Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Intact”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Impact of Different Vegetative Cover Scenarios on Infiltration Rates for the E-Area PA Intact Case

This memorandum addresses the effects of vegetative cover type (bamboo versus Bahia grass) and the timing of pine tree intrusion on intact infiltration rate for the proposed E-Area Low-Level Waste Facility (LLWF) closure cap system. It builds upon earlier reports whose purpose is to lay the foundation for the infiltration data package that will be assembled during the next revision of the E-Area LLWF Performance Assessment (PA).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Intact Infiltration Model Design Check for E-Area LLWF

A design check will be performed on the infiltration-rate time profile for the intact case for the proposed E-Area Low-Level Waste Facility (LLWF) final closure cap design.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

Intact, Commercial Lithium-Polymer Batteries: Spatially Resolved Grating-Based Interferometry Imaging, Bragg Edge Imaging, and Neutron Diffraction

We survey several neutron imaging and diffraction methods for non-destructive testing and evaluation of intact, commercial lithium-ion batteries. Specifically, far-field interferometry was explored as an option to probe a wide range of autocorrelation lengths within the batteries via neutron imaging. The dark-field interferometry images change remarkably from fresh to worn batteries, and from charged to discharged batteries. When attempting to search for visual evidence of battery degradation, neutron Talbot-Lau grating interferometry exposed battery layering and particle scattering through dark-field imaging. Bragg edge imaging also reveals battery wear and state of charge. Neutron diffraction observed chemical changes between fresh and worn, charged and discharged batteries. However, the utility of these methods, for commercial batteries, is dependent upon battery size and shape, with 19 to 43 mAh prismatic batteries proving most convenient for these experimental methods. This study reports some of the first spatially resolved, small angle scattering (dark-field) images showing battery degradation.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Comparison of Intact Fish Skin Graft and Allograft as Temporary Coverage for Full-Thickness Burns: A Non-Inferiority Study

The extent and depth of burn injury may mandate temporary use of cadaver skin (allograft) to protect the wound and allow the formation of granulation tissue while split-thickness skin grafts (STSGs) are serially harvested from the same donor areas. However, allografts are not always available and have a high cost, hence the interest in identifying more economical, readily available products that serve the same function. This study evaluated intact fish skin graft (IFSG) as a temporary cover to prepare the wound bed for STSG application. Thirty-six full-thickness (FT) 5 × 5 cm burn wounds were created on the dorsum of six anesthetized Yorkshire pigs on day -1. To mimic the two-stage clinical situation, on day 0, wounds were excised down to a bleeding wound bed and a temporary cover (either IFSG or cadaver porcine skin) was applied; then, on day 7, wounds were debrided to a viable wound bed prior to the application of autologous 1.5:1 meshed STSG (mSTSG). Rechecks were performed on days 14, 21, 28, 45, and 60 with digital images, non-invasive measurements, and punch biopsies. The IFSG created a granulated wound bed receptive to the application of an mSTSG. FT burn wounds treated with an IFSG had similar outcome measures, including contraction rates, trans-epidermal water loss (TEWL) measurements, hydration, and blood perfusion levels, compared to cadaver skin-treated burn wounds. Pathology scoring indicated significant differences between the allograft- and IFSG-treated wounds on day 7, with the IFSG having increased angiogenesis, granulation tissue formation, and immune cells. Pathology scoring indicated no significant differences once mSTSGs were applied to wounds. The IFSG performed as well as cadaver skin as a temporary cover and was not inferior to the standard of care, suggesting the potential to transition IFSGs into clinical use for burns.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2021

Counting mRNA copies in intact bacterial cells by fluctuation localization imaging-based fluorescence in situ hybridization (fliFISH)

A method for measuring mRNA copies in intact bacterial cells by fluctuation localization imaging-based fluorescence in situ hybridization (fliFISH) is presented. Unlike conventional single molecule FISH, where the presence of a transcript is determined by fluorescence intensity, fliFISH relies on On-Off duty cycles of photo-switching dyes to set a predetermined threshold for distinguishing true signals from background noise. The method provides a quantitative approach for detecting and counting true mRNA copies and rejecting false signals with high accuracy.

Hu, Dehong↗
DOE OSTI2018

Dynamic Leaching Method for Intact Salt-stone Samples - 18495

At the Savannah River Site (SRS) low activity salt solution is stabilized via encapsulation within a grout termed salt-stone. Salt-stone is emplaced into large (multi-million liter) concrete storage containers referred to as Salt-stone Disposal Units (SDUs). Technetium-99 (Tc-99) and iodine-129 (I-129) are long-lived radionuclides contained in the low activity salt waste and subsequently incorporated into the grout waste form: both radionuclides are contributors to the potential long-term radiation exposure of the public and environment surrounding the SDUs. With respect to Tc-99, in the reducing, high pH environment within the grout, Tc-99 is expected to be relatively immobile since it exists in a reduced Tc(IV) oxidation state in the form of sparingly soluble hydrated oxides (TcO{sub 2}.xH{sub 2}O) or sulfides (TcS{sub x}). However, in the presence of O{sub 2} (associated with the future infiltration of air or oxygenated ground waters into the salt-stone monolith) it is possible for redox-sensitive Tc(IV) to transition into highly soluble (and mobile) Tc(VII) species, such as pertechnetate (TcO{sub 4}{sup -}), which are more readily transported to the surrounding environment. In contrast, I-129 is highly soluble and its leaching behavior is not anticipated to be significantly impacted by potential changes in redox environment or pH within salt-stone. Traditional approaches to quantifying the leaching behavior of Tc-99 and I-29 from cementitious matrices have involved partitioning experiments using size-reduced (crushed/ground) samples, and determination of the radionuclide fraction immobilized by the cementitious solids. Such experiments create artificially high solid-liquid contact areas that likely result in higher Tc-99 and I-129 leachate concentrations than would be expected for intact, monolithic samples. In the current study a new technique, termed the Dynamic Leaching Method (DLM), is being used to initially investigate the Tc-99 leaching behavior from monolithic salt-stone samples; the system will be used at a later date to evaluate the leaching characteristics of I-129. The data derived using this technique is intended to inform the SRS Salt-stone Disposal Facility (SDF) Performance Assessment (PA) which models the long-term transport of radionuclides from the SDUs to the environment. The DLM utilizes a flexible-wall permeameter to achieve saturated leaching under an elevated hydraulic gradient to simulate and accelerate the future transport of groundwater through salt-stone. Leachates are regularly analyzed with respect to radionuclide concentrations, key constituent concentrations (e.g., Al, Ca, Mg, Na, Si, CO{sub 3}{sup 2-}, NO{sub 2}{sup -}, NO{sub 3}{sup -}, SO{sub 4}{sup 2-}), pH, and reduction potential (E{sub h}) in order to develop an understanding of how chemical changes associated with the pore solution influence grout weathering and radionuclide leaching behavior. This paper provides a brief update with respect to data derived from preliminary Tc-99 leaching evaluations as the DLM was being developed, but the paper is predominantly focused on new sample data in which the DLM technique, pre- and post-DLM salt-stone sample characterization, and leachate analysis protocols have been optimized. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

Binding, Release and Functionalization of Intact Pnictogen Tetrahedra Coordinated to Dicopper Complexes

The bridging MeCN ligand in the dicopper(I) complexes [(DPFN)Cu 2 (μ,η 1 : η 1 -MeCN)][X] 2 (X=weakly coordinating anion, NTf 2 (1 a), FAl[OC 6 F 10 (C 6 F 5 )] 3 (1 b), Al[OC(CF 3 ) 3 ] 4 (1 c)) was replaced by white phosphorus (P 4 ) or yellow arsenic (As 4 ) to yield [(DPFN)Cu 2 (μ,η 2 : η 2 -E 4 )][X] 2 (E=P (2 a-c), As (3 a-c)). The molecular structures in the solid state reveal novel coordination modes for E 4 tetrahedra bonded to coinage metal ions. Experimental data and quantum chemical computations provide information concerning perturbations to the bonding in coordinated E 4 tetrahedra. Reactions with N-heterocyclic carbenes (NHCs) led to replacement of the E 4 tetrahedra with release of P 4 or As 4 and formation of [(DPFN)Cu 2 (μ,η 1 : η 1 - Me NHC)][X] 2 (4 a,b) or to an opening of one E-E bond leading to an unusual E 4 butterfly structural motif in [(DPFN)Cu 2 (μ,η 1 : η 1 -E 4 Dipp NHC)][X] 2 (E=P (5 a,b), E=As (6)). With a cyclic alkyl amino carbene ( Et CAAC), cleavage of two As-As bonds was observed to give two isomers of [(DPFN)Cu 2 (μ,η 2 : η 2 -As 4 Et CAAC)][X] 2 (7 a,b) with an unusual As 4 -triangle+1 unit.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Shining a spotlight on intact proteins

Cells react to cues from their environment using various mechanisms that include changes in metabolites, gene expression, protein binding partners, protein localization, and protein posttranslational modifications (PTMs), all of which contribute to altered cellular signatures that enable appropriate cellular responses. Given the seemingly infinite number of mechanisms available to affect protein function and modulate biological processes, the question arises as to how cells manage to interpret protein readouts to accomplish the appropriate cell-type specific response to a particular stimulus.

Environmental Molecular Sciences Laboratory↗
DOE OSTI2022

Land use-land cover gradient demonstrates the importance of perennial grasslands with intact soils for building soil carbon in the fertile Mollisols of the North Central US

The impact of land use change and agricultural management on the cycling of soil organic carbon (SOC) is not well understood, limiting our ability to manage for, and accurately model, soil carbon changes at both local and regional scales. To address this issue, here we combined long-term soil incubations with acid-hydrolysis and dry combustion to parse total SOC (C t ) into three operationally defined SOC pools (active, slow, and recalcitrant) from 9 long-term sites with varying land uses on current and former tallgrass prairie soil. Land uses represented a gradient of soil disturbance histories including remnant prairie, restored prairie, grazed pasture, annual crop rotations, and continuous maize. Dry combustion was used to estimate total carbon (C t , physical), while acid hydrolysis of both the active (C a ) and slow (C s ) pools was used to estimate a recalcitrant carbon pool (C r , chemical). Non-linear modeling of CO 2 efflux data from the long-term incubations was then used to estimate C a , and the decomposition rates of both C a and C s (k a and k r , biological). The size of the slow pools C s was then defined mathematically as C t- (C a + C r ). Remnant prairie had the highest C t , while cool-season pasture and a 35-y-old restored prairie had higher C t than the other agricultural systems. All agricultural systems, including pasture, had the highest fraction of C t as C r (~50%), whose mean residence time (MRT) in these soils is ≥500 years (Paul et al., 2001a) demonstrating that this fraction persists, while the more labile fractions were lost over the course of a few months (C a ) to a few decades (C s ) as a result of tillage-intensive agriculture. The two- to four-decade MRT time of C s indicated a pool likely to be more responsive to the 20 to 40 years of land-use practices used at some of the sites. The C s pool was largest in the remnant- and 35-y-old prairies indicating significant C accrual and stabilization compared to the agricultural ecosystems. Interestingly, the remnant prairie maintained the highest C a pool as well, demonstrating the strong connection between the quantity of fresh C inputs and the potential for long-term C stabilization and accrual. The accumulation of C in active (≈labile) pools as a first step toward long-term stabilization highlights the tenuous nature of early carbon gains, which can be quickly lost in response to climate change or poor management.

54 ENVIRONMENTAL SCIENCES↗