The Lid Domain of the MCP Hydrolase DxnB2 Contributes to the Reactivity toward Recalcitrant PCB Metabolites
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Shock compression experiments in the few hundred GPa (multi-Mbar) regime were performed on Lithium Deuteride single crystals. This study utilized the high velocity flyer plate capability of the Sandia Z Machine to perform impact experiments at flyer plate velocities in the range of 17–32 km/s. Measurements included pressure, density, and temperature between ~190 and 570 GPa along the Principal Hugoniot—the locus of end states achievable through compression by large amplitude shock waves—as well as pressure and density of reshock states up to ~920 GPa. As a result, the experimental measurements are compared with density functional theory calculations, tabular equation of state models, and legacy nuclear driven results that have been reanalyzed using modern equations of state for the shock wave standards used in the experiments.
A laboratory scale laser induced thermal desorption spectroscopy system is developed and tested on tungsten-deuterium and titanium-deuterium codeposits, and its feasibility as a hydrogenic inventory measurement diagnostic is demonstrated over a range of retention values from 5 × 10 19 m -2 to 7 × 10 23 m -2 for absorbed laser power densities as low as 8 MW m -2 . Codeposit layer samples are grown by magnetron sputtering and immersed in a weak argon rf plasma. A 1 kW fiber laser (λ = 1100 nm) heats the samples up to a peak surface temperature ranging from 900 to 1500 K using pulse widths of 0.5 and 1 s. Spectral line emission from Balmer series Dα and Hα from thermally desorbed deuterium and hydrogen, as well as line emission from argon, are monitored as a function of time using an optical spectrometer with maximum temporal resolution of 1 ms. To correct for wall recycling and pumping speed, and to accurately measure the time evolution of the laser-induced thermal desorption, the raw Dα signal is deconvolved with the system response function, which is obtained by injecting a short burst of D 2 to approximate an impulse. Calibration is done with a standard D 2 leak, and laser induced desorption spectroscopy deuterium retention values are found to be in good agreement with companion measurements made using conventional temperature programmed desorption on samples from the same codeposit batch.
Abstract not provided
Work is ongoing to create an instrumented and sampling system for monitoring aluminum clad spent nuclear fuel (ASNF) in dry storage. The anticipated system will be composed of a custom canister assembly and a modular instrument manifold. The conceptual design was first laid out in the Task Technical and Quality Assurance Plan (SRNL-RP-2019-00225). In this document, we outline the project progress to date, and describe the final system design.
The 3013-container package is used for the long-term storage of plutonium bearing materials at Department of Energy (DOE) sites. The package consists of three nested stainless-steel containers: outer, inner and convenience, which are made of stainless steel. The requirements of the DOE 3013 Standarda, also entail the development of a surveillance program, tasked to ensure structural integrity of the outer container for at least 50 years. The Materials Identification and Surveillance Working Group (MIS-WG) is specified to be responsible for selecting the containers for the surveillance as well as analyzing results. The MIS-WG determined that corrosion is a potential mechanism for container degradation with the most credible type of failure to be stress corrosion cracking (SCC) through wall breach of the inner container closure weld region (ICCWR). A breach of the inner container has the potential of allowing corrosive gases to be released into the safety class outer container.
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Objective: Create a means of evaluating seals w/o prototypes. Motivation: Cost Prototype 54" seal approx.$100k per seal pair FEA license + high end workstation approx. $30k per year. Development time: 6 months lead time for a new seal design Many designs per day (solution time <1 minute) Understanding: Difficult to experimentally measure strains, contact pressure profile, stresses, displacements
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An apparatus and a process for forming a protective barrier seal along a "ring of concern" of a transfer container used with double door systems is provided. A protective substrate is supplied between a "ring of concern" and a safety cover in which an adhesive layer of the substrate engages the "ring of concern". A compressive foam strip along an opposite side of the substrate engages a safety cover such that a compressive force is maintained between the "ring of concern" and the adhesive layer of the substrate.