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At least 73 records · Page 4

Physical and electrical properties of melt-spun Fe-Si (3–8 wt.%) soft magnetic ribbons

Highlights: • Increasing processing wheel speed during melt spinning refined both the ribbon cross-sectional thickness and grain size. • Mössbauer studies indicated Si content influenced the number of Fe sites and the magnetic field/structural environments. • Vickers hardness and the elastic modulus were observed to increase in response to elevated Si content and wheel speed. • Increasing Si content diluted the magnetization. - Abstract: Fe-Si alloys ranging from 3 to 8 wt% Si were rapidly solidified using melt spinning. Wheel speeds of 30 m/s and 40 m/s were employed to vary cooling rates. Mössbauer spectroscopic studies indicated the Si content significantly influenced the number of Fe sites, relative abundance of various Fe species, and internal magnetic fields/structural environments. Wheel speed altered Fe speciation only in the 3 wt% sample. Scanning electron microscopy confirmed that increasing the wheel speed refined both the ribbon thickness and grain size. Electron backscatter diffraction results suggest tailoring melt spinning process parameters and alloy chemistry may offer the ability to manipulate {001} texture development. Electrical resistivity measurements were observed to increase in response to elevated Si content. Increased hardness was correlated to elevated Si content and wheel speed.

36 MATERIALS SCIENCE↗

Design and Comparison of Surface Inset Permanent Magnet Machine and Surface Permanent Magnet Machine without Heavy Rare Earth Magnets for Traction Applications

This paper presents two machine designs: a surface inset permanent magnet (SIPM) machine and a surface permanent magnet (SPM) machine, both without heavy rare-earth magnets, that achieve 50 kW/L active power density and a constant-power speed ratio of 3 for EV traction applications. Compared to surface PM machines, SIPM machines do not require a special containment sleeve to hold the magnets in place at high speeds, provided that the rotor laminations are carefully designed together with the magnet mounting configuration to ensure the rotor’s structural integrity. Comparisons between the SPM and SIPM machines sharing the same stator, same current level, and same power speed envelope are presented. Both deliver very similar performance characteristics, but the SIPM machine’s simpler magnet containment configuration may give it an advantage in terms of reduced material and manufacturing costs.

42 ENGINEERING↗

Observation of a Large Magnetic Anisotropy and a Field-Induced Magnetic State in SrCo(VO 4 )(OH): A Structure with a Quasi One-Dimensional Magnetic Chain

A new member of the descloizite family, a cobalt vanadate, SrCo(VO 4 )(OH), has been synthesized as large single crystals using high-temperature and high-pressure hydrothermal methods. SrCo(VO 4 )(OH) crystallizes in the orthorhombic crystal system in space group P 2 1 2 1 2 1 with the following unit cell parameters: a = 6.0157(2) Å, b = 7.645(2) Å, c = 9.291(3) Å, V = 427.29(2) Å 3 , and Z = 4. It contains one-dimensional Co–O–Co chains of edge-sharing CoO 6 octahedra along the a -axis connected to each other via VO 4 tetrahedra along the b -axis forming a three-dimensional structure. The magnetic susceptibility of SrCo(VO 4 )(OH) indicates an antiferromagnetic transition at 10 K as well as unusually large spin orbit coupling. Single-crystal magnetic measurements in all three main crystallographic directions displayed a significant anisotropy in both temperature- and field-dependent data. Single-crystal neutron diffraction at 4 K was used to characterize the magnetically ordered state. The Co 2+ magnetic spins are arranged in a staggered configuration along the chain direction, with a canting angle that follows the tipping of the CoO 6 octahedra. The net magnetization along the chain direction, resulting in ferromagnetic coupling of the a -axis spin components in each chain, is compensated by an antiferromagnetic interaction between nearest neighbor chains. A metamagnetic transition appears in the isothermal magnetization data at 2 K along the chain direction, which seems to correspond to a co-alignment of the spin directions of the nearest neighbor chain. We propose a phenomenological spin Hamiltonian that describes the canted spin configuration of the ground state and the metamagnetic transition in SrCo(VO 4 )(OH).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Correlation between Epitaxial Strain and Magnetic Properties in La0.7Sr0.3CoO3/La0.7Sr0.3MnO3 bilayers

Magnetic properties arising at interfaces of perovskite oxides such as La0.7Sr0.3MnO3 (LSMO) and La0.7Sr0.3CoO3 (LSCO) depend sensitively on the fine details of their structural properties. In this work, we use high-resolution transmission electron microscopy and spectroscopy to examine the structural and electronic phenomena at the interfaces in two LSMO/LSCO bilayers with reversed growth order. Two different strain mechanisms are at work in these films; compressive or tensile epitaxial strain, and distortion of the octahedral tilt pattern to maintain the network of corner-sharing octahedra. While the epitaxial strain is constant, regardless of growth order, the modification of the octahedral tilt pattern depends on whether the film is grown directly on the substrate, or as the second sublayer. As a consequence, exchange spring behavior is observed only when the LSCO sublayer is grown first. The different mechanisms of strain accommodation within the oxygen octahedra network in each material prove to be of critical importance in determining the interfacial structure and thus magnetic and electronic properties of the bilayers.

perovskites, interfaces, microscopy, magnetism↗

Magnetic force microscopy revealing long-range room temperature stable molecule bridge-induced magnetic ordering on magnetic tunnel junction (MTJ) pillars

Magnetic tunnel junctions (MTJs) can integrate novel single molecular device elements to overcome long-standing fabrication challenges, thus unlocking their novel potential. This study employs magnetic force microscopy (MFM) to demonstrate that organometallic molecules, when placed between two ferromagnetic electrodes along cross-junction shaped MTJ edges, dramatically altered the magnetic properties of the electrodes, affecting areas several hundred microns in size around the molecular junction vicinity at room temperature. These findings are supported by magnetic resonance and magnetometer studies on ∼7000 MTJ pillars. MFM on the pillar sample showed an almost complete disappearance of the magnetic contrast. The spatial magnetic image suggests that molecular channels significantly impacted the spin density of states in the ferromagnetic electrodes. This advancement in MTJ-based molecular devices paves the way for a new generation of commercially viable logic and memory devices controlled by molecular quantum states at near-room temperatures.

Tyagi, Pawan (ORCID:0000000275411344)↗

Using an Analytic-Based Magnetic Charge Fourier Series Model to Study a Magnetic Lead Screw when Operating as a Magnetic Spring

A magnetic charge field analysis approach is presented that models an array of magnets by using a magnetic vector Fourier series representation. Using a Fourier series function enables the magnets' relative permeability to be accounted for and also reduces the computational burden. The accuracy of the presented modelling approach is validated by studying the fields and forces created by a magnetic lead screw when acting as a magnetic spring

Kouhshahi, Mojtaba Bahrami↗

Magnetic anisotropy and spin dynamics in the kagome magnet Fe 4 Si 2 Sn 7 O 16 : NMR and magnetic susceptibility study on oriented powder

Fe 4 Si 2 Sn 7 O 16 hosts an undistorted kagome lattice of Fe 2+ (3d 6 , S = 2) ions. We present results of bulk magnetization and Sn nuclear magnetic resonance (NMR) measurements on an oriented Fe 4 Si 2 Sn 7 O 16 powder sample oriented in geometries parallel (∥) and perpendicular (⊥) to the external applied magnetic field used for orienting the powder (Bori). The bulk susceptibility χ shows a broad peak at T N ~ 3 K associated with antiferromagnetic ordering. NMR spectra indicate the presence of planar anisotropy in the kagome planes. From an analysis of the static NMR shift (K) and dynamic spin-lattice relaxation rate (1/T 1 ) we conclude the presence of dominant magnetic fluctuations in the kagome planes. For the ∥ orientation, K scales linearly with the bulk susceptibility for temperatures down to ~ 4 K, while in the ⊥ orientation K starts to deviate strongly below T ~ 30 K. We associate this deviation with the onset of spin-tilting towards the kagome planes. These correlations are also reflected in the 1/T 1 data for the ∥ orientation, which starts to decrease below T ~ 30 K. Here, in this correlated regime, T N < T < ~ 30 K, we discuss the formation of positive chiral spin correlations in the kagome planes.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Evolution of structural and magnetic properties due to nanocrystallization of mechanically milled amorphous Pr-Co-B powders

Pr{sub 2}Co{sub 14}B permanent magnet powders were prepared by mechanical milling of an arc-melted ingot. X-ray diffraction analysis revealed the presence of the 2:14:1 phase after 1 h of milling which transformed into an amorphous phase with additional milling time. Increasing the milling time also lowered the intrinsic coercivity while the saturation magnetization increased up to 105 emu/g. Differential scanning calorimetry measurements revealed a crystallization temperature of around 560 °C. Upon annealing 30 h of as-milled amorphous powders between 500 and 900 °C, we observed the precipitation of the 2:14:1 phase. The optimum post-milling annealing temperature was 600 °C with an intrinsic coercivity of 7 kOe and maximum energy product of 6 MGOe.

36 MATERIALS SCIENCE↗

Use of external magnetic fields in hohlraum plasmas to improve laser-coupling

Efficient coupling of laser energy into hohlraum targets is important for indirect drive ignition. Laser-plasma instabilities can reduce coupling, reduce symmetry, and cause preheat. We consider the effects of an external magnetic field on laser-energy coupling in hohlraum targets. Experiments were performed at the Omega Laser Facility using low-Z gas-filled hohlraum targets which were placed in a magnetic coil with B{sub z} ≤ 7.5-T. We found that an external field B{sub z} = 7.5-T aligned along the hohlraum axis results in up to a 50% increase in plasma temperature as measured by Thomson scattering. The experiments were modeled using the 2-D magnetohydrodynamics package in HYDRA and were found to be in good agreement.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗