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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1966

Optical and infrared spectroscopy

Optical and infrared spectroscopic studies of single crystal fluoride perovskites and potassium compounds to determine transmission spectra and ferroelectricity

OPTICAL SPECTRUM↗
NASA NTRS1993

PG 0308 + 096 and PG 1026 + 002 - Two new short period binary stars resulting from common-envelope evolution

Ultraviolet spectroscopy, optical spectroscopy, and spectrophotometry have been used to study the excess UV stars PG 0308 + 096 and PG 1026 + 002. Both objects are short-period binary systems, each containing a DA white dwarf star and a dM star. Orbital periods of approximately 0.284 day for PG 0308 + 096, and aproximately 0.597 day for PG 1026, have been found by spectroscopic analysis of the H-alpha emission line. Ly-alpha and Balmer line profile fitting were used to estimate the mass of white dwarf stars; mass estimates for the dM stars are based on their spectral types. The orbital inclinations are derived from these masses, the periods, and amplitudes of the H-alpha radial velocity curves. The equivalent width of the H-alpha emission line, in each binary system, varies with the orbital phase in such a manner as to imply that it arises, in large part at least, from the hemisphere of the M star that faces the white dwarf star.

Saffer, Rex A.↗
NASA NTRS2013

The NuSTAR Extragalactic Survey: A First Sensitive Look at the High-Energy Cosmic X-Ray Background Population

We report on the first 10 identifications of sources serendipitously detected by the Nuclear Spectroscopic Telescope Array (NuSTAR) to provide the first sensitive census of the cosmic X-ray background source population at approximately greater than 10 keV. We find that these NuSTAR-detected sources are approximately 100 times fainter than those previously detected at approximately greater than 10 keV and have a broad range in redshift and luminosity (z = 0.020-2.923 and L(sub 10-40 keV) approximately equals 4 × 10(exp 41) - 5 × 10(exp 45) erg per second; the median redshift and luminosity are z approximately equal to 0.7 and L(sub 10-40 keV) approximately equal to 3 × 10(exp 44) erg per second, respectively. We characterize these sources on the basis of broad-band approximately equal to 0.5 - 32 keV spectroscopy, optical spectroscopy, and broad-band ultraviolet-to-mid-infrared spectral energy distribution analyses. We find that the dominant source population is quasars with L(sub 10-40 keV) greater than 10(exp 44) erg per second, of which approximately 50% are obscured with N(sub H) approximately greater than 10(exp 22) per square centimeters. However, none of the 10 NuSTAR sources are Compton thick (N(sub H) approximately greater than 10(exp 24) per square centimeters) and we place a 90% confidence upper limit on the fraction of Compton-thick quasars (L(sub 10-40 keV) greater than 10(exp 44) erg per second) selected at approximately greater than 10 keV of approximately less than 33% over the redshift range z = 0.5 - 1.1. We jointly fitted the rest-frame approximately equal to 10-40 keV data for all of the non-beamed sources with L(sub 10-40 keV) greater than 10(exp 43) erg per second to constrain the average strength of reflection; we find R less than 1.4 for gamma = 1.8, broadly consistent with that found for local active galactic nuclei (AGNs) observed at approximately greater than 10 keV. We also constrain the host-galaxy masses and find a median stellar mass of approximately 10(exp 11) solar mass, a factor approximately 5 times higher than the median stellar mass of nearby high-energy selected AGNs, which may be at least partially driven by the order of magnitude higher X-ray luminosities of the NuSTAR sources. Within the low source-statistic limitations of our study, our results suggest that the overall properties of the NuSTAR sources are broadly similar to those of nearby high-energy selected AGNs but scaled up in luminosity and mass.

Spectroscopic↗
NASA NTRS2004

Spitzer 24 Micron Observations of Optical/Near-Infrared-Selected Extremely Red Galaxies: Evidence for Assembly of Massive Galaxies at Z approximately equal to 1-2?

We carried out direct measurement of the fraction of dusty sources in a sample of extremely red galaxies with (R - Ks) >= 5.3 mag and Ks < 20:2 mag, using 24 micron data from the Spitzer Space Telescope. Combining deep 24 micron Ks- and R-band data over an area of ~64 arcmin(sup 2) in ELAIS N1 of the Spitzer First Look Survey (FLS), we find that 50% +/- 6% of our extremely red object (ERO) sample have measurable 24 micron flux above the 3 (sigma) flux limit of 40 (micro)Jy. This flux limit corresponds to a star formation rate (SFR) of 12 solar masses per year ~1, much more sensitive than any previous long-wavelength measurement. The 24 micron-detected EROs have 24 micron/2.2 micron and 24 micron/0.7 micron flux ratios consistent with infrared luminous, dusty sources at z >= 1, and are an order of magnitude too red to be explained by an infrared quiescent spiral or a pure old stellar population at any redshift. Some of these 24 micron-detected EROs could be active galactic nuclei; however, the fraction among the whole ERO sample is probably small, 10%-20%, as suggested by deep X-ray observations as well as optical spectroscopy. Keck optical spectroscopy of a sample of similarly selected EROs in the FLS field suggests that most of the EROs in ELAIS N1 are probably at z ~1. The mean 24 micron flux (167 (micro)Jy) of the 24 micron-detected ERO sample roughly corresponds to the rest-frame 12 micron luminosity, (nu)L(nu)(12 micron, of 3x10(exp 10)(deg) solar luminosities at z ~1. Using the c IRAS (nu)L(nu)(12 (micron) and infrared luminosity LIR(8-1000 (micron), we infer that the (LIR) of the 24 micron- detected EROs is 3 x 10(exp 11) and 1 x 10(exp 12) solar luminosities at z = 1.0 and similar to that of local luminous infrared galaxies (LIRGs) and ultraluminous infrared galaxies (ULIRGs). The corresponding SFR would be roughly 50-170 solar masses per year. If the timescale of this starbursting phase is on the order of 108 yr as inferred for the local LIRGs and ULIRGs, the lower limit on the masses of these 24 micron-detected EROs is 5 x 10(exp 9) to 2 x 10(exp 10) solar masses. It is plausible that some of the starburst EROs are in the midst of a violent transformation to become massive early type galaxies at the epoch of z ~1-2.

high redshift↗
NASA NTRS2004

Spitzer 24micron Observations of Optical/Near-IR Selected Extremely Red Galaxies: Evidence for Assembly of Massive Galaxies at z approximately 1 - 2?

We carried out the direct measurement of the fraction of dusty sources in a sample of extremely red galaxies with (R-K(sub s)) greater than or equal to 5.3 mag and K(sub s) less than 20.2 mag, using from the Spitzer Space Telescope. Combining deep 24 micrometers, K(sub s)- and R-band data over an area of approximately 64 sq.arcmin in the ELAIS N1 field of the Spitzer First Look Survey (FLS), we find that 50 +/- 60% of our ERO sample have measurable 24 micrometer flux above the 3(sigma) flux limit of 40 microns Jy. This flux limit corresponds to a SFR of 12 solar mass/yr at z approximately 1, much mo previous long wavelength measurement. The 24fJ,m-detected EROs have 24-to2.2 and 24-to-0.7micrometr flux ratios consistent with infrared luminous, dusty sources at z approx. 1, and an order of magnitude too red to be explained by an infrared quiescent spiral or a pure old stellar population at any redshift. Some of these 24 micrometer-detected EROs could be AGN, however, the fraction among the whole ERO sample is probably small, 10-20%, as suggested by deep X-ray observations as well as optical spectroscopy. Keck optical spectroscopy of a sample of similarly selected EROs in the FLS field suggests that most of the EROs in ELAIS Nl are probably at z approx. 1.

galaxy evolution↗
NASA NTRS2013

Optical Reflection Spectroscopy of GEO Objects

We report on optical reflection spectroscopy of geosynchronous (GEO) objects in the US Space Surveillance Network (SSN) catalog. These observations were obtained using imaging spectrographs on the 6.5-m Magellan telescopes at the Las Campanas Observatory in Chile. Our goal is to determine the composition of these objects by comparing these spectral observations with ground-based laboratory measurements of spacecraft materials. The observations are all low resolution (1 nm after smoothing) obtained through a 5 arcsecond wide slit and using a grism as the dispersing element. The spectral range covered was from 450 nm to 800 nm. All spectra were flux calibrated using observations of standard stars with the exact same instrumental setup. An effort was made to obtain all observations within a limited range of topocentric phase angle, although the solar incident angle is unknown due to the lack of any knowledge of the attitude of the observed surface at the time of observation.

Seitzer, Patrick↗
DOE OSTI2025

Monitoring Sulfuric Acid and Temperature Using Raman Spectroscopy and Multivariate Chemometrics

Multivariate regression models were optimized for the quantification of sulfuric acid (H 2 SO 4 ) [0–8 M] and temperature (20 °C–80 °C) in the presence of ammonium sulfate ((NH 4 ) 2 SO 4 [0–0.6 M]) using Raman spectroscopy. Optical vibrational spectroscopy is a useful nondestructive technique for the in situ analysis of complex chemical systems notoriously difficult to monitor in situ and in real-time. Multivariate analysis, a chemometrics method, can be paired with these nondestructive optical methods for determining analyte concentration and speciation in complex solutions, such as dissociated species in polyprotic acids, e.g., H 2 SO 4 . The effect of temperature is often overlooked although it can have a major influence on speciation and the corresponding Raman spectra. Here, in this study, partial least squares regression models were optimized for the quantification of H 2 SO 4 and its two deprotonated forms as a function of temperature. Measuring bisulfate as a function of temperature is particularly challenging owing to changes in the second dissociation constant. A designed training set effectively minimized the sample set size and trained a robust predictive model with percent root mean square error of <3% for H 2 SO 4 . The practical strategy employed here was demonstrated to be effective for building chemometric models that directly account for dynamic temperatures with static samples and is shown to be amenable to flow cell analysis applications with a simple calibration transfer for process monitoring applications.

D-optimal design↗
NASA NTRS1986

Annealing of electron damage in mid-IR transmitting fluoride glass

Damage in ZrF4-BaF2-LaF3 glass induced by high-energy electrons was studied by ESR and optical spectroscopy. An optical absorption band at 314 nm in the irradiated glass annealed rapidly above about 50 C, probably by a second-order reaction at room temperature; the ESR lines annealed very slowly at room temperature.

Bansal, Narottam P.↗
NASA NTRS1990

The kinematics and morphology of NGC 520

New long-slit optical spectroscopy and optical and NIR images of NGC 520 are presented. Velocity-dispersion and radial-velocity profiles are obtained from the spectra with the Fourier quotient and cross-correlation techniques. At the NW optical emission peak, a sharp rise in the velocity dispersions implies a concentration of mass. The NW optical peak is also apparent as a peak in the K-band image, whose NIR colors are consistent with the presence of a typical bulge steller population. These data suggest that the NW peak may be the bulge of one of two galaxies in the system. A larger bulge is clearly evident in the K-band image in the middle of an optical dust lane. The optical colors and H-alpha emission imply that both bulges and the disk of the NW galaxy have experienced recent star formation. The radial-velocity profile in the central 10 arcsec at the larger bulge is consistent with a counterrotating core, in agreement with the CO radial-velocity profile (Sanders et al., 1988). This core could be explained as an accreted gas-rich irregular galaxy which is forming a counterrotating stellar disk.

Standord, S. A.↗
NASA NTRS2008

Near-Field Spectroscopy with Nanoparticles Deposited by AFM

An alternative approach to apertureless near-field optical spectroscopy involving an atomic-force microscope (AFM) entails less complexity of equipment than does a prior approach. The alternative approach has been demonstrated to be applicable to apertureless near-field optical spectroscopy of the type using an AFM and surface enhanced Raman scattering (SERS), and is expected to be equally applicable in cases in which infrared or fluorescence spectroscopy is used. Apertureless near-field optical spectroscopy is a means of performing spatially resolved analyses of chemical compositions of surface regions of nanostructured materials. In apertureless near-field spectroscopy, it is common practice to utilize nanostructured probe tips or nanoparticles (usually of gold) having shapes and dimensions chosen to exploit plasmon resonances so as to increase spectroscopic-signal strengths. To implement the particular prior approach to which the present approach is an alternative, it is necessary to integrate a Raman spectrometer with an AFM and to utilize a special SERS-active probe tip. The resulting instrumentation system is complex, and the tasks of designing and constructing the system and using the system to acquire spectro-chemical information from nanometer-scale regions on a surface are correspondingly demanding.

Anderson, Mark S.↗
NASA NTRS1992

Optical luminescence spectroscopy as a probe of the surface mineralogy of Mars

Optical luminescence (OpL) spectroscopy is an attractive use of a visible-near-IR spectrometer on a Mars lander because mineral products of atmosphere-surface interactions on Mars will probably have characteristic OpL spectra. Optical luminescence spectra would be taken at night, when a spectrometer might otherwise sit idle. Also needed would be a source of exciting radiation, which could be shared with other experiments. Optical luminescence is emission of nonthermal optical photons (near-UV through near-IR) as a response to energy input. On absorption of energy, an atom (or ion) will enter an excited state. The favored decay of many such excited states involving valence-band electrons is emission of an optical photon. Optical luminescence spectra can be useful in determining mineralogy and mineral composition. Optical luminescence in crystals can arise from essential elements (or ions), trace-element substituents (activators), or defects. Common activators in salts of alkali and alkaline earth elements include Mn(2+)(VI), other transition metals, the rare earths, and the actinides. Trace substituents of other species can enhance or quench OpL (e.g., Pb(2+) vs. Fe(3+)). Optical luminescence can also arise from defects in crystal structures, including those caused by radiation and shock.

Treiman, A. H.↗
NASA NTRS2001

Measuring Rocket Engine Temperatures with Hydrogen Raman Spectroscopy

Optically accessible, high pressure, hot fire test articles are available at NASA Marshall for use in development of advanced rocket engine propellant injectors. Single laser-pulse ultraviolet (UV) Raman spectroscopy has been used in the past in these devices for analysis of high pressure H2- and CH4-fueled combustion, but relies on an independent pressure measurement in order to provide temperature information. A variation of UV Raman (High Resolution Hydrogen Raman Spectroscopy) is under development and will allow temperature measurement without the need for an independent pressure measurement, useful for flows where local pressure may not be accurately known. The technique involves the use of a spectrometer with good spectral resolution, requiring a small entrance slit for the spectrometer. The H2 Raman spectrum, when created by a narrow linewidth laser source and obtained from a good spectral resolution spectrograph, has a spectral shape related to temperature. By best-fit matching an experimental spectrum to theoretical spectra at various temperatures, a temperature measurement is obtained. The spectral model accounts for collisional narrowing, collisional broadening, Doppler broadening, and collisional line shifting of each Raman line making up the H2 Stokes vibrational Q-branch spectrum. At pressures from atmospheric up to those associated with advanced preburner components (5500 psia), collisional broadening though present does not cause significant overlap of the Raman lines, allowing high resolution H2 Raman to be used for temperature measurements in plumes and in high pressure test articles. Experimental demonstrations of the technique are performed for rich H2-air flames at atmospheric pressure and for high pressure, 300 K H2-He mixtures. Spectrometer imaging quality is identified as being critical for successful implementation of technique.

Wehrmeyer, Joseph A.↗