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At least 73 records · Page 4

Two-directional-flow, axial-motion-joint flow liner

Flow liner eliminates high-cycle fatigue in ducts carrying cryogenic fluids. It is capable of handling two-directional, high-velocity cryogenic liquid flow with a 3-inch axial motion without binding within a 25-inch length.

Bissing, L. L.↗

A computer program to evaluate optical systems

A computer program is used to evaluate a 25.4 cm X-ray telescope at a field angle of 20 minutes of arc by geometrical analysis. The object is regarded as a point source of electromagnetic radiation, and the optical surfaces are treated as boundary conditions in the solution of the electromagnetic wave propagation equation. The electric field distribution is then determined in the region of the image and the intensity distribution inferred. A comparison of wave analysis results and photographs taken through the telescope shows excellent agreement.

Innes, D.↗

Rate of recombination of oxygen atoms and CO at temperatures below ambient

The measurements reported were conducted with 30.0 torr CO, 40.0 torr argon, and varying amounts of carbon dioxide from about 20 to 230 torr. Measurements were made at 277, 272, 263, and 257 K. The pseudo-first-order decay rate as a function of carbon dioxide pressure is shown in a graph. An Arrhenius plot for the rate constants obtained from the measurements is also presented. A value for the activation energy was determined on the basis of a linear least-squares fit to the data.

Inn, E. C. Y.↗

Lyman-band fluorescence intensity vs H2 pressure

The fluorescence intensity of the H2 Lyman bands excited by the argon 1066 A line is found to be a linear function of the H2 pressure. The fluorescence from naturally occurring HD is linearly dependent on the HD partial pressure. The experiments described show that these fluorescence intensities can be used to measure the H2 and HD densities below 10 trillion molecules per cu cm.

Inn, E. C. Y.↗

Absorption coefficient of HCl in the region 1400 to 2200 A

The results of absorption coefficient measurements of HCl in the region 1400 to 2200 A are reported and compared with those previously published. It is concluded that the present results represent the best compromise of all measurements and should be used for any calculations on the photodissociation rate of HCl in planetary atmospheres.

Inn, E. C. Y.↗

Lower stratosphere measurements of variation with latitude of CF2Cl2, CFCl3, CCl4, and N2O profiles in the northern hemisphere

Measurements were made from a U-2 aircraft of profiles of CF2Cl2, CFCl3, CCl4 and N2O in the lower stratosphere in a meridional survey at a longitude of 159 deg W during the period October 1 to November 14, 1976. The latitude distributions obtained show a marked decrease in mixing ratio with increasing latitude from about 7 deg N in the Intertropical Convergence Zone to about 79 deg N. The results suggest the importance of meridional transport and mixing in the stratosphere in accounting, at least in part, for the observed profile variation with latitude. The contaminants C2F4Cl2, C2F3Cl3, CHCCl3 and SF6 were also detected but their mixing ratios were small and no accurate standards were prepared for them.

Vedder, J. F.↗

Trace constituent mixing ratios in the lower stratosphere during the 1977 intertropical convergence zone experiment

Minor constituents in the atmosphere can play an important role as tracers in studies of atmospheric transport and mixing. Simultaneous measurements of the vertical distribution of trace constituents in the troposphere and lower stratosphere were conducted in the region of the Intertropical Convergence Zone (ITCZ). An effort was made to measure the mixing ratios of selected trace constituents. A cryogenic sampling system on board a U-2 aircraft was used to acquire whole-air samples and to cryogenically collect samples at 13.7 to 21.3 km. Simultaneous tropospheric measurements using whole-air sampling canisters on board a Learjet aircraft were also carried out.

Vedder, J. F.↗

COS in the stratosphere

Carbonyl sulfide (COS) has been detected in the stratosphere, and mixing ratio measurements are reported for altitudes of 15.2 to 31.2 km. A large volume, cryogenic sampling system mounted on board a U-2 aircraft has been used for lower stratosphere measurements and a balloon platform for measurement at 31.2 km. These observations and measurements strongly support the concept that stratospheric COS is an important precursor in the formation of sulfuric acid aerosols.

Inn, E. C. Y.↗

Aircraft NO/x/ emissions and stratospheric ozone reductions - Another look

New estimates for stratospheric ozone perturbations attributable to supersonic transport (SST) emissions are presented. First, a review is given of recent data pointing to lower OH concentrations below 30 km, as compared to the values predicted by photochemical models. The evidence for lower OH comes from a wide range of laboratory and atmospheric studies. The sensitivity of theoretical estimates of ozone change to OH abundances, and the coupling mechanisms between the O(x)-NO(x)-HO(x)-Cl(x) families which are responsible for the sensitivity, are discussed. Updated calculations for SST-induced ozone alterations are compared with older predictions. For example, assuming continuous aircraft injection of NO2 at 20 km at a rate of 1 x 10 to the 9th kg per year (globally), a 4% ozone decrease, is now calculated where earlier a 3% ozone increase was found. This large variance from previous forecasts suggests that new assessments of certain other polluting agents, particularly nitrogen fertilizers, are needed.

Turco, R. P.↗

Gaseous constituents in the plume from eruptions of Mount St. Helens

Measurements in the stratosphere of gaseous constituents in the plume of Mount St. Helens were obtained during five flights of the NASA U-2 aircraft between 19 May and 17 June 1980. Mixing ratios from gas chromatographic measurements on samples acquired about 24 hours after the initial eruption show considerable enhancement over nonvolcanic concentrations for sulfur dioxide (more than 1000 times), methyl chloride (about 10 times), and carbon disulfide (more than 3 times). The mixing ratio of carbonyl sulfide was comparable to nonvolcanic mixing ratios although 3 days later it was enhanced two to three times. Ion chromatography measurements on water-soluble constituents are also reported. Very large concentrations of chloride, nitrate, and sulfate ions were measured, implying large mixing ratios for the water-soluble gaseous constituents from which the anions are derived. Measurements of radon-222 present in the plume are also reported.

Inn, E. C. Y.↗

Stratospheric hydroxyl radical concentrations - New limitations suggested by observations of gaseous and particulate sulfur

A one-dimensional aerosol model is employed in investigating the sensitivity of the stratospheric distributions of gaseous sulfur compounds and sulfate aerosol particles to changes in OH and CS2 concentrations, in eddy diffusion coefficients, and in important chemical rate constants. By comparing model predictions with recent observational data for SO2, OCS, and particulates, it is found that, with regard to atmospheric sulfur, CS2 is only a secondary source of sulfur for the stratosphere relative to OCS and that background tropospheric CS2 concentrations by volume are likely to be less than 70 parts per trillion. It is also established that under stratospheric conditions the rate coefficients for the reactions of OH with OCS and CS2 may be substantially smaller than the room temperature laboratory values of Kurylo (1978).

Turco, R. P.↗