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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Report Summarizing the Mechanical Properties of a Large ODS Ferritic Alloy Ingot by Forging at High Temperatures for Future Mother Tube Production

Oxide dispersion strengthened (ODS) ferritic alloys are considered the benchmark fuel cladding and core structural material in advanced nuclear energy reactors that require high-temperature strength and creep properties and resistance to radiation damage. The ODS ferritic alloys including 14YWT are produced by mechanical alloying (MA), which is time-consuming and is associated with high manufacturing costs that are not beneficial to being used in advanced nuclear energy reactors. This report summarizes the accomplishments in FY24 in the INM program for producing an ODS ferritic alloy by high-deformation, high-temperature processing of reactive and ferritic alloy powders for advanced reactor fuel cladding applications. Following four hot forging experiments, it was concluded that several significant challenges were encountered that were difficult to overcome. These challenges were related to using high annealing temperatures for pressure assisted sintering processes to produce dense microstructures, but the high annealing temperatures result in long range diffusion of Ti through the bcc Fe lattice and react with the YIG particles that are distributed on the prior surfaces of the ferritic alloy powders. In addition, it was determined that the high deformations induced by forging at high temperatures were not very effective for fracturing the reactive YIG particles into smaller particles and distributing them into the interior of the ferritic alloy powders. Spark plasma sintering was attempted for shortening the time at high temperatures, which led to full densification but the microstructure characterization results still showed that Ti atoms diffused over long distances in the bcc Fe lattice and reacted with the YIG particles. Finally, a short 30 minute high intensity ball milling experiment was conducted on blended 14WT and YIG powders for inducing severe deformations that caused the initially spherical powders of 14WT decorated with the YIG particles on the surfaces to transform to flakes and fracturing of YIG particles into smaller particles that were incorporated into the bcc Fe lattice. Two forgings were performed with the high intensity milled powders: first annealing for 20 minutes at 850ºC followed by forging and second annealing for 20 minutes at 1,100ºC followed by forging. At 850ºC, Ti atoms are effectively immobile, thus allowing for densification albeit incomplete. The deformation by forging after annealing for 20 minutes at 1,100ºC favored dynamic recrystallization processes that led to nano-size grains with very high stored energy due to high dislocation density. The corresponding VH data showed significant hardening that correlated with estimated strengthening of ~1650 MPa. This hybrid processing approach combining high intensity ball milling of powder with annealing and forging showed the most promise for producing an oxide dispersing strengthened ferritic alloy.

36 MATERIALS SCIENCE↗
NASA NTRS1975

Lifetimes for OH and OD electronic states with resonance transitions in the region between 1700 and 1950 A

The upper states of the OH and OD bands in the region between 1700 and 1950 A have been studied with a phase-shift radiative lifetime apparatus. Lifetimes varying from 1.8 to 2.9 ns have been found. Lifetimes for OH and OD are essentially the same, indicating that the upper states are likely to be depopulated via purely radiative processes under the present experimental conditions. Lifetimes have also been obtained for the C(2)Sigma(+) - A(2)Sigma(+) transition in OH and OD. These results are consistent with the preliminary analysis of Pryce (private communication) that the bands between 1700 and 1950 A in OH are partly due to the C(2)Sigma(+) - X(2)Pi sub i transition.

Smith, W. H.↗
NASA NTRS1985

Emission by OD in comets

A calculation has been made of the complete fluorescent equilibrium of OD in sunlight including ultraviolet (A-X) transitions, vibrational and rotational transitions (A-A and X-X), and Lambda-doubling transitions in the X state. The dependence on heliocentric radial velocity is strong. No lines of OD are visible in any cometary spectra taken with IUE, but the limits vary, considerably from one comet to another. In the most favorable case, comet Austin 1982 VI, the limit is OD/OH less than 0.004. Optimum conditions for detecting OD in comet Halley are also discussed.

Ahearn, M. F.↗
NASA NTRS1990

The oxidation and corrosion of ODS alloys

The oxidation and hot corrosion of high temperature oxide dispersion strengthened (ODS) alloys are reviewed. The environmental resistance of such alloys are classified by oxide growth rate, oxide volatility, oxide spalling, and hot corrosion limitations. Also discussed are environmentally resistant coatings for ODS materials. It is concluded that ODS NiCrAl and FeCrAl alloys are highly oxidation and corrosion resistant and can probably be used uncoated.

Lowell, Carl E.↗
NASA NTRS1993

Oxidation And Hot Corrosion Of ODS Alloy

Report reviews oxidation and hot corrosion of oxide-dispersion-strengthened (ODS) alloys, intended for use at high temperatures. Classifies environmental resistances of such alloys by rates of growth of oxides, volatilities of oxides, spalling of oxides, and limitations imposed by hot corrosion. Also discusses environmentally resistant coatings for ODS materials. Concludes ODS NICrAl and FeCrAl alloys highly resistant to oxidation and corrosion and can be used uncoated.

Lowell, Carl E.↗
NASA NTRS2002

Optical Displacement Sensor (ODS), a LISA's inertial reference sensor candidate.

We propose here an optical displacement sensor (ODS) as a supplemental or backup sensor for the LISA inertial reference sensor concept. This simple ODS consists of a laser diode and a quad-cell photodiode (both commercially available). The inertial mass’ reflective surface directs the laser beam onto the quad-cell photodiode. Changes in the inertial mass’ position and orientation are then extracted from ratios of the differences and sums of the quad-cell photodiode outputs. A simpler proto-type using a 200 microns wide slit has demonstrated a resolution of 10 nm/√Hz at 1 mHz and 1 nm/√Hz above 5 mHz. The electronics noise was 1 nm/√Hz at and above 1 mHz with simple and off the shelf electronics components. Although this ODs’ current performance does not meet the LISA’s system requirement’ of 1 nm/ at 1 mHz, we think that is achievable in the near future

Abramocivi, Alex↗
DOE OSTI2016

In Situ Synchrotron Tensile Investigations on 14YWT, MA957 and 9-Cr ODS Alloys

Nanostructured ferritic alloys (NFAs) provide exceptional radiation tolerance and high-temperature mechanical properties when compared to traditional ferritic and ferritic/martensitic (F/M) steels. Their remarkable properties result from ultrahigh density and ultrafine size of Y-Ti-O nanoclusters within the ferritic matrix. In this work, we applied a high-energy synchrotron radiation X-ray to study the deformation process of two NFAs including 14YWT and MA957, and a 9-Cr ODS steel. Only the relatively large nanoparticles in the 9-Cr ODS were observed in the synchrotron X-ray diffraction. The nanoclusters in both 14 YWT and MA957 were invisible in the measurement due to their non-stoichiometric nature. Due to the different sizes of nanoparticles and nanoclusters in the materials, the Orowan looping was considered to be the major strengthening mechanism in the 9-Cr ODS, while the dispersed-barrier-hardening is dominant strengthening mechanism in both 14YWT and MA957, respectively. This analysis was inferred from the different build-up rates of dislocation density when plastic deformation was initiated. Finally, the dislocation densities interpreted from the X-ray measurements were successfully modeled using the Bergstr m s dislocation models.

Lin, Jun-Li↗
DOE OSTI2017

Analysis of the Human Biohazard of Long-Lived Fission Products and Actinides for BREST-OD-300 Spent Fuel

The aim of this work is to perform a comparative analysis of the biohazard for the population of long-lived fission products and actinides from BREST-OD-300 reactor spent fuel taking account of the time required for different radionuclides to reach Earth’s surface by migrating from a deep disposal site. It was found that the biohazard of fission products is significantly greater than that of actinides for a long time (20000 years according to the accepted scenario of radionuclide migration). The radiological impact on the population is predicted after {sup 99}Tc – radionuclide with high migration capability – reaches the soil surface. {sup 137}Cs and {sup 90}Sr will not appreciably affect the dose load because of their relatively short half-life. In order to maintain radio-ecological balance between long-lived wastes and native uranium during the entire possible time period, it is sufficient to extract from the BREST-OD-300 spent fuel 90% of the technetium and 75% of the americium with 99.9% of the fissile materials extracted.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2016

Evaluation of Pb-17Li compatibility of ODS Fe-12Cr-5Al alloys

The Dual Coolant Lead Lithium (DCLL: eutectic Pb–17Li and He) blanket concept requires improved Pb–17Li compatibility with ferritic steels in order to demonstrate acceptable performance in fusion reactors. As an initial step, static Pb-17at.%Li (Pb-17Li) capsule experiments were conducted on new oxide dispersion strengthened (ODS) FeCrAl alloys ((1) Y 2 O 3 (125Y), (2) Y 2 O 3 +ZrO 2 (125YZ), (3) Y 2 O 3 +HfO 2 (125YH), and (4) Y 2 O 3 +TiO 2 (125YT)) produced at ORNL via mechanical alloying (MA). Tests were conducted in static Pb–17Li for 1000 h at 700°C. Alloys showed promising compatibility with Pb–17Li with small mass change after testing for 125YZ, 125YH and 125YT, while the 125Y alloy experienced the highest mass loss associated with some oxide spallation and subsequent alloy dissolution. X-ray diffraction methods identified the surface reaction product as LiAlO 2 on all four alloys. A small decrease (~1 at.%) in Al content beneath the oxide scale was observed in all 4 ODS alloys, which extended through 60 μm beneath the oxide/metal interface. This indicates improvements in alloy dissolution by decreasing the amount of Al loss from the alloy. Scales formed on 125YZ, 125YH and 125YT were examined via scanning transmission electron microscopy (S/TEM) and revealed incorporation of Zr-, Hf-, and Ti-rich precipitates within the LiAlO2 product, respectively. This indicates an inward scale growth mechanism. Future work in flowing Pb–17Li is needed to further evaluate the effectiveness of this strategy in a test blanket module.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Advanced TEM characterization of oxide nanoparticles in ODS Fe–12Cr–5Al alloys

For oxide nanoparticles present in three oxide-dispersion-strengthened (ODS) Fe–12Cr–5Al alloys containing additions of (1) Y 2 O 3 (125Y), (2) Y 2 O 3 + ZrO 2 (125YZ), and (3) Y 2 O 3 + HfO 2 (125YH), were investigated using transmission and scanning transmission electron microscopy. Furthermore, in all three alloys nano-sized (<3.5 nm) oxide particles distributed uniformly throughout the microstructure were characterized using advanced electron microscopy techniques. In the 125Y alloy, mainly Al 2 O 3 and yttrium–aluminum garnet (YAG) phases (Y 3 Al 5 O 12 ) were present, while in the 125YZ alloy, additional Zr(C,N) precipitates were identified. The 125YH alloy had the most complex precipitation sequence whereby in addition to the YAG and Al 2 O 3 phases, Hf(C,N), Y 2 Hf 2 O 7 , and HfO 2 precipitates were also found. The presence of HfO 2 was mainly due to the incomplete incorporation of HfO 2 powder during mechanical alloying of the 125YH alloy. The alloy having the highest total number density of the oxides, the smallest grain size, and the highest Vickers hardness was the 125YZ alloy indicating, that Y 2 O 3 + ZrO 2 additions had the strongest effect on grain size and tensile properties. Finally, high-temperature mechanical testing will be addressed in the near future, while irradiation studies are underway to investigate the irradiation resistance of these new ODS FeCrAl alloys.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Laser Powder Bed Fusion of ODS 14YWT from Gas Atomization Reaction Synthesis Precursor Powders

Abstract Laser powder bed fusion (LPBF) additive manufacturing (AM) is a promising route for the fabrication of oxide dispersion strengthened (ODS) steels. In this study, 14YWT ferritic steel powders were produced by gas atomization reaction synthesis (GARS). The rapid solidification resulted in the formation of stable, Y-containing intermetallic Y 2 Fe 17 on the interior of the powder and a stable Cr-rich oxide surface. The GARS powders were consolidated with LPBF. Process parameter maps identified a stable process window resulting in a relative density of 99.8%. Transmission electron microscopy and high-energy x-ray diffraction demonstrated that during LPBF, the stable phases in the powder dissociated in the liquid melt pool and reacted to form a high density (1.7 × 10 20 /m 3 ) of homogeneously distributed Ti 2 Y 2 O 7 pyrochlore dispersoids ranging from 17 to 57 nm. The use of GARS powder bypasses the mechanical alloying step typically required to produce ODS feedstock. Preliminary mechanical tests demonstrated an ultimate tensile and yield strength of 474 MPa and 312 MPa, respectively.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Mechanism and Energetics of the Hydrolysis of Th + To Form Th(OD) 3 + : Guided Ion Beam and Theoretical Studies of ThO + , ThO 2 + , and OThOD + Reacting with D 2 O

The kinetic energy dependences of the reactions of ThO + , ThO 2 + , and OThOD + with D 2 O, ThO 2 + with D 2 , and OThOD + with Xe were studied using guided ion beam tandem mass spectrometry. Exothermic formation of OThOD + is the dominant process observed in reactions of both ThO + and ThO 2 + with D 2 O. Minor products formed in endothermic reactions include ThO 2 + , DThO + , and ThO 2 D 2 + . OThOD + is also formed in the reaction of ThO 2 + with D 2 but in an endothermic process. Collision-induced dissociation of OThOD + with Xe leads to endothermic loss of the hydroxide ligand. OThOD + reacts further with D 2 O to form the associative complex ThO 3 D 3 + , which is long-lived before dissociating back to the reactants. The OThOD + D 2 O bond energy of the associative complex is measured to be 2.96 ± 0.05 eV by modeling the kinetic energy dependent cross section for association using a phase space theory (PST) model that rigorously conserves angular momentum. By comparison with theory, this bond energy identifies the ThO 3 D 3 + species as the trihydroxide cation, Th(OD) 3 + . From the endothermic reactions and CID of OThOD + with Xe, the OTh + -D, OTh + -O, and OTh + -OD bond dissociation energies are measured to be 2.33 ± 0.24, 4.66 ± 0.15, and 6.00 ± 0.17 eV, respectively. All four of these BDEs are experimentally determined for the first time and agree reasonably well with values calculated at the B3LYP, B3PW91, and PBE0 levels of theory with cc-pVQZ basis sets. Complete potential energy surfaces for all reactions were calculated at the B3LYP/cc-pVTZ level and elucidate the mechanisms for all processes observed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

SGD-OD: investigating the potential oxygen demand of submarine groundwater discharge in coastal systems

Submarine groundwater discharge (SGD) supplies nutrients, carbon, metals, and radionuclide tracers to estuarine and coastal waters. One aspect of SGD that is poorly recognized is its direct effect on dissolved oxygen (DO) demand in receiving waters, denoted here as SGD-OD. Sulfate-mediated oxidation of organic matter in salty coastal aquifers produces numerous reduced byproducts including sulfide, ammonia, dissolved organic carbon and nitrogen, methane, and reduced metals. When these byproducts are introduced to estuarine and coastal systems by SGD and are oxidized, they may substantially reduce the DO concentration in receiving waters and impact organisms living there. We consider six estuarine and coastal sites where SGD derived fluxes of reduced byproducts are well documented. Using data from these sites we present a semiquantitative model to estimate the effect of these byproducts on DO in the receiving waters. Without continued aeration with atmospheric oxygen, the study sites would have experienced periodic hypoxic conditions due to SGD-OD. The presence of H2S supplied by SGD could also impact organisms. This process is likely prevalent in other systems worldwide.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

The preparation and phase diagrams of ( 7 Li 1-x Fe x OD)FeSe and (Li 1-x Fe x OH)FeSe superconductors

We report the phase diagram for the superconducting system ( 7 Li 1-x Fe x OD)FeSe and contrast it with that of (Li 1-x Fe x OH)FeSe both in single crystal and powder forms. Samples were prepared via hydrothermal methods and characterized by laboratory and synchrotron X-ray diffraction, high-resolution neutron powder diffraction (NPD), and high intensity NPD. We find a correlation between the tetragonality of the unit cell parameters and the critical temperature, Tc, which is indicative of the effects of charge doping on the lattice and formation of iron vacancies in the FeSe layer. We observe no appreciable isotope effect on the maximum Tc in substituting H by D. The NPD measurements definitively rule out an antiferromagnetic ordering in the non-superconducting (Li 1-x Fe x OD)FeSe samples below 120 K, which has been reported in non-superconducting (Li 1-x Fe x OH)FeSe. A likely explanation for the observed antiferromagnetic transition in (Li 1-x Fe x OH)FeSe samples is the formation of impurities during their preparation such as Fe 3 O 4 and Li x FeO 2 , which express a charge ordering transition known as the Verwey transition near 120 K. The concentration of these oxide impurities is found to be dependent on the concentration of the lithium hydroxide reagent and the use of H 2 O vs. D 2 O as the solvent during synthesis. We also describe the reaction conditions that lead to some of our superconducting samples to exhibit ferromagnetism below T c .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2026

Microstructure-dependent particulate populations in ODS steels revealed by single-particle ICP-TOF-MS

In this work, we evaluated the ability of single-particle inductively coupled plasma time-of-flight mass spectrometry (SP-ICP-TOF-MS) to characterize particulates generated from 300 series stainless steels and oxide dispersion–strengthened (ODS) steels. Particulates were produced using two different rotary tools (cutting disk and grinding bit) to assess the influence of particle generation on effluent particulates. Across all materials and preparation techniques, SP-ICP-TOF-MS detected a substantial population of particles containing the expected constituent elements, with average compositions closely matching the nominal alloy values. A secondary population of Y-bearing particles was evident in ODS steels; their formation is strongly favored in particulates generated using the grinding bit. Specifically, in PM2000, Y-bearing particles were predominantly colocated with Al, whereas in 14YWT, Y-bearing particles were less frequently Fe-free but showed stronger colocation with Ti. These trends are consistent with the known microstructural differences between Y–Al–O oxide particles in PM2000 and finer Y–Ti–O nanoclusters in 14YWT. Together, these results demonstrate that SP-ICP-TOF-MS can resolve distinct particulate populations in complex, multicomponent steels at the femtogram mass scale, enabling particle-resolved insight into microstructure-driven phase separation and preparation-dependent particle generation.

Brubaker, Zach E. [Oak Ridge National Laboratory (↗
DOE OSTI2015

Microwave spectroscopy of the seeded binary and ternary clusters CO-(pH{sub 2}){sub 2}, CO-pH{sub 2}-He, CO-HD, and CO-(oD{sub 2}){sub N=1,2}

We report the Fourier transform microwave spectra of the a-type J = 1-0 transitions of the binary and ternary CO-(pH{sub 2}){sub 2}, CO-pH{sub 2}-He, CO-HD, and CO-(oD{sub 2}){sub N=1,2} clusters. In addition to the normal isotopologue of CO for all clusters, we observed the transitions of the minor isotopologues, {sup 13}C{sup 16}O, {sup 12}C{sup 18}O, and {sup 13}C{sup 18}O, for CO-(pH{sub 2}){sub 2} and CO-pH{sub 2}-He. All transitions lie within 335 MHz of the experimentally or theoretically predicted values. In comparison to previously reported infrared spectra [Moroni et al., J. Chem. Phys. 122, 094314 (2005)], we are able to tentatively determine the vibrational shift for CO-pH{sub 2}-He, in addition to its b-type J = 1-0 transition frequency. The a-type frequency of CO-pH{sub 2}-He is similar to that of CO-He{sub 2} [Surin et al., Phys. Rev. Lett. 101, 233401 (2008)], suggesting that the pH{sub 2} molecule has a strong localizing effect on the He density. Perturbation theory analysis of CO-oD{sub 2} reveals that it is approximately T-shaped, with an anisotropy of the intermolecular potential amounting to ∼9 cm{sup −1}.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Direct measurements of DOCO isomers in the kinetics of OD + CO

Quantitative and mechanistically detailed kinetics of the reaction of hydroxyl radical (OH) with carbon monoxide (CO) have been a longstanding goal of contemporary chemical kinetics. This fundamental prototype reaction plays an important role in atmospheric and combustion chemistry, motivating studies for accurate determination of the reaction rate coefficient and its pressure and temperature dependence at thermal reaction conditions. This intricate dependence can be traced directly to details of the underlying dynamics (formation, isomerization, and dissociation) involving the reactive intermediates cis- and trans-HOCO, which can only be observed transiently. Using time-resolved frequency comb spectroscopy, comprehensive mechanistic elucidation of the kinetics of the isotopic analog deuteroxyl radical (OD) with CO has been realized. By monitoring the concentrations of reactants, intermediates, and products in real time, the branching and isomerization kinetics and absolute yields of all species in the OD + CO reaction are quantified as a function of pressure and collision partner.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Strangeness Photoproduction at the BGO-OD Experiment

The BGO-OD experiment at the ELSA accelerator facility uses an energy tagged bremstrahlung photon beam to investigate the excitation structure of the nucleon. The setup consists of a highly segmented BGO calorimeter surrounding the target, with a particle tracking magnetic spectrometer at forward angles. BGO-OD is ideal for investigating low momentum transfer processes due to the acceptance and high momentum resolution at forward angles. In particular, this enables the investigation of strangeness photoproduction where t-channel exchange mechanisms play an important role. This also allows access to a kinematic region where extended, molecular structure may manifest in reaction mechanisms. The extensive strangeness photoproduction programme includes the photoproduction of neutral and charged kaons using both hydrogen and deuterium targets.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗