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At least 73 records · Page 4

BioEarth: Envisioning and developing a new regional earth system model to inform natural and agricultural resource management

As managers of agricultural and natural resources are confronted with uncertainties in global change impacts, the complexities associated with the interconnected cycling of nitrogen, carbon, and water present daunting management challenges. Existing models provide detailed information on specific sub-systems (land, air, water, economics, etc). An increasing awareness of the unintended consequences of management decisions resulting from interconnectedness of these sub-systems, however, necessitates coupled regional earth system models (EaSMs). Decision makers’ needs and priorities can be integrated into the model design and development processes to enhance decision-making relevance and "usability" of EaSMs. BioEarth is a current research initiative with a focus on the U.S. Pacific Northwest region that explores the coupling of multiple stand-alone EaSMs to generate usable information for resource decision-making. Direct engagement between model developers and non-academic stakeholders involved in resource and environmental management decisions throughout the model development process is a critical component of this effort. BioEarth utilizes a "bottom-up" approach, upscaling a catchment-scale model to basin and regional scales, as opposed to the "top-down" approach of downscaling global models utilized by most other EaSM efforts. This paper describes the BioEarth initiative and highlights opportunities and challenges associated with coupling multiple stand-alone models to generate usable information for agricultural and natural resource decision-making.

agricultural↗

Methods of natural gas liquefaction and natural gas liquefaction plants utilizing multiple and varying gas streams

A method of natural gas liquefaction may include cooling a gaseous NG process stream to form a liquid NG process stream. The method may further include directing the first tail gas stream out of a plant at a first pressure and directing a second tail gas stream out of the plant at a second pressure. An additional method of natural gas liquefaction may include separating CO.sub.2 from a liquid NG process stream and processing the CO.sub.2 to provide a CO.sub.2 product stream. Another method of natural gas liquefaction may include combining a marginal gaseous NG process stream with a secondary substantially pure NG stream to provide an improved gaseous NG process stream. Additionally, a NG liquefaction plant may include a first tail gas outlet, and at least a second tail gas outlet, the at least a second tail gas outlet separate from the first tail gas outlet.

03 NATURAL GAS↗

Reference Natural Gas Flames at Nominally Autoignitive Engine-Relevant Conditions

Laminar natural gas flames are investigated at engine-relevant thermochemical conditions where the ignition delay time r is short due to very high ambient temperatures and pressures. At these conditions, it is not possible to measure or calculate well-defined values for the laminar flame speed S-l, laminar flame thickness delta(l), and laminar flame time scale tau(l) = delta(l)/S-l due to the explosive thermochemical state. Here, the corresponding reference values, S-R, delta(R), and tau(R) = S-R/S-R, that account for the effects of autoignition, are numerically estimated to investigate the enhancement of flame propagation, and the competition with autoignition that arises under nominally autoignitive conditions (characterised here by the number tau/tau(R)). Large values of tau/tau(R) indicate that autoignition is unimportant, values near or below unity indicate that flame propagation is not possible, and intermediate values indicate that a combination of both flame propagation and autoignition may be important, depending upon factors such as device geometry, turbulence, stratification, et cetera. The reference quantities are presented for a wide range of temperatures, equivalence ratios, pressures, and hydrogen concentrations, which includes conditions relevant to stationary gas turbine reheat burners and boosted spark ignition engines. It is demonstrated that the transition from flame propagation to autoignition is only dependent on residence time, when the results are non-dimensionalised by the reference values. The temporal evolution of the reference values are also reported for a modelled boosted SI engine. It is shown that the nominally autoignitive conditions enhance flame propagation, which may be an ameliorating factor for the onset of engine knock. The calculations are performed using a recently-developed, detailed 177 species mechanism for C0-C3 chemistry that is derived from theoretical chemistry and is suitable for a wide range of thermochemical conditions as it is not tuned or optimised for a particular operating condition. (C) 2018 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

autoignition↗

Temperature Dependence of Uranium and Vanadium Adsorption on Amidoxime-Based Adsorbents in Natural Seawater

Recent advances in the development of amidoxime-based adsorbents have made it highly promising for seawater uranium extraction. However, there is a great need to understand the influence of temperature on the uranium sequestration performance of the adsorbents in natural seawater. Here in this work, the apparent enthalpy and entropy of the sorption of uranium (VI) and vanadium (V) with amidoxime-based adsorbents were determined in natural seawater tests at 8, 20, and 31 °C that cover a broad range of ambient seawater temperature. The sorption of U was highly endothermic, producing apparent enthalpies of 57 ± 6.0 and 59 ± 11 kJ mol -1 and apparent entropies of 314 ± 21 and 320 ± 36 J K-1 mol -1 , respectively, for two adsorbent formulations. In contrast, the sorption of V showed a much smaller temperature sensitivity, producing apparent enthalpies of 6.1 ± 5.9 and -11 ± 5.7 kJ mol -1 and apparent entropies of 164 ± 20 and 103 ± 19 J K -1 mol -1 , respectively. This new thermodynamic information suggests that amidoxime-based adsorbents will deliver significantly increased U adsorption capacities and improved selectivity in warmer waters. A separate field study of seawater uranium adsorption conducted in a warm seawater site (Miami, FL, USA) confirm the observed strong temperature effect on seawater uranium mining. Lastly, this strong temperature dependence demonstrates that the warmer the seawater where the amidoxime-based adsorbents are deployed the greater the yield for seawater uranium extraction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Fastness Properties and Color Analysis of Natural Indigo Dye and Compatibility Study of Different Natural Reducing Agents

Conventional reduction process of indigo dyes with sodium dithionite produced lots of harmful byproducts and caused environmental pollution. A new reduction method should be introduced to textile dyer so that reduction can be less hazardous with low impact on the environment and energy resources. This study investigates an alternative reducing agent obtained from natural resources. Three different types of reducing agent are used, extracted from the Date palm, Banana and Apple by boiling method. To compare their effect on the reduction of the natural indigo dyestuff, different color fastness properties, pH and the color yield (K/S) were measured according to the concentration of reducing agent and hydrated lime concentration. Outcomes show that K/S value varies with the amount of reducing agent. Average higher value shows from date palm among the three reducing agents at 25 °C & pH range 10.8–11. By using natural reducing agents, it can be possible to get satisfactory colorfastness and depth of shed compared to a synthetic reducing agent.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

On the Natural Frequency of Tidal Current Power Systems - A Discussion of Sea Testing

In order to study its wet natural frequency (in water) and dry frequency (in air), we conducted a two-year measurement campaign by deploying a full-scale prototype tidal current turbine system. A theoretical model is validated, and reveals the measured wet natural frequency of the device could be 54.6% of the dry frequency. Among short-term physics, inflow turbulence is important in the excitation of system resonances that can lead to fatigue damage and system failure. Among long-term physics, the wet natural frequency is highly dependent on tidal constituents, the semi-diurnal tides (M2 and S2) and diurnal tides (K1 and O1).

Li, Ye↗

Effective field theory analysis of Higgs naturalness

Assuming the presence of physics beyond the Standard Model ( SM) with a characteristic scale M ~ O (10) TeV, we investigate the naturalness of the Higgs sector at scales below M using an effective field theory (EFT) approach. We obtain the leading 1 -loop EFT contributions to the Higgs mass with a Wilsonian-like hard cutoff, and determine t he constraints on the corresponding operator coefficients for these effects to alleviate the little hierarchy problem up to the scale of the effective action Λ < M , a condition we denote by “EFT-naturalness”. We also determine the types of physics that can lead to EFT-naturalness and show that these types of new physics are best probed in vector-boson and multiple-Higgs production. The current experimental constraints on these coefficients are also discussed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Natural, incidental, and engineered nanomaterials and their impacts on the Earth system

Nanoparticles (NPs) are critical components in Earth’s complex (bio)geochemical system. They have been present since Earth’s origin. Life, from the earliest cells to modern humans, has evolved in intimate association with naturally occurring NPs. This synergy began to shift dramatically with human industrialization. Starting in the Anthropocene, incidental NPs (produced by human activity unintentionally) have been distributed worldwide in ever increasing quantities. In the last half century, engineered NPs are being produced in amounts large enough to make them a consequential nano-component of the planet. Due to major advances in experimental, computational, analytical, and field approaches, it is becoming possible to better assess all types and origins of NPs in Earth systems, and to better frame their longer-term impact on environmental and human health at local, regional, and global scales.

Hochella, Michael F.↗

Naturalness confronts nature: searches for supersymmetry with the CMS detector in pp collisions at √s = 8 and $13$ TeV

In this thesis, we present two inclusive searches for supersymmetric particles at √s = 8 and 13 TeV using the razor variables and guided by the principle of naturalness. We build a framework to explore the natural supersymmetry parameter space of gluino and top squark masses and branching ratios, which is a unique attempt to cover this parameter space in a more complete way than ever before using LHC data. With this approach, the production of top squarks and gluinos are excluded below ~ 700 GeV and ~ 1.6 TeV, respectively, independent of the branching ratios, constituting one of the tightest constraints on natural supersymmetry from the LHC. Motivated by the need to mitigate the effects of multiple interactions per bunch crossing (pileup), an essential feature of present and future hadron colliders, in this thesis we also study the precision timing capabilities of a LYSO-based sampling calorimeter, and achieve a time resolution of ~ 30 ps in electron test beam measurements. The achieved resolution corresponds to the precision needed to significantly reduce the inclusion of pileup particles in the reconstruction of the event of interest. This study is foundational in building an R&D program on precision timing for the high-luminosity LHC and other future hadron colliders. We also propose alternative simplified models to study Higgs-plus-jets events at the LHC, and reinterpret an excess observed at 8 TeV in the context of these models. Finally, we discuss a search for narrow resonances in the dijet mass spectrum at 13 TeV using the data-scouting technique at CMS, which records a smaller event format to increase the maximum recordable rate. For the benchmark models with a vector or axial-vector mediator that couples to quarks and dark matter particles, the dijet search excludes mediator masses from 0.5 TeV up to ~ 2.7 TeV largely independent of the dark matter particle mass, which constitutes a larger exclusion than traditional mono-X searches at the LHC. In the plane of the dark matter-nucleon interaction cross section versus dark matter mass, the dijet search is also more sensitive than direct detection experiments for spin-dependent cross sections.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Analysis of natural gas bubble in NETL High Pressure Water Tunnel (HPWT) experiment and its application to natural seeps

Conference Presentation at the 9th International Symposium on Environmental Hydraulics. Analysis of natural gas bubbles under deep-ocean conditions, including hydrate armoring. Compares numerical simulations using the Texas A&M Oil spill / outfall Calculator (TAMOC) to data observed in the NETL High Pressure Water Tunnel. Also, presents simulations of natural seep bubbles in the oceans off the coast of Oregon with comparison to acoustic observations of natural gas seep flares.

Kim, Byungjin↗

Single-throughput Complementary High-resolution Analytical Techniques for Characterizing Complex Natural Organic Matter Mixtures

Natural organic matter (NOM) is composed of a highly complex mixture of thousands of organic compounds which, historically, proved difficult to characterize. However, to understand the thermodynamic and kinetic controls on greenhouse gas (carbon dioxide [CO 2 ] and methane [CH 4 ]) production resulting from the decomposition of NOM, a molecular-level characterization coupled with microbial proteome analyses is necessary. Further, climate and environmental changes are expected to perturb natural ecosystems, potentially upsetting complex interactions that influence both the supply of organic matter substrates and the microorganisms performing the transformations. A detailed molecular characterization of the organic matter, microbial proteomics, and the pathways and transformations by which organic matter is decomposed will be necessary to predict the direction and magnitude of the effects of environmental changes. This article describes a methodological throughput for comprehensive metabolite characterization in a single sample by direct injection Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS), gas chromatography mass spectrometry (GC-MS), nuclear magnetic resonance (NMR) spectroscopy, liquid chromatography mass spectrometry (LC-MS), and proteomics analysis. Furthermore, this approach results in a fully-paired dataset which improves statistical confidence for inferring pathways of organic matter decomposition, the resulting CO 2 and CH 4 production rates, and their responses to environmental perturbation. Herein we present results of applying this method to NOM samples collected from peatlands; however, the protocol is applicable to any NOM sample (e.g., peat, forested soils, marine sediments, etc.).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Evaluation of Geothermal and Natural Gas Resources Beneath Camp Dawson and Opportunities for Deep Direct Use of Geothermal Energy or Natural Gas for Heat and Electricity Production; NETL-TRS-8-2017; NETL Technical Report Series; U.S. Department of Energy, National Energy Technology Laboratory: Morgantown, WV, 2017; p 148.

NETL has reviewed available information and evaluated the deep geothermal and natural gas resources located beneath the Camp Dawson National Guard Training Center in West Virginia. This facility is located in the northeastern portion of the state in Preston County, near the town of Kingwood. This study reviews options for the onsite drilling of wells for the production of geothermal heat or natural gas, as well as the utilization of these resources for on-site power and heating needs. Resources of potential interest are at subsurface depths between 7,000 feet and 15,000 feet.

03 NATURAL GAS↗