An EPR investigation of the dynamic Jahn-Teller effect in SrCl2-La/2 plus/
Second-order solutions of Hamiltonian functions for EPR study of Jahn-Teller effect in SrCl2-La/2 plus/
Boatner, L. A.↗
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Electron-paramagnetic-resonance investigation of the dynamic Jahn-Teller effect in SrC12-La/2 plus/
Electron paramagnetic resonance spectral investigation of dynamic Jahn-Teller effect in La doped strontium chloride, discussing structural variations as function of temperature
Boatner, L. A.↗
La Posta Astrogeophysical Observatory
An overview is presented of the equipment and data acquisition procedures at La Posta Astrogeophysical Observatory, located in the mountains, east of San Diego, Calif. It is a solar observatory, focusing on solar flares and the effect of solar activity on earth. It makes daily radio and optical observations of solar activity. Radio transmission in the earth atmosphere is monitored with VLF and HF equipment. A magnetometer monitors the state of the geomagnetic field.
Bleiweiss, M. P.↗
Resonance lines and energy levels of Cs III, Ba IV, and La V
Spectra of Cs III, Ba IV, and La V were photographed in a low-voltage sliding spark on a 10.7 m normal-incidence vacuum spectrograph. These ions are isoelectronic with neutral iodine and display a halogen-like energy level structure. Detailed isoelectronic comparisons, level transition diagrams, and tabular data on the transitions of the ions and percentage compositions of Cs III configurations are presented.
Epstein, G. L.↗
Astometry at La Silla
Astronomy of comets and minor planets is done regularly at ESO, La Silla, Chile. Plates are obtained with the 1 m Schmidt telescope and the 40 cm GPO, and CCD frames with the Danish 1.5 m telescope. Reductions are carried out by microdensitometer scanning and image processing at ESO, Garching, FRG. P/Halley will be observed intensively during the interval from perihelion passage on 9 February 1986 until the middle of March 1986. Almost real-time, accurate positions will be made in support of the spacecraft missions.
West, R. M.↗
A direct time series comparison between the La Jolla and Belfast radiocarbon records
For many years it has been widely assumed that the variations in the level of atmospheric carbon-14 were due to statistical fluctuations arising from experimental error. This is understandable since the signal/noise ratio is very low and the time sequences representing the variations are strongly stochastic. Interlaboratory comparisons show that baseline variations in the absolute value of the carbon-14 concentration do exist. However, assuming linearity, the delta 14C values are independent of these. The importance of assessing the quantitive reality of the delta 14C values is based upon their expression of the interplanetary cosmic ray source function, because in the range of 100 to 1000 year periods, there appears to be no evidence that the Earth's magnetic field is the source modulating function. Therefore the modulation is either due to changes in the solar atmosphere propagated out into the solar wind, or extra-heliospheric pressure effects, but these appear to be unlikely for the periods noted here. The recent availability of the new high quality Belfast time sequence of delta 14C now permits a simple mutual assessment of the several sequences which are available. Since the La Jolla record has been a standard for many years , these two were chosen for a simple comparison. Although differences exist, the close agreement between these two sequences, one carried out on White mountain Bristlecone pines, and the other done using Irish peat bog wood, is striking. This correlation between the two strongly reinforces the statistical view that the delta 14C record is that of real interplanetary modulation of the cosmic ray source leading to the generation of atmospheric 14C.
Sonett, C. P.↗
Evidence for superconductivity above 40 K in the La-Ba-Cu-O compound system
An apparent superconducting transition with an onset temperature above 40 K has been detected under pressure in the La-Ba-Cu-O compound system synthesized directly from a solid-state reaction of La2O3, CuO, and BaCO3 followed by a decomposition of the mixture in a reduced atmosphere. The experiment is described and the results of effects of magnetic field and pressure are discussed.
Chu, C. W.↗
Superconductivity above 90 K in the square-planar compound system ABa2Cu3O(6 + x) with A = Y, La, Nd, Sm, Eu, Gd, Ho, Er, and Lu
Superconductivity has been found in the 90-K range in ABa2Cu3O(6 + x) with A = La, Nd, Sm, Eu, Gd, Ho, Er, and Lu in addition to Y. The results suggest that the unique square-planar Cu atoms, each surrounded by four or six oxygen atoms, are crucial to the superconductivity of oxides in general. In particular, the high Tc of ABa2Cu3O(6 + x) is attributed mainly to the quasi-two-dimensional assembly of the CuO2-Ba-CuO(2 + x)Ba-CuO2 layers sandwiched between two A layers, with particular emphasis in the CuO(2 + x) layers. Higher-Tc oxides are predicted for compounds with bigger assemblies of CuO2 layers coupled by Ba layers.
Hor, P. H.↗
Magnetic field penetration depth of La(1.85)Sr(0.15)CuO4 measured by muon spin relaxation
Muon-spin-relaxation measurements have been performed on a high-Tc superconductor La(1.85)Sr(0.15)CuO4. In an external transverse magnetic field of 500 G, a magnetic field penetration depth of 2000 A at T = 10 K has been determined from the muon-spin-relaxation rate which increased with decreasing temperature below Tc. From this depth and the Pauli susceptibility, the superconducting carrier density is estimated at 3 x 10 to the 21st per cu cm. The zero-field relaxation rates above and below Tc were equal, which suggests that the superconducting state in this sample is not associated with detectable static magnetic ordering.
Kossler, W. J.↗
High-resolution synchrotron X-ray study of the structure of La(1.8)Ba(0.2)CuO(4-y)
X-ray diffraction of La(1.8)Ba(0.2)CuO(4-y) reveals two macroscopically segregated tetragonal (K2NiF4-type) phases of nearly identical lattice parameter. Many peaks show additional broadening upon cooling. This broadening is consistent with a spontaneous monoclinic distortion, with an onset temperature of about 150 K, and is possibly relevant to the superconducting properties. Small single crystals of about 70 micron diameter within the powder aggregate are also studied and show a similar two-phase constituency and a resolvable peak splitting at low temperature.
Moss, S. C.↗
NASA-UVA light aerospace alloy and structures technology program (LA(sup 2)ST)
The general objective of the Light Aerospace Alloy and Structures Technology (LA(sup 2)ST) Program is to conduct interdisciplinary graduate student research on the performance of next generation, light weight aerospace alloys, composites, and thermal gradient structures in collaboration with Langley researchers. Specific technical objectives are established for each research project. We aim to produce relevant data and basic understanding of material behavior and microstructure, new monolithic and composite alloys, advanced processing methods, new solid and fluid mechanics analyses, measurement advances, and critically, a pool of educated graduate students for aerospace technologies. Four research areas are being actively investigated, including: (1) Mechanical and Environmental Degradation Mechanisms in Advanced Light Metals and Composites; (2) Aerospace Materials Science; (3) Mechanics of Materials and Composites for Aerospace Structures; and (4) Thermal Gradient Structures.
Gangloff, Richard P.↗
The 1934 Contest for the Deutsch De La Meurthe Trophy
This report presents a description of the rules, history and new technical innovations in the Deutsch de la Meurthe Cup race of 1934.
Leglise, Pierre↗
Oxygen Tracer Diffusion in LA(z-x) SR(X) CUO(4-y) Single Crystals
The tracer diffusion of O-18 in La(2-x)Sr(x)CuO(4-y) single crystals (x = 0 to 0.12) has been measured from 400 to 700 C in 1 atm of oxygen using SIMS analysis. Evidence for diffusion by a vacancy mechanism was found at low strontium contents. Oxygen diffusivities for x greater than or = 0.07 were depressed by several orders of magnitude below the diffusivity for undoped La2CuO(4+/-y). The observed effects of strontium doping on oxygen diffusivity are discussed in terms of defect chemical models. The decreasing oxygen diffusivity with increasing strontium was attributed to the ordering of oxygen vacancies at large defect concentrations. A diffusion anisotropy D(sub ab)/D(sub c) of nearly 600 was also found at 500 C.
OXYGEN DIFFUSIVITY↗
X-Ray Photoemission Measurements of La(1-x)Ca(x)CoO3(x = 0, 0.5)
X-ray photoemission measurements of the core levels and valence electronic structure of LaCoO3 and La(0.5)Ca(0.5)CoO3 high quality epitaxial films are presented. Shifts of the core levels and main valence band features are consistent with a doping-induced change in the chemical potential. Oxygen states are found to significantly contribute to a peak in the valence band at 1 eV binding energy, verifying earlier results of cluster calculations. A Fermi level crossing of this same band upon doping is observed, yielding a high Fermi level density of states.
Vasquez, R. P.↗
A View from Space: Evolution of the 1997-98 El Nino and La Nina
After the last extreme El Nino in 1982-1983, an extensive in situ observing system was deployed in the tropical Pacific Ocean in support of monitoring and predicting El Nino. Within the past ten years a series of ocean and atmosphere remote sensing satellites have been launched that serve to supplement and enhance the observations being taken at the surface, and at depth, in the equatorial Pacific Ocean. The 1997-1998 "El Nino Event of the Century" has been the best monitored El Nino on record. The 1997-1998 El Nino will be the first time a major El Nino event and subsequent La Nina will have been observed from start to finish from a combination of remotely-sensed measurements of sea surface temperature, sea surface topography, sea surface winds, ocean color, and precipitation. Among some of the lessons learned to date from the 1997-1998 event have been the need for global observations in addition to just those in the equatorial Pacific Ocean. In this presentation the evolution of the 1997-1998 El Nino will be depicted from the unique vantage point provided by these space-based observations as analyzed separately, and together as a representation of the coupled system. Comparisons and contrasts with the evolution 1982-1983 El Nino and how the in situ and space-based observations complement each other will be discussed.
Busalacchi, Antonio J.↗
A View from Space: Evolution of the 1997-1998 El Nino and La Nina
After the last extreme El Nino in 1982-1983, an extensive in situ observing system was deployed in the tropical Pacific Ocean in support of monitoring and predicting El Nino. Within the past ten years a series of ocean and atmosphere remote sensing satellites have been launched that serve to supplement and enhance the observations being taken at the surface, and at depth, in the equatorial Pacific Ocean. The 1997-1998 "El Nino Event of the Century" has been the best monitored El Nino on record. The 1997-1998 El Nino will be the first time a major El Nino event and subsequent La Nina will have been observed from start to finish from a combination of remotely-sensed measurements of sea surface temperature, sea surface topography, sea surface winds, ocean color, and precipitation. Among some of the lessons learned to date from the 1997-1998 event have been the need for global observations in addition to just those in the equatorial Pacific Ocean. In this presentation the evolution of the 1997-1998 El Nino will be depicted from the unique vantage point provided by these space-based observations as analyzed separately, and together as a representation of the coupled system. Comparisons and contrasts with the evolution 1982-1983 El Nino and how the in situ and space-based observations complement each other will be discussed.
Busalacchi, Antonio J.↗
A View From Space: Evolution of the 1997-1998 El Nino and La Nina
After the last extreme El Nino in 1982-1983, an extensive in situ observing system was deployed in the tropical Pacific Ocean in support of monitoring and predicting El Nino. Within the past ten years a series of ocean and atmosphere remote sensing satellites have been launched that serve to supplement and enhance the observations being taken at the surface, and at depth, in the equatorial Pacific Ocean. The 1997-1998 "El Nino Event of the Century" has been the best monitored El Nino on record. The 1997-1998 El Nino will be the first time a major El Nino event and subsequent La Nina will have been observed from start to finish from a combination of remotely-sensed measurements of sea surface temperature, sea surface topography, sea surface wind, ocean color, and precipitation, Among some of the lessons learned to date from the 1997-1998 event have been the need for global observation in addition to just those in the equatorial Pacific Ocean. In this presentation the evolution of the 1997-1998 El Nino will be depicted from the unique vantage point provided by these space-based observations as analyzed separately, and together as a representation of the coupled system. Comparisons and contrasts with the evolution 1982-1983 El Nino and how the in situ and space-based observations complement each other will be discussed.
Busalacchi, Antonio↗
Global Surface Solar Energy Anomalies Including El Nino and La Nina Years
This paper synthesizes past events in an attempt to define the general magnitude, duration, and location of large surface solar anomalies over the globe. Surface solar energy values are mostly a function of solar zenith angle, cloud conditions, column atmospheric water vapor, aerosols, and surface albedo. For this study, solar and meteorological parameters for the 10-yr period July 1983 through June 1993 are used. These data were generated as part of the Release 3 Surface meteorology and Solar Energy (SSE) activity under the NASA Earth Science Enterprise (ESE) effort. Release 3 SSE uses upgraded input data and methods relative to previous releases. Cloud conditions are based on recent NASA Version-D International Satellite Cloud Climatology Project (ISCCP) global satellite radiation and cloud data. Meteorological inputs are from Version-I Goddard Earth Observing System (GEOS) reanalysis data that uses both weather station and satellite information. Aerosol transmission for different regions and seasons are for an 'average' year based on historic solar energy data from over 1000 ground sites courtesy of Natural Resources Canada (NRCan). These data are input to a new Langley Parameterized Shortwave Algorithm (LPSA) that calculates surface albedo and surface solar energy. That algorithm is an upgraded version of the 'Staylor' algorithm. Calculations are performed for a 280X280 km equal-area grid system over the globe based on 3-hourly input data. A bi-linear interpolation process is used to estimate data output values on a 1 X 1 degree grid system over the globe. Maximum anomalies are examined relative to El Nino and La Nina events in the tropical Pacific Ocean. Maximum year-to-year anomalies over the globe are provided for a 10-year period. The data may assist in the design of systems with increased reliability. It may also allow for better planning for emergency assistance during some atypical events.
Whitlock, C. H.↗