated corn stover, from 8.2 to 15.5% glucan conversion, at 5% solid loading using 1 FPU Cellic® CTec2 per g solids. Compositional analysis indicates that loose and pelleted corn stover have similar non-dissolvable compositions, although their extractives are different. Enzymatic hydrolysis of corn stover after size reduction to normalize particle sizes and removal of extractives confirms that pelleting improves corn stover digestibility. Such differences may be explained by the decreased particle size, improved substrate accessibility, and hydrolysis of cross-linking structures induced by pelleting. These findings are useful for the development of processing schemes for sustainable and efficient use of lignocellulose.

09 BIOMASS FUELS↗

Enhanced energy confinement after series of pellets in Wendelstein 7-X

A series of ice pellets was injected into the advanced stellarator Wendelstein 7-X (W7-X). Although the pellets were small and slow, deep and efficient particle fueling could be observed experimentally. The most striking feature appearing after the injection of the pellets, however, was a transient increase in the energy confinement time. This transient phase resembled in several aspects modes of enhanced confinement after gas-puff or pellet injection, as observed in other fusion experiments. All experimental attempts, to prolong this phase, failed. In this paper, discharges are described that show the enhanced energy confinement, and some conditions are summarized which seem to be essential in order to generate it. The focus here is on deep particle fueling by pellets, and shaping of the density profiles during and after the series of pellets. During this time, neutral gas particle re-fueling at the plasma edge is reduced, while density profile peaking and low impurity radiation losses are present.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Self-consistent investigation of density fueling needs on ITER and CFETR utilizing the new Pellet Ablation Module

Abstract Self-consistent modeling using the stability, transport, equilibrium, and pedestal (STEP) workflow in the OMFIT integrated modeling framework (predicting pedestal with EPED, core profiles with TGYRO, current profile with ONETWO, and EFIT for equilibrium) suggests ITER and future devices such as China Fusion Engineering Test Reactor (CFETR) Zhuang et al (2019 Nucl. Fusion 59 112010) will benefit from high-density operation (Greenwald limit fraction f g w ≈ 0.7−1.3). Regimes with an operational density near the Greenwald limit will likely need peaked density profiles so that the pedestal density remains below the Greenwald limit. Peaked density profiles can be achieved with the help of pellet injection. A flexible Pellet Ablation Module (PAM), which predicts the density source based on a comprehensive analytical pellet ablation model, has been developed for predicting pellet fueling for transport studies, and has been incorporated into the STEP workflow for predictive modeling. This workflow is applied to DIII-D and finds good agreement with experiments. On ITER the effect of pellet fueling is examined in an advanced inductive scenario, where a fusion gain of up to Q = 9 is predicted with strong central pellet fueling. On CFETR, with a mid-radius density source, an average of 1.5 × 10 22 electrons s −1 are required to achieve the density and temperature profiles necessary for the 1000 MW advanced scenario with a tritium burn-up fraction of ∼ 3 % .

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Simulation of triggering and evolution of ELM by pellet injection in EAST under BOUT++ framework

A BOUT ++ three-field magnetohydrodynamic model is employed to study the triggering and evolution of edge localized mode (ELM) by Li pellets injected along the outer mid-plane in the EAST configuration. The linear simulation shows that compared with a large deposition on the pedestal top (scenario I), a smaller deposition within the steep-gradient pedestal region (scenario II) can stimulate much larger linear growth rates of all-n peeling-ballooning modes (PBMs). The nonlinear simulation shows that there exists a pellet size threshold for ELM triggering for two deposition locations; the threshold for scenario I predicted in the present study matches the EAST observation well. Comparison of the two scenarios reveals that a smaller deposition is sufficient to trigger an ELM in a much shorter time in scenario II, whose ELM size is comparable to that in scenario I. This conclusion confirms previous DIII-D and ASDEX-Upgrade observations, suggesting that the steep-gradient pedestal region is a favorable deposition location for ELM triggering with minimum pellet size. Simulation analyses also find that the positive radial gradient of the hump-like pressure profile in the outer mid-plane induced by the pellet deposition plays a different role in the two scenarios. In scenario I, the force resulting from the gradient hinders the outflow of core plasmas and in return, the perturbation is suppressed from spreading inwards after ELM crashes. In scenario II, with a sizable deposition, the gradient results in another competitive perturbation growth region during the linear phase, thus dispersing the free energy and reducing the efficiency of destabilizing PBMs by pellet injection. The suppressing effect of saturated zonal flow on other modes, the short ELM fast crash phase, and the restricting transport effect of the positive radial pressure gradient work together to constrain the pedestal energy loss, especially when the pellet deposition amount is high.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Infrared Optical Constants from Pressed Pellets of Powders: I. Improved n and k Values of (NH4)(2)SO(4)from Single-Angle Reflectance

In combination with other parameters, the real, n(?), and imaginary, k(?), components of the complex refractive index, = n + ik, can be used to simulate the optical properties of a material in different forms, e.g. its infrared spectra. But obtaining reliable values of the optical constants n/k for solid materials is challenging due to the lack of optical quality specimens, usually crystals, large enough to measure. An alternative to crystals is to press the powder into a uniform disk. We have produced pellets from ammonium sulfate, (NH4)2SO4, powder and derived the pellets’ n and k values via single-angle reflectance using a specular reflectance device in combination with a Fourier transform infrared spectrometer. The single-angle technique measures amplitude of light reflected from the material as a function of wavelength over a wide spectral domain; the optical constants are determined from the reflectance data using the Kramers-Kronig relationship. We investigate several parameters associated with the pellets and pellet formation and their effects upon delivering the most reliable n/k values. Parameters studied include pellet diameter, mass and density (void space), drying, grinding, sieving and particle size in the pellet formation, as well as pressing pressure and duration. Of these parameters, using size-selected mixtures of dried, small (< 100 µm) particles and pressing at = 10 tons for at least 30 minutes were found key to forming highly reflective samples. Comparison to two sets of previous literature n(?) and k(?) values obtained from crystalline (NH4)2SO4 both as crystal reflectance as well as extinction spectra of aerosols measured in a flow tube show reasonable agreement, but suggests the present values, as confirmed from two independent techniques, represent a substantial improvement for n/k values for (NH4)2SO4, also demonstrating promise to measure the optical constants of other materials.

Optical constants, index of refraction, single-ang↗

Cracking in first ramp to power of standard versus high thermal conductivity UO2 pellets via internal nuclear heating

Advanced fuel designs that incorporate thinner fuel UO2 pellets interspaced by high thermal conductivity inserts have been proposed, with the primary goals of reducing peak centerline temperatures and temperature gradients across fuel pellets and enhancing heat transfer from the fuel to the coolant. An initial series of experiments has been performed on this design, including laboratory experiments and a series of experiments using the Idaho National Laboratory (INL) Transient Reactor Test (TREAT) Facility, the latter of which compared thermal gradient driven fracture of standard pellet designs with that in the proposed advanced fuel design. Although reducing fracture is not the primary objective of the new fuel design, the lower thermal gradients are expected to reduce fracture, so it can serve as an indicator of the thermal behavior of this fuel in the reactor. The in-reactor tests were conducted at multiple linear heat generation rates and confirm the expected result that fracture in both the standard and advanced fuel pellets occurs during the first ramp to power in standard light-water reactor conditions. Post-irradiation examination of the experiment material was performed and included quantification of the extent of fracture in the fuel pellets. It was found that the advanced-design pellets reduce the extent of fracture in a statistically significant way. This confirms the expected behavior predicted by two-dimensional axisymmetric models of this experiment. This study is an important first experimental confirmation of the efficacy of the proposed inserts for achieving their desired effect on the thermal behavior of the fuel.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Framework for assessing land‐management effects on at‐risk species: Example of SE USA wood pellet production and gopher tortoise ( Gopherus polyphemus )

Abstract Land‐management choices made for economic and societal gains intrinsically influence landscapes and species that are dependent upon them. We propose a simple analysis framework to examine critical intersections between land‐management choices and the life‐history conditions of selected species of concern, thereby facilitating the identification of mitigation practices that can reduce negative impacts on species at risk. We test the proposed framework through application to gopher tortoise ( Gopherus polyphemus ), a keystone species that is the focus of conservation efforts across the southeastern region of United States of America, where wood pellets are being produced for bioenergy. Production of these wood pellets for export to Europe and Asia has drastically increased in the past decade, raising concerns about potential harm to biodiversity since many species in the forests sourcing pellet production were already at risk prior to the development of this new commodity. Identifying the mechanisms of potential impacts of wood pellet production on species of concern is essential to establishing meaningful management recommendations that can enhance conservation efforts while supporting sustainable bioenergy. By considering the intersections between life‐history conditions of gopher tortoise and forest‐management practices related to woody biomass extraction for pellet production, we identify several mechanisms by which the wood‐pellet industry might affect this species of concern, both positively and negatively. We then identify mitigation practices that can help offset the potential impacts of logging, thinning, and dead wood removal on gopher tortoise. Our analysis framework may be transferable to other species of concern and land‐management practices across diverse landscapes. This article is categorized under: Bioenergy > Economics and Policy Bioenergy > Climate and Environment

54 ENVIRONMENTAL SCIENCES↗

Metal alloy microparticle tagging of UO 2 fuel pellets for nuclear forensics

A tagging strategy for UO 2 fuel pellets will be discussed which involves the creation of alloyed metal microparticles that can be tuned to create a unique identification (“barcode”) indicating provenance of the pellets. These specialized markers would contain high temperature resistant materials, such as Ti, Mo, and Cr, in small quantities such that they do not interfere with the performance of the pellets but are recoverable by standard analytical techniques. The Amazemet rePowder ultrasonic atomization system was used to manufacture the microparticles, and sample pellets were fabricated and sintered containing these dopants. Various techniques, such as Scanning Electron Microscopy (SEM) and Electron Probe Microanalysis (EPMA), were used to evaluate these sample pellets to determine if particles (and their alloy compositions) were recoverable. Details on how the particles were manufactured and characterized will be detailed, as well as results from their incorporation into test pellets. Next steps will involve the scale of this technique using more conventional mass production methods, as well as the implementation of other alloys.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Neutron Irradiation Induced Changes in Isotopic Abundance of 6Li and 3D Nanoscale Distribution of Tritium in LiAlO2 Pellets Analyzed by Atom Probe Tomography

Tritium, a radioactive isotope of hydrogen is produced by neutron irradiation of 6Li enriched LiAlO2 pellets in Tritium producing burnable absorber rods (TPBARs). Three-dimensional nanoscale mapping of Tritium in irradiated pellets is critical to understand its spatial variation and its association with various microstructural features in the pellets. Spatially resolved analysis of 6Li isotopic enrichment in such ceramic pellets before and after irradiation can provide insights to heterogeneities in Li isotopic distribution. However, Li being a light isotope, its spatially resolved compositional or isotopic analysis is a challenging task to most analytical methods. Here we used atom probe tomography, to evaluate the Li isotopic enrichment in both the LiAlO¬2 matrix and the Li deficient secondary phase LiAl5O8 before irradiation. These results were then compared with 6Li isotopic ratio measured by APT analysis of neutron irradiated pellets to clearly demonstrate the unique capability of APT to quantitatively analyze the isotopic enrichment of 6Li as well as for other light elements present in these materials. Evidence for heterogenous nanoscale distribution of 3H and O3H within irradiated pellet microstructure is also provided, which is attributed to 3H trapping in irradiation induced vacancy clusters or voids within the LiAlO2 matrix. The characterization results given here, now prove the feasibility for using APT for analyzing nanoscale spatially resolved isotopic enrichment of Li as well as other light elements such as Tritium in TPBARs. This work also paves way to adopt APT for analyzing light elements such as Li and tritium in materials used for nuclear fusion reactor applications, geochemistry, astrophysics as well as for energy storage applications.

Devaraj, Arun↗

Measurement of near- and far-field impurity flows during pellet-induced rapid shutdown in DIII-D

Both near-field (<1 m away toroidally from the pellet) and far-field (>1 m away toroidally from the pellet) poloidal and toroidal impurity (carbon ion) flows are measured using visible imaging and fast bolometry during a polypropylene pellet-induced rapid plasma shutdown in the DIII-D tokamak. In the near field, the pellet appears to increase poloidal flow in the ion diamagnetic direction, possibly due to the strong radial temperature gradient caused by the pellet ablation. In the far field, the poloidal impurity flow typically appears slower and in the opposite direction. Toroidal impurity flow appears to be strongly influenced by the plasma initial toroidal rotation, especially in the far field. These results demonstrate that rapid shutdown impurity flows are not necessarily global in structure but can be quite different close to and far from the injected pellet.

Electromagnetic radiation detectors↗