Mean lives of excited levels in O I-O VI
Ion beam-foil produced oxygen spectra in wavelength range between 450 and 2200 A, determining mean radiative lives of O I - O VI excitation levels
Berry, H. G.↗
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Tropical F region winds from O I 1356-A and forbidden O I 6300-A emissions. II - Analysis of OGO 4 data
The OGO 4 tropical nightglow data on the O I 1356-A and forbidden O I 6300-A emissions during several months in the fall of 1967 are analyzed in conjunction with theoretical models. From the latitudinal asymmetry present in the tropical emissions the neutral wind velocities in the magnetic meridian at the time of the observations are found to reach 150 m/s near 2000 LT in the Pacific sector and 110 m/s in the Indian sector. The longitudinal dependence of the emissions indicates a strong zonal component (referred to geographic coordinates) and allows the resolution of the inferred wind velocities into geographic zonal and meridional wind components. The geographic zonal component reaches a maximum velocity of 260 m/s near 2200 LT.
Bittencourt, J. A.↗
Reaction rates for O3 + HCl yielding O + O2 + HCl, Cl + O3 yielding ClO + O2, and HCl + O yielding OH + Cl at elevated temperatures
Ozone and a much greater quantity of hydrogen chloride, slightly diluted by oxygen and argon, were heated by a shock wave process to temperatures in the range 480-1300 K at pressures from four to eight atmospheres. From variations in ozone concentration, determined by the attentuation of 2537-A radiation, the rate coefficient for the reaction O3 + HCl yielding O + O2 + HCl was determined to be k1 = (4.0 plus or minus 1.5) x 10 to the minus 10 exp(-10,408/T)cm3/s for temperatures of 480-720 K. From the concentration of ClO remaining at the end of ozone decomposition the rate coefficients for the reactions Cl + O3 yielding ClO + O2 and HCl + O yielding OH + Cl were also deduced for a temperature of about 1100 K.
Park, C.↗
Auroral O I /989 A/ and O I /1027 A/ emissions
Rocket observations of the extreme ultraviolet spectrum of the aurora from 550 to 1250 A are presented, and the results for the O I (989 A) and O I (1027 A) multiplets are examined in detail. The intensity of these emissions and the observed anisotropic radiation field are inconsistent with the relative intensity of the branching radiations. Several possible solutions to the problem are discussed, and evidence is presented that suggests the need to lower the branching ratios by several orders of magnitude.
Christensen, A. B.↗
Laboratory measurements of the O+/2D/ + N2 and O+/2D/ + O2 reaction rate coefficients and their ionospheric implications
Rate coefficients which have been measured at thermal energies for the charge transfer reactions of metastable O+/2D/ ions with N2 and O2 are reported. It is found that at an effective temperature of about 550 K, k(n2) = (8 + or - 2) x 10 to the -10 cu cm/sec and k(O2) = (7 + or - 2) x 10 to the -10 cu cm/sec. Drift tube-mass spectrometer measurements employ the reaction He(+) + O2 as the source of metastable O+ ions, showing that the ions produced in this manner are in the 2D state rather than the 2P state, a possible alternative identification. Finally, consideration is given to the ionospheric implications of the laboratory measurements.
Johnsen, R.↗
Transport properties for the oxygen system - O2, O, O(+), and e
The transport properties of the oxygen system, O2, O, O(+), and the electron, e, are calculated and their applications are discussed. The possible two-body interactions in the oxygen system are examined and the exponential repulsive potential is used to determine collision integrals for these interactions. Values are presented for the viscosity of the pure gases, the self-diffusion coefficient of the pure gases at 1 atm pressure, the translational thermal conductivity of the pure gases, and the internal thermal conductivity of O2.
Biolsi, Louis↗
The winds of O-stars. II - The terminal velocities of stellar winds of O-type stars
The SEI method (Lamers et al., 1987) is used to obtain P Cygni profiles of the UV resonance lines of C IV, N V, and S IV and of the subordinate UV lines of N IV and C III observed in the spectra of 27 O-type stars. Theoretical profiles which include the turbulence effects agree well with the observations, and they can account for the deep absorption troughs, the shape of the violet absorption wings, and the wavelength of the emission peak. The resulting terminal velocities of the stellar winds are found to be systematically lower by about 400 km/s than previous estimates obtained using the Sobolev approximation (Castor and Lamers, 1979), suggesting that the narrow absorption components, observed in the UV resonance lines of O and B stars, reach the terminal velocity of the winds.
Groenewegen, M. A. T.↗
Further observations of rotationally excited far-infrared O-16H and O-18H emission in Orion-KL - Tighter constraints on the nature of the emitting region
Observations within 1 arcmin of Orion-KL have led to the detection of the O-16H rotational cross-ladder transition at 53.351 microns and the O-18H rotational ground-state transition at 120.1719 microns, both of which exhibit a P-Cygni profile and demonstrate that the OH gas is expanding out from the central BN/KL IR cluster. The best overall fit to these data requires emission from the three main components of the gas: (1) postshocked gas, (2) the cool postshocked region, and (3) the plateau region. All three components require a significant radiative background in order to fit the data.
Melnick, G. J.↗
Predissociation linewidths of the (3,0)-(11,0) Schumann-Runge absorption bands of (O-18)2 and O-16O-18 in the wavelength region 180-196 nm
The Yoshino et al. (1988) measurements of absolute cross sections and those of Cheung et al. (1988) for spectroscopic constants are presently used to derive the predissociation linewidths of the (3,0)-(11,0) Schumman-Runge bands of (O-18)2 and O-16O-18, in the 180-196 nm wavelength region. Linewidths are determined as parameters in the nonlinear, least-squares fitting of calculated cross-sections to measured ones. The predissociation linewidths obtained are noted to often be greater than previously obtained experimental values for both isotopic molecules.
Chiu, S. S.-L.↗
Measurement of the O-18 to O-16 isotope ratio for characterizing oxide surface layers on LDEF samples
The ratio of the density of the oxygen 18 isotope (O-18) to the density of the oxygen 16 isotope (O-16) is a strong function of altitude in the atmosphere because of the stronger gravitational attraction on the heavier isotope. It is proposed that the measurement of this ratio for oxide surface layers on LDEF samples can easily distinguish oxides formed in orbit from contaminative oxides formed during retrieval procedures. Since the satellite altitude is known as a function of time, it may be possible to use the measured ratio to determine the time of formation of oxide layers, the accuracy depending upon the stability of the atmosphere.
Sagalyn, Paul L.↗
Resonance charge transfer, transport cross sections, and collision integrals for N(+)(3P)-N(4S0) and O(+)(4S0)-O(3P) interactions
N2(+) and O2(+) potential energy curves have been constructed by combining measured data with the results from electronic structure calculations. These potential curves have been employed to determine accurate charge exchange cross sections, transport cross sections, and collision integrals for ground state N(+)-N and O(+)-O interactions. The cross sections have been calculated from a semiclassical approximation to the scattering using a computer code that fits a spline curve through the discrete potential data and incorporates the proper long-range behavior of the interactions forces. The collision integrals are tabulated for a broad range of temperatures 250-100,000 K and are intended to reduce the uncertainty in the values of the transport properties of nonequilibrium air, particularly at high temperatures.
Stallcop, James R.↗
Transport cross sections and collision integrals for N(4S0)-O(+)(4S0) and N(+)(3P)-O(3P) interactions
The transport cross sections and collision integrals are reported for the N(+)-O and N-O(+) interactions. The cross sections are determined using accurate potential energy curves and a semiclassical description of the scattering. The computed collision integrals differ substantially from the estimated values currently recommended for flow-field studies.
Partridge, Harry↗
The isotopic composition of cosmic-ray B, C, N, and O - Evidence for an overabundance of O-18
New observations of galactic cosmic rays at higher energies (about 400-780 MeV/nucleon) than obtained in previous direct mass measurements have resulted in determinations of the isotopic composition of B, C, N, and O. The derived cosmic-ray source abundances provide evidence for an enhancement of O-18/O-16 by a factor of 5.6 +/- 1.9 over the solar system value and give a C-13/C-12 ratio consistent with the solar system abundance ratio, but lower than some recent measurements of the local interstellar medium.
Gibner, P. S.↗
Conductor-backed coplanar waveguide resonators of Y-Ba-Cu-O and Tl-Ba-Ca-Cu-O on LaAlO3
Conductor-backed coplanar waveguide (CBCPW) resonators operating at 10.8 GHz have been fabricated from Tl-Ba-Ca-O (TBCCO) and Y-Ba-Cu-O (YBCO) thin films on LaAlO3. The resonators consist of a coplanar waveguide (CPW) patterned on the superconducting film side of the LaAlO3 substrate with a gold ground plane coated on the opposite side. These resonators were tested in the temperature range from 14 to 106 K. At 77 K, the best of our TBCCO and YBCO resonators have an unloaded quality factor (Qo) 7 and 4 times, respectively, larger than that of a similar all-gold resonator. In this study, the Qo's of the TBCCO resonators were larger than those of their YBCO counterparts throughout the aforementioned temperature range.
Miranda, F. A.↗
High temperature kinetic study of the reactions H + O2 = OH + O and O + H2 = OH + H in H2/O2 system by shock tube-laser absorption spectroscopy
The reactions: (1) H + O2 = OH + O; and (2) O + H2 = OH + H are the most important elementary reactions in gas phase combustion. They are the main chain-branching reaction in the oxidation of H2 and hydrocarbon fuels. In this study, rate coefficients of the reactions and have been measured over a wide range of composition, pressure, density and temperature behind the reflected shock waves. The experiments were performed using the shock tube - laser absorption spectroscopic technique to monitor OH radicals formed in the shock-heated H2/O2/Ar mixtures. The OH radicals were detected using the P(1)(5) line of (0,0) band of the A(exp 2) Sigma(+) from X(exp 2) Pi transition of OH at 310.023 nm (air). The data were analyzed with the aid of computer modeling. In the experiments great care was exercised to obtain high time resolution, linearity and signal-to-noise. The results are well represented by the Arrhenius expressions. The rate coefficient expression for reaction (1) obtained in this study is k(1) = (7.13 +/- 0.31) x 10(exp 13) exp(-6957+/- 30 K/T) cu cm/mol/s (1050 K less than or equal to T less than or equal to 2500 K) and a consensus expression for k(1) from a critical review of the most recent evaluations of k(1) (including our own) is k(1) = 7.82 x 10(exp 13) exp(-7105 K/T) cu cm/mol/s (960 K less than or equal to T less than or equal to 5300 K). The rate coefficient expression of k(2) is given by k(2) = (1.88 +/- 0.07) x 10(exp 14) exp(-6897 +/- 53 K/T) cu cm/mol/s (1424 K less than or equal to T less than or equal to 2427 K). For k(1), the temperature dependent A-factor and the correlation between the values of k(1) and the inverse reactant densities were not found. In the temperature range of this study, non-Arrhenius expression of k(2) which shows the upward curvature was not supported.
Ryu, Si-Ok↗
Simultaneous UV and optical study of O star winds and UV and optical covariability of O star winds
Simultaneous ultraviolet and optical observations of 10 bright O stars were organized in several observing campaigns lasting 3-6 days each. The observing campaigns included 12 observatories in the Northern hemisphere obtaining high resolution spectroscopy, photometry, and polarimetry, as well as 24-hour coverage with the IUE (International Ultraviolet Explorer) observatory. Over 600 high dispersion SWP spectra were acquired with IUE at both NASA and VILSPA for the completion of this work. The massive amount of data from these observing campaigns, both from IUE and the ground-based instruments, has been reduced and analyzed. The accompanying paper describes the data acquisition, analysis, and conclusions of the study performed. The most important results of this study are the strong confirmation of the ubiquitous variability of winds of O stars, and the critical correlation between rotation of the star and the wind variability as seen in the ultraviolet and optical spectral lines.
Nichols, Joy S.↗
Electronic properties of Y-Ba-Cu-O superconductors as seen by Cu and O NMR/NQR
Nuclear Magnetic Resonance (NMR) and Nuclear Quadrupole Resonance (NQR) allow the investigation of electronic properties at the atomic level. We will report on such studies of typical members of the the Y-Ba-Cu-O family such as YBa2Cu30(6 + x) (1-2-3-(6 + x)), YBa2Cu4O8 (1-2-4) and Y2Ba4Cu7015 (2-4-7) with many examples of recent work performed in our laboratory. In particular, we will deal with Knight shift and relaxation studies of copper and oxygen. We will discuss important issues of current studies such as: (1) Existence of a common electronic spin-susceptibility in the planes (and perhaps in the chains) of 1-2-4; (2) Strong evidence for the existence of a pseudo spin-gap of the antiferromagnetic fluctuations in 1-2-4 and 2-4-7; (3) Evidence for d-wave pairing in 1-2-4; (4) Strong coupling of inequivalent Cu-O planes in 2-4-7 and possible origin for the high Tc value of this compound; and (5) The possibility to describe NMR data in the framework of a charge-excitation picture.
Brinkmann, D.↗
Pressure Broadening and Pressure Shift Coefficients in the 2nu(sup 0, sub 2) and nu(sub 1) Bands of (16)O(13)C(18)O
In this study we report the first measurements of the pressure broadening and the pressure-induced line shift coefficients due to air and nitrogen for 93 individual rovibrational lines, P(46) to R(46) and P(50) to R(45), respectively, belonging to the 2nu(sup 0, sub 2) and nu(sub 1) bands of (16)O(13)C(18)O. The results were obtained by analyzing ten long path, high-resolution laboratory, absorption spectra using a multispectrum nonlinear least-squares technique. Broadening due to nitrogen was about 4% larger than by air. Similar to broadening coefficients, the pressure-shift coefficients were found to be transition dependent, but different for the P- and R-branch lines with the same rotational quantum number, J. Except for a few R-branch lines, the measured shift coefficients were negative. The shift coefficients varied from + 4 x 10(exp -3)/cm.atm at 296 K to -5.6 x 10(exp -3)/cm.atm at 296 K. Comparisons of the broadening and shift coefficients between the two bands, between the P and R branches, and between the two broadening gases are reported. No significant difference between shift coefficients of the two bands or the two broadening gases was observed. The results obtained were compared with those reported in the literature for the more abundant (12)C(16)O2 species.
Devi, V. Malathy↗