Millimeter- and submillimeter-wave detection by paramagnetic materials
Millimeter and submillimeter wave radiation detection by paramagnetic materials, noting noise equivalent power dependence on various parameters
Haddad, G. I.↗
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Growth Kinetics of the S Sub H Center on Magnesium Oxide Using Electron Paramagnetic Resonance
Electron paramagnetic resonance spectroscopy was used to study the growth of S sub H centers on magnesium oxide powder which had hydrogen adsorbed on its surface. The centers were produced by ultraviolet radiation. The effects of both radiation intensity and hydrogen pressure were also studied. At constant hydrogen pressure and radiation dose, the initial S sub H center growth rate was found to be zero order. Beyond the initial region the growth rate deviated from zero order and finally approached saturation. The results are interpreted in terms of a model which assumes that the S sub H center is a hydrogen atom associated with a surface vacancy. Saturation appears to result from a limited supply of surface vacancies.
Jayne, J. P.↗
Resonance spectra of a paramagnetic probe dissolved in a viscous medium
A model is presented for calculating the paramagnetic resonance (EPR) spectrum of vanadyl acetylacetonate (VAAC) dissolved in either a liquid crystal or isotropic solvent. It employs density matrix formulation in the rotating reference frame. The molecules occupy several discrete angles with respect to the magnetic field and can relax to neighboring positions in a characteristic time tau(theta). The form of tau(theta) is found from a diffusion approach, and the magnitude of tau(theta) is a measure of how freely the VAAC probe tumbles in the solvent. Spectra are predicted for values of tau between 10 to the minus 11th power sec and 10 to the minus 7th power sec. The EPR spectrum, in the isotropic case, is obtained be summing the contributions from the allowed angles weighted by the polar volume element, sin theta. When applying the model to the nematic liquid crystal case it is also necessary to multiply by the Saupe distribution function. For this case tau(theta) is obtained from the diffusion approach in which two diffusion constants are employed to reflect the difference in the parallel and perpendicular components of the viscosity.
Kaplan, J. I.↗
Electron paramagnetic resonance study of two smectic A liquid crystals.
Study of the molecular ordering in two smectic A liquid crystals using vanadyl acetylacetonate as a paramagnetic probe. The average hyperfine splitting of the spectrum in the smectic A mesophase is measured as a function of the orientation relative to the dc magnetic field of the spectrometer after alignment of the molecules of the liquid crystal.
Fryburg, G. C.↗
Resonance spectra of a paramagnetic probe dissolved in a viscous medium.
The paramagnetic resonance spectrum of Vanadyl acetylacetonate (VAAC) dissolved in either a liquid crystal or isotropic solvent is calculated with the aid of a presented model. Density matrix formulation is employed in the rotating reference frame. The molecules occupy several discrete angles with respect to the magnetic field and can relax to neighboring positions in a characteristic time. The form of this characteristic time is found from a diffusion approach, and the magnitude of this time is a measure of how freely the VAAC probe tumbles in the solvent. Spectra are predicted for time values ranging from 10 picoseconds to 10 microseconds.
Kaplan, J. I.↗
Electron paramagnetic resonance study of alinement induced by magnetic fields in two smectic-A liquid crystals not exhibiting nematic phases
Using vanadyl acetylacetonate (VAAC) as a paramagnetic probe, the molecular ordering in two smectic-A liquid crystals that do not display nematic phases were studied. Reproducible alinement was attained by slow cooling throughout the isotropic smectic-A transition in dc magnetic fields of 1.1 and 2.15 teslas. The degree of order attained is small for a smectic-A liquid crystal. Measurements were made of the variation of the average hyperfine splitting of the alined samples as a function of orientation relative to the dc magnetic field of the spectrometer. This functional dependence is in agreement with the theoretical prediction except where the viscosity of the liquid crystal becomes large enough to slow the tumbling of the VAAC, as indicated by asymmetry in the end lines of the spectrum.
Fryburg, G. C.↗
Electron paramagnetic resonance studies of a viscous nematic liquid crystal: Evidence counter to a second-order phase change
The ordering in a viscous, nematic, liquid crystal was studied using vanadyl acetyl acetonate and several nitroxides as paramagnetic probes. The ordering curve for VAAC at both K-band and X-band shows a slope discontinuity at a reduced temperature of 0.85. This discontinuity is caused by the tumbling time of the VAAC becoming comparable with the hyperfine splitting. The slope discontinuity is not present in the ordering curves of the nitroxides. The results are taken as evidence counter to the presence of a second-order phase transition.
Shutt, W. E.↗
Paramagnetism and shake-up satellites in X-ray photoelectron spectra
The correlation between paramagnetism and the shake-up satellites in the X-ray photoelectron spectra of the 3d transition-metal compounds is examined and explained in terms of modified selection rules governing the shake-up transitions.
Yin, L.↗
Remanent magnetization of a 'paramagnetic' composition in the ilmenite-hematite solid solution stress
In the ilmenite-hematite solid solution series, compositions more ilmenite-rich than Ilm(73)Hem(27) are classically thought to be paramagnetic at room temperature. Ilm(80)Hem(20) samples have nevertheless been synthesized that acquire hard saturation remanent and thermoremanent moments. From analysis of AC demagnetization data, the source of the measured remanence is believed to be a single-domain (SD) like material within the IlM(80)Hem(20) grains themselves. On the basis of transmission electron microscope observations, it is suggested that transformation-induced domain boundaries, which in part are enriched in hematite component relative to the bulk composition of the grains, could act as the magnetic carrier of the SD-like remanence.
Lawson, C. A.↗
Paramagnetic Precipitates May Raise Supercurrent
Addition of Mn to Ti/Nb superconducting alloy increases critical current. Adding Mn to Ti/Nb alloy has little effect on major superconducting phase, but confers strong paramagnetic susceptibility on alpha-phase particles. beta-phase particles become stronger flux pinners, resulting in increase in critical current.
Collings, E. W.↗
Investigation of paramagnetic response of metallic epoxies
The paramagnetic properties of epoxies which were impregnated with metal ions were examined as the primary task in this research. A major conclusion was that the quality control of the epoxies was insufficient to permit reliable evaluation. Subsequently, a new set of specimens is being prepared. As an additional task, a new method is investigated for estimating heats of combustion for saturated hydrocarbons. The results of that investigation have shown that the empirical approach is a promising method for on-line measurements.
Ash, R. L.↗
The role of spinning electrons in paramagnetic phenomena
An attempt is made to explain paramagnetic phenomena without assuming the orientation of a molecule or ion in a magnetic field. Only the spin angular momentum is assumed to be responsible. A derivative of the Gurie-Langevin law and the magnetic moments of ions are given as a function of the number of electrons in an inner, incomplete shell. An explanation of Gerlach's experiments with iron and nickel vapors is attempted. An explanation of magnetomechanical experiments with ferromagne elements is given.
Bose, D. M.↗
Alignment mechanisms of paramagnetic grains revisited
Taking into account the tight coupling of grain axis with angular momentum due to effective dissipation of rotation energy, the alignment of spheroidal grains was investigated by paramagnetic relaxation. Alignment degree will be significantly improved in diffuse clouds. The inclusions of superparamagnetic (SPM) substances may play a key role in grain alignment in dark clouds as well as in diffuse clouds.
Seki, Munezo↗
Paramagnetic propellant orientation
Deep space or low earth orbital propellant tanks require a fluid orientation system prior to engine firing or transfer. Some propellants such as cryogenic hydrogen, oxygen, and air are paramagnetic and respond to electromagnetic fields. A simple magnetic scheme is described for propellant orientation and a video tape presentation is provided that demonstrates some effects of magnetic fields on liquid air and oxygen in a low gravity simulator using the Leidenfrost phenomenon. When these Leidenfrost drops intersect the field lines, their flight paths are altered, some directly into the poles, some to the edges, and others move out of the field.
Hendricks, R. C.↗
Paramagnetic propellant orientation
Deep space or low earth orbital propellant tanks require a fluid orientation system prior to engine firing or transfer. Some propellants such as cryogenic hydrogen, oxygen, and air are paramagnetic and respond to electromagnetic fields. A simple magnetic scheme is described for propellant orientation and a video tape presentation is provided that demonstrates some effects of magnetic fields on liquid air and oxygen in a low gravity simulator using the Leidenfrost phenomenon. When these Leidenfrost drops intersect the field lines, their flight paths are altered, some directly into the poles, some to the edges, and others move out of the field.
Hendricks, R. C.↗
Paramagnetic-Salt Thermometer With Flux Pump And SQUID's
Paramagnetic-salt low-temperature thermometer incorporates improved superconducting magnetic-flux pump, multiple superconducting quantum interference devices as magnetometers, and feedback stabilization of magnetic flux. Requires much smaller initial magnetizing currents and provides improved temperature resolution via suppression of drift in magnetic induction.
Strayer, Donald M.↗
Scaling craters in carbonates: Electron paramagnetic resonance analysis of shock damage
Carbonate samples from the 8.9-Mt nuclear (near-surface explosion) crater, OAK, and a terrestrial impact crater, Meteor Crater, were analyzed for shock damage using electron paramagnetic resonance (EPR). Samples from below the OAK apparent crater floor were obtained from six boreholes, as well as ejecta recovered from the crater floor. The degree of shock damage in the carbonate material was assessed by comparing the sample spectra to the spectra of Solenhofen and Kaibab limestone, which had been skocked to known pressures. Analysis of the OAK Crater borehole samples has identified a thin zone of allocthonous highly shocked (10-13 GPa) carbonate material underneath the apparent crater floor. This approx. 5- to 15-m-thick zone occurs at a maximum depth of approx. 125 m below current seafloor at the borehole, sited at the initial position of the OAK explosive, and decreases in depth towards the apparent crater edge. Because this zone of allocthonous shocked rock delineates deformed rock below, and a breccia of mobilized sand and collapse debris above, it appears to outline the transient crater. The transient crater volume inferred in this way is found to by 3.2 +/- 0.2 times 10(exp 6)cu m, which is in good agreement with a volume of 5.3 times 10(exp 6)cu m inferred from gravity scaling of laboratory experiments. A layer of highly shocked material is also found near the surface outside the crater. The latter material could represent a fallout ejecta layer. The ejecta boulders recovered from the present crater floor experienced a range of shock pressures from approx. 0 to 15 GPa with the more heavily shocked samples all occurring between radii of 360 and approx. 600 m. Moreover, the fossil content, lithology and Sr isotopic composition all demonstrate that the initial position of the bulk of the heavily shocked rock ejecta sampled was originally near surface rock at initial depths in the 32 to 45-m depth (below sea level) range. The EPR technique is also sensitive to prehistoric shock damage. This is demonstrated by our study of shocked Kaibab limestone from the 49,000-year-old Meteor (Barringer) Crater Arizona.
Polanskey, Carol A.↗
Magnetothermal Convection in Nonconducting Diamagnetic and Paramagnetic Fluids
Nonuniform magnetic fields exert a magnetic body force on electrically nonconducting classical fluids. These include paramagnetic fluids such as gaseous and liquid oxygen and diamagnetic fluids such as helium. Recent experiments show that this force can overwhelm the force of gravity even at the surface of the earth; it can levitate liquids and gases, quench candle flames, block gas flows, and suppress heat transport. Thermal gradients render the magnetic force nonuniform through the temperature-dependent magnetic susceptibility. These thermal gradients can therefore drive magnetic convection analogous to buoyancy-driven convection. This magnetothermal convection can overwhelm convection driven by gravitational buoyancy in terrestrial experiments. The objectives of the proposed ground-based theoretical study are (a) to supply the magnetothermohydrodynamic theory necessary to understand these recent experiments and (b) to explore the consequences of nonuniform magnetic fields in microgravity. Even the linear theory for the onset of magnetothermal convection is lacking in the literature. We intend to supply the linear and nonlinear theory based on the thermohydrodynamic equations supplemented by the magnetic body force. We intend to investigate the effect of magnetic fields on gas blockage and heat transport in microgravity. Since magnetic fields provide a means of creating arbitrary, controllable body force distributions, we intend to investigate the possibility of using magnetic fields to position and control fluids in microgravity. We also intend to investigate the possibility of creating stationary terrestrial microgravity environments by using the magnetic force to effectively cancel gravity. These investigations may aid in the design of space-based heat-transfer, combustion, and human-life-support equipment.
Edwards, Boyd F.↗