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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS2007

Impact of Ring Current Ions on Electromagnetic Ion Cyclotron Wave Dispersion Relation

Effect of the ring current ions in the real part of electromagnetic ion Cyclotron wave dispersion relation is studied on global scale. Recent Cluster observations by Engebretson et al. showed that although the temperature anisotropy of is energetic (> 10 keV) ring current protons was high during the entire 22 November 2003 perigee pass, electromagnetic ion cyclotron waves were observed only in conjunction with intensification of the ion fluxes below 1 keV by over an order of magnitude. To study the effect of the ring current ions on the wave dispersive properties and the corresponding global wave redistribution, we use a self-consistent model of interacting ring current and electromagnetic ion cyclotron waves, and simulate the May 1998 storm. The main findings of our simulation can be summarized as follows: First, the plasma density enhancement in the night MLT sector during the main and recovery storm phases is mostly caused by injection of suprathermal plasma sheet H + (approximately < 1 keV), which dominate the thermal plasma density. Second, during the recovery storm phases, the ring current modification of the wave dispersion relation leads to a qualitative change of the wave patterns in the postmidnight-dawn sector for L > 4.75. This "new" wave activity is well organized by outward edges of dense suprathermal ring current spots, and the waves are not observed if the ring current ions are not included in the real part of dispersion relation. Third, the most intense wave-induced ring current precipitation is located in the night MLT sector and caused by modification of the wave dispersion relation. The strongest precipitating fluxes of about 8 X 10(exp 6)/ (cm(exp 2) - s X st) are found near L=5.75, MLT=2 during the early recovery phase on 4 May. Finally, the nightside precipitation is more intense than the dayside fluxes, even if there are less intense waves, because the convection field moves ring current ions into the loss cone on the nightside, but drives them out of the loss cone on the dayside. So convection and wave scattering reinforce each other in the nightside, but interfere in the dayside sector.

Khazanov, G. V.↗
NASA NTRS2010

The Biological Effectiveness of Silicon Ions is Significantly Higher than Iron Ions for the Induction of Chromosome Damage in Human Lymphocytes

Chromosome aberrations were measured in human peripheral blood lymphocytes after in vitro exposure to Si-28-ions with energies ranging from 90 to 600 MeV/u, or Fe-56-ions with energies ranging from 200 to 5,000 MeV/u. The LET of the various Fe beams in this study ranged from 145 to 440 keV/micron and the LET Si ions ranged from 48 to 158 keV/micron. Doses delivered were in the 10 to 200 cGy range. Dose response curves for chromosome exchanges in cells at first division after exposure, measured using fluorescence in situ hybridization (FISH) with whole chromosome probes, were fitted with linear or linear-quadratic functions. The relative biological effectiveness (RBE) was estimated from the initial slope of the dose response curve for chromosome damage with respect to gamma-rays. The estimates of RBE(sub max) values for total chromosome exchanges ranged from 4.4+/-0.4 to 31.5+/-2.6 for Fe ions, and 11.8+/-1.0 to 42.2+/-3.3 for Si ions. The highest RBE(sub max) value for Fe ions was obtained with the 600 Mev/u beam and 170 MeV/u beam produced the highest RBE(sub max) value for Si ions. For both ions the RBE(sub max) values increased with LET, reaching a maximum at about 180 keV/micron for Fe and about 100 keV/micron for Si, and decreased with further increase in LET.

George, Kerry↗
NASA NTRS2015

Initial Thrust Measurements of Marshall's Ion-ioN Thruster

Electronegative ion thrusters are a variation of tradition gridded ion thruster technology differentiated by the production and acceleration of both positive and negative ions. Benefits of electronegative ion thrusters include the elimination of lifetime-limiting cathodes from the thruster architecture and the ability to generate appreciable thrust from both charge species. Following the continued development of electronegative ion thruster technology as exhibited by the PEGASES (Plasma Propulsion with Electronegative GASES) thruster, direct thrust measurements are required to push interest in electronegative ion thruster technology forward. For this work, direct thrust measurements of the MINT (Marshall's Ion-ioN Thruster) will be taken on a hanging pendulum thrust stand for propellant mixtures of Sulfur Hexafluoride and Argon at volumetric flow rates of 5-25 sccm at radio frequency power levels of 100-600 watts at a radio frequency of 13.56 MHz. Acceleration grid operation is operated using a square waveform bias of +/-300 volts at a frequency of 25 kHz.

Schloeder, Natalie R.↗
NASA NTRS2018

Numerical Investigation of Ion Transport in the MOMA Ion Mass Spectrometer

The Mars Organic Molecule Analyzer (MOMA) is a miniature ion trap mass spectrometer designed for the upcoming ExoMars Rover mission. The spectrometer uses laser desorption to ionize a Martian soil sample within an instrument internal clean zone maintained at ambient Martian pressure. A high-speed aperture valve transiently opens to allow ionized constituents, along with the ambient gas, to enter a vacuum cavity containing a linear ion trap mass spectrometer. The ambient clean zone and the vacuum cavity are connected via a few centimeter long aperture valve ion guide tube. In this paper, we present results from a recently completed numerical investigation of ion transport from the ion source across the ion guide. Specifically, we focus on collisional coupling between ions and the neutral molecules flowing into the vacuum cavity. The simulation domain contains the ambient region, and we consider the variation in ion conductance with ambient pressure. We also analyze the impact of a fixed potential bias applied to the aperture valve. Simulations are performed with a two-dimensional axisymmetric PIC / DSMC code Starfish. Numerical results are compared to experimental data.

Breida, Lubos↗
DOE OSTI2025

Multi-Ion Complexes and Competition from Bulky BArF – Anions for Chloride Binding in Ion Pairing Conditions

Cationic charges have long been used to enhance anion binding. Embedding charge introduces strong ion pairing for target anions but also for off-target ions, ultimately generating a mixture of multi-ion species that are hard to identify and quantify. While many sidestep this problem using polar solvents and weakly coordinating ions, these approaches exclude a substantial cross-section of conditions found in applications spanning recognition, assembly, separations, templation, and catalysis. To confront this complexity, we study the binding of an anion to a cationic receptor featuring low shape complementarity in a low-polarity solvent to maximize ionic interactions. We prepared the receptor as a salt of the weakly coordinating tetrakis­[3,5-bis­(trifluoromethyl)­phenyl]­borate (BArF – ) anion and studied the binding of small chloride (Cl – ) and medium-sized iodide (I – ) anions. Surprisingly, the use of the bulky BArF – anion does not suppress ion pairing interactions, with 65% of the receptor being paired at 0.5 mM in dichloromethane. We observe multi-ion receptor-Cl – complexes (2:1, 1:1, 1:2), reinforcing the complexity that emerges when working in low-polarity media. Here, we reveal the dependence of affinity on anion charge density and size and that bulky BArF – counteranions compete for chloride binding. These studies reveal the noninnocence of BArF – anions and strategies to quantify multi-ion species.

Ion pairing↗
DOE OSTI2025

Revisiting the Role of Mobile Ion Size for the Activation Barrier of Charge Transport in Single Ion Conducting Polymers

The development of polymer electrolytes for energy storage and conversion technologies requires a fundamental understanding of the material parameters controlling the energy barriers for ion transport. In glassy polymers, these activation barriers are usually extracted by using Arrhenius procedures. However, our recent studies of single ion conducting polymers reveal that this traditional Arrhenius description provides anomalously small prefactors, an issue that is widely disregarded in the literature. Here, to address it, an alternative approach was introduced for extracting the effective activation barrier E by imposing a physically valid limit (∼10 –13 s) for the ion hopping attempt time. Two consequences of this recent approach are that in polymer electrolytes (i) E is significantly (∼30–40%) lower than the barrier estimated using traditional Arrhenius fits and (ii) E displays significant temperature dependence even in the glassy state. Under these circumstances, we are revisiting the role of ion size, glass transition temperature T g , and dielectric and elastic constants of the polymer matrix on the effective activation barriers for ion transport as extracted using the recently proposed approach and highlight the differences from the picture that previously emerged based on simplistic apparent Arrhenius analysis. To this end, we investigate cation transport in three families of single ion conducting trifluoromethane sulfonimide-based polyanions with varied T g . Our results indicate that E decreases with mobile cation size and is highly sensitive to changes in the dielectric permittivity of the matrix, even for large cations. These insights call for revisions of many earlier results based on apparent Arrhenius fits as the proposed approach can provide more accurate guidance for the design of polymer electrolytes with enhanced ionic conductivity.

energy barrier↗
DOE OSTI2025

The ion-ion correlations in organic ionic plastic crystal

Organic ionic plastic crystals (OIPCs) are emerging as promising electrolyte materials for solid-state batteries. However, despite the fast ionic diffusion, OIPCs exhibit relatively low DC conductivity in solid phases caused by strong ion-ion correlations that suppress charge transport. To understand the origin of this suppression, we performed a study of ion dynamics in the OIPC 1-Ethyl-1-methylpyrrolidinium bis (trifluoromethyl sulfonyl) imide [P 12 ][TFSI] utilizing dielectric spectroscopy, light scattering, and Nuclear Magnetic Resonance diffusometry. Comparison of the results obtained in this study with the published earlier results on an OIPC with a completely different structure (Diethyl(methyl)(isobutyl)phosphonium Hexafluorophosphate [P 1,2,2,4 ][PF 6 ]) revealed strong similarities in ion dynamics in both systems. Unlike DC conductivity, which may drop more than ten times between melted and solid phases, diffusion of anions and cations remains high and does not show strong changes at phase transition. The conductivity spectra in the broad frequency range demonstrate unusual shapes in solid phases with an additional step separating fast local ion motions from suppressed long-range charge diffusion controlling DC conductivity. We suggested that in solid phases, anions and cations can jump only between the specific ion sites defined by the crystalline structure. These constraints lead to strong cation-cation and anion-anion correlations strongly suppressing long-range charge transport.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Modifying Specific Ion Effects: Studies of Monovalent Ion Interactions with Amines

Specific ion effects in the interactions of monovalent anions with amine groups-one of the hydrophilic moieties found in proteins-were investigated using octadecylamine monolayers floating at air–aqueous solution interfaces. Here, we find that at solution pH 5.7, larger monovalent anions induce a nonzero pressure starting at higher areas/molecules, i.e., a wider “liquid expanded” region in the monolayer isotherms. Using X-ray fluorescence at near total reflection (XFNTR), an element- and surface-specific technique, ion adsorption to the amines at pH 5.7 is confirmed to be ion-specific and to follow the conventional Hofmeister series. However, at pH 4, this ion specificity is no longer observed. We propose that at the higher pH, the amine headgroups are only partially protonated, and large polarizable ions such as iodine are better able to boost amine protonation. At the lower pH, on the other hand, the monolayer is fully protonated, and electrostatic interactions dominate over ion specificity. These results demonstrate that ion specificity can be modified by changing the experimental conditions.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Porin-Inspired Ionomers with sub-nm Gated Ion Channels for High Ion Conductivity and Selectivity (Final Project Report (2026))

The physiological functions of living systems heavily rely on biological ion channels, whose malfunction can lead to disease. These channels enable selective and regulated transport of water, ions, or small molecules across membranes. Analogously, ionomers used in energy conversion and storage technologies govern ion transport within membrane separators and catalyst binder layers. This DOE Office of Science Early CAREER project aimed to achieve molecular-level control over ionic conductivity and ion permselectivity by translating the functionalities of biological, gated ion channels into a novel class of ion-conducting polymers (ionomers) incorporating macrocyclic calix[4]arene-based repeat units. The overarching goal was to establish fundamental design principles and elucidate proton conduction mechanisms through strategic design of macrocyclic calix[4]arene-containing ionomers, with close relevance to energy conversion and storage devices, including proton exchange membrane fuel cells (PEMFCs). The project leveraged sub-nm-sized macrocyclic pores to facilitate exceptionally fast ion transport (beneficial to addressing sluggish ORR kinetics of PEMFC electrodes) and achieve functionalities of ionic diodes under applied electrochemical fields, beneficial for selective transport/separation.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1980

Ion heating by strong electrostatic ion cyclotron turbulence

A theory of the ion heating due to electrostatic ion cyclotron (EIC) waves in the auroral zone is presented. Due to the slowly convecting nature of the EIC mode, quasi-linear plateau formation cannot stabilize the waves, and growth occurs until the nonlinear mechanisms of ion resonance broadening and electron trapping provide saturation. The large amplitude and coherent nature of the resulting wave imply that quasi-linear theory provides only a lower limit to the ion heating. An upper bound on the heating rate is derived using a time-average model of ion dynamics in the coherent waves. The effects of ion heating in the presence of the magnetic gradient force and parallel electric fields are considered, with the result that perpendicular energies over 100 eV are easily attainable from a 1 eV source plasma. Perpendicular heating in the absence of a parallel electric field yields conical ion distributions, which in the presence of an electric field become field-aligned beams.

Lysak, R. L.↗
NASA NTRS1983

Evolution of ion distributions across the nearly perpendicular bow shock - Specularly and non-specularly reflected-gyrating ions

Data from ISEE 1 and 2 spacecraft were used to study the evolution of the ion distributions in the perpendicular terrestrial bow shock. The plasma data were taken during passage of the spacecraft downstream of and through the shock. Solar wind ions had velocities ranging from Mach 2-12.4, and reflected ions featured a relative density of 1-3 percent of the solar wind density at Mach 2 to 15-25 percent at Mach 8-12. Computer simulations have indicated that the ions provide essential dissipation at the shock and gyrate about the magnetic field lines in the plasma rest frame at a speed twice that of the normal incident solar wind flow. The ion density decreases by up to two orders of magnitude at the forward end of the foot of the shock profile, suggesting that the ions are reflected by the shock specularly, and may enhance downstream ion thermalization.

Sckopke, N.↗
NASA NTRS1985

Simulations of heavy ion heating by electromagnetic ion cyclotron waves driven by proton temperature anisotropies

Heating of heavy ions by the electromagnetic ion cyclotron (EMIC) waves, which are driven by proton temperature anisotropies, is studied by means of hybrid particle simulations. Initially, relaxation of the temperature anisotropies in the proton distribution and isotropic heating of the heavy ions are observed (phase I), followed by substantial perpendicular heating of the heavy ions (phase II). The heavy ions are distinctly gyrophase modulated by the EMIC waves. The isotropic heating in phase I is due to magnetic trapping by the excited proton cyclotron waves. The perpendicular heating in phase II is attributed to cyclotron resonance with the EMIC waves, which becomes possible by means of the preceding heating in phase I. Saturation of the EMIC instability is instead attributed to magnetic trapping of the majority ions: protons. When the proton anisotropy is very large, frequency shift (decrease) of the proton cyclotron waves to less than 1/2 Ohm(p) is observed. The present mechanism is not only relevant to He(+) heating in the dayside equator of the magnetosphere, but it also predicts hot He2(+) ions behind the earth's bow shock.

Tanaka, M.↗
NASA NTRS1986

Ion energization in upwelling ion events

A source of H(+), He(+), O(+), and N(+) outflow from the ionosphere has been identified near the polar cusp/cleft using the Dynamics Explorer/retarding ion mass spectrometer data set. This ion outflow termed 'upwelling ions' is characterized by large outfluxes of H(+) and O(+) ions and high transverse ion temperatures. This paper reports on the associated particle and field characteristics of one such upwelling ion event on March 12, 1982. Field-aligned currents and strong E x B convection channels are associated with the event as well as strong broadband plasma wave emission. One or all of these sources may play an important role in the ion energization in this region.

Waite, J. H., Jr.↗
NASA NTRS1989

Dayside observations of thermal-ion upwellings at 800-km altitude - An ionospheric signature of the cleft ion fountain

There is a growing body of evidence that energetic heavy ions observed at one or more earth radii over the polar cap originate from the dayside ionosphere in the vicinity of the dayside cleft. The ions, consisting mostly of O(+), are often characterized by conic pitch-angle distributions, suggesting that they have undergone acceleration transverse to geomagnetic field lines. This process of ion injection from a latitudinally localized source region in the dayside auroral oval followed by dispersal throughout the entire polar cap has been called the 'cleft ion fountain'. Here, results are presented of upward thermal-ion flows measured at 800-km altitude in the dayside polar ionosphere by the Hilat satellite. The characteristics of these thermal-ion upwellings (TIU) are described and shown to be closely associated with the cleft ion fountain. It is shown that TIU events are latitudinally confined and spatially collocated with cleft electron precipitation, upward field-aligned currents, and velocity gradients in magnetospheric convection.

Tsunoda, R. T.↗
NASA NTRS1995

Characteristics of low energy ions in the Heavy Ions In Space (HIIS) experiment

We present preliminary data on heavy ions (Z greater than or equal to 10) detected in the topmost Lexan sheets of the track detector stacks of the Heavy Ions in space (HIIS) experiment (M0001) on LDEF. The energy interval covered by these observations varies with the element, with (for example) Ne observable at 18-100 MeV nuc and Fe at 45-200 MeV/nuc. All of the observed ions are at energies far below the geomagnetic cutoff for fully-ionized particles at the LDEF orbit. Above 50 MeV/nuc (where most of our observed particles are Fe), the ions arrive primarily from the direction of lowest geomagnetic cutoff. This suggests that these particles originate outside the magnetosphere from a source with a steeply-falling spectrum and may therefore be associated with solar energetic particle (SEP) events. Below 50 MeV/nuc, the distribution of arrival directions suggests that most of the observed heavy ions are trapped in the Earth's magnetic field. Preliminary analysis, however, shows that these trapped heavy ions have a very surprising composition: they include not only Ne and Ar, which are expected from the trapping of anomalous cosmic rays (ACR's), but also Mg and Si, which are not part of the anomalous component. Our preliminary analysis shows that trapped heavy ions at 12 less than or equal to Zeta less than or equal to 14 have a steeply-falling spectrum, similar to that reported by the Kiel experiment (exp 1,2,3) on LDEF (M0002) for trapped Ar and Fe at E less than 50 MeV/nuc. The trapped Mg, Si, and Fe may also be associated with SEP events, but the mechanism by which they have appeared to deep in the inner magnetosphere requires further theoretical investigation.

Kleis, Thomas↗
NASA NTRS1994

Response of thermal ions to electromagnetic ion cyclotron waves

Electromagnetic ion cyclotron waves generated by 10 - 50 keV protons in the Earth's equatorial magnetosphere will interact with the ambient low-energy ions also found in this region. We examine H(+) and He(+) distribution functions from approx. equals 1 to 160 eV using the Hot Plasma Composition Experiment instrument on AMPTE/CCE to investigate the thermal ion response to the waves. A total of 48 intervals were chosen on the basis of electromagnetic ion cyclotron (EMIC) wave activity: 24 with prevalent EMIC waves and 24 with no EMIC waves observed on the orbit. There is a close correlation between EMIC waves and perpendicular heated ion distributions. For protons the perpendicular temperature increase is modest, about 5 eV, and is always observed at 90 deg pitch angles. This is consistent with a nonresonant interaction near the equator. By contrast, He(+) temperatures during EMIC wave events averaged 35 eV and sometimes exceeded 100 eV, indicating stronger interaction with the waves. Furthermore, heated He(+) ions have X-type distributions with maximum fluxes occurring at pitch angles intermediate between field-aligned and perpendicular directions. The X-type He(+) distributions are consistent with a gyroresonant interaction off the equator. The concentration of He(+) relative to H(+) is found to correlate with EMIC wave activity, but it is suggested that the preferential heating of He(+) accounts for the apparent increase in relative He(+) concentration by increasing the proportion of He(+) detected by the ion instrument.

Anderson, B. J.↗
NASA NTRS1994

A Monte Carlo simulation of the effect of ion self-collisions on the ion velocity distribution function in the high-latitude F-region

Non-Maxwellian ion velocity distribution functions have been theoretically predicted and confirmed by observations, to occur at high latitudes. These distributions deviate from Maxwellian due to the combined effect of the E x B drift and ion-neutral collisions. At high altitude and/or for solar maximum conditions, the ion-to-neutral density ratio increases and, hence, the role of ion self-collisions becomes appreciable. A Monte Carlo simulation was used to investigate the behavior of O(+) ions that are E x B-drifting through a background of neutral O, with the effect of O(+) (Coulomb) self-collisions included. Wide ranges of the ion-to-neutral density ratio n(sub i)/n(sub n) and the electrostatic field E were considered in order to investigate the change of ion behavior with solar cycle and with altitude. For low altitudes and/or solar minimum (n(sub i)/n(sub n) less than or equal to 10(exp -5)), the effect of self-collisions is negligible. For higher values of n(sub i)/n(sub n), the effect of self-collisions becomes significant and, hence, the non-Maxwellian features of the O(+) distribution are reduced. The Monte Carlo results were compared to those that used simplified collision models in order to assess their validity. In general, the simple collision models tend to be more accurate for low E and for high n(sub i)/n(sub n).

Barghouthi, I. A.↗
NASA NTRS1994

Evidence for ion transport and molecular ion dominance in the Venus ionotail

We present analyses from the five Pioneer Venus Orbiter plasma experiments and the plasma wave experiment when a patch of plasma with enhanced densities was encountered in the near-Venus ionotail during atmospheric entry at an altitude of approximately 1100 km in the nightside ionosphere. Our analyses of the thermal and superthermal ion measurements in this plasma feature provides the first evidence that at times molecular ions in the 28-32 amu mass range are dominant over atomic mass species thus yielding evidence for a transport mechanism that reaches into the lower ionosphere. Analysis of plasma analyzer (OPA) observations at this time indicates the presence of ions measured in the rest frame of the spacecraft at approximately 27 and 37 volt energy per unit charge steps. In the rest frame of the planet these superthermal ions are flowing from the dawn direction at speeds (assuming they are O2(+)) of approximately 8 km/s and with a flow component downward (perpendicular to the ecliptic plane) at speeds of approximately 2 km/s. OPA analyses also determine the ion number flux, energy, flow angles, and angular distributions. Plasma wave bursts appear to indicate that plasma density decreases within and on the equatorward edge of the patch of enhanced plasma densities are associated with ion acoustic waves and relative ion streaming.

Intriligator, D. S.↗