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At least 73 records · Page 4

Water Misting and Injection of Commercial Aircraft Engines to Reduce Airport NOx

This report provides the first high level look at system design, airplane performance, maintenance, and cost implications of using water misting and water injection technology in aircraft engines for takeoff and climb-out NOx emissions reduction. With an engine compressor inlet water misting rate of 2.2 percent water-to-air ratio, a 47 percent NOx reduction was calculated. Combustor water injection could achieve greater reductions of about 85 percent, but with some performance penalties. For the water misting system on days above 59 F, a fuel efficiency benefit of about 3.5 percent would be experienced. Reductions of up to 436 F in turbine inlet temperature were also estimated, which could lead to increased hot section life. A 0.61 db noise reduction will occur. A nominal airplane weight penalty of less than 360 lb (no water) was estimated for a 305 passenger airplane. The airplane system cost is initially estimated at $40.92 per takeoff giving an attractive NOx emissions reduction cost/benefit ratio of about $1,663/ton.

Daggett, David L.↗

The plasma membrane-associated NADH oxidase (ECTO-NOX) of mouse skin responds to blue light

NADH oxidases of the external plasma membrane surface (ECTO-NOX proteins) are characterized by oscillations in activity with a regular period length of 24 min. Explants of mouse skin exhibit the oscillatory activity as estimated from the decrease in A(340) suggesting that individual ECTO-NOX molecules must somehow be induced to function synchronously. Transfer of explants of mouse skin from darkness to blue light (495 nm, 2 min, 50 micromol m(-1) s(-1)) resulted in initiation of a new activity maximum (entrainment) with a midpoint 36 min after light exposure followed by maxima every 24 min thereafter. Addition of melatonin resulted in a new maximum 24 min after melatonin addition. The findings suggest that the ECTO-NOX proteins play a central role in the entrainment of the biological clock both by light and by melatonin.

NASA Discipline Cell Biology↗

Preferential inhibition of the plasma membrane NADH oxidase (NOX) activity by diphenyleneiodonium chloride with NADPH as donor

The cell-surface NADH oxidase (NOX) protein of plant and animal cells will utilize both NADH and NADPH as reduced electron donors for activity. The two activities are distinguished by a differential inhibition by the redox inhibitor diphenyleneiodonium chloride (DPI). Using both plasma membranes and cells, activity with NADPH as donor was markedly inhibited by DPI at submicromolar concentrations, whereas with NADH as donor, DPI was much less effective or had no effect on the activity. The possibility of the inhibition being the result of two different enzymes was eliminated by the use of a recombinant NOX protein. The findings support the concept that NOX proteins serve as terminal oxidases for plasma membrane electron transport involving cytosolic reduced pyridine nucleotides as the natural electron donors and with molecular oxygen as the electron acceptor.

Non-NASA Center↗

Midlatitude Lightning NOx Production Efficiency Inferred From OMI and WWLLN Data

Oxides of nitrogen are critical trace gases in the troposphere and are precursors for nitrate aerosol and ozone, which is an important pollutant and greenhouse gas. Lightning is the major source of NOx(NO + NO2) in the mid-to upper troposphere. We estimate the production efficiency (PE) of lightning NOx (LNOx) using satellite data from the Ozone Monitoring Instrument (OMI) and the ground-based WorldWide Lightning Location Network (WWLLN) in three northern midlatitude, primarily continental regions that include much of North America, Europe and East Asia. Data were obtained over 5 boreal summers, 2007 –2011 and comprise the largest number of midlatitude convective events to date for estimating the LNOx PE with satellite NO2and ground-based lightning measurements. In contrast to some previous studies, the algorithm assumes no minimum flash-rate threshold and estimates freshly produced LNOxby subtracting a background of aged NOx estimated from the OMI dataset itself. We infer an average value of 180 ± 100 moles LNOx produced per lightning flash. We also show evidence of a dependence of PE on lightning flash rate and find an approximate empirical power function relating moles LNOxto flashes. PE decreases by an order of magnitude for a 2-order of magnitude increase in flash rate. This phenomenon has not been reported in previous satellite LNOxstudies but is consistent with ground-based observations suggesting an inverse relationship between flash rate and size.

LNOx↗

Tropospheric Ozone in the NASA GEOS Model: Effects of Satellite NO2 Data Assimilation and Improvements in Background NOx Chemistry

Tropospheric ozone is a major atmospheric oxidant, the primary source of the hydroxyl radical, and a greenhouse gas. In the troposphere, it is produced from the oxidation of carbon monoxide and volatile organic compounds in the presence of nitrogen oxides (NOx=NO+NO2) or has its origins in the stratosphere. The tropospheric ozone burdens in global atmospheric chemistry models disagree by a factor of 1.5, indicating an incomplete understanding of ozone sources and sinks. Here we examine the tropospheric ozone simulation in NASA Global Modeling and Assimilation Office’s (GMAO’s) GEOS model with the GEOS-Chem chemistry mechanism (version 14.2), using observations from satellites, aircraft, ozonesondes, and surface sites. This modeling framework is used to produce GMAO’s GEOS Composition Forecasts (GEOS-CF), and it has been updated extensively with new emission inventories, improved model physics, satellite data assimilation capability, and an up-to-date chemical mechanism that includes tropospheric halogen chemistry and NOx recycling from particulate nitrate. Earlier versions of the model using GEOS-Chem version 12.0 showed an underestimate in tropospheric ozone in the northern hemisphere. We evaluate the ozone simulation in the updated model, focusing on the effects of assimilating satellite NO2 data from the Ozone Monitoring Instrument (OMI), constraining stratospheric ozone to satellite data, and updates to the NOx chemistry. We will examine changes in the vertical profiles of tropospheric ozone over the US in support of the Tropospheric Emissions: Monitoring of Pollution (TEMPO), and discuss implications for the tropospheric ozone budget.

V. Shah↗

NO, NO2. NOx measurements; SGP GIF; April 2022

This file contains measurements of nitric oxide (NO), nitrogen dioxide (NO2), and nitrogen oxides (NOx = NO + NO1). Measurements were made using a Teledyne NO-NOx Analyzer Model T200UP. Zeros were conducted daily and calibrations were completed at the end of the campaign. The instrument was located at the Atmospheric Radiation Measurement Southern Great Plains Guest Instrumentation Facility and measured from April 9, 2022 to May 6, 2022. The file is in ICARTT format.

54 ENVIRONMENTAL SCIENCES↗

SCILLA nitrogen oxide (NOx) airborne data

Nitrogen oxides mixing ratios in ppb are measured using a Teledyne API Model T200UP. The analyzer uses chemiluminescence to determine NO concentration. Alternating measurement of the concentrations of total NOx (NO + NO2) and just NO are made by directing the sample through a blue light converter that photolyzes NO2 to NO and bypassing it, respectively, with the NO2 concentration calculated as the difference between the two. Sampled air was pulled from above the Naval Postgraduate School’s (NPS) Twin Otter aircraft through a rear-facing, ¼” OD PFA Teflon tube. The sample stream was split between several other gas analyzers (CO, O3, and H2O) and an oxidation flow reactor. The NO, NO2, and NOx mixing ratios were recorded once per minute.

NOx concentration↗

Estimates of Power Plant NOx Emissions and Lifetimes from OMI NO2 Satellite Retrievals

Isolated power plants with well characterized emissions serve as an ideal test case of methods to estimate emissions using satellite data. In this study we evaluate the Exponentially-Modified Gaussian (EMG) method and the box model method based on mass balance for estimating known NOx emissions from satellite retrievals made by the Ozone Monitoring Instrument (OMI). We consider 29 power plants in the USA which have large NOx plumes that do not overlap with other sources and which have emissions data from the Continuous Emission Monitoring System (CEMS). This enables us to identify constraints required by the methods, such as which wind data to use and how to calculate background values. We found that the lifetimes estimated by the methods are too short to be representative of the chemical lifetime. Instead, we introduce a separate lifetime parameter to account for the discrepancy between estimates using real data and those that theory would predict. In terms of emissions, the EMG method required averages from multiple years to give accurate results, whereas the box model method gave accurate results for individual ozone seasons.

Emissions inventory↗

NO, NO2. NOx measurements; SGP GIF; May 2023

This file contains measurements of nitric oxide (NO), nitrogen dioxide (NO2), and nitrogen oxides (NOx = NO + NO2). Measurements were made using a Teledyne NO-NOx Analyzer Model T200UP. Zeros were conducted daily and calibrations were completed at the end of the campaign. The instrument was located at the Atmospheric Radiation Measurement Southern Great Plains Guest Instrumentation Facility and measured from April 30, 2023 to May 31, 2023. The file is in ICARTT format.

54 ENVIRONMENTAL SCIENCES↗

NO, NO2. NOx measurements; SGP GIF; May 2023

This file contains measurements of nitric oxide (NO), nitrogen dioxide (NO2), and nitrogen oxides (NOx = NO + NO2). Measurements were made using a Teledyne NO-NOx Analyzer Model T200UP. Zeros were conducted daily and calibrations were completed at the end of the campaign. The instrument was located at the Atmospheric Radiation Measurement Southern Great Plains Guest Instrumentation Facility and measured from April 30, 2023 to May 31, 2023. The file is in ICARTT format.

54 ENVIRONMENTAL SCIENCES↗

Wide range operation of advanced low NOx aircraft gas turbine combustors

The paper summarizes the results of an experimental test rig program designed to define and demonstrates techniques which would allow the jet-induced circulation and vortex air blast combustors to operate stably with acceptable emissions at simulated engine idle without compromise to the low NOx emissions under the high-altitude supersonic cruise condition. The discussion focuses on the test results of the key combustor modifications for both the simulated engine idle and cruise conditions. Several range-augmentation techniques are demonstrated that allow the lean-reaction premixed aircraft gas turbine combustor to operate with low NOx emissons at engine cruise and acceptable CO and UHC levels at engine idle. These techniques involve several combinations, including variable geometry and fuel switching designs.

Roberts, P. B.↗

Low NOx heavy fuel combustor concept program, phase 1

Combustion tests were completed with seven concepts, including three rich/lean concepts, three lean/lean concepts, and one catalytic combustor concept. Testing was conducted with ERBS petroleum distillate, petroleum residual, and SRC-II coal-derived liquid fuels over a range of operating conditions for the 12:1 pressure ratio General Electric MS7001E heavy-duty turbine. Blends of ERBS and SRC-II fuels were used to vary fuel properties over a wide range. In addition, pyridine was added to the ERBS and residual fuels to vary nitrogen level while holding other fuel properties constant. Test results indicate that low levels of NOx and fuel-bound nitrogen conversion can be achieved with the rich/lean combustor concepts for fuels with nitrogen contents up to 1.0% by weight. Multinozzle rich/lean Concept 2 demonstrated dry low Nox emissions within 10-15% of the EPA New Source Performance Standards goals for SRC-II fuel, with yields of approximately 15%, while meeting program goals for combustion efficiency, pressure drop, and exhaust gas temperature profile. Similar, if not superior, potential was demonstrated by Concept 3, which is a promising rich/lean combustor design.

Cutrone, M. B.↗

Investigation of a low NOx full-scale annular combustor

An atmospheric test program was conducted to evaluate a low NOx annular combustor concept suitable for a supersonic, high-altitude aircraft application. The lean premixed combustor, known as the vortex air blast (VAB) concept, was tested as a 22.0-cm diameter model in the early development phases to arrive at basic design and performance criteria. Final demonstration testing was carried out on a full scale combustor of 0.66-m diameter. Variable geometry dilution ports were incorporated to allow operation of the combustor across the range of conditions between idle (T(in) = 422 K, T(out) = 917 K) and cruise (T(in) = 833 K, T(out) - 1778 K). Test results show that the design could meet the program NOx goal of 1.0 g NO2/kg fuel at a one-atmospheric simulated cruise condition.

Source record↗

NOx Emissions from a Lobed Fuel Injector/Burner

The present experimental study examines the performance of a novel fuel injector/burner configuration with respect to reduction in nitrogen oxide NOx emissions. The lobed injector/burner is a device in which very rapid initial mixing of reactants can occur through strong streamwise vorticity generation, producing high fluid mechanical strain rates which can delay ignition and thus prevent the formation of stoichiometric diffusion flames. Further downstream of the rapid mixing region. this flowfield produces a reduced effective strain rate, thus allowing ignition to occur in a premixed mode, where it is possible for combustion to take place under locally lean conditions. potentially reducing NOx emissions from the burner. The present experiments compare NO/NO2/NOx emissions from a lobed fuel injector configuration with emissions from a straight fuel injector to determine the net effect of streamwise vorticity generation. Preliminary results show that the lobed injector geometry can produce lean premixed flame structures. while for comparable flow conditions, a straight fuel injector geometry produces much longer. sooting diffusion flames or slightly rich pre-mixed flames. NO measurements show that emissions from a lobed fuel injector/burner can be made significantly lower than from a straight fuel injector under comparable flow conditions.

Mitchell, M. G.↗

Advanced Low NOx Combustors for Aircraft Gas Turbines

A test rig program was conducted with the objective of evaluating and minimizing the exhaust emissions, in particular NOx, of two advanced aircraft combustor concepts at a simulated high-altitude cruise condition. The two pre-mixed, lean-reaction designs are known as the Jet Induced Circulation (JIC) combustor and the Vortex Air Blast (VAB) combustor and were rig tested in the form of reverse flow can combustors in the 0.13 ni (5.0 in. ) size range. Various configuration modifications were applied to the JIC and VAB combustor designs in an effort to reduce the emissions levels. The VAB combustor demonstrated a NOx level of 1.11 gm NO2/kg fuel with essentially 100 percent combustion efficiency at the simulated cruise combustor condition of 507 kPa (5 atm), 833 K (1500 R), inlet pressure and temperature respectively, and 1778 K (3200 R) outlet temperature on Jet-Al fuel. These configuration screening tests were carried out on essentially reaction zones only, in order to simplify the construction and modification of the combustors and to uncouple any possible effects on the emissions produced by the dilution flow. Tests were also conducted however at typical engine idle conditions on both combustors equipped with dilution ports in order to better define the problem areas involved in the operation of such concepts over a complete engine operational envelope. Versions of variable-geometry, JIC and VAB annular combustors are proposed.

Roberts, P. B.↗

Investigation of NOx Removal from Small Engine Exhaust

Contribution of emissions from small engines to the air pollution is significant. Due to differences in operating conditions and economics, the pollution control systems designed for automobiles will be neither suitable nor economically feasible for use on small engines. The objective of this project was to find a catalyst for the removal of NOx from the exhaust of small engines which use a rich air to fuel ratio. The desired catalyst should be inexpensive so that the cost of the pollution control unit will be only a small fraction of the total equipment cost. The high cost of noble metals makes them too expensive for use as NOx catalyst for small engines. Catalytic reduction of Nitrogen Oxide (NO) can also be accomplished by base-metal oxide catalysts. The main disadvantage of base-metal catalysts is their deactivation by poisons and high temperatures. Requirements for the length of the life of the small engine exhaust catalysts are much less than those for automobile exhaust catalysts. Since there is no oxygen in the exhaust gases, reduction selectivity is not a problem. Also, the reducing exhaust gases might help prevent the harmful interactions of the catalyst with the support. For these reasons only the supported metal oxide catalysts were investigated in this project.

Akyurtlu, Ates↗

Method for the control of NOx emissions in long-range space travel

The wheat straw, an inedible biomass that can be continuously produced in a space vehicle has been used to produce activated carbon for effective control of NOx emissions from the incineration of wastes. The optimal carbonization temperature of wheat straw was found to be around 600 degrees C when a burnoff of 67% was observed. The BET surface area of the activated carbon produced from the wheat straw reached as high as 300 m2/g. The presence of oxygen in flue gas is essential for effective adsorption of NO by activated carbon. On the contrary, water vapor inhibits the adsorption efficiency of NO. Consequently, water vapor in flue gas should be removed by drying agents before adsorption to ensure high NO adsorption efficiency. All of the NO in the flue gas was removed for more than 2 h by the activated carbons when 10% oxygen was present and the ratio of carbon weight to the flue gas flow rate (W/F) was 30 g min/L, with a contact time of 10.2 s. All of NO was reduced to N2 by the activated carbon at 450 degrees C with a W/F ratio of 15 g min/L and a contact time of 5.1 s. Reduction of the adsorbed NO also regenerated the activated carbon, and the regenerated activated carbon exhibited an improved NO adsorption efficiency. However, the reduction of the adsorbed NO resulted in a loss of carbon which was determined to be about 0.99% of the activated carbon per cycle of regeneration. The sufficiency of the amount of wheat straw in providing the activated carbon based on a six-person crew, such as the mission planned for Mars, has been determined. This novel approach for the control of NOx emissions is sustainable in a closed system such as the case in space travel. It is simple to operate and is functional under microgravity environment.

NASA Discipline Life Support Systems↗

Tropospheric sources of NOx: lightning and biology

Laboratory experiments to quantify the global production of NOx (NO + NO2) in the troposphere due to atmospheric lightning and biogenic activity in soil are presented. These laboratory experiments, as well as other studies, suggest that the global production of NOx by lightning probably ranges between 2 and 20 MT(N)y-1 of NO and is strongly dependent on the total energy deposited by lightning, a quantity not well-known. In our laboratory experiments, nitrifying micro-organisms is soil were found to be a significant source of both NO and nitrous oxide (N2O). The measured production ratio of NO to N2O averaged 2-3 for oxygen partial pressures of 0.5-10%. Extrapolating these laboratory measurements to the global scale, which is somewhat risky, suggests that nitrifying micro-organisms in soil may account for as much as 10 MT(N) y-1 of NO. Additional experiments with denitrifying micro-organisms gave an NO to N2O production ratio ranging from 2 to 4 for an oxygen partial pressure of 0.5% and a ratio of less than unity for oxygen partial pressures ranging from 1 to 20%. The production of NO and N2O, normalized with respect to micro-organism number indicates that the production of both NO and N2O by denitrifying micro-organisms is at least an order of magnitude less than production by nitrifying micro-organisms for the micro-organisms studied.

Atmosphere/chemistry↗