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At least 73 records · Page 4

Structural analysis and design of multivariable control systems: An algebraic approach

The application of algebraic system theory to the design of controllers for multivariable (MV) systems is explored analytically using an approach based on state-space representations and matrix-fraction descriptions. Chapters are devoted to characteristic lambda matrices and canonical descriptions of MIMO systems; spectral analysis, divisors, and spectral factors of nonsingular lambda matrices; feedback control of MV systems; and structural decomposition theories and their application to MV control systems.

Tsay, Yih Tsong

Key factors limiting the open circuit voltage of n(+)pp(+) indium phosphide solar cells

Solar cells made from gallium arsenide (GaAs), with a room temperature bandgap of E(sub g) = 1.43 eV have exhibited the best measured open circuit voltage (V sub OC) of 1.05 V at 1 AMO, 25 C. The material InP is in many ways similar to GaAs. A simple calculation comparing InP to GaAs then shows that solar cells made from InP, with E(sub g) = 1.35 at 300 K, should exhibit the best measured (V sub OC) of approximately 950 mV at 1 AMO, 300 K. However, to date, the best measured V(sub OC) for InP solar cells made by any fabrication method is 899 mV at AM1.5, 25 C which would translate to 912 mV at 1 AMO, 25 C. The V(sub OC) of an n(+)pp(+) InP solar cell is governed by several factors. Of these, some factors, such as the thickness and doping of the emitter and base regions, are easily controlled and can be adjusted to desired values dictated by a good performance optimizing model. Such factors were not considered. There are other factors which also govern V(sub OC), and their values are not so easily controlled. The primary ones among these are (1) the indirect or Hall-Shockley-Read lifetimes in the various regions of the cell, (2) the low-doping intrinsic carrier concentration n(sub i) of the InP material, (3) the heavy doping factors in the emitter and BSF regions, and (4) the front surface recombination velocity S(sub F). The influence of these latter factors on the V(sub OC) of the n(+)pp(+) InP solar cell and the results were used to produce a near-optimum design of the n(+)pp(+) InP solar cell.

Goradia, Chandra

Key factors limiting the open circuit voltage of n(+)pp(+) indium phosphide solar cells

Solar cells made from gallium arsenide (Gaas), with a room temperature bandgap of E(sub g) = 1.43 eV have exhibited the best measured open circuit voltage (V sub oc) of 1.05 V at 1 AM0, 25 C. The material InP is in many ways similar to GaAs. A simple calculation comparing InP to GaAs then shows that solar cells made from InP, with E(sub g) = 1.35 at 300 K, should exhibit the best measured V sub oc of approximately 950 mV at 1 AM0, 300 K. However, to date, the best measured V sub oc for InP solar cells made by any fabrication method is 899 mV at AM1.5, 25 C which would translate to 912 mV at 1 AM0, 25 C. The V sub oc of an n(+)pp(+) InP solar cell is governed by several factors. Of these, some factors, such as the thickness and doping of the emitter and base regions, are easily controlled and can be adjusted to desired values dictated by a good performance optimizing model. Such factors were not considered. There are other factors which also govern V sub oc, and their values are not so easily controlled. The primary ones among these are (1) the indirect or Hall-Shockley-Read lifetimes in the various regions of the cell, (2) the low-doping intrinsic carrier concentration n(sub i) of the InP material, (3) the heavy doping factors in the emitter and BSF regions, and (4) the front surface recombination velocity S(sub F). The influence of these latter factors on the V sub oc of the n(+)pp(+) InP solar cell and the results were used to produce a near-optimum design of the n(+)pp(+) InP solar cell.

Goradia, Chandra

Microwave vision for robots

Microwave Vision (MV), a concept originally developed in 1985, could play a significant role in the solution to robotic vision problems. Originally our Microwave Vision concept was based on a pattern matching approach employing computer based stored replica correlation processing. Artificial Neural Network (ANN) processor technology offers an attractive alternative to the correlation processing approach, namely the ability to learn and to adapt to changing environments. This paper describes the Microwave Vision concept, some initial ANN-MV experiments, and the design of an ANN-MV system that has led to a second patent disclosure in the robotic vision field.

Lewandowski, Leon

Progress in p(+)n InP solar cells fabricated by thermal diffusion

In SPRAT XI, we proposed that p(sup +)n diffused junction InP solar cells should exhibit a higher conversion efficiency than their n(sup +)p counterparts. This was mainly due to the fact that our p(sup +)n (Cd,S) cell structures consistently showed higher V (sub OC) values than our n(sup +)p (S,Cd) structures. The highest V(sub OC) obtained with the p(sup +)n (Cd,S) cell configuration was 860 mV, as compared to the highest V(sub OC) 840 mV obtained with the n(sup +)p (S,Cd) configuration (AMO, 25 C). In this work, we present the performance results of our most recent thermally diffused cells using the p(sup +)n (Cd,S) structure. We have been able to fabricate cells with V(sub OC) values approaching 880 mV. Our best cell with an unoptimized front contact grid design (GS greater than or equal to 10%) showed a conversion efficiency of 13.4% (AMO, 25 C) without an AR coating layer. The emitter surface was passivated by a -50A P rich oxide. Achievement of such high V(sub OC) values was primarily due to the fabrication of emitter surfaces, having EPD densities as low as 2E2 cm(sup -2) and N(sub a)N(sub d) of about 3E18 cm (sup -3). In addition, our preliminary investigation of p(sup +)n structures seem to suggest that Cd-doped emitter cells are more radiation resistant than Zn-doped emitter cells against both high energy electron and proton irradiation.

Faur, Mircea

Study of cosmic-ray H and He isotopes at 23 AU

We have measured the spectra of H and He isotopes during the 1987 solar minimum with the cosmic-ray detector system (CRS) on the Voyager 2 spacecraft. By carrying out the measurement near solar minimum and at large heliospheric distances, the effects of solar modulations were reduced. In particular, the adiabatic energy losses were smaller, and these results from 23 AU over the solar minimum period of cycle 21 represent observations at energies not accessible from previous measurements near 1 AU. The modulated spectra with the diffusion coefficient constant k(sub 0) = 3.15 x 10(exp 22) sq cm/s (which corresponds to a solar modulation parameter of 360 MV at 23 AU and 500 MV at 1 AU) agree well with both our data at 23 AU and the previous solar minimum measurements at 1 AU. The measured H-1 and H-2 spectra are both consistent with the calculated spectra, using standard Galactic and heliospheric propagation models without invoking an anomalous hydrogen component. With the fixed modulation parameter of 360 MV, the mean pathlengths, source spectra, and cross sections were varied to study the effects of different input parameters on the spectra and relative abundances. At this stage of our work, we have not found any strong evidence from the low-energy H-2 and He-3 data that H-1 and He-4 should have a different propagation history, or different types of source spectra from the heavier cosmic-ray nuclei.

Seo, E. S.

Gravity-induced changes in intracellular potentials in elongating cortical cells of mung bean roots

Gravity-induced changes in intracellular potentials in primary roots of 2-day-old mung bean (Vigna mungo L. cv. black matpe) seedlings were investigated using glass microelectrodes held by 3-dimensional hydraulic micro-drives. The electrodes were inserted into outer cortical cells within the elongation zone. Intracellular potentials, angle of root orientation with respect to gravity, and position within the root of the impaled cortical cell were measured simultaneously. Gravistimulation caused intracellular potential changes in cortical cells of the elongation zone. When the roots were oriented vertically, the intracellular potentials of the outer cortical cells (2 mm behind the root apex) were approximately - 115 mV. When the roots were placed horizontally cortical cells on the upper side hyperpolarized to - 154 mV within 30 s while cortical cells on the lower side depolarized to about - 62 mV. This electrical asymmetry did not occur in cells of the maturation zone. Because attempts to insert the electrode into cells of the root cap were unsuccessful, these cells were not measured. The hyperpolarization of cortical cells on the upper side was greatly reduced upon application of N,N'-dicyclohexylcarbodiimide (DCCD), an inhibitor of respiratory energy coupling. When stimulated roots were returned to the vertical, the degree of hyperpolarization of cortical cells on the previous upper side decreased within 30 s and approached that of cortical cells in non-stimulated roots. This cycle of hyperpolarization/loss of hyperpolarization was repeatable at least ten times by alternately turning the root from the vertical to the horizontal and back again. The very short (<30 s) lag period of these electrical changes indicates that they may result from stimulus-perception and transduction within the elongation zone rather than from transmission of a signal from the root cap.

NASA Discipline Plant Biology

Hydrogen Passivation of Interstitial Zn Defects in Heteroepitaxial InP Cell Structures and Influence on Device Characteristics

Hydrogen passivation of heteroepitaxial InP solar cells is of recent interest for deactivation of dislocations and other defects caused by the cell/substrate lattice mismatch that currently limit the photovoltaic performance of these devices. In this paper we present strong evidence that, in addition to direct hydrogen-dislocation interactions, hydrogen forms complexes with the high concentration of interstitial Zn defects present within the p(+) Zn-doped emitter of MOCVD-grown heteroepitaxial InP devices, resulting in a dramatic increase of the forward bias turn-on voltage by as much as 280 mV, from ~680 mV to ~960 mV. This shift is reproducible and thermally reversible and no such effect is observed for either n(+)p structures or homoepitaxial p(+)n structures grown under identical conditions. A combination of photoluminescence (PL), electrochemical C-V dopant profiling, SIMS and I-V measurements were performed on a set of samples having undergone a matrix of hydrogenation and post-hydrogenation annealing conditions to investigate the source of this voltage enhancement and confirm the expected role of interstitial Zn and hydrogen. A precise correlation between all measurements is demonstrated which indicates that Zn interstitials within the p(+) emitter and their interaction with hydrogen are indeed responsible for this device behavior.

Ringel, S. A.

Electrophysiology of the mammillary complex in vitro. II. Medial mammillary neurons

1. The electrophysiological properties of guinea pig medial mammillary body (MMB) neurons were studied using an in vitro slice preparation. 2. The neurons (n = 80) had an average resting potential of -57 +/- 5.5 (SD) mV, an input resistance of 176 +/- 83 M omega, and a spike amplitude of 58 +/- 15.7 mV. Most of the neurons were silent at rest (n = 52), but some fired spontaneous single spikes (n = 16) or spike bursts (n = 14). 3. The main electrophysiological characteristic of MMB neurons was the ability to generate Ca(2+)-dependent regenerative events, which resulted in very robust burst responses. However, this regenerative event was not the same for all neurons, ranging from typical low-threshold Ca2+ spikes (LTSs) to intermediate-threshold plateau potentials (ITPs). 4. The ITPs were distinct from the LTSs in that they lasted > or = 100 ms and were not inactivated at membrane potentials at or positive to -55 mV. 5. Some cells with a prominent ITP and no LTS (n = 36) displayed repetitive, usually rhythmic, bursting (n = 14). This ITP could be powerful enough to maintain rhythmic membrane potential oscillations after pharmacological block of Na+ conductances. 6. A group of 32 MMB neurons displayed complex bursting that was generated by activation of both LTSs and ITPs. This was established on the basis of their distinct time- and voltage-dependent characteristics. In a group of neurons (n = 14), the burst responses were exclusively generated by an LTS; however, a Ca(2+)-dependent plateau potential contributed to the generation of rebound-triggered oscillatory firing. 7. In addition to the Ca(2+)-dependent LTS and/or ITP, MMB neurons always displayed high-threshold Ca2+ spikes after reduction of K+ conductances with tetraethylammonium. 8. MMB neurons display one of the richer varieties of voltage-dependent Ca2+ conductances so far encountered in mammalian CNS. We propose that the very prominent endogenous bursting and oscillatory properties of MB neurons allow this nuclear complex to function as an oscillatory relay for the transmission of low-frequency rhythmic activities throughout the limbic circuit.

NASA Discipline Neuroscience

Molecular Dynamics Simulation of the Antiamoebin Ion Channel: Linking Structure and Conductance

Molecular dynamics simulations were carried out in order to ascertain which of the potential multimeric forms of the transmembrane peptaibol channel, antiamoebin, is consistant with its measured conductance. Estimates of the conductance obtained through counting ions that cross the channel and by solving the Nernst-Planck equation yield consistent results, indicating that the motion of ions inside the channel can be satisfactorily described as diffusive.The calculated conductance of octameric channels is markedly higher than the conductance measured in single channel recordings, whereas the tetramer appears to be non-conducting. The conductance of the hexamer was estimated to be 115+/-34 pS and 74+/-20 pS, at 150 mV and 75 mV, respectively, in satisfactory agreement with the value of 90 pS measured at 75 mV. On this basis we propose that the antiamoebin channel consists of six monomers. Its pore is large enough to accommodate K(+) and Cl(-) with their first solvation shells intact. The free energy barrier encountered by K(+) is only 2.2 kcal/mol whereas Cl(-) encounters a substantially higher barrier of nearly 5 kcal/mol. This difference makes the channel selective for cations. Ion crossing events are shown to be uncorrelated and follow Poisson statistics. keywords: ion channels, peptaibols, channel conductance, molecular dynamics

Wilson, Michael A.

Normal Incidence for Graded Index Surfaces

A plane wave is incident normally from vacuum (eta(sub 0) = 1) onto a smooth surface. The substrate has three layers; the top most layer has thickness d(sub 1) and permittivity epsilon(sub 1). The corresponding numbers for the next layer are d(sub 2); epsilon(sub 2), while the third layer which is semi-in nite has index eta(sub 3). The Hallikainen model [1] is used to relate volumetric soil moisture to the permittivity. Here, we consider the relation for the real part of the permittivity for a typical loam soil: acute epsilon(mv) = 2.8571 + 3.9678 x mv + 118:85 x mv(sup 2).

plane wave

WFIRST Low Order Wavefront Sensing and Control Testbed Performance under Flight Like Photon Flux

To maintain the required performance for the WFIRST Coronagraph Instrument (CGI) in a realistic space environment, a Low Order Wavefront Sensing and Control (LOWFS/C) subsystem is necessary. The WFIRST CGI LOWFS/C subsystem would use the Zernike wavefront sensor, which has the phase-shifting disk combined with the coronagraph’s focal plane mask, to sense the low-order wavefront drift and line-of-sight (LoS) error using the rejected starlight. The dynamic tests on JPL’s on the Occulting Mask Coronagraph (OMC) Testbed have demonstrated that LOWFS/C can maintain coronagraph contrast to better than 10-8 in presence of WFIRST-like line of sight and low order wavefront disturbances in both Shaped Pupil Coronagraph (SPC) and Hybrid Lyot Coronagraph (HLC) modes. However, the previous dynamic tests have been done using a bright source with photon flux equivalent to stellar magnitude of Mv = -3.5. The LOWFS/C technology development continues on the OMC testbed especially in evaluating and improving the LOWFS/C performance under the realistic photon flux that is equivalent to WFIRST Coronagraph target stars. Our recent testbed tests have demonstrated that the LOWFS/C can work cohesively with the stellar light suppression wavefront control, which brings broad band coronagraph contrast from 1x10-6 to 6x10-9, while LOWF/C is simultaneously suppressing the WFIRST like LoS and low order wavefront drift disturbances on a source that photon flux is equivalent to a Mv = 2 star. This demonstration mimics the CGI initial dark hole establish process on a bright reference star. We also demonstrated on the testbed that LOWFS/C can maintain the coronagraph contrast by suppressing the WFIRST like line-of-sight disturbances on a fainter Mv = 5 star. This mimics scenario of CGI science target observations. In this paper we will present the recent testbed results on LOWFS/C LoS loops and low order wavefront error correction loop performance on the flight like photon flux.

Truong, Tuan

LOFTID Heat Flux Gauge Calibration: What is Truth?

The Low-Earth Orbit Flight Test of an Inflatable Decelerator (LOFTID) is a demonstration of Hypersonic Inflatable Aerodynamic Decelerator (HIAD) technology, which may enable the delivery of heavy payloads to Mars, Venus, and Titan, as well as return to Earth. Unlike rigid aeroshells that are constrained by the size of the rocket’s shroud, inflatable aeroshells can be deployed to a much larger scale, thus allowing a spacecraft to begin its deceleration earlier and experience less heating. On LOFTID, there will be 4 total heat flux gauges (HFG) with a range of 70 W/cm2 and 1 radiometer with a range of 3 W/cm2, arranged as shown in Fig. 1. Both the radiometer and total HFGs are Schmidt-Boelter gauges purchased from an external vendor. Radiative calibrations were performed in-house at NASA Ames’ Sensors and TPS Advanced Research Laboratories (STAR Labs) before and after environmental testing to investigate how the testing affected the sensors' response. Additional rounds of radiative calibration at STAR Labs were also performed in order to investigate the large uncertainties associated with these tests. For example, a survey of multiple calibration facilities concluded that the uncertainty within a given facility was +/-3% [1]. An additional NIST study that calibrated heat flux gauges at 7 different facilities also found the variation in calibration coefficients to be up to ~3% within a given facility, but up to 15% between facilities, suggesting systematic differences between test setups [2]. Finally, the response of heat flux gauges to radiative versus convective heat flux has shown to differ by up to 20% [3],[4]. Because the heat flux gauges on LOFTID will predominantly experience convective heat flux during flight, a convective calibration study was performed at Boeing's Large-Core Arc Tunnel (LCAT) facility. Radiative Calibration Procedure The calibrations performed at STAR Labs utilize a quartz lamp bank (QLB) that provides a maximum heat flux of 50 W/cm2, which bounds the expected LOFTID flight environment. The calibration involves exposing a water-cooled Gardon gauge (reference) and then the unit-under-test (UUT) to 5 different heat fluxes multiple times for 10 seconds each, and then calculating a linear fit. The test setup is shown in Fig. 2. The total HFGs were calibrated at STAR Labs 3 times, denoted as STAR 1 (before environmental testing), STAR 2 (after protoflight vibration and thermal-vacuum testing), and STAR 3 (no change from previous test). All 8 flight-lot total HFGs showed a decrease in full-scale output from STAR 1 to STAR 2 by between 0.5% and 10. The first portion of this investigation was to determine whether the change could be due to differences in temperature between the two calibration runs. A typical linear fit to the calibration data was performed using Eq. 1 where q’ is the heat flux in W/cm2, c is the calibration coefficient, and mV is the sensor output. To account for temperature, the data were fit to a nonlinear function that included both the sensor output (mV) and the temperature from the thermocouple embedded inside the HFG near the surface (T): q'=mV/(c1* T + c0}. The residuals between the fits and the actual data points were calculated for every point, and proven to be much smaller for the temperature-compensated fits than for the linear fits for all sensors. An example is shown in Fig. 3. When the temperature-compensated fits from STAR 1 were applied to the STAR 2 data, the residuals did not improve, suggesting that the change in sensitivity between these two calibration runs was not due to temperature. A third round of calibration (STAR 3) was conducted to further address the temperature dependence of the total HFGs, and the resulting sensitivities matched closely to STAR 2 (within 2%). Temperature-compensated calibration curves were once again fit to the data. In this case, when the temperature-compensated fits from STAR 3 were applied to STAR 2 data, the residuals between the fits and STAR 2 data were much lower than the residuals due to the linear fits. This suggests that the changes seen between STAR 1 and STAR 2 were likely due to actual changes in the sensors caused by the environmental testing between the two calibrations. A modification of the original calibration process, in which the UUT was exposed to each heat flux for just 3 seconds (instead of 10) to reduce the temperature increase during the test, was additionally performed on several of the HFGs. In general, the sensitivities were 1-1.5% lower than from the 10-second tests, but the temperatures were also significantly lower. When the temperature-compensated fits from the 10-second tests were applied to the 3-second test data, the residuals were greatly improved than when just using the linear fits, further suggesting that the temperature-compensated fits may lead to better accuracy than the linear fits in flight. Convective Calibration The second portion of this study was to create a mapping between the radiative and convective calibration coefficients. The majority of the heating during flight will be convective, so it is important to understand how the HFG response differs under these conditions. However, there are no standardized methods for convective calibration [5]. Because the TPS aerothermal response models were validated at LCAT, the same facility was chosen for convective calibration of two of the total HFGs (Fig. 4). Preliminary results showed that the full-scale output was 3% and 8% higher in convective heat flux as compared to radiative heat flux. However, tunnel variation may have contributed to noise and uncertainty in the measurements, and more testing and analysis remains to be done. Scope of Presentation The presentation will include an overview of the changes seen in HFG calibration before and after environmental testing, differences between radiative and convective calibrations, the modeling work done to aid in understanding the sensor response to varying environments, and recommended future work.

H S Alpert

Ultraviolet Laser Activation of Phosphorus-Doped Polysilicon Layers for Crystalline Silicon Solar Cells

In crystalline silicon photovoltaics (c-Si PV), a pulsed laser can be used as a substitute for a high-temperature furnace dopant diffusion/activation step. In contrast to furnace-based activation, lasers can be used to achieve highly localized doping with controlled dopant concentrations, useful in advanced architectures such as the interdigitated back contact (IBC) solar cell. In this study, a pulsed ultraviolet (UV) laser is utilized for phosphorus dopant activation within a low-pressure chemical vapor deposited (LPCVD) polycrystalline silicon (poly-Si) passivated contact layer. The highest implied open-circuit voltage iV oc values achieved using this approach reach 726 mV. However, this comes at the expense of high specific contact resistivities ρ c , which is attributed to a lower dopant concentration across the poly-Si(n + )/SiO x /c-Si interface. Regardless, the optimum iV oc , ρ c combination is measured at a laser fluence of 0.78 J cm -2 producing values of 712 mV and 89 mΩ-cm 2 , respectively. These values are still compatible with high-efficiency solar cell designs, underscoring the feasibility and effectiveness of this approach.

14 SOLAR ENERGY

Increased Voltage in CdSe Solar Cells by Mitigation of Charge Carrier Trapping Due to Se Vacancies

Cadmium selenide (CdSe), with a 1.7 eV bandgap, is a promising high-bandgap semiconductor for tandem solar cells, yet device efficiencies are hindered by rapid minority carrier recombination. Here, in this study, polycrystalline CdSe solar cells are investigated using radiative emission spectroscopy, time-resolved photoluminescence, and density functional theory, revealing fast (sub-nanosecond) minority carrier trapping by selenium vacancy-related defect states with densities of (5–50) × 10 17 cm −3 , limiting carrier mobility and increasing recombination. By reducing absorber thickness to ≈0.5 µm, trapping effects are mitigated, achieving a record open-circuit voltage of 917 mV, a 165 mV improvement over prior reports. These findings clarify the role of Se vacancies in limiting CdSe solar cell performance and provide insights applicable to CdSe and CdSeTe thin-film photovoltaics. This work advances understanding of defect-mediated losses in II–VI semiconductors and suggests pathways for improving solar cell performance through defect control.

14 SOLAR ENERGY

Sustainable Synthesis of NiMo Alloy Nanoparticles for Hydrogen Evolution Catalysis Using a Recyclable Ionic Liquid Solvent

Advancing the sustainability of nanoparticle electrocatalyst synthesis requires reducing solvent waste without compromising catalytic performance. Here, we report a rapid, microwave‐assisted colloidal synthesis of NiMo alloy nanoparticles in the ionic liquid 1‐butyl‐3‐methylimidazolium bis(trifluoromethylsulfonyl)imide (BMIM‐NTf 2 ), which serves as both reaction medium and recyclable solvent. NiMo nanoparticles with tunable compositions were obtained within 1 min at 230 °C, with Ni 0.86 Mo 0.14 giving the highest activity toward the hydrogen evolution reaction (HER), achieving an onset potential of −129 mV, an overpotential at 10 mA cm −2 of −290 mV versus RHE in acidic electrolyte, and >99% Faradaic efficiency. The ionic liquid was recovered and purified via aqueous NH 4 OH extraction, removing over 99% of residual Mo species, and reused for up to five successive syntheses. Nanoparticles prepared in recycled BMIM‐NTf 2 retained comparable crystallinity, morphology, and catalytic activity, with stable HER performance over 45 h of electrolysis. These results demonstrate that ionic liquid recycling can improve the sustainability of the preparation of NiMo nanoparticle electrocatalysts while preserving performance and material integrity.

bimetallic alloy

Porous CeO 2 /CuO Heterostructure for Efficient Hydrogen Evolution Reaction in an Acidic Medium

A composite electrocatalyst CeO 2 /CuO is fabricated for the hydrogen evolution reaction (HER) via a simple, facile, one‐step hydrothermal method, using F‐127 as a template and structure directing agent. The prepared composite CeO 2 /CuO shows top‐notch HER activities with a small overpotential of 98 mV at 10 mA cm −2 and just 160 mV overpotential to attain a current density of 50 mA cm −2 with good stability for 20 h in an acidic medium. The enhanced catalytic activities of CeO 2 /CuO nanocomposite are attributed to their synergetic interface interaction, which lead to improved conductivity, reactive sites, and oxygen vacancies in their lattices. This study aims to advance the development of earth‐abundant transition metal oxides–based electrocatalysts as economical, durable, and efficient HER electrocatalysts to replace noble metal–based materials in the future.

Chemistry

Demonstration of GaAs-Based Photovoltaics on Acoustically Spalled Surfaces Grown by MOCVD

This study demonstrates the potential of sonic lift-off (SLO) technology for repeatable substrate reuse in gallium arsenide (GaAs)–based photovoltaics (PVs), offering a pathway toward cost effective production for terrestrial PV applications. Single-junction GaAs solar cells fabricated on acoustically spalled substrates achieved performance metrics comparable with those grown on standard commercial substrates, exhibiting short-circuit current densities (J sc ) of approximately 26.2–26.4 mA/cm 2 , open-circuit voltages (V oc ) around 1001 mV, fill factors (FFs) of 84%, and AM1.5G efficiencies near 22%. These results confirm that one reuse cycle can be realized without a performance penalty, offering a direct pathway to reducing substrate cost in fabrication. Furthermore, subsequent reuse of the substrates highlighted critical challenges, as devices fabricated from reused substrates showed significant degradation in performance (J sc of 15.5 mA/cm 2 , V oc of 748 mV, FF of 72%, and efficiency of 8%), primarily due to degradation of the epitaxial structure resulting from repeated spalling cycles.

Acoustic Spalling