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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Novel nitrogen-based organosulfur electrodes for advanced intermediate temperature batteries

Advanced secondary batteries operating at intermediate temperatures (100 to 200 C) have attracted considerable interest due to their inherent advantages (reduced corrosion and safety risks) over higher temperature systems. Current work in this laboratory has involved research on a class of intermediate temperature Na/beta double prime- alumina/RSSR batteries conceptually similar to Na/S cells, but operating within a temperature range of 100 to 150 C, and having an organosulfur rather than inorganic sulfur positive electrode. The organosulfur electrodes are based on the reversible, two electron eduction of organodisulfides to the corresponding thiolate anions, RSSR + 2 electrons yield 2RS(-), where R is an organic moiety. Among the advantages of such a generic redox couple for battery research is the ability to tailor the physical, chemical, and electrochemical properties of the RSSR molecule through choice of the organic moiety. The viscosity, liquidus range, dielectric constant, equivalent weight, and redox potential can in fact be verified in a largely predictable manner. The current work concerns the use of multiple nitrogen organosulfur molecules, chosen for application in Na/RSSR cells for their expected oxidizing character. In fact, a Na/RSSR cell containing one of these materials, the sodium salt of 5-mercapto 1-methyltetrazole, yielded the highest open circuit voltage obtained yet in the laboratory; 3.0 volts in the charged state and 2.6 volts at 100 percent discharge. Accordingly, the cycling behavior of a series of multiple nitrogen organodisulfides as well as polymeric organodisulfides are presented in this manuscript.

Visco, S. J.↗
NASA NTRS1990

Synthesis of Y1Ba2Cu3O(sub x) superconducting powders by intermediate phase reaction

One of the more striking problems for the synthesis of the Y1Ba2Cu3Ox compound is the high-temperature decomposition of the BaCO3. This compound is present as raw material or as an intermediate compound in chemical processes such as amorphous citrate, coprecipitation oxalate, sol-gel process, acetate pyrolisis, etc. This fact makes difficult the total formation reaction of the Y1Ba2Cu3Ox phase and leads to the presence of undesirable phases such as the BaCuO2 phase, the 'green phase', Y2BaCuO5 and others. Here, a new procedure to overcome this difficulty is studied. The barium cation is previously combined with yttrium and/or copper to form intermediate compounds which can react between them to give Y1Ba2Cu3Ox. BaY2O4 and BaCu2O3 react according to the equation BaY2O4+3BaCu2O3 yields 2Y1Ba2Cu3Ox. BaY2O4 is a stable compound of the Y2O3-BaO system; BaCu2O3 is an intimate mixture of BaCuO2 and uncombined CuO. The reaction kinetics of these phases have been established between 860 and 920 C. The phase evolution has been determined. The crystal structure of the Y1Ba2Cu3Ox obtained powder was studied. According to the results obtained from the kinetics study the Y1Ba2Cu3Ox the synthesis was performed at temperatures of 910 to 920 C for short treatment times (1 to 2 hours). Pure Y1Ba2Cu3Ox was prepared, which develops orthorombic type I structure despite of the cooling cycle. Superconducting transition took place at 91 K. The sintering behavior and the superconducting properties of sintered samples were studied. Density, microstructure and electrical conductivity were measured. Sintering densities higher than 95 percent D(sub th) were attained at temperatures below 940 C. Relatively fine grained microstructure was observed, and little or no-liquid phase was detected.

Moore, C.↗
NASA NTRS1990

Molecular gas in intermediate luminosity IRAS galaxies

Single dish CO (J = 1-0) measurements are reported for 29 galaxies of intermediate IR lumionosity in the IRAS Bright Galaxy sample, at distances in the range 20-40 Mpc. Most of the galaxies were mapped at 3-7 points with a 55 arcsec beam. The total H2 masses, assuming a standard Galactic CO-to-H2 conversion ratio, lie in the range of 500 million to 20 billion solar masses. The mean ratio of L(FIR)/M(H2) for this intermediate luminosity sample is approximately three times that found for Virgo spirals and approximately one-third of that found for a sample of higher-luminosity IRAS Bright Galaxies.

Tinney, C. G.↗
NASA NTRS1991

Formation of intermediate shocks in both two-fluid and hybrid models

Intermediate shocks are studied in a two-fluid model that includes finite ion inertia dispersion and in a hybrid model in which the full ion dynamics is retained while the electrons are treated as a massless fluid. It is shown that in both models intermediate shocks can be formed through wave steepening, meaning that they are stable and possess shock structures.

Wu, C. C.↗
NASA NTRS1992

Disk instability and outburst properties of the intermediate polar GK Persei

The present study reproduces the observed recurrence time scales and duration of the 1981-1989 dwarf nova-type outbursts of the intermediate polar GK Per with a model based on the time-dependent disk instability model. The model gives approximately symmetric (type B, inside-out) outbursts, as observed. This agreement suggests that the outbursts cannot result from a mass transfer instability. A modest variation of the mass transfer rate from the companion is sufficient to account for the variable outburst recurrence time scale. Contamination from the companion and the hot spot dominate the light from the disk except during a bright outburst. An intermediate temperature stagnation wave followed by a full heating wave is consistent with the observed rapid rise and double-peaked structure in the UV and optical light curves. It is argued that the hard X-ray efficiency is dime-dependent, and it is found to be much smaller in outburst than in quiescence.

Kim, Soon-Wook↗
NASA NTRS1992

Short- and intermediate-period oxygen-rich Miras

Available IR photometry and the period-IR luminosity relationship are used to analyze a nearly complete sample of oxygen-rich Miras at Galactic latitudes with /b/ greater than 30 deg. In agreement with previous kinematic studies, a marked difference is found in the spatial distributions between the stars with periods less than and those with periods greater than 300 d. For stars with periods in the range 300-400 d, the exponential scale height from the Galactic plane is close to 240 pc, the projected surface density is about 100/sq kpc, and the local space density is about 210/cu kpc. The progenitors of the Miras with periods greater than 300 d appear to be disk dwarfs with typical main-sequence masses of between 1.0 and 1.2 solar masses. The masses of the main-sequence progenitors of the short-period Miras are 1.1 solar masses or less. The duration of the Mira phase for the intermediate-period stars is estimated to be about 20,000 yr, somewhat longer than other recent estimates. Both short- and intermediate-period oxygen-rich Miras characteristically lose mass at about 10 exp -7 solar mass/yr.

Jura, M.↗
NASA NTRS1993

Physical properties and evolutionary time scales of disks around solar-type and intermediate mass stars

Recent observations of circumstellar disks and their evolutionary timescales are reviewed. It is concluded that disks appear to be a natural outcome of the star-formation process. The disks surrounding young stars initially are massive, with optically thick structures comprised of gas and micron-sized grains. Disk masses are found to range from 0.01 to 0.2 solar masses for solar-type PMS stars, and from 0.01 to 6 solar masses for young, intermediate mass stars. Massive, optically thick accretion disks have accretion rates between 10 exp -8 and 10 exp -6 solar masses/yr for solar type PMS stars and between 10 exp -6 and 10 exp -4 solar masses/yr for intermediate stars. The results suggest that a significant fraction of the mass comprising the star may have passed through a circumstellar accretion disk.

Strom, Stephen E.↗
NASA NTRS1939

Loads imposed on intermediate frames of stiffened shells

The loads imposed on intermediate frames by the curvature of the longitudinal and by the diagonal-tension effects are treated. A new empirical method is proposed for analyzing diagonal-tension effects. The basic formulas of the pure diagonal-tension theory are used, and the part of the total shear S carried by diagonal tension is assumed to be given the expression S (sub DT) = S (1-tau sub o/tau)(sup n) where tau (sub o) is the critical shear stress, tau the total (nominal shear stress), and n = 3 - sigma/tau where sigma is the stress in the intermediate frame. Numerical examples illustrate all cases treated.

STRESSED SKIN↗
NASA NTRS1992

Composite intermediate case manufacturing scale-up for advanced engines

This Manufacturing Technology for Propulsion Program developed a process to produce a composite intermediate case for advanced gas turbine engines. The method selected to manufacture this large, complex part uses hard tooling for surfaces in the airflow path and trapped rubber to force the composite against the mold. Subelements were manufactured and tested to verify the selected design, tools, and processes. The most significant subelement produced was a half-scale version of a composite intermediate case. The half-scale subelement maintained the geometry and key dimensions of the full-scale case, allowing relevant process development and structural verification testing to be performed on the subelement before manufacturing the first full-scale case.

Ecklund, Rowena H.↗
NASA NTRS1994

The intermediate line region of QSOs

Our recent statistical investigations of broad UV lines of luminous quasars (QSOs) suggest that the traditional broadline region (BLR) consists of two components-one of width approximately 2000 km/s FWHM with the peak within a few hundred kilometers per second of the systemic redshift, and another very broad component of width greater than or equal to 7000 km/s FWHM and blueshifted by greater than or equal to 1000 km/s. Differences in the relative strengths of these components account for much of the diversity of broad-line profiles, as well as relations among line strength, line width, asymmetry, and peak blueshift. We have suggested that the narrower component arises in a distinct intermediate-line region (ILR) that is an inner extension of the narrow-line region (NLR). We form spectra of the ILR and very broad line region (VBLR) in two complementary ways. First, using a small sample of high-quality spectra, we difference two composite spectra, one with FWHM (sub C IV) approximately 3000 km/s, the other with FWHM (sub C IV) approximately 7000 km/s (essentially a VBLR spectrum)-revealing a narrower line spectrum with FWHM approximately 2000 km/s. Second, we use a principal component analysis of 200 low signal-to-noise ratio spectra from the Large Bright Quasar Survey. The ILR is identified with the first principal component-that component accounting for most of the spectrum-to-spectrum variation. The VBLR spectrum is derived by subtracting this ILR from the mean spectrum. The two methods yield similar results, and the spectra of the ILR and VBLR are very different. Additional support for the existence of two component is the lack of a correlation between the equivalent widths of the ILR and VBLR. We discuss the relationships between the VBLR, the ILR, and the traditional NLR. The ILR line intensity ratios are distinctly different from those of the VBLR, with (relative to C IV lambda 1549) stronger Lyman alpha and weaker N v lambda 1240, lambda 1400 feature, He II lambda 1640, O III lambda 1663, and Al III lambda 1860. Comparison with other active galactic nuclei (AGN) emission-line regions shows that the ILR spectrum tends to be intermediate between that of the VBLR and that of gas more distant from the ionizing continuum, such as the NLR and extended Lyman alpha nebulosity. Comparison of the spectra with results from photoionization models suggests that, compared with the VBLR, the ILR is about 10 times more distant from the ionizing continuum (approximately 1 pc), 100 to 1000 times less dense (10(exp 10)/cu cm), and has a smaller covering factor (less than or approximately 3%, compared with approximately 24% for the VBLR).

Brotherton, M. S.↗
NASA NTRS1994

The hard X-ray emission spectra from accretion columns in intermediate polars

We consider the hard (greater than 2 keV) X-ray emission from accretion columns in an intermediate polar system, GK Per, using a simple settling solution. The rate of photon emission per logarithmic energy interval can be fitted with a power law, E(exp -gamma), with gamma approximately 2.0, in agreement with observations. This index is only weakly dependent on the mass accretion rate, dot-M, for dot-M in the range of a few times 10(exp 16-18) g/s. The peak energy of the photon spectra (after photoelectric absorption) is expected to be E(sub p) approximately (5 keV) gamma(exp -1/3) (N(sub H)/10(exp 23)/sq cm)(exp 1/3) where N(sub H) is the hydrogen column density along the line of sight. The observed spectra of GK Per and possibly of V1223 Sgr suggest N(sub H) approximately 10(exp 23)/sq cm. This large N(sub H) may be due to partially ionized preshock column material. Alternatively, we also consider absorption by the cool outer parts of an accretion disk. In this case the photoelectric absorption depth in the disk is a sensitive function of inclination. For GK Per the required inclination is approximately 83 deg. For mass accretion rates larger than a critical rate of approximately 10(exp 18) g/s, X-ray emission from the column accretion is significantly affected by radiation drag. Although the mass accretion rate increases dramatically during outbursts, the observed hard (greater than 2 keV) X-ray luminosity will not rise proportionately. The slope and peak energy of the outburst spectra are only weakly affected. We conclude that the observed X-ray spectra can be explained by this simple analytic solution and that the production of hard X-rays from the accretion shock at the magnetic poles in the intermediate polars is in general agreement with the observations. However, since the X-ray emission and absorption depend on the mass accretion rate in a complicated manner, observed hard X-ray luminosities (greater than 2 keV) are not a good indicator of the mass accretion rate in the X-ray emitting regions.

Yi, Insu↗
NASA NTRS1994

Spectral energy distributions of the brightest Palomar-Green quasars at intermediate redshifts

We have combined low-dispersion International Ultraviolet Explorer (IUE) spectra with the optical/near-IR spectrophotometry of Neugebauer et al. (1987) in order to study the spectral energy distributions of seven of the brightest Palomar-Green (PG) quasars at intermediate redshifts (Z(sub em) greater than or equal to 0.9 and less than or equal to 1.5). Some of these PG quasars are barely detectable in long IUE exposures, so we have used the Gaussian Extraction (GEX) technique to maximize the signal-to-noise of the IUE data, and we have co-added all spectra available from the IUE archive for each QSO unless the ultraviolet spectra varied significantly from one exposure to the next. We have corrected the spectral energy distributions for Milky Way reddening using the observed neutral hydrogen column densities on each sight line and the gas-to-dust relation recently derived by Diplas & Savage. Six of the seven quasars are detected down to lambda much less than 700 A in the rest frame, and consequently continuum reddening due to dust in the immediate vicinity of the quasar can have a dramatic effect on the spectral energy distributions. In order to explore the possible importance of intrinsic continuum reddening, we have assembled a heuristic extinction curve which extends to lambda much less than 912 A. Using this heuristic extinction curve, we derive reasonable upper limits on the intrinsic E(B-V) for each quasar. We briefly discuss some of the implications of the derived intrinsic continuum reddening limits. We use geometrically thin accretion disk models to derive the black hole masses and accretion rates implied by the spectral energy distributions. Even if we neglect intrinsic reddening, we find that a large fraction of the quasars require super-Eddington accretion rates (which is not consistent with the thin disk assumption). Comparison of the data in this paper to a large body of data from the literature on the accretion disk M(sub BH) - M dot grid calculated by Wandel & Petrosian reveals that our quasars are among the brightest in the sky at 1450 A, and ostensibly suggests that the fraction of quasars which require super-Eddington accretion rates is much smaller than the fraction that we derive from our data alone. However, intrinsic continuum reddening has been ignored in this comparison, and a small amount of intrinsic reddening will push more of the quasars into the super-Eddington regime. We also plot the recent reverberation monitoring results on NGC 5548 and NGC 3783 on the Wandel & Petrosian grid, and we find that these Seyfert galaxies appear to vary along lines of constant M(sub BH). Continuum flux from two of the quasars in our main sample, PG 1338+416 and PG 1630+377, is detected at lambda(sub rest) less than 584 A. These quasars can in principle be used for the He I Gunn-Peterson test, but the S/N of IUE spectra of individual objects is usually too low to place interesting limits on the Gunn-Peterson optical depth. In order to improve the S/N, we have formed a composite spectrum from the spectra of five quasars detected with IUE at lambda(sub rest) less than 584 A, and we have used this composite spectrum to place a tighter limit on tau(sub GP, He I). We briefly discuss intermediate-redshift Lyman limit systems (Z(sub LL) greater than or equal to 0.5 and less than or equal to 1.6) detected in the IUE spectra of five quasars, including lower limits on N(H I) in each Lyman limit system.

Tripp, Todd M.↗
NASA NTRS1995

Physics of intermediate shocks: A review

Intermediate shocks (ISs) lead to a transition from super-Alfvenic to sub-Alfvenic flow and are different from slow and fast shocks in that an IS rotates the component of the magnetic field tangent to the shock plane by 180 deg. Another peculiarity of ISs is that for the same upstream conditions an IS can have two different downstream states. There also exist a second class of ISs which rotate the magnetic field by an angle other than 180 deg. Due to their noncoplanar nature they cannot be time-stationary and are referred to as time-dependent intermediate shocks (TDIS). The existence of ISs has been the subject of much controversy over the years. Early studies questioned the physical reality of ISs. However, the studies of ISs found a new impetus when C.C. Wu showed that ISs do exist and are stable within the resistive MHD framework. In this paper, after a brief historical overview of the subject, we will review the latest developments in the study of ISs. In particular, we will address the questions of stability and structure of ISs and the relationship between ISs and other discontinuities. One of the recent developments has been the finding that ISs can be unsteady, reforming in time. Details of this process will be discussed. Finally, we examine the effect of anisotropy on the resolutions and discuss the relevance of ISs to the observed field rotations at the Earth's magnetopause.

Karimabadi, H.↗
NASA NTRS1995

The influence of intermediate-scale variations in the heliospheric magnetic field on the transport of galactic cosmic rays

Variations in the heliospheric magnetic field occur on most scales including those lying intermediate between the gyro-radii of galactic cosmic rays and heliocentric radial distance. It is demonstrated that a correlation exists between these intermediate-scale variations in the magnetic field and the variations in the cosmic ray distribution function that result from the field variations. This correlation will affect the average transport of galactic cosmic rays by significantly altering the patterns of gradient and curvature drifts in the heliosphere. During the current solar cycle, the altered drift patterns can lead to larger radial gradients of the galactic cosmic rays and significantly smaller latitude gradients than is expected only from drifts in the mean magnetic field.

Fisk, L. A.↗
NASA NTRS1994

Intermediates in the Formation of Aromatics in Hydrocarbon Combustion

The formation of the first benzene ring is believed to be the rate limiting step in soot formation. Two different mechanisms have been proposed for formation of cyclic C6 species. The first involves the reaction of two acetylenes to give CH2CHCCH (vinyl acetylene), the loss of a H to give CHCHCCH (n-C41-13) or CH2CCCH (iso-C4H3), and addition of another acetylene to n-C4H3, followed by ring closure to give phenyl radical. Miller and Melius argue that only n-C4H3 leads to phenyl radical and since iso-C4H3 is more stable than n-C4H3 this mechanism is unlikely. An alternative mechanism proposed by them is formation of benzene from the dimerization of two CH2CCH (propargyl) radicals (formed by the reaction of singlet methylene with C2H2). We report reaction pathways and accurate energetics (from CASSCF/internally contracted CI calculations) for the reactions of CH(pi-2) and CH2-1 with acetylene, the reaction of vinylidene with acetylene, and the reaction of n-C4H3 and iso-C4H3 with acetylene. These calculations identify two new reactive intermediates CHCHCH ( a A"-2 ground state in Cs symmetry; spin coupling is a doublet from three singly occupied orbitals) and CHCCH (B-3 ground state in C2 symmetry) from the reaction of CH with acetylene. These species dimerize with no barrier to form benzene and para-benzyne, respectively. CHCCH is proposed as a reactive intermediate which can add to benzene to give higher polynuclear aromatic hydrocarbons or fullerenes. The addition of a C3H2 unit releases two C-C bond energies and thus the resulting addition product contains sufficient energy to break several CH bonds leading to a reduction in the H to C ratio as the cluster size increases. It is found that iso-C4H3 adds to acetylene to initially give a fulvene radical but that this species rearranges to phenyl radical. Thus, the reaction of acetylene with iso-C4H3 does lead to phenyl radical and the cyclization pathway may also contribute to formation of the initial benzene ring.

Walch, Stephen P.↗
NASA NTRS2002

XTE Observations of Intermediate Polars: RXTE TOO Observations of Supernovae

Two intermediate polar cataclysmic variables, PQ Gem and AO Psc, were observed jointly with the Rossi X-ray Timing Explorer (RXTE) and ground-based photometry. The analysis of intermediate polars (IPs) is complex because these objects exhibit light curves that behave differently as a function of energy and that behave differently when phased on the orbital or on the spin periods. The presence of two periods in one system is essentially equivalent to analyzing two different X-ray sources. A preliminary analysis of the PQ Gem data was carried out and presented at the Annapolis Workshop on Magnetic Cataclysmic Variables. The final analysis of the data were held up by problems with the background estimation. The RXTE PCA team has released a new version of the background estimator. The PQ Gem must be reanalyzed using the new background. We have also installed a spectral model that calculates the expected emission from an accretion column. That model is undergoing final testing before we apply it to the data.

Schlegel, E.↗
NASA NTRS1993

Deriving the intermediate spectra and photocycle kinetics from time-resolved difference spectra of bacteriorhodopsin. The simpler case of the recombinant D96N protein

The bacteriorhodopsin photocycle contains more than five spectrally distinct intermediates, and the complexity of their interconversions has precluded a rigorous solution of the kinetics. A representation of the photocycle of mutated D96N bacteriorhodopsin near neutral pH was given earlier (Varo, G., and J. K. Lanyi. 1991. Biochemistry. 30:5008-5015) as BRhv-->K<==>L<==>M1-->M2--> BR. Here we have reduced a set of time-resolved difference spectra for this simpler system to three base spectra, each assumed to consist of an unknown mixture of the pure K, L, and M difference spectra represented by a 3 x 3 matrix of concentration values between 0 and 1. After generating all allowed sets of spectra for K, L, and M (i.e., M1 + M2) at a 1:50 resolution of the matrix elements, invalid solutions were eliminated progressively in a search based on what is expected, empirically and from the theory of polyene excited states, for rhodopsin spectra. Significantly, the average matrix values changed little after the first and simplest of the search criteria that disallowed negative absorptions and more than one maximum for the M intermediate. We conclude from the statistics that during the search the solutions strongly converged into a narrow region of the multidimensional space of the concentration matrix. The data at three temperatures between 5 and 25 degrees C yielded a single set of spectra for K, L, and M; their fits are consistent with the earlier derived photocycle model for the D96N protein.

NASA Program Exobiology↗
NASA NTRS1992

Protein changes associated with reprotonation of the Schiff base in the photocycle of Asp96-->Asn bacteriorhodopsin. The MN intermediate with unprotonated Schiff base but N-like protein structure

The difference Fourier transform infrared spectrum for the N intermediate in the photoreaction of the light-adapted form of bacteriorhodopsin can be recorded at pH 10 at 274 K (Pfefferle, J.-M., Maeda, A., Sasaki, J., and Yoshizawa, T. (1991) Biochemistry 30, 6548-6556). Under these conditions, Asp96-->Asn bacteriorhodopsin gives a photoproduct which shows changes in protein structure similar to those observed in N of wild-type bacteriorhodopsin. However, decreased intensity of the chromophore bands and the single absorbance maximum at about 400 nm indicate that the Schiff base is unprotonated, as in the M intermediate. This photoproduct was named MN. At pH 7, where the supply of proton is not as restricted as at pH 10, Asp96-->Asn bacteriorhodopsin yields N with a protonated Schiff base. The Asn96 residue, which cannot deprotonate as Asp96 in wild-type bacteriorhodopsin, is perturbed upon formation of both MN at pH 10 and N at pH 7. We suggest that the reprotonation of the Schiff base is preceded by a large change in the protein structure including perturbation of the residue at position 96.

Non-NASA Center↗