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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

An Investigation into the Surface Skidding Response of PBX 9501 and PBX 9502

While polymer-bonded explosives, PBX, have reduced sensitivity to ignition from mechanical shock or heating compared to conventional explosives, the investigation of the mechanical ignition mechanisms for PBX remains vital to assessing the safety during machining and general handling. Under frictional heating, hot spot generation due to high melting point contaminants in the interface is a suspected source for increased probability of detonation. Here, to investigate such frictional heating, samples of PBX 9501 and PBX 9502 were impacted and skidded against a tangentially moving target and thermally imaged. Temporally resolved temperature and forces were simultaneously measured with and without 300 µm silica grit at the frictional interface. A trend of increasing temperature was observed as the speed and tangential force on the sample increased. Grit particles in the frictional interface were found to act as frictional heat concentration spots owing to the grit's protrusion from the surface and lesser susceptibility to melting compared to the PBX. The coefficient of friction between PBX 9501 and the skidding surface was observed to be largely constant for forces and speeds at the lower end of the test range. In contrast, at high tangential speeds, the coefficient was found to be significantly lower.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Effects of non-thermal termolecular reactions on detonation development in hydrogen (H 2 )/methane (CH 4 ) - air mixtures

The binary fuel blend of H 2 /CH 4 is one of the most promising hydrogen-enriched hydrocarbon fuels in spark-ignition (SI) engines. Yet, the undesirable phenomenon of super-knock, which can severely and in-stantaneously damage an SI engine, limits its widespread adoption. Moreover, there is still a lack of con-sensus on the precise mechanism by which this phenomenon occurs i.e. via flame acceleration or spon-taneous ignition, despite numerous previous investigations. At the same time, recent studies [M. P. Burke, S. J. Klippenstein, Nat. Chem. 9 (2017) 1078 -1082, Y. Tao, A. W. Jasper, Y. Georgievskii, S. J. Klippenstein, R. Sivaramakrishnan, Proc. Combust. Inst. 38 (2021) 515-522] have demonstrated a high probability of occurrence of non-thermal reactions in premixed flames of such H 2 /CH 4 fuel blends with air due to the presence of non-trivial amounts of highly reactive radicals including H, O and OH apart from O 2 . The present study focuses on the evolution of an initial deflagration front to a detonation wave in H 2 /CH 4 - air mixtures under SI engine relevant conditions through fully resolved, constant volume 1D simulations with and without non-thermal reactivity. Non-thermal reactions were included in the macroscopic kinetics model as chemically termolecular reactions facilitated by the H + CH 3 and H + OH radical-radical recombination and the H + O 2 radical-molecule association reactions. Further, the nonthermal reactions result in a corresponding decrease in the reaction fluxes of the incipient recombination/association reactions. Therefore, an additional set of simulations were performed by applying corrections to the respective incipient recombination/association rate constants using the methodology demonstrated by Tao et al. [Y. Tao, A. W. Jasper, Y. Georgievskii, S. J. Klippenstein, R. Sivaramakrishnan, Proc. Combust. Inst. 38 (2021) 515-522]. Compared to the baseline case, the onset of spontaneous ignition in the end-gas region was observed to be delayed in the presence of non-thermal termolecular reactions. Concurrently, the developing detonation was observed to be significantly stronger. In contrast, applying corrections to the recombi-nation/association rate constants resulted in a completely different behavior. Specifically, detonation was observed to occur due to self acceleration of the primary flame in the absence of spontaneous ignition in the end-gas region. Sensitivity analysis was performed to quantify the effects of non-thermal reactions on the duration of heat release rate and thereby the mechanism of detonation formation. In addition, chemical explosive mode analysis (CEMA) was performed to identify the dominant species/reactions re-sponsible for the observed results.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Variability in the Massive Open Cluster NGC 1817 from K2: A Rich Population of Asteroseismic Red Clump, Eclipsing Binary, and Main-sequence Pulsating Stars

We present a survey of variable stars detected in K2 Campaign 13 within the massive intermediate-age (∼1 Gyr) open cluster NGC 1817. We identify a complete sample of 44 red clump stars in the cluster, and have measured asteroseismic quantities (ν {sub max} and/or Δν) for 29 of them. Five stars showed suppressed dipole modes, and the occurrence rates indicate that mode suppression is unaffected by evolution through core helium burning. A subset of the giants in NGC 1817 (and in the similarly aged cluster NGC 6811) have ν {sub max} and Δν values at or near the maximum observed for core helium–burning stars, indicating they have core masses near the minimum for fully nondegenerate helium ignition. Further asteroseismic study of these stars can constrain the minimum helium core mass in red clump stars and the physics that determines this limit. Two giant stars show photometric variations on timescales similar to previously measured spectroscopic orbits. Thirteen systems in the field show eclipses, but only five are probable cluster members. We identify 32 δ Sct pulsators, 27 γ Dor candidates, and 7 hybrids that are probable cluster members, with most being new detections. We used the ensemble properties of the δ Sct stars to identify stars with possible radial pulsation modes. Among the oddities we have uncovered are: an eccentric orbit for a short-period binary containing a δ Sct pulsating star; a rare subgiant within the Hertzsprung gap showing δ Sct pulsations; and two hot γ Dor pulsating star candidates.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Measurement of the strengths of Be and Pb4Sb by quasi-isentropic compress and release at near 100 GPa

The Ramp-compression experiments have been performed on the “Z” pulsed-power facility to investigate the strengths of Be and lead-antimony alloy. Yield strength and shear stress near peak pressure were obtained from measurements of the sound speed on release and using the Asay self-consistent method. Two S-65 grade Be samples, from batches which showed a significant difference in yield strength at ambient conditions, were found to have near identical yield strengths, which were also in agreement with similar earlier measurements on S-200 grade Be. Yield strength of Pb4Sb alloy at ~120 GPa was 1.35 GPa, while a National Ignition Facility (NIF) experiment by A. Krygier et al. (Phys. Rev. Lett. 123, 205701 (2020)) found 3.8 GPa at ~400 GPa pressure. Our result is intermediate between the ambient value and the Krygier one, but the significantly increased strength is probably not associated with the transition to the high-pressure bcc phase of lead.

42 ENGINEERING↗
NASA NTRS1980

The influence of structural response on sympathetic detonation

The role that a munition's structural response plays in the ignition process and the development of violent reactions and detonations is explored. The munition's structural response is identified as one of the factors that influences reaction violence. If the structural response of a round is known, this knowledge can be used to redstruce the probability that a large explosion would result from the sequential detonation of individual rounds within a large storage array. The response of an acceptor round was studied. The castings fail in the same manner regardless of whether or not there is a fill material present in the round. These failures are caused by stress waves which are transformed from compressive waves to tensile waves by reflection as the impact energy moves around the casting. Since these waves move in opposite directions around the projectile circumference and collide opposite the point of impact, very high tensile forces are developed which can crack the casing.

Watson, J. L.↗
NASA NTRS1948

Knocking Combustion Observed in a Spark-Ignition Engine with Simultaneous Direct and Schlieren High-Speed Motion Pictures and Pressure Records

Simultaneous direct and Schlieren photographs at 40,000 frames per second and correlated pressure records were taken of knocking combustion in a special spark-ignition engine to ascertain the intensity of certain end-zone reactions previously noted from Schlieren photography alone. A violent propagated homogeneous autoignition, or a similar phenomenon, previously observed, was again observed. The pressure records show autoignition of varying violence before the passage of a probable detonation wave. Extensive autoignition without occurrence of gas vibrations was seen in one explosion.

Osterstrom, Gordon E↗
NASA NTRS2004

Most Probable Fire Scenarios in Spacecraft and Extraterrestrial Habitats: Why NASA's Current Test 1 Might Not Always be Conservative

NASA's current method of material screening determines fire resistance under conditions representing a worst-case for normal gravity flammability - the Upward Flame Propagation Test (Test 1). Its simple pass-fail criteria eliminates materials that burn for more than 12 inches from a standardized ignition source. In addition, if a material drips burning pieces that ignite a flammable fabric below, it fails. The applicability of Test 1 to fires in microgravity and extraterrestrial environments, however, is uncertain because the relationship between this buoyancy-dominated test and actual extraterrestrial fire hazards is not understood. There is compelling evidence that the Test 1 may not be the worst case for spacecraft fires, and we don t have enough information to assess if it is adequate at Lunar or Martian gravity levels.

Olson, S. L.↗
NASA NTRS1982

Clarification of confirmation in the FACE-2 experiment

Definitions of the data acquisition and interpretation goals which were sought in the Florida Area Cumulus Experiment (FACE) phase-II experiment as confirmation of results from FACE-I are presented. The FACE-1 trials in cloud seeding to increase rainfall were conducted in 1970, '71, '73, '75, and '76 and phase II proceeded from June 1978-August 1980. The data from the second set were to be treated with a block randomization scheme using the mean vector wind speed and direction and superposition of rainfall data, considering fixed and floating target clouds. A first level of probability was configured to eliminate cells from further investigation, and then two other levels are included in the analyses, each of continually increasing levels of likelihood. The instances of rainfall with seeding cover periods of either 60 or more or 60 or less seeding flares being ignited.

Woodley, W. L.↗
NASA NTRS2004

Most Probable Fire Scenarios in Spacecraft and Extraterrestrial Habitats: Why NASA's Current Test 1 Might Not Always Be Conservative

NASA s current method of material screening determines fire resistance under conditions representing a worst-case for normal gravity flammability - the Upward Flame Propagation Test (Test 1[1]). Its simple pass-fail criteria eliminates materials that burn for more than 12 inches from a standardized ignition source. In addition, if a material drips burning pieces that ignite a flammable fabric below, it fails. The applicability of Test 1 to fires in microgravity and extraterrestrial environments, however, is uncertain because the relationship between this buoyancy-dominated test and actual extraterrestrial fire hazards is not understood. There is compelling evidence that the Test 1 may not be the worst case for spacecraft fires, and we don t have enough information to assess if it is adequate at Lunar or Martian gravity levels.

Olson, S. L.↗
NASA NTRS2009

Old Faithful Model for Radiolytic Gas-Driven Cryovolcanism at Enceladus

A new model is presented on how chemically driven cryovolcanism might contribute to episodic outgassing at the icy moon Enceladus and potentially elsewhere including Europa and Kuiper Belt Objects. Exposed water ices can become oxidized from radiolytic chemical alteration of near-surface water ice by space environment irradiation. In contact with primordially abundant reductants such as NH3, CH4, and other hydrocarbons, the product oxidants can react exothermically to produce volatile gases driving cryovolcanism via gas-piston forces on any subsurface liquid reservoirs. Radiolytic oxidants such as H2O2 and O2 can continuously accumulate deep in icy regoliths and be conveyed by rheological flows to subsurface chemical reaction zones over million-year time scales indicated by cratering ages for active regions of Enceladus and Europa. Surface blanketing with cryovolcanic plume ejecta would further accelerate regolith burial of radiolytic oxidants. Episodic heating from transient gravitational tides, radioisotope decay, impacts, or other geologic events might occasionally accelerate chemical reaction rates and ignite the exothermic release of cumulative radiolytic oxidant energy. The time history for the suggested "Old Faithful" model of radiolytic gas-driven cryovolcanism at Enceladus and elsewhere therefore consists of long periods of chemical energy accumulation punctuated by much briefer episodes of cryovolcanic activity. The most probable sequence for detection of activity in the current epoch is a long evolutionary phase of slow but continuous oxidant accumulation over billions of years followed by continuous but variable high activity over the past 10(exp 7)-10(exp 8) years. Detectable cryovolcanic activity could then later decline due to near-total oxidation of the rheologically accessible ice crust and depletion the accessible reductant abundances, as may have already occurred for Europa in the more intense radiation environment of Jupiter's magnetosphere. Astrobiological potential of Enceladus could correspondingly be higher than at Europa due to a less extreme state of oxidation and greater residual abundance of organics.

Cooper, John F.↗
NASA NTRS2008

Modeling the Risk of Fire/Explosion Due to Oxidizer/Fuel Leaks in the Ares I Interstage

A significant flight hazard associated with liquid propellants, such as those used in the upper stage of NASA's new Ares I launch vehicle, is the possibility of leakage of hazardous fluids resulting in a catastrophic fire/explosion. The enclosed and vented interstage of the Ares I contains numerous oxidizer and fuel supply lines as well as ignition sources. The potential for fire/explosion due to leaks during ascent depends on the relative concentrations of hazardous and inert fluids within the interstage along with other variables such as pressure, temperature, leak rates, and fluid outgasing rates. This analysis improves on previous NASA Probabilistic Risk Assessment (PRA) estimates of the probability of deflagration, in which many of the variables pertinent to the problem were not explicitly modeled as a function of time. This paper presents the modeling methodology developed to analyze these risks.

Ring, Robert W.↗
DOE OSTI2021

Hydrogen Plus Other Alternative Fuels Risk Assessment Models (HyRAM+) (Technical Reference Manual V.4)

The HyRAM+ software toolkit provides a basis for conducting quantitative risk assessment and consequence modeling for hydrogen, methane, and propane infrastructure and transportation systems. HyRAM+ is designed to facilitate the use of state-of-the-art science and engineering models to conduct robust, repeatable assessments of safety, hazards, and risk. HyRAM+ includes generic probabilities for equipment failures, probabilistic models for the impact of heat flux on humans and structures, and experimentally validated first-order models of release and flame physics. HyRAM+ integrates deterministic and probabilistic models for quantifying accident scenarios, predicting physical effects, and characterizing hazards (thermal effects from jet fires, overpressure effects from delayed ignition), and assessing impact on people and structures. HyRAM+ is developed at Sandia National Laboratories to support the development and revision of national and international codes and standards. HyRAM+ is a research software in active development and thus the models and data may change. This report will be updated at appropriate developmental intervals. This document provides a description of the methodology and models contained in HyRAM+ version 4.0. The most significant change for HyRAM+ version 4.0 from HyRAM version 3.1 is the incorporation of other alternative fuels, namely methane (as a proxy for natural gas) and propane into the toolkit. This change necessitated significant changes to the installable graphical user interface as well as changes to the back-end Python models. A second major change is the inclusion of physics models for the overpressure associated with the delayed ignition of an unconfined jet/plume of flammable gas.

02 PETROLEUM↗
NASA NTRS1958

Origin and Prevention of Crash Fires in Turbojet Aircraft

The tendency for the jet engine rotor to continue to rotate after crash presents the probability that crash-spilled combustibles suspended in the air or puddled on the ground at the engine inlet may be sucked into the engine. Studies with jet engines operating on a test stand and full-scale crashes of turbojet-powered airplanes showed that combustibles drawn into the engine in this way ignite explosively within the engine. Experiment showed that the gas flow through the engine is too rapid to permit the ignition of ingested combustibles on the hot metal in contact with the main gas stream. Ignition will occur on those hot surfaces not in the main gas stream. The portion of the engine airflow is diverted for cooling and ventilation to these zones where the gas moves slowly enough for ignition to occur.

Pinkel, I. Irvin↗
DOE OSTI2024

Global burned area increasingly explained by climate change

Fire behaviour is changing in many regions worldwide. However, nonlinear interactions between fire weather, fuel, land use, management and ignitions have impeded formal attribution of global burned area changes. Here, in this work, we demonstrate that climate change increasingly explains regional burned area patterns, using an ensemble of global fire models. The simulations show that climate change increased global burned area by 15.8% (95% confidence interval (CI) [13.1–18.7]) for 2003–2019 and increased the probability of experiencing months with above-average global burned area by 22% (95% CI [18–26]). In contrast, other human forcings contributed to lowering burned area by 19.1% (95% CI [21.9–15.8]) over the same period. Moreover, the contribution of climate change to burned area increased by 0.22% (95% CI [0.22–0.24]) per year globally, with the largest increase in central Australia. Our results highlight the importance of immediate, drastic and sustained GHG emission reductions along with landscape and fire management strategies to stabilize fire impacts on lives, livelihoods and ecosystems.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Machine learning assisted bayesian inference of mix and hot-spot conditions in NIF implosions

Experiments on the National Ignition Facility (NIF) have provided clear evidence of ablator material mixing into the Hot-Spot, leading to degraded performance. However, inferring the amount of mix and Hot-Spot conditions from typical experimental observations (e.g. x-ray spectra and images) is highly challenging. Here, we have developed an analysis method that utilizes machine learning assisted Bayesian inference to find the probability distributions of the Hot-Spot and mix conditions. This approach uses a neural network, trained on an idealized 2-dimensional representation of the Hot-Spot and mix distribution, and Bayesian inference to find the statistical distributions of Hot-Spot conditions that provide a match with observations. We have tested this method with synthetic data from simulations.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS2021

Effect of Preconditioning on Post-Soldering Failures in Tantalum Capacitors

Soldering have a strong effect on performance and reliability of most surface mount technology components, including tantalum capacitors. High quality tantalum capacitors are likely the only type of components where soldering simulation is the first step during screening. Nevertheless, post-soldering failures of tantalum capacitors do happen and require additional analysis. Popcorning is a well-known effect in plastic encapsulated microcircuits (PEM) and it occurs also in chip tantalum capacitors. The sensitivity of parts to the presence of moisture during soldering is characterized by the moisture sensitivity level (MSL); however, contrary to PEMs, there is no standard procedure for establishing MSL for tantalum capacitors, and standard J-STD-020 is applicable partially only. In this work, the effect of absorbed moisture on soldering related degradation and failures in tantalum capacitors have been studied using 22 types of polymer and 11 types of MnO2 cathodes tantalum capacitors including single and multianode parts. The amount of moisture released during soldering has been estimated by measurements of mass and capacitance variations. Results show that moisture uptake in similar parts is approximately two times greater in polymer than in MnO2 capacitors. Cracking of the case and degradation of parameters can occur in both types of parts, but MnO2 capacitors are much more susceptible to catastrophic short circuit failures and their ignition is possible during the first power-on cycle. This type of failure in MnO2 capacitors is lot-related, can occur even at derated voltages and relatively low levels of moisture sorption corresponding to room conditions. Baking before soldering is an effective measure to prevent failures even in lots susceptible to popcorning damage. Recommendations for testing to establish MSL and for baking to reduce the probability of failures are suggested.

tantalum polymer capacitors↗
NASA NTRS1992

Evolved stars in Omega Centauri. I - Radial distribution of blue subdwarfs

A U - V color-magnitude diagram containing over 5000 stars from 10 fields in Omega Centauri at or brighter than the main-sequence turnoff is presented. Completeness corrections are obtained as a continuous function of magnitude and radial distance are obtained and used to show that the blue subdwarfs are centrally concentrated with respect to subgiants and stars on the horizontal branch proper. The chance probability of this result is less than 1 percent. Since the blue subdwarfs probably consist of helium-burning cores of about 0.5 solar mass surrounded by a thin hydrogen envelope, mass segregation could not produce this result if these stars had evolved singly. Two kinds of possible precursor systems are considered: pairs of degenerate dwarfs which subsequently merge to form helium-burning stars, and moderately wide binaries in which mass transfer is initiated shortly before the helium flash is ignited.

Bailyn, Charles D.↗
NASA NTRS1973

Rate of reaction between molecular hydrogen and molecular oxygen

The shock tube data of Jachimowski and Houghton were rigorously analyzed to obtain rate constants for the candidate initiation reactions H2 + O2 yields H + HO2, H2 + O2 yields H2O + O, and H2 + O2 yields OH + OH. Reaction (01) is probably not the initiation process because the activation energy obtained is less than the endothermicity and because the derived rates greatly exceed values inferred in the literature from the reverse of reaction (01). Reactions (02) and (03) remain as possibilities, with reaction (02) slightly favored on the basis of steric and statistical considerations. The solution of the differential equations is presented in detail to show how the kinetics of other ignition systems may be solved.

Brokaw, R. S.↗