The simultaneous inference of stratospheric trace gases with overlapping spectral signatures using limb sounding radiometry
An inversion algorithm has been developed to simultaneously infer the concentrations of two gases with overlapping spectral signatures using limb emission measurements. The algorithm is efficient and provides a solution in two or three iterations. It has been applied in a simulation study to the inference of stratospheric NO2-H2O and HNO3-CF2Cl2. Existing satellite instrumentation was the basis for errors used in the calculations. It is estimated that concentrations of all four gases can be determined with errors of about 20 percent. This assumes an estimated 1980 CF2Cl2 level. Also, other error sources due to contaminant gas, aerosol emission, and the temperature profile must be included to obtain a better estimate of experimental accuracies.