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Probing the Sustainable Reduction of CO 2 , N 2 and NO 3 to Fuels and Chemicals using Non-Traditional Porphyrinoid Catalysts

For the last several decades, numerous strategies have been proposed to be able to interconvert electricity and commodity fuels for transportation and other applications. Even as solar and wind energy become more widely available, these renewable energy sources are not always available where the population is most dense or during peak times of energy demand. One plausible solution to the issue of electricity storage and transport is to use electricity to drive the formation of high-energy compounds and chemical fuels. As a result, the electrochemical conversion of CO 2 into chemical fuels has received major attention as a multi-pronged approach for electricity coversion, storage, and transport. Similar strategies are also attractive for conversion of N 2 and NO x into value added compounds such as ammonia. Metalloporphyrin and metallocorrole complexes are comprised of aromatic tetrapyrrole scaffolds and have been extensively studied as homogeneous catalysts for critical catalytic processes like the electrochemical CO 2 reduction reaction (eCO 2 RR) to generate CO as feedstock for the Fischer–Tropsch process to generate a variety of hydrocarbons as chemical fuels. Despite their significance and impact, efficiently driving such catalytic reduction processes is challenging for multiple reasons. Such processes require multiple-electron transfer events, as opposed to single-electron redox chemistry that forms high-energy singly-reduced intermediates. In addition, these electron transfer events must be coupled to proton-transfer steps and avoid application of high overpotentials where proton (H + ) reduction to generate H 2 (as well as other side-reactions) can lower the selectivity and energy efficiency of the eCO 2 RR process. Certain Fe(III) aromatic tetrapyrroles (e.g., porphyrins and corroles) have been reported to overcome these challenges, but are often difficult to synthesize and modify, and have a tendency to support single-electron redox chemistry at the metal as opposed to multielectron redox involving the ligand and metal in concert. Other families of tetrapyrroles in which all four meso-carbons are reduced (i.e., sp 3 -hybridized) are also known in the literature. These non-aromatic tetrapyrroles are known as porphyrinogens and support multi-electron redox chemistry which has been elaborated by several groups, prompting researchers to consider whether these scaffolds may improve the kinetics and efficiencies of multi-electron steps attendant to activation of thermodynamically stable small-molecule substrates such as CO 2 , N 2 , NO 3 − , and NO 2 − . Although porphyrinogens support multi-electron redox properties, the four sp 3 -hybridized meso-carbons inherent to the tetrapyrrole core completely disrupt π-conjugation between pyrrolic units, which compromises the photochemical properties of porphyrinogens in comparison to that of traditional porphyrinoids. Moreover, the highly reducing nature of porphyrinogens predisposes these platforms to extreme air and water sensitivity. Accordingly, such metalated porphyrinogens are often pyrophoric and/or incompatible with many common organic solvents (CH 2 Cl 2 , CHCl 3 , CH 3 CN, EtOAc, etc.). Hence, reports of efficient small-molecule activation or catalysis supported by porphyrinogens have been limited. To overcome the instability of porphyrinogens while retaining the scaffold’s attractive multi-electron redox properties, we have directed attention to establishing less-well studied groups of non-aromatic tetrapyrroles (i.e., phlorins, biladienes, and isocorroles). These non-traditional tetrapyrroles each contain just a single sp 3 -hybridized meso-carbon, which ablates the platforms aromaticity but still provides an extended π-framework. In addition to developing innovative platforms that may be used to sustainably generate value-added chemicals, fuels, and ammonia via either photo- or electrocatalytic approaches our work also has significantly broadened our understanding of how to prepare and modulate the properties of non-aromatic tetrapyrroles for other applications. Our efforts entailed a synergistic partnership and active collaborations with Drs. David C. Grills and Mehmed Z. Ertem (both of Brookhaven National Lab) to better characterize isocorroles (and related non-aromatic tetrapyrroles) using a variety of advanced spectroscopic and theoretical methods. Our combined efforts have shown that the combination of properties that isocorroles (and related tetrapyrroles) provide results in good chemical stability paired with unique redox and photochemical characteristics that are not typically supported by simple and/or unadorned aromatic tetrapyrroles. Beside redox chemistry, the photochemistry of isocorroles and other non-aromatic tetrapyrroles containing one sp 3 -hybridized meso-carbon is also appealing due to their absorption in the long-visible to near-IR regions, which are essential for photocatalysis and related applications that benefit from direct excitation at these wavelengths. The results reported vastly improve our understanding of non-aromatic tetrapyrrole synthesis, properties and utility for activation of small molecule substrates such as O 2 and CO 2 in the presence of weak cationic organic acids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Using the Baryonic Tully–Fisher Relation to Measure H{sub o}

We explore the use of the baryonic Tully–Fisher relation (bTFR) as a new distance indicator. Advances in near-IR imaging and stellar population models, plus precise rotation curves, have reduced the scatter in the bTFR such that distance is the dominant source of uncertainty. Using 50 galaxies with accurate distances from Cepheids or the tip magnitude of the red giant branch, we calibrate the bTFR on a scale independent of H {sub o}. We then apply this calibrated bTFR to 95 independent galaxies from the SPARC sample, using CosmicFlows-3 velocities, to deduce the local value of H {sub o}. We find H {sub o} = 75.1 ± 2.3 (stat) ±1.5 (sys) km s{sup −1} Mpc{sup −1}.

79 ASTRONOMY AND ASTROPHYSICS↗

The Hubble Space Telescope's Near-UV and Optical Transmission Spectrum of Earth as an Exoplanet

We observed the 2019 January total lunar eclipse with the Hubble Space Telescope’s STIS spectrograph to obtain the first near-UV (1700–3200 Å) observation of Earth as a transiting exoplanet. The observatories and instruments that will be able to perform transmission spectroscopy of exo-Earths are beginning to be planned, and characterizing the transmission spectrum of Earth is vital to ensuring that key spectral features (e.g., ozone, or O{sub 3}) are appropriately captured in mission concept studies. O{sub 3} is photochemically produced from O{sub 2}, a product of the dominant metabolism on Earth today, and it will be sought in future observations as critical evidence for life on exoplanets. Ground-based observations of lunar eclipses have provided the Earth’s transmission spectrum at optical and near-IR wavelengths, but the strongest O{sub 3} signatures are in the near-UV. We describe the observations and methods used to extract a transmission spectrum from Hubble lunar eclipse spectra, and identify spectral features of O{sub 3} and Rayleigh scattering in the 3000–5500 Å region in Earth’s transmission spectrum by comparing to Earth models that include refraction effects in the terrestrial atmosphere during a lunar eclipse. Our near-UV spectra are featureless, a consequence of missing the narrow time span during the eclipse when near-UV sunlight is not completely attenuated through Earth’s atmosphere due to extremely strong O{sub 3} absorption and when sunlight is transmitted to the lunar surface at altitudes where it passes through the O{sub 3} layer rather than above it.

79 ASTRONOMY AND ASTROPHYSICS↗

Discovery of a Nearby Young Brown Dwarf Disk

We report the discovery of the youngest brown dwarf with a disk at 102 pc from the Sun, WISEA J120037.79−784508.3 (W1200−7845), via the Disk Detective citizen science project. We establish that W1200−7845 is located in the 3.7{sub −1.4}{sup +4.6} Myr old ε Cha association. Its spectral energy distribution (SED) exhibits clear evidence of an infrared (IR) excess, indicative of the presence of a warm circumstellar disk. Modeling this warm disk, we find the data are best fit using a power-law description with a slope α = −0.94, which suggests that it is a young, Class II type disk. Using a single blackbody disk fit, we find T{sub eff,disk}=521 K and L{sub IR}/L{sub ∗}=0.14. The near-IR spectrum of W1200−7845 matches a spectral type of M6.0 γ ± 0.5, which corresponds to a low surface gravity object, and lacks distinctive signatures of strong Paβ or Brγ accretion. Both our SED fitting and spectral analysis indicate that the source is cool (T {sub eff} = 2784–2850 K), with a mass of 42–58 M {sub Jup}, well within the brown dwarf regime. The proximity of this young brown dwarf disk makes the system an ideal benchmark for investigating the formation and early evolution of brown dwarfs.

79 ASTRONOMY AND ASTROPHYSICS↗

ACCESS: Confirmation of No Potassium in the Atmosphere of WASP-31b

We present a new optical (400–950 nm) transmission spectrum of the hot Jupiter WASP-31b (M = 0.48 M {sub J}; R = 1.54 R {sub J}; P = 3.41 days), obtained by combining four transit observations. These transits were observed with IMACS on the Magellan Baade Telescope at Las Campanas Observatory as part of the ACCESS project. We investigate the presence of clouds/hazes in the upper atmosphere of this planet, as well as the contribution of stellar activity on the observed features. In addition, we search for absorption features of the alkali elements Na i and K i, with particular focus on K i, for which there have been two previously published disagreeing results. Observations with Hubble Space Telescope (HST)/STIS detected K i, whereas ground-based low- and high-resolution observations did not. We use equilibrium and nonequilibrium chemistry retrievals to explore the planetary and stellar parameter space of the system with our optical data combined with existing near-IR observations. Our best-fit model is that with a scattering slope consistent with a Rayleigh slope (α=5.3{sub −3.1}{sup +2.9}), high-altitude clouds at a log cloud top pressure of −3.6{sub −2.1}{sup +2.7} bars, and possible muted H{sub 2}O features. We find that our observations support other ground-based claims of no K i. Clouds are likely why signals like H{sub 2}O are extremely muted and Na or K cannot be detected. We then juxtapose our Magellan/IMACS transmission spectrum with existing VLT/FORS2, HST/WFC3, HST/STIS, and Spitzer observations to further constrain the optical-to-infrared atmospheric features of the planet. We find that a steeper scattering slope (α = 8.3 ± 1.5) is anchored by STIS wavelengths blueward of 400 nm and only the original STIS observations show significant potassium signal.

79 ASTRONOMY AND ASTROPHYSICS↗

A Search for Polarized Thermal Emission from Directly Imaged Exoplanets and Brown Dwarf Companions to Nearby Stars

Aerosols in the atmospheres of cloudy gas giant exoplanets and brown dwarfs scatter and polarize these objects’ thermal emission. If such an object has an oblate shape or nonuniform cloud distribution, the net degree of linear polarization can show an increase ranging from several tenths of a percent to a few percent. Modern high-contrast imaging polarimeters are now poised to detect such low-polarization signals, opening up a new window into the rotational velocities and cloud properties of substellar companions to nearby stars. In this paper, we present the results of a near-IR survey searching for linearly polarized thermal emission from a sample of two planetary-mass companions and five brown dwarf companions using GPI and SPHERE-IRDIS. We probe the subpercent linear polarization regime that typifies polarized free-floating brown dwarfs and place limits on each object’s degree of linear polarization. We relate our upper limits on each target’s degree of linear polarization to its rotation rate, and place our results in the context of rotation rates measured using high-resolution spectroscopy.

79 ASTRONOMY AND ASTROPHYSICS↗

A Differential Measurement of Circumstellar Extinction for AA Tau’s 2011 Dimming Event

AA Tau is a classical T Tauri star with a highly inclined, warped circumstellar disk. For decades, AA Tau exhibited photometric and spectroscopic variabilities that were successfully modeled as occultations of the primary star by circumstellar material. In 2011, AA Tau entered an extended faint state, presumably due to enhanced levels of circumstellar dust. We use two sets of contemporaneous optical–near-IR (NIR) spectra of AA Tau, obtained in 2008 and 2014 December, to directly measure the wavelength-dependent extinction associated with the dust enhancement driving AA Tau’s 2011 optical fade. Taken alone, AA Tau’s apparent optical–NIR increased extinction curve cannot be fit well with standard extinction laws. At optical wavelengths, AA Tau’s dimming event is consistent with predictions of common extinction models for an increase of A {sub V} = 2, but no such model reproduces AA Tau’s color–color excess at NIR wavelengths. We show that veiling emission accounts for the apparent anomalous NIR extinction: after including this veiling flux, AA Tau’s dimming event is consistent with a standard A {sub V} = 2 extinction law across the full optical–NIR range. We also report an increase in AA Tau’s mid-IR flux since its 2011 fade and suggest that an increase in the height of AA Tau’s inner disk is the most likely explanation for both the IR brightening and the additional extinction along the line of sight. In addition to informing our understanding of AA Tau, this analysis demonstrates that caution should be exercised when inferring extinction (and stellar parameters) from the NIR color–color excess of young stars with measurable NIR veiling fluxes.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The Red Supergiant Content of M31 and M33

We identify red supergiants (RSGs) in our spiral neighbors M31 and M33 using near-IR (NIR) photometry complete to a luminosity limit of logL/L{sub ⊙}=4.0. Our archival survey data cover 5 deg{sup 2} of M31, and 3 deg{sup 2} for M33, and are likely spatially complete for these massive stars. Gaia is used to remove foreground stars, after which the RSGs can be separated from asymptotic giant branch (AGB) stars in the color–magnitude diagram. The photometry is used to derive effective temperatures and bolometric luminosities via MARCS stellar atmosphere models. The resulting H-R diagrams show superb agreement with the evolutionary tracks of the Geneva evolutionary group. Our census includes 6400 RSGs in M31 and 2850 RSGs in M33 within their Holmberg radii; by contrast, only a few hundred RSGs are known so far in the Milky Way. Our catalog serves as the basis for a study of the RSG binary frequency being published separately, as well as future studies relating to the evolution of massive stars. Here we use the matches between the NIR-selected RSGs and their optical counterparts to show that the apparent similarity in the reddening of OB stars in M31 and M33 is the result of Malmquist bias; the average extinction in M31 is likely higher than that of M33. As expected, the distribution of RSGs follows that of the spiral arms, while the much older AGB population is more uniformly spread across each galaxy’s disk.

47 OTHER INSTRUMENTATION↗

Hunting for Planetary Nebulae toward the Galactic Center

We present near-infrared (IR) spectra of two planetary nebula (PN) candidates in close lines of sight toward the Galactic center (GC) using the Gemini Near-Infrared Spectrograph at Gemini North. High-resolution images from radio continuum and narrowband IR observations reveal ringlike or barrel-shaped morphologies of these objects, and their mid-IR spectra from the Spitzer Space Telescope exhibit rich emission lines from highly-excited species such as [S iv], [Ne iii], [Ne v], and [O iv]. We also derive elemental abundances using the Cloudy synthetic models, and find an excess amount of the s-process element krypton in both targets, which supports their nature as PNe. We estimate foreground extinction toward each object using near-IR hydrogen recombination lines, and find significant visual extinctions (A {sub V} > 20). The distances inferred from the size versus surface brightness relation of other PNe are 9.0 ± 1.6 kpc and 7.6 ± 1.6 kpc for SSTGC 580183 and SSTGC 588220, respectively. These observed properties along with the abundance patterns and close proximity to Sgr A* (projected distances ≲20 pc) make it highly probable that these objects are the first confirmed PN objects in the nuclear stellar disk. The apparent scarcity of such objects resembles the extremely low rate of PN formation in old stellar systems, but is in line with the current rate of sustained star formation activity in the Central Molecular Zone.

47 OTHER INSTRUMENTATION↗

The Stability of Fiber Spectrographs in the Faint-source Regime

The use of optical fibers in astronomical instrumentation offers high-multiplex and light-gathering flexibility. However, with most previous fiber spectrographs optimized for large fields of view on modest-aperture telescopes, the performance of fibers in the context of faint targets on large telescopes remains largely untested. In this paper, we evaluate aspects of fiber stability, especially as they apply in the context of precision sky subtraction of faint sources at modest spectral resolution ($R$ ~ 3000). After introducing a framework for describing potential systematic errors, we use publicly available data from existing instruments, including instrumentation used by the fourth-generation Sloan Digital Sky Survey’s MaNGA project (MaNGA: Mapping Nearby Galaxies at Apache Point Observatory) and the Very Large Telescope’s FLAMES: Fiber Large Array Multi Element Spectrograph. We isolate sources of fiber systematics and estimate the observed amplitude of persistent residuals as well as stochastic noise contributions resulting from changing fiber stresses. Comparing these levels against their impact on various sky subtraction schemes demonstrates that 0.1% precision sky subtraction with fiber instruments is possible. As a demonstration, we show that the MaNGA instrument can deliver 0.2% residuals on bright near-IR sky lines with nonlocal sky subtraction, if pseudo-slit limitations are addressed by allocating 50% of its fibers to sky. We further highlight recently published deep exposures that achieved a 1$σ$ background level of 27.6 AB per square arc second, equivalent to a precision of 0.2% of the sky background continuum.

79 ASTRONOMY AND ASTROPHYSICS↗

Cloud Atlas: Unraveling the Vertical Cloud Structure with the Time-series Spectrophotometry of an Unusually Red Brown Dwarf

Rotational modulations of emission spectra in brown dwarf and exoplanet atmospheres show that clouds are often distributed non-uniformly in these ultracool atmospheres. The spatial heterogeneity in cloud distribution demonstrates the impact of atmospheric dynamics on cloud formation and evolution. In this study, we update the Hubble Space Telescope (HST) time-series data analysis of the previously reported rotational modulations of WISEP J004701+680352—an unusually red late-L brown dwarf with a spectrum similar to that of the directly imaged planet HR 8799e. We construct a self-consistent spatially heterogeneous cloud model to explain the HST and the Spitzer time-series observations, as well as the time-averaged spectra of WISE 0047. Additionally, in the heterogeneous cloud model, a cloud thickness variation of around one pressure scale height explains the wavelength dependence in the HST near-IR spectral variability. By including disequilibrium CO/CH 4 chemistry, our models also reproduce the redder $J-{K}_{{\rm{s}}}$ color of WISE 0047 compared to that of field brown dwarfs. We discuss the impact of vertical cloud structure on atmospheric profile and estimate the minimum eddy diffusivity coefficient for other objects with redder colors. Our data analysis and forward modeling results demonstrate that time-series spectrophotometry with a broad wavelength coverage is a powerful tool for constraining heterogeneous atmospheric structure.

79 ASTRONOMY AND ASTROPHYSICS↗

The High Latitude Spectroscopic Survey on the Nancy Grace Roman Space Telescope

The Nancy Grace Roman Space Telescope will conduct a High Latitude Spectroscopic Survey (HLSS) over a large volume at high redshift, using the near-IR grism (1.0–1.93 μm, R = 435–865) and the 0.28 deg 2 wide-field camera. We present a reference HLSS that maps 2000 deg 2 and achieves an emission-line flux limit of 10 -16 erg s -1 cm -2 at 6.5σ, requiring ~0.6 yr of observing time. We summarize the flowdown of the Roman science objectives to the science and technical requirements of the HLSS. We construct a mock redshift survey over the full HLSS volume by applying a semianalytic galaxy formation model to a cosmological N-body simulation and use this mock survey to create pixel-level simulations of 4 deg 2 of HLSS grism spectroscopy. We find that the reference HLSS would measure ~10 million H α galaxy redshifts that densely map large-scale structure at z = 1–2 and 2 million [O III] galaxy redshifts that sparsely map structures at z = 2–3. We forecast the performance of this survey for measurements of the cosmic expansion history with baryon acoustic oscillations and the growth of large-scale structure with redshift-space distortions. We also study possible deviations from the reference design and find that a deep HLSS at f line > 7 × 10 -17 erg s -1 cm -2 over 4000 deg 2 (requiring ~1.5 yr of observing time) provides the most compelling stand-alone constraints on dark energy from Roman alone. This provides a useful reference for future optimizations. The reference survey, simulated data sets, and forecasts presented here will inform community decisions on the final scope and design of the Roman HLSS.

79 ASTRONOMY AND ASTROPHYSICS↗

A Quasar Shedding Its Dust Cocoon at Redshift 2

We present the first near-IR spectroscopy and joint analyses of multiwavelength observations for SDSS J082747.14+425241.1, a dust-reddened, weak broad emission-line quasar (WLQ) undergoing a remarkable broad-absorption line (BAL) transformation. The systemic redshift is more precisely measured to be z = 2.070 ± 0.001 using Hβ compared to z = 2.040 ± 0.003 using Mg ιι from the literature, signifying an extreme Mg ιι blueshift of 2140 ± 530 km s –1 relative to Hβ. Using the Hβ-based single-epoch scaling relation with a systematic uncertainty of 0.3 dex, its black hole (BH) mass and Eddington ratio are estimated to be M BH ~ 6.1 × 10 8 M ⊙ and λ Edd ~ 0.71, indicative of being in a rapidly accreting phase. Our investigations confirm the WLQ nature and the LoBAL → HiBAL transformation, along with a factor of 2 increase in the Mg ιι+Fe ιι emission strength and a decrease of 0.1 in E(B – V) over two decades. The kinetic power of this LoBAL wind at R ~ 15 pc from its BH is estimated to be ~43% of the Eddington luminosity, sufficient for quasar feedback upon its host galaxy albeit with an order-of-magnitude uncertainty. This quasar provides a clear example of the long-sought scenario where LoBAL quasars are surrounded by dust cocoons, and wide-angle nuclear winds play a key role in the transition of red quasars evolving into the commonly seen blue quasars.

79 ASTRONOMY AND ASTROPHYSICS↗

Modeling the Spectral Energy Distribution of the Active Galactic Nucleus inside NGC 4395

We study the broadband spectral energy distribution (SED) of the prototypical low-mass active galactic nucleus (AGN) in NGC 4395. We jointly model the optical through mid-IR SED with a combination of galaxy and AGN light, and find that on arcsecond scales the AGN dominates at most wavelengths. However, there is still some ambiguity about emission from the galaxy, owing partially to the strong short-term variability of the black hole. We investigate the use of smooth- and clumpy-torus models in order to disentangle the nuclear IR emission, as well as exploring the use of poloidal wind emission to account for the blue spectral slope observed in the near-IR. Even when simultaneously fitting the full optical–IR spectral range, we find that degeneracies still remain in the best-fit models. We conclude that high-spatial-resolution and wider-wavelength coverage with the JWST is needed to understand the mid-IR emission in this complex, highly variable object, which is the best nearby example to provide a blueprint to finding other low-mass AGNs via their mid-IR emission in the future.

79 ASTRONOMY AND ASTROPHYSICS↗

Optical Photometric Indicators of Galaxy Cluster Relaxation

Abstract The most dynamically relaxed clusters of galaxies play a special role in cosmological studies as well as astrophysical studies of the intracluster medium (ICM) and active galactic nucleus feedback. While high-spatial-resolution imaging of the morphology of the ICM has long been the gold standard for establishing a cluster’s dynamical state, such data are not available from current or planned surveys, and thus require separate, pointed follow-up observations. With optical and/or near-IR photometric imaging, and red-sequence cluster finding results from those data, expected to be ubiquitously available for clusters discovered in upcoming optical and millimeter-wavelength surveys, it is worth asking how effectively photometric data alone can identify relaxed cluster candidates, before investing in, e.g., high-resolution X-ray observations. Here we assess the ability of several simple photometric measurements, based on the redMaPPer cluster finder run on Sloan Digital Sky Survey data, to reproduce X-ray classifications of dynamical state for an X-ray selected sample of massive clusters. We find that two simple metrics contrasting the bright central galaxy (BCG) to other cluster members can identify a complete sample of relaxed clusters with a purity of ∼40% in our data set. Including minimal ICM information in the form of a center position increases the purity to ∼60%. However, all three metrics depend critically on correctly identifying the BCG, which is presently a challenge for optical red-sequence cluster finders.

79 ASTRONOMY AND ASTROPHYSICS↗

Using Gravitational Lensing to Probe for Candidate Quintessential Galaxies in the Epoch of Reionization

Abstract Understanding the properties of the first generation of galaxies is an ongoing challenge in observational astrophysics. James Webb Space Telescope deep-field observations have led to the identification of large numbers of galaxies within the Epoch of Reionization (EoR); however, it remains observationally challenging to study the detailed properties of the most numerous, faint high- z galaxies without strong gravitational lensing. To this end, we present five m AB ≃ 24 galaxies, all projected behind the cores of massive clusters where high lensing magnifications significantly (≳1.5 mag) boost their observed brightness. These galaxies are each characterized by a drop-off in their spectra between the near-IR and optical wavelengths, suggesting the presence of a Lyman break at z > 6. The bright sources enable precise dropout color constraints. We combine the dropout data with follow-up imaging to constrain continuum slopes redward of their breaks. Using the open-source spectral energy distribution modeling software Prospector , we characterize two of these galaxies as probable high- z ( z ∼ 6.5–7) and three as probable low- z ( z ∼ 2) sources, demonstrating that for very bright ( m AB < 24) dropout candidates even limited photometric data have good power to distinguish between high- z galaxies and red or dusty low- z galaxies. The two candidate high- z dropouts are comparably bright to the brightest galaxies identified at such redshifts in deep fields, but due to lensing magnifications are intrinsically fainter by at least 1.5 mag. If confirmed, these galaxies represent exciting laboratories for performing detailed follow-up studies of galaxy properties within the EoR.

Roberson, Joshua [University of Cincinnati] (ORCID↗

Infrared Galaxies Detected by the Atacama Cosmology Telescope

We report on 167 infrared (IR) galaxies selected by AKARI and IRAS and detected in the Atacama Cosmology Telescope (ACT) Data Release 5 (DR5) sky maps at the 98, 150, and 220 GHz frequency bands. Of these detections, 134 (80%) of the millimeter counterparts are first-time identifications with ACT. We expand the previous ACT extragalactic source catalogs, by including new 98 GHz detections and measurements from ACT DR5. We also report flux density measurements at the 98, 150, and 220 GHz frequency bands. We compute α 98-150 , α 98-220 , and α 150-220 millimeter-wave spectral indices and far-IR to millimeter-wave spectral indices between 90 μm and 98, 150, and 220 GHz. We specify the galaxy type, based on α 150-220 . We combine publicly available multiwavelength data—including ultraviolet, optical, near-IR, mid-IR, far-IR, and the millimeter measurements obtained in this work—and perform spectral energy distribution (SED) fitting with CIGALE. With the radio emission decomposition advantage of CIGALE V2022.0, we identify the origins of the millimeter emissions for 69 galaxies in our sample. Our analysis also shows that millimeter data alone indicates the need for a radio synchrotron component in the SEDs that are produced by active galactic nuclei (AGNs) and/or star formation. We present SEDs and measured physical properties of these galaxies, such as the dust luminosity, AGN luminosity, the total IR luminosity, and the ratio of the IR and radio luminosity. We quantify the relationships between the total IR luminosity and the millimeter-band luminosities, which can be used in the absence of SED analysis.

79 ASTRONOMY AND ASTROPHYSICS↗

Multiwavelength Bulge–Disk Decomposition for the Galaxy M81 (NGC 3031). I. Morphology

A panchromatic investigation of morphology for the early-type spiral galaxy M81 is presented in this paper. We perform bulge–disk decomposition in M81 images at a total of 20 wave bands from far-UV to near-IR (NIR) obtained with GALEX, Swift, Sloan Digital Sky Survey, WIYN, Two Micron All Sky Survey, Wide-field Infrared Survey Explorer, and Spitzer. Morphological parameters such as Sérsic index, effective radius, position angle, and axis ratio for the bulge and the disk are thus derived at all of the wave bands, which enables quantifying the morphological K -correction for M81 and makes it possible to reproduce images for the bulge and the disk in the galaxy at any wave band. The morphology as a function of wavelength appears as a variable-slope trend of the Sérsic index and the effective radius, in which the variations are steep at UV–optical and shallow at optical–NIR bands; the position angle and the axis ratio keep invariable at least at optical–NIR bands. It is worth noting that the Sérsic index for the bulge reaches ~4–5 at optical and NIR bands, but drops to ~1 at UV bands. This difference brings forward a caveat that a classical bulge is likely misidentified for a pseudobulge or no bulge at high redshifts where galaxies are observed through rest-frame UV channels with optical telescopes. The next work of this series is planned to study spatially resolved spectral energy distributions for the bulge and the disk, respectively, and thereby explore stellar population properties and star formation/quenching history for the galaxy composed of the subsystems.

79 ASTRONOMY AND ASTROPHYSICS↗