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The potential accuracy of an active multifrequency millimeter-wave technique for the remote measurement of atmospheric pressure at the Earth's surface was investigated by numerical simulation.
The superheterodyne millimeter-wave radiometer on the Columbia-GISS 4-ft telescope is described. This receiver uses a room-temperature Schottky diode mixer, with a resonant-ring filter as LO diplexer. The diplexer has low signal loss, efficient LO power coupling, and suppresses most of the LO noise at both sidebands. The receiver IF section has a parametric amplifier as its first stage with sufficient gain to overcome the second-stage amplifier noise. A broad-banded quarter-wave impedance transformer minimizes the mismatch between mixer and paramp. At 115 GHz, the SSB receiver noise temperature is 860 K, which is believed to be the lowest figure so far reported for a room-temperature receiver at this frequency.
Methyl mercaptan (CH3SH) has been identified in Sgr B2 from observations of six lines in its millimeter-wave spectrum. The CH3SH rotational temperature and column density in Sgr B2 are T(rot) = 9 plus or minus 3 K and N = 1.5 plus or minus 0.2 x 10 to the 14th per sq cm, respectively. The CH3SH/CH3OH ratio is apparently not greatly different from the cosmic S/O ratio.
Isothiocyanic acid (HNCS) has been identified in Sgr B2 from millimeter-wave spectral line observations. We have definitely detected three rotational lines, and have probably detected two others. The rotational temperature of HNCS in Sgr B2 is 14 plus or minus 5 K, its column density is 2.5 plus or minus 1.0 x 10 to the 13th per sq cm, and its abundance relative to HNCO is consistent with the cosmic S/O ratio, 1/42.
Stratospheric chlorine oxide, a significant intermediate product in the catalytic destruction of ozone by atomic chlorine, has been detected and measured by a ground-based 204 GHz, millimeter-wave receiver. Data taken at latitude 42 deg N on 17 days between January 10 and February 18, 1980 yield an average chlorine oxide column density of approximately 1.05 x 10 to the 14th/sq cm or approximately 2/3 that of the average of eight in situ balloon flight measurements (excluding the anomalously high data of July 14, 1977) made over the past four years at 32 deg N. Less chlorine oxide below 35 km and a larger vertical gradient than predicted by theoretical models of the stratospheric ozone layer are found.
A 1.2-m millimeter-wave telescope has been used to survey CO in the constellations of Orion and Monoceros. Many new molecular clouds have been found. The distribution of molecular material shows two striking characteristics: (1) Most of the molecular clouds in this region appear to be connected by continuous extensions and filaments. To judge from continuity in radial velocity, most of these connections appear to be real, and are not merely the result of projection along the line of sight; (2) There are at least two slender filamentary features longer than 10 deg in angular extent. These filaments may connect the molecular clouds lying well out of the Galactic plane to clouds lying in the plane. Their shape and orientation suggest that magnetic fields may play a role in their evolution. The observed velocity gradients may be explained by accelerated gas flow along the filament.
Accurate theoretical collisional excitation rates are used to determine the emissivities of CO rotational lines for an H2 molecule content of at least 10,000/cu cm, temperature in the range 100-3000 K, and J not more than 60 under the assumption that the lines are optically thin. An approximate analytic expression for the emissivities which is valid in this region is obtained. Population inversions in the lower rotational levels occur for densities of molecular H2 around 1000-100,000/cu cm and temperatures T not more than about 50 K provided photon trapping is unimportant. Interstellar shocks observed edge-on are a potential source of weak millimeter-wave CO maser emission.
The possibilities of using millimeter-wave technology to probe the subsurface processes of comets to investigate links between cometary materials and the origins of life are explored. It is noted that current theories hold that the necessities for life to begin comprise a fairly uniform temperature, the presence of a solvent to give materials mobility, and the presence of atoms which can form long chains of molecules. Consideration is given to two cometary nuclei models: a core with an equal amount of liquid water and lunar material, and a nucleus with equal amounts of frozen water ice and lunar material. Solutions to the radiative transfer equation for the two models are presented to characterize identifiable emissions using radiometric spectrometer instrumentation on a spacecraft. Particular species such as OH, CN, HCN, and glycine are expected to be detectable if present.
A submillimeter heterodyne radiometer, developed for astronomical applications, uses an optically pumped laser local oscillator and a quasi-optical Schottky diode mixer. The resultant telescope-mounted system, which has a noise temperature less than 4000 K (double sideband) and high frequency and spatial resolution, has been used to detect the J = 6 to 5 rotational transition of carbon monoxide at 434 micrometers in the Orion molecular clouds. The measurements, when compared with previous millimeter-wave data, indicate that the broad carbon monoxide emission feature is produced by an optically thin gas whose temperature exceeds 180 K.
Silicon dicarbide was first observed in 1926 in spectra of cool carbon stars. The carrier of these bands around 5000 A was tentatively identified as SiC2 by Kleman (1956) who produced similar spectra by inserting silicon into the graphite tube of a King furnace heated to over 2500 K. This identification was strengthened by subsequent mass spectral studies which showed SiC2 as a major molecular component of vaporized silicon carbide. The present investigation is concerned with calculations which were initiated in an attempt to understand more recent astronomical observations of unidentified lines in the millimeter-wave region of the spectrum. The calculations were designed to determine the ground state equilibrium structure and to obtain vibrational and rotational constants. Calculations for estimating the positions and structure of low-lying electronic states were also performed. Self-consistent field (SCF) calculations were performed assuming a closed-shell electronic structure analogous to that in C3. Calculations were conducted for symmetric CSiC, and asymmetric SiCC forms.
The millimeter-wave spectra of the linear carbon chain free radicals C3N and C4H, first identified in IRC + 10216 and hitherto observed only in a few astronomical sources, have been detected with a Zeeman-modulated spectrometer in laboratory glow discharges through low pressure flowing mixtures of N2 + HC3N and He + HCCH, respectively. Four successive rotational transitions between 168 and 198 GHz have been measured for C3N, and five rotational transitions between 143 and 200 GHz for C4H; each is a well-resolved spin doublet owing to the unpaired electron present in both species. Precise values for the rotational, centrifugal distortion, and spin doubling constants have been obtained, which, with hyperfine constants derived from observations of the lower rotational transitions in the astronomical source TMC 1, allow all the rotational transitions of C3N and C4H at frequencies less than 300 GHz to be calculated to an absolute accuracy exceeding 1 ppm.
Far-infrared, near-infrared, millimeter-wave, and optical data are presented for two of the large molecular clouds which border the W5 (IC 1848) giant H II region. These data are combined to identify three B0-B2 zero-age main-sequence stars which are forming in these clouds and to study the density distribution and kinematic structure of their surrounding molecular gas. This investigation into the environment in which massive stars have formed in these clouds, when considered alongside similar studies of the W5A/S201 molecular cloud, leads to the conclusion that the expanding W5 H II region has played an important role in initiating the formation of these massive stars.
New far-infrared continuum and millimeter-wave molecular observations of NGC 2024 are presented. The measurements were obtained at relatively high angular resolution making it possible to describe the source energetics and mass distribution in greater detail than previously reported. The object appears to be dominated by a dense ridge of material, extended in the north-south direction and centered on the dark lane that is seen in visual photographs. The maps of the source using the 'high-density' molecules CS and HCN confirm this picture and makes it possible to describe the core structure and molecular abundances. The radio molecular and infrared observations support the idea that an important exciting star in NGC 2024 has yet to be identified and is centered on the dense ridge about 1 arcmin south of the bright mid-infrared source IRS 2. The data presented here, along with other observations, make it possible to describe a model for the source.
W3 has been observed in the J = 1-0 transition of HCN with the millimeter-wave interferometer at the Hat Creek Observatory with a resolution of 11.5 by 11.1 arcsec. The HCN emission is detected in an isolated cloud with a diameter of 40 arcsec. The cloud is located to the south of IRS 4 and the compact H II region C and coincides with the western far-IR cloud mapped at 400 microns by Jaffe (1983). The total mass of the cloud is estimated to be in the range 250-2500 solar masses. No HCN emission was detected around IRS 5, the location of the other 400 micron peak. Also, no evidence for a new (heretofore undetected at other wavelengths), young main-sequence star earlier than B0 was found in the new continuum map at 3 mm.
Two spacecraft, one following the other with a separation of a few hundred kilometers and orbiting at an altitude of 160 km in a 90-degree polar orbit, are used to detect the minute variations in the earth's gravitational field. Housed in a capacitive cavity located at the centroid of the spacecraft is a free-floating metallic spherical proof-mass, which is the sensor controlling the thrusters that nullify all nongravitational forces on the spacecraft. The proof-mass in each spacecraft is the inertial-guidance reference for its host spacecraft, and the proof-masses are coupled together by a millimeter-wave link. This coupled system detects minute changes in the spacecraft's orbital positions and thus measures the anomalies present in the gravitational field of the earth. To derive a global geodetic model of the gravitational field with an amplitude resolution of 1 milligal and a spatial resolution of 100 km requires that the relative velocity between the proof-mass references be determined to within 1 micron/s.
The study of printed circuit discontinuities is necessary in order to design, for example, transitions between rectangular waveguides and printed circuits. New developments with respect to the analytical approaches to this problem are discussed. A summary of the progress in the experimental approach is presented. The accurate solution for the modes in various millimeter-wave waveguides is essential in the analysis of many integrated circuit components, such as filters and impedance transformers. Problems associated with the numerical computation of these modes in two frequently used waveguide forms, namely, the finline and microstrip, are presented. The spectral domain method of formulation, with a moment method solution, is considered. This approach can be readily extended to analyze an arbitrary configuration of dielectric and metallized regions in a shielded enclosure. Galerkin's method is used, where the testing and basic functions are the same. It is shown that the mode functions, or eigenfunctions, are more sensitive to errors than the phase constants, or eigenvalues. The approximate mode functions do not satisfy the orthogonality relationship well, resulting in difficulties when these modal solutions are used to form an approximate Green's function or are used in a mode matching analysis.
Research activities were carried out in the following areas during this reporting period: (1) astrophysics; (2) climate and atmospheric modeling; and (3) climate applications of earth observations & geological studies. An ultra-low-noise 115 GHz receiver based upon a superconducting tunnel diode mixer has been designed and constructed. The first laboratory tests have yielded spectacular results: a single-sideband noise temperature of 75 K considerably more sensitive than any other receiver at this frequency. The receiver will replace that currently in use on the Columbia-GISS CO Sky Survey telescope. The 1.2 meter millimeter-wave telescope at Columbia University has been used to complete two large-scale surveys of molecular matter in the part of the inner galaxy which is visible from the Northern hemisphere (the first galactic quadrant); one of the distant galaxy and one of the solar neighborhood. The research conducted during the past year in the climate and atmospheric modeling programs has been focused on the development of appropriate atmospheric and upper ocean models, and preliminary applications of these models. Principal models are a one-dimensional radiative-convective model, a three-dimensional global climate model, and an upper ocean model. During the past year this project has focused on development of 2-channel satellite analysis methods and radiative transfer studies in support of multichannel analysis techniques.
The molecular component of the mass outflow at high resolution was mapped with the Owens Valley Millimeter-Wave Interferometer in two well-known objects, CRL 2688 and CIT 6. Interferometric observations of a pair of carbon stars which are evolving toward the planetary nebula stage have revealed evidence of episodic, nonspherically symmetric mass loss, and may lead to a fuller understanding of shielding properties of the dust grains involved in these flows.