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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Glass-crystallisation synthesis is harnessed to probe structure prediction in a search for new inorganic compounds, yielding a new ribbon silicate Sr 2 Si 3 O 8 .
Here, we present a comprehensive study of static and dynamic magnetic properties in the Ising-like dipolar antiferromagnet (AFM) DyScO 3 by means of DC and AC magnetization measurements supported by classical Monte Carlo calculations. Our AC-susceptibility data show that the magnetic dynamics exhibit a clear crossover from an Arrhenius-like regime to quantum tunneling of magnetization (QTM) at T*=10K. Below T N =3.2K, DyScO 3 orders in an antiferromagnetic GxAy-type magnetic structure and the magnetization dynamics slow down to the minute timescale. The low-temperature magnetization curves exhibit complex hysteretic behavior, which depends strongly on the magnetic field sweep rate. We demonstrate that the low-field anomalies on the magnetization curve are related to the metamagnetic transition, while the hysteresis at higher fields is induced by a strong magnetocaloric effect. Our theoretical calculations, which take into account dipolar interaction between Dy 3+ moments, reproduce essential features of the magnetic behavior of DyScO 3 . We demonstrate that DyScO 3 represents a rare example of an inorganic compound, which exhibits QTM at a single-ion level and magnetic order due to classical dipolar interaction.
Abstract High‐temperature calorimetry (HTC) originated in the 20th century as a niche method to enable measurements not easily accomplished with acid solution calorimetry, combustion calorimetry, vapor pressure, or EMF methods. Over time, HTC has evolved into a versatile approach to accurately quantify formation, phase transition, surface and interfacial enthalpies of a wide range of materials including minerals and refractory inorganic compounds. This evolution has been the result of numerous adjustments to experimental setups and procedures, followed by rigorous testing. The commercial availability and the scientific success of this technique have led to an increase in the number of laboratories applying HTC. However, the knowledge acquired by researchers over the past 70 years is scattered throughout the literature or only available as laboratory internal documentation and personal experience. This publication is a collaborative effort among several leading HTC laboratories to summarize and unify current state‐of‐the‐art HTC techniques and procedures. The text starts by summarizing various HT techniques that are commonly used for readers with an interest in HTC in general. It is then directed toward HTC users and includes a brief section on data evaluation procedures as well as a comprehensive compilation of reference data utilizing molten sodium molybdate and lead borate solvents. Finally, for experienced HTC users, an in‐depth discussion of some common difficulties and a discussion of uncertainties are presented.
Data from Cravotta, Brady, "Priority pollutants and associated constituents in untreated and treated discharges from coal mining or processing facilities in Pennsylvania, USA". Applied Geochemistry, 2015. https://doi.org/10.1016/j.apgeochem.2015.03.001 Dataset includes information on water quality composition including inorganic compounds from untreated and treated streams of coal-mine discharge from coal mining and coal processing locations. Data is provided in the original version as well as in a summarized version for easy input into aqueous chemistry modeling software.
Unconventional oil and gas exploration generates an enormous quantity of wastewater, commonly referred to as flowback and produced water (FPW). Limited freshwater resources and stringent disposal regulations have provided impetus for FPW reuse. Organic and inorganic compounds released from the shale/brine formation, microbial activity, and residual chemicals added during hydraulic fracturing bestow a unique as well as temporally varying chemical composition to this wastewater. Studies indicate that many of the compounds found in FPW are amenable to biological degradation, indicating biological treatment may be a viable option for FPW processing and reuse. This review discusses commonly characterized contaminants and current knowledge on their biodegradability, including the enzymes and organisms involved. Further, a perspective on recent novel hybrid biological treatments and application of knowledge gained from omics studies in improving these treatments is explored.
Abstract. The impacts of soot particles on climate and human health depend on the concentration of black carbon (BC) as well as the thickness and composition of the coating material, i.e., organic and inorganic compounds internally mixed with BC. In this study, the size-resolved chemical composition of BC-containing aerosol was measured using a high-resolution soot particle aerosol mass spectrometer (SP-AMS) during wintertime in Fresno, California, a location influenced by abundant combustion emissions and frequent fog events. Concurrently, particle optical properties were measured to investigate the BC absorption enhancement. Positive matrix factorization (PMF) analysis was performed on the SP-AMS mass spectral measurements to explore the sources of soot particles and the atmospheric processes affecting the properties of BC coatings. The analysis revealed that residential woodburning and traffic are the dominant sources of soot particles. Alongside primary soot particles originating from biomass burning (BBOABC) and vehicles (HOABC) two distinct types of processed BC-containing aerosol were identified: fog-related oxidized organic aerosol (FOOABC) and winter-background OOABC (WOOABC). Both types of OOABC showed evidence of having undergone aqueous processing, albeit with differences. The concentration of FOOABC was substantially elevated during fog events, indicating the formation of aqueous secondary organic aerosol (aqSOA) within fog droplets. On the other hand, WOOABC was present at a relatively consistent concentration throughout the winter and was likely related to the formation of secondary organic aerosol (SOA) in both the gas phase and aerosol liquid water. By comparing the chemical properties and temporal variations in FOOABC and WOOABC, we gain insights into the key aging processes of BC aerosol. It was found that aqueous-phase reactions facilitated by fog droplets had a significant impact on the thickness and chemical composition of BC coatings, thereby affecting the light absorption and hygroscopic properties of soot particles. These findings underscore the important role of chemical reactions occurring within clouds and fogs and influencing the climate forcing of BC aerosol in the atmosphere.
Opaque, reflective coatings are produced on aluminum articles by an anodizing process wherein the anodizing bath contains an aqueous dispersion of finely divided insoluble inorganic compounds. These particles appear as uniformly distributed occlusions in the anodic deposit on the aluminum.
Organic cyanine dye for detection of protein in trace amounts - dye reaction mechanism, methods of eliminating inorganic compound reaction with dye, and detection of humic acid
Silicon difluoride reactions and properties, describing production from commercial silicon tetrafluoride and versatility of reactions with organic and inorganic compounds
In the evolution of life forms nonphotosynthetic mechanisms are developed. The question remains whether a total life system could evolve which is not dependent upon photosynthesis. In trying to visualize life on other planets, the photosynthetic process has problems. On Mars, the high intensity of light at the surface is a concern and alternative mechanisms need to be defined and analyzed. In the UV search for alternate mechanisms, several different areas may be identified. These involve activated inorganic compounds in the atmosphere, such as the products of photodissociation of carbon dioxide and the organic material which may be created by natural phenomena. In addition, a life system based on the pressure of the atmospheric constituents, such as carbon dioxide, is a possibility. These considerations may be important for the understanding of evolutionary processes of life on another planet. Model systems which depend on these alternative mechanisms are defined and related to presently planned and future planetary missions.
The papers deal with the detection of hazardous environmental pollutants, the development of emission control plans, and the design of compliance monitoring systems. Topics include remote sensing techniques in environmental pollution monitoring, monitoring of atmospheric particulate matter, air pollution due to sulfur dioxide and other inorganic compounds, marine pollution, atmospheric aerosols, industrial pollution, and legal aspects of pollution monitoring. Other papers examine the toxic effects of heavy metals and halogenated hydrocarbons, pollution associated with waste-disposal processes, pesticide residues in soil and groundwater, evaluations of groundwater quality, and monitoring of nuclear wastes. The interaction of climate and pollution is also discussed along with global pollutant transport, environmental modeling, ambient environmental air quality, aircraft and ground-vehicle emissions, and pollution associated with energy extraction and utilization processes. Individual items are announced in this issue.
Various applications of thermal plasma to extraction metallurgy and related fields are surveyed, chiefly on the basis of documents published during the past two or three years. Applications to melting and smelting, to thermal decomposition, to reduction, to manufacturing of inorganic compounds, and to other fields are considered.
A wet oxidation system will be useful in the Closed Ecological Life Support System (CELSS) as a facility to treat organic wastes and to redistribute inorganic compounds and elements. However at rather higher temperatures needed in this reaction, for instance, at 260 deg C, only 80% of organic in a raw material can be oxidized, and 20% of it will remain in the liquid mainly as acetic acid, which is virtually noncombustible. Furthermore, nitrogen is transformed to ammonium ions which normally cannot be absorbed by plants. To resolve these problems, it becomes necessary to use catalysts. Noble metals such as Ru, Rh and so on have proved to be partially effective as these catalysts. That is, oxidation does not occur completely, and the unexpected denitrification, instead of the expected nitrification, occurs. So, it is essential to develop the catalysts which are able to realize the complete oxidation and the nitrification.
Mechanisms and kinetics of some reactions of the ground state of oxygen atoms, O(3P), are briefly summarized. Attention is given to reactions of oxygen atoms with several different types of organic and inorganic compounds such as alkanes, alkenes, alkynes, aromatics, and some oxygen, nitrogen, halogen and sulfur derivatives of these compounds. References to some recent compilations and critical evaluations of reaction rate constants are given.
In response to the hazardous-waste generating processes associated with the launch of the Space Shuttle, a hazardous waste management plan has been developed. It includes waste recycling, product substitution, waste treatment, and waste minimization at the source. Waste material resulting from the preparation of the nonmotor segments of the solid rocket boosters include waste paints (primer, topcoats), waste solvents (methylene chloride, freon, acetone, toluene), waste inorganic compounds (aluminum anodizing compound, fixer), and others. Ways in which these materials are contended with at the Kennedy Space Center are discussed.
The carbon metabolism of the cryptoendolithic microbiota in sandstones from the Ross Desert region of Antarctica was studied in situ and in vitro. Organic and inorganic compounds were metabolized by the microbiota, with bicarbonate being metabolized maximally in the light. There was a linear response of photosynthesis to light up to 200 to 300 micromole photons/sq m/s. The community photosynthetic response to temperature was a minimum at -5 C, two optima at +5 and +15 C and a maximum at +35 C. Photosynthetic metabolism occurred maximally in the presence of liquid water, but could occur in an environment of water vapor. Biomass of the cryptoendolithic microbiota was measured as the amount of lipid phosphate present. The in situ biomass ranged from 1.92 to 3.26 g carbon/sq m of rock and 2 orders of magnitude less than epilithic lichen microbiota from Antarctica in a location 7 degrees more north in latitude. With these data, it was possible to calculate primary production and carbon turnover in this simple microbiota. Production values ranged from 0.108 to 4.41 mg carbon/sq m/yr, while carbon turnover values ranged from 576 to 23,520 years. These values are the lowest and longest yet recorded for any ecosystem on Earth. If life did evolve on Mars to the level of prokaryotes or primitive eukaryotes, the possibility that the organisms retreated, to the protection of the inside of the rock so that metabolism could continue during planetary cooling, cannot be overlooked.
Recovery of water soluble, inorganic nutrients from the inedible portion of wheat was found to be an effective means of recycling nutrients within hydroponic systems. Through aqueous extraction (leaching), 60 percent of the total inorganic nutrient weight was removed from wheat straw and roots, although the recovery of individual nutrients varied. Leaching also removed about 20 percent of the total organic carbon from the biomass. In terms of dry weight, the leachate was comprised of approximately 60 percent organic and 40 percent inorganic compounds. Direct use of wheat straw leachate in static hydroponic systems had an inhibitory effect on wheat growth, both in the presence and absence of microorganisms. Biological treatment of leachate either with a mixed microbial community or the oyster mushroom Pleurotus ostreatus L., prior to use in hydroponic solutions, significantly reduced both the organic content and the inhibitory effects of the leachate. The inhibitory effects of unprocessed leachate appear to be a result of rapidly acting phytotoxic compounds that are detoxified by microbial activity. Leaching holds considerable promise as a method for nutrient recycling in a Controlled Ecological Life Support System (CELSS).
The crystals of most proteins or other biological macromolecules are poorly ordered and diffract to lower resolutions than those observed for most crystals of simple organic and inorganic compounds. Crystallization in the microgravity environment of space may improve crystal quality by eliminating convection effects near growing crystal surfaces. A series of 11 different protein crystal growth experiments was performed on U.S. Space Shuttle flight STS-26 in September 1988. The microgravity-grown crystals of gamma-interferon D1, porcine elastase, and isocitrate lyase are larger, display more uniform morphologies, and yield diffraction data to significantly higher resolutions than the best crystals of these proteins grown on earth.