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Theoretical Prediction of Microgravity Ignition Delay of Polymeric Fuels in Low Velocity Flows

A new flammability apparatus and protocol, FIST (Forced Flow Ignition and Flame Spread Test), is under development. Based on the LIFT (Lateral Ignition and Flame Spread Test) protocol, FIST better reflects the environments expected in spacebased facilities. The final objective of the FIST research is to provide NASA with a test methodology that complements the existing protocol and provides a more comprehensive assessment of material flammability of practical materials for space applications. Theoretical modeling, an extensive normal gravity data bank and a few validation space experiments will support the testing methodology. The objective of the work presented here is to predict the ignition delay and critical heat flux for ignition of solid fuels in microgravity at airflow velocities below those induced in normal gravity. This is achieved through the application of a numerical model previously developed of piloted ignition of solid polymeric materials exposed to an external radiant heat flux. The model predictions will provide quantitative results about ignition of practical materials in the limiting conditions expected in space facilities. Experimental data of surface temperature histories and ignition delay obtained in the KC-135 aircraft are used to determine the critical pyrolysate mass flux for ignition and this value is subsequently used to predict the ignition delay and the critical heat flux for ignition of the material. Surface temperature and piloted ignition delay calculations for Polymethylmethacrylate (PMMA) and a Polypropylene/Fiberglass (PP/GL) composite were conducted under both reduced and normal gravity conditions. It was found that ignition delay times are significantly shorter at velocities below those induced by natural convection.

Fernandez-Pello, A. C.

Catalytic Microtube Rocket Igniter

Devices that generate both high energy and high temperature are required to ignite reliably the propellant mixtures in combustion chambers like those present in rockets and other combustion systems. This catalytic microtube rocket igniter generates these conditions with a small, catalysis-based torch. While traditional spark plug systems can require anywhere from 50 W to multiple kW of power in different applications, this system has demonstrated ignition at less than 25 W. Reactants are fed to the igniter from the same tanks that feed the reactants to the rest of the rocket or combustion system. While this specific igniter was originally designed for liquid methane and liquid oxygen rockets, it can be easily operated with gaseous propellants or modified for hydrogen use in commercial combustion devices. For the present cryogenic propellant rocket case, the main propellant tanks liquid oxygen and liquid methane, respectively are regulated and split into different systems for the individual stages of the rocket and igniter. As the catalyst requires a gas phase for reaction, either the stored boil-off of the tanks can be used directly or one stream each of fuel and oxidizer can go through a heat exchanger/vaporizer that turns the liquid propellants into a gaseous form. For commercial applications, where the reactants are stored as gases, the system is simplified. The resulting gas-phase streams of fuel and oxidizer are then further divided for the individual components of the igniter. One stream each of the fuel and oxidizer is introduced to a mixing bottle/apparatus where they are mixed to a fuel-rich composition with an O/F mass-based mixture ratio of under 1.0. This premixed flow then feeds into the catalytic microtube device. The total flow is on the order of 0.01 g/s. The microtube device is composed of a pair of sub-millimeter diameter platinum tubes connected only at the outlet so that the two outlet flows are parallel to each other. The tubes are each approximately 10 cm long and are heated via direct electric resistive heating. This heating brings the gasses to their minimum required ignition temperature, which is lower than the auto-thermal ignition temperature, and causes the onset of both surface and gas phase ignition producing hot temperatures and a highly reacting flame. The combustion products from the catalytic tubes, which are below the melting point of platinum, are injected into the center of another combustion stage, called the primary augmenter. The reactants for this combustion stage come from the same source but the flows of non-premixed methane and oxygen gas are split off to a secondary mixing apparatus and can be mixed in a near-stoichiometric to highly lean mixture ratio. The primary augmenter is a component that has channels venting this mixed gas to impinge on each other in the center of the augmenter, perpendicular to the flow from the catalyst. The total crosssectional area of these channels is on a similar order as that of the catalyst. The augmenter has internal channels that act as a manifold to distribute equally the gas to the inward-venting channels. This stage creates a stable flame kernel as its flows, which are on the order of 0.01 g/s, are ignited by the combustion products of the catalyst. This stage is designed to produce combustion products in the flame kernel that exceed the autothermal ignition temperature of oxygen and methane.

Schneider, Steven J.

Plasma assisted NH 3 /H 2 /air ignition in nanosecond discharges with non-equilibrium energy transfer

Ammonia (NH 3 ), with its high energy density and easiness to store and transport as a hydrogen carrier, has become a promising alternative green fuel. However, its adoption in power generation is hindered by challenges such as low burning velocity, slow low-temperature oxidation, high NO x emissions, and ignition difficulty. Here, this work computationally investigates the effects of non-equilibrium energy transfer by nanosecond discharges on NH 3 ignition and flame propagation in an NH 3 /H 2 /air flow at 700 K and 1 atm. The simulation results demonstrate that NH 3 /air mixtures require a large ignition energy due to their large critical ignition radius. It is shown that adding 30 % hydrogen significantly reduces the critical ignition radius and minimum ignition energy. Two-dimensional modeling further shows a non-monotonic dependence of ignition kernel volume on the applied voltage and reduced electric field. The optimum ignition enhancement occurs at 200 Td where the generation of electronically excited species and radicals including N 2 (B), O( 1 D) and OH becomes most efficient. Higher voltages divert electron energy toward ionization, which makes it less effective for NH 3 ignition. The study also identifies an optimal electrode gap size for a given pulse energy. Smaller gap sizes increase deposited energy density, raising temperature and radical concentrations. However, excessive reduction of the gap distance reduces flame propagation speed due to the flame stretch effect in rich mixtures with the effective Lewis number greater than unity. A nonlinear relationship between pulse repetition frequency and ignition kernel volume is observed in a nanosecond pulsed high frequency discharge (NPHFD). An optimal frequency range of 200 kHz to 2 MHz is found when two pulses are used. In addition, an optimal number of pulses exists for each pulse repetition frequency, with higher frequencies requiring more pulses to maximize the overlap region. These findings provide critical insights on developing controlled plasma discharge techniques for efficient NH 3 ignition in reactive flows within internal combustion engines and gas turbines.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

Combustion-wave ignition for rocket engines

The combustion wave ignition concept was experimentally studied in order to verify its suitability for application in baffled sections of a large booster engine combustion chamber. Gaseous oxygen/gaseous methane (GOX/GH4) and gaseous oxygen/gaseous hydrogen (GOX/GH2) propellant combinations were evaluated in a subscale combustion wave ignition system. The system included four element tubes capable of carrying ignition energy simultaneously to four locations, simulating four baffled sections. Also, direct ignition of a simulated Main Combustion Chamber (MCC) was performed. Tests were conducted over a range of mixture ratios and tube geometries. Ignition was consistently attained over a wide range of mixture ratios. And at every ignition, the flame propagated through all four element tubes. For GOX/GH4, the ignition system ignited the MCC flow at mixture ratios from 2 to 10 and for GOX/GH2 the ratios is from 2 to 13. The ignition timing was found to be rapid and uniform. The total ignition delay when using the MCC was under 11 ms, with the tube-to-tube, as well as the run-to-run, variation under 1 ms. Tube geometries were found to have negligible effect on the ignition outcome and timing.

Liou, Larry C.

Ignition Transient Calculations in the Space Shuttle Solid Rocket Motor

The work presented is part of an effort to develop a multidimensional ignition transient model for large solid propellant rocket motors. On the Space Shuttle, the ignition transient in the slot is induced when the igniter, itself a small rocket motor, is fired into the head-end portion of the main rocket motor. The computational results presented in this paper consider two different igniter configurations. The first configuration is a simulated Space Shuttle RSRM igniter which has one central nozzle that is parallel to the centerline of the motor. The second igniter configuration has a nozzle which is canted at an angle of 45 deg from the centerline of the motor. This paper presents a computational fluid dynamic (CFD) analyses of certain flow field characteristics inside the solid propellant star grain slot of the Space Shuttle during the ignition transient period of operation for each igniter configuration. The majority of studies made to date regarding ignition transient performance in solid rocket motors have concluded that the key parameter to be determined is the heat transfer rate to the propellant surface and hence the heat transfer coefficient between the gas and the propellant. In this paper the heat transfer coefficients, pressure and velocity distributions are calculated in the star slot. In order to validate the computational method and to attempt to establish a correlation between the flow field characteristics and the heat transfer rates a series of cold flow experimental investigations were conducted. The results of these experiments show excellent qualitative and quantitative agreement with the pressure and velocity distributions obtained from the CFD analysis. The CFD analysis utilized a classical pipe flow type correlation for the heat transfer rates. The experimental results provide an excellent qualitative comparison with regard to spatial distribution of the heat transfer rates as a function of nozzle configuration and igniter pressure. The results indicate that from a quantitative point of view that the pipe flow correlation gives reasonably good results. Furthermore, there appears to be a direct correlation between igniter pressure and an average Reynolds number in the star grain slot. This may lead to a simple method for modifying the convection heat transfer correlation. Calculated results of pressure-vs-time for the first 200 msec of motor firing of the Space Shuttle RSRM support the trends shown for the heat transfer rate comparisons between the cold flow CFD and experimental data.

Jenkins, Rhonald M.

Ignition of Cellulosic Paper at Low Radiant Fluxes

The ignition of cellulosic paper by low level thermal radiation is investigated. Past work on radiative ignition of paper is briefly reviewed. No experimental study has been reported for radiative ignition of paper at irradiances below 10 Watts/sq.cm. An experimental study of radiative ignition of paper at these low irradiances is reported. Experimental parameters investigated and discussed include radiant power levels incident on the sample, the method of applying the radiation (focussed vs. diffuse Gaussian source), the presence and relative position of a separate pilot ignition source, and the effects of natural convection (buoyancy) on the ignition process in a normal gravity environment. It is observed that the incident radiative flux (in W/sq.cm) has the greatest influence on ignition time. For a given flux level, a focussed Gaussian source is found to be advantageous to a more diffuse, lower amplitude, thermal source. The precise positioning of a pilot igniter relative to gravity and to the fuel sample affects the ignition process, but the precise effects are not fully understood. Ignition was more readily achieved and sustained with a horizontal fuel sample, indicating the buoyancy plays a role in the ignition process of cellulosic paper. Smoldering combustion of doped paper samples was briefly investigated, and results are discussed.

White, K. Alan

Ignition of Hydrogen-Oxygen Rocket Combustor with Chlorine Trifluoride and Triethylaluminum

Ignition of a nominal-125-pound-thrust cold (2000 R) gaseous-hydrogen - liquid-oxygen rocket combustor with chlorine trifluoride (hypergolic with hydrogen) and triethylaluminum (hypergolic with oxygen) resulted in consistently smooth starting transients for a wide range of combustor operating conditions. The combustor exhaust nozzle discharged into air at ambient conditions. Each starting transient consisted of the following sequence of events: injection of the lead main propellant, injection of the igniter chemical, ignition of these two chemicals, injection of the second main propellant, ignition of the two main propellants, increase in chamber pressure to its terminal value, and cutoff of igniter-chemical flow. Smooth ignition was obtained with an ignition delay of less than 100 milliseconds for the reaction of the lead propellant with the igniter chemical using approximately 0.5 cubic inch (0-038 lb) of chlorine trifluoride or 1.0 cubic inch (0-031 lb) of triethylaluminum. These quantities of igniter chemical were sufficient to ignite a 20-percent-fuel hydrogen-oxygen mixture with a delay time of less than 15 milliseconds. Test results indicated that a simple, light weight chemical ignition system for hydrogen-oxygen rocket engines may be possible.

Gregory, John W.

Ignition Delay Associated with a Strained Strip

Ignition processes associated with two adjacent fuel-oxidizer interferences bounding a strained fuel strip are explored here using single-step activation energy asymptotics. Calculations are made for constant as well as temporally decaying strain fields. There possible models of ignition are determined: one in which the two interfaces ignite independently as diffusion flames; one in which the two interfaces ignite dependently and in which ignition occurs to form a single , premixed flame at very high strain rates before ignition is completely prevented. In contrast to a single, isolated interface in which ignition can be prevented by overmatching heat production with heat convection due to strain, ignition of a strained fuel strip can also be prevented if the finite extend of fuel is diluted by oxidizer more quickly than heat production can cause a positive feedback thermal runaway. These behaviors are dependent on the relative sizes of timescales associated with species and heat diffusion, with convection due to strain, and with the chemical reaction. The result here indicate that adjacent, strained species interfaces may ignite quite differently in nature from ignition of a single, strained intrface and that their interdependence should be considered as the interfaces are brought closer together in complex strain fields. Critical strain rates leading to complete ignition delay are found to be considerably smaller for the fuel strip than those for single interfaces as the fuel strip is made thin in comparison to diffusion and chemical length scales.

Gerk, T. J.

Test System to Study the Ignition of Metals by Polymers in Oxygen

A new test system that uses Laser energy to ignite a polymer promoter has been developed at the NASA White Sands Test Facility. It will facilitate the study of the spread of fire from a burning polymer material to the metal surrounding it. The system can be used to answer questions regarding the effects of configuration on ignition and combustion. The data obtained from this test could also be used to develop mathematical models for analyzing the effects of configuration on ignition and combustion. The system features a 10,000-psi (69-MPa) test chamber with sight glass windows on either end and a 25-watt carbon dioxide Laser for an ignition source. The test system can be used with gaseous oxygen, nitrogen or any mixture of the two gases. To minimize the effect of preheating the metallic, the polymer is ignited with a minimal amount of Laser energy. Igniting the polymer in this fashion also simplifies the thermodynamic analysis of the ignition and propagation reactions. The system is very robust, versatile and straightforward to use. Depending on the test pressure and configuration, the test system operator can perform as many as 20 tests per day. Test results verify that ignition and combustion of the metallic sample is not only dependent on pressure, material type and temperature, but configuration of both the polymer promoter and metallic sample. Both 6061 aluminum and 316 stainless steel 0.25-inch (6.35-mm) diameter rods with a standard 0-ring groove were tested with Buna-N, Silicone, Teflon and Viton 0-rings. The system ignited all four types of 0-rings in oxygen at pressures ranging from ambient to 10,000 psi (69 MPa). However, neither the stainless steel nor the aluminum rods on which the O-rings were mounted ignited in any test conditions. Future testing may be done on the 0.25-inch (6.35-mm) rod and O-ring configuration to evaluate the lack of ignition in these tests. Future configurations may include a plug of polymer in the base of the sample and replicas of fire-damaged components. Furthermore, the test system may be used in the future to analyze the oxidation rate of Laser-heated metals in gaseous oxygen.

Shoffstall, Michael S.

Ignition Characterization Tests of the LOX/Ethanol Propellant Combination

A series of contracts have been issued by the Marshall Space Flight Center (MSFC) of the National Aeronautics and Space Administration (NASA) to explore candidate technologies considered to be important for the Next Generation Launch Technology (NGLT) effort. One aspect of the NGLT effort is to explore the potential of incorporating non-toxic propellants for Reaction Control Subsystems (RCS). Contract NAS8-01109 has been issued to Aerojet to develop a dual thrust Reaction Control Engine (RCE) that utilizes liquid oxygen and ethanol as the propellants. The dual thrust RCE incorporates a primary thrust level of 870 lbf, and a vernier thrust level of 10 - 30 lbf. Aerojet has designed and tested a workhorse LOX igniter to determine LOX/Ethanol ignition characteristics as part of a risk mitigation effort for the dual thrust RCE design. The objective of the ignition testing was to demonstrate successfid ignition from GOX to LOX, encompassing potential two-phase flow conditions. The workhorse igniter was designed to accommodate the full LOX design flowrate, as well as a reduced GOX flowrate. It was reasoned that the initial LOX flow through the igniter would flash to GOX due to the inherent heat stored in the hardware, causing a reduced oxygen flowrate because of a choked, or sonic, flow condition through the injection elements. As LOX flow continued, the inherent heat of the test hardware would be removed and the hardware would chill-in, with the injected oxygen flow transitioning from cold GOX through two-phase flow to subcooled LOX. Pressure and temperature instrumentation permitted oxygen state points to be determined, and gas-side igniter chamber thermocouples provided chamber thermal profile characteristics. The cold flow chamber pressure (P(sub c)) for each test was determined and coupled with the igniter chamber diameter (D(sub c)) to calculate the characteristic quench parameter (P(sub c) x D(sub c)), which was plotted as a function of core mixture ratio, MR(sub c). Ignition limits were determined over a broad range of valve inlet conditions, and ignition was demonstrated with oxygen inlet conditions that ranged from subcooled 173 R LOX to 480 R GQX. Once ignited at cold GOX conditions, combustion was continuous as the hardware chilled in and the core mixture ratio transitioned from values near 1.0 to over 12.5.

Popp, Christopher G.

Component Testing of the J-2X Augmented Spark Igniter (ASI)

In support of the development of the J-2X engine, 201 low pressure, liquid oxygen / liquid hydrogen (LOX/LH2) J-2X Augmented Spark Igniter (ASI) subsystem ignition tests were conducted at Marshall Space Flight Center (MSFC). The main objective of these tests was to start the ASI within the anticipated J-2X engine start box, as well as outside of it, to check for ignition margin. The setup for the J-2X ASI component testing simulated, as much as possible, the tank-head start-up configuration of the ASI within the J-2X Engine. The ignition tests were divided into 124 vacuum start tests to simulate altitude start on a flight engine, and 77 sea-level start tests to simulate the first set of ground tests for the J-2X Engine at Stennis Space Center (SSC). Other ignition parameters that were varied included propellant tank pressures, oxidizer temperature entering the ASI oxidizer feedline, oxidizer valve timing, spark igniter condition (new versus damaged), and oxidizer and fuel feedline orifice sizes. Propellant blowdowns using venturis sized to simulate the ASI resistance allowed calculation of transient propellant mass flow rates as well as global mixture ratio for all ignition tests. Global mixture ratio within the ASI at the time of ignition varied from 0.2 to 1.2. Detailed electronics data obtained from an instrumented ignition lead allowed characterization of the breakdown voltage, sustaining voltage and energy contained in each spark as the ASI propellants ignited. Results indicated that ignition always occurred within the first five sparks when both propellants were present in the ASI chamber.

Osborne, Robin J.

Enabling Low-Temperature (LTP) Ignition Technologies for Multi-Mode Engines through the Development of a Validated High-Fidelity LTP Model for Predicative Simulations Tools

The goal of multi-mode engine architectures is to extend current lean-burn dilution limits with renewable fuels, which requires spark plugs to deposit high energies (hundreds of mJ) in order to initiate ignition and complete combustion. At elevated energy deposition rates, spark plugs experience increased electrode erosion and thermal losses, which ultimately shortens the spark-plug lifetime and lowers ignition efficiency. As such, in order to safeguard the efficiency gains of multi-mode concepts, new and improved ignition technologies are required. Recently, non-equilibrium low-temperature plasmas (LTP) have been shown to promote energy-efficient ignition via quenching and transport of electronically excited atoms and molecules, selective radical production and fast heating of hydrocarbon/air mixtures [1-2]. Thus, LTP is seen as a technology that can potentially improve the energy extraction efficiency of fuels, while enabling kinetically controlled combustion modes towards fuel leaner conditions to realize current DOE VTO goals of improving the sustainability of future mobility [3]. Although many previous studies have demonstrated the efficacy of plasma-assisted ignition to enhance combustion, the detailed enhancement mechanisms remain largely unknown, especially for oxygenated fuels and at elevated pressures that are most relevant to practical engine conditions. These barriers hinder the development of accurate and comprehensive numerical models that seek to describe LTP-based ignition in existing engine design software tools and methods. Current state-of-the-art simulation capabilities for LTP ignition systems are in need of improvements since they deliver qualitative results only due to important limitations of existing approaches. Firstly, validated kinetic models with elementary steps for plasma discharges in oxygenated fuel/air mixtures of relevance to the transportation sector are required. Such kinetic models do not exist at present and will be developed and validated within this project. Secondly, plasma discharges and reactive mixture ignition are multi-scale, unsteady processes requiring high-performance numerical methods and software that execute efficiently on DOE supercomputers. Such software does not exist at present and will be developed and applied to practical LTP ignition scenarios as part of this project. Thirdly, experimental databases that are tailored to serve as benchmark in support of the development of predictive computational models of LTP ignition do not exist and will be part of this project.

33 ADVANCED PROPULSION SYSTEMS

Ignition of metals and alloys in gaseous oxygen by frictional heating

The ignition of metals and alloys have been investigated by rotating the end of a hollow cylinder against an identical stationary cylinder on a common axis (frictional heating) in gaseous oxygen. A ranking criterion that measures the resistance of metals and alloys to ignition is discussed. It consists of the power per unit area required for ignition conveniently expressed as the product of contact pressure P and average linear velocity ALV. Data are presented that demonstrate that materials that are high in nickel and copper require greater P-ALV products for ignition (more resistant to ignition) than materials that are high in iron. Aluminum and titanium alloys are shown to require the lowest P-ALV products for ignition. The effects of varying surface velocity, contact pressure, coefficient of friction, and oxygen pressure on P-ALV products required for ignition are discussed. The results indicate that P-ALV product required for ignition increases as surface velocity increases, as contact pressure decreases, and as the coefficient of friction decreases. Increasing oxygen pressure will cause the P-ALV product required for ignition to decrease at low pressures and increase at high pressures. In some cases, the relative ranking of materials based on P-ALV products will also change as conditions are varied. The data presented in this paper are from a development program to determine the merits of using such a dynamic test method for ranking materials for oxygen service. The results to date have indicated that more testing is required before this method can be made into a standard test. The data presented do show some of the major parameters affecting the ignition of materials when exposed to frictional heating. The repeatability of the data at any set of conditions have not been thoroughly investigated.

Benz, F. J.

LOX/Methane Main Engine Igniter Tests and Modeling

The LOX/methane propellant combination is being considered for the Lunar Surface Access Module ascent main engine propulsion system. The proposed switch from the hypergolic propellants used in the Apollo lunar ascent engine to LOX/methane propellants requires the development of igniters capable of highly reliable performance in a lunar surface environment. An ignition test program was conducted that used an in-house designed LOX/methane spark torch igniter. The testing occurred in Cell 21 of the Research Combustion Laboratory to utilize its altitude capability to simulate a space vacuum environment. Approximately 750 ignition test were performed to evaluate the effects of methane purity, igniter body temperature, spark energy level and frequency, mixture ratio, flowrate, and igniter geometry on the ability to obtain successful ignitions. Ignitions were obtained down to an igniter body temperature of approximately 260 R with a 10 torr back-pressure. The data obtained is also being used to anchor a CFD based igniter model.

Breisacher, Kevin J.

Testing of the J-2X Augmented Spark Igniter (ASI) and Its Electronics

Reliable operation of the spark ignition system electronics in the J‐2X Augmented Spark Igniter (ASI) is imperative in assuring ASI ignition and subsequent Main Combustion Chamber (MCC) ignition events are reliable in the J‐2X Engine. Similar to the man‐rated J‐2 and RS‐25 engines, the J‐2X ignition system electronics are equipped with spark monitor outputs intended to indicate that the spark igniters are properly energized and sparking. To better understand anomalous spark monitor data collected on the J‐2X development engines at NASA Stennis Space Center (SSC), a comprehensive subsystem study of the engine's low‐ and high‐tension spark ignition system electronics was conducted at NASA Marshall Space Flight Center (MSFC). Spark monitor output data were compared to more detailed spark diagnostics to determine if the spark monitor was an accurate indication of actual sparking events. In addition, ignition system electronics data were closely scrutinized for any indication of an electrical discharge in some location other than the firing tip of the spark igniter ‐ a problem not uncommon in the development of high voltage ignition systems.

Osborne, Robin

FLEX-FUEL MIXING CONTROLLED COMBUSTION ENABLED BY PRECHAMBER IGNITION

There is an imminent need to displace fossil diesel fuel with cleaner burning, domestically produced, renewable fuels for use in heavy-duty engines. Bioethanol is a prime candidate as it widely adopted in the U.S. as a gasoline additive ranging in volume percentage from 10% (E10) up to 85% (E85). Direct substitution of market available ethanol-gasoline blends for diesel fuel is not plausible as the stark reactivity differences would not constitute the same ignition quality nor achieve auto-ignition at all. This work focuses on the development of prechamber enabled mixing-controlled combustion (PC-MCC) as an advanced combustion strategy to facilitate reliable ignition and diffusion style combustion ethanol-gasoline fuel blends. PC-MCC involves integration of an actively fueled prechamber (PC) into a conventional compression ignition combustion system. When ignited, the PC ejects hot turbulent jets into the main combustion chamber that then interact with the direct injected fuel, prompting immediate ignition. The PC jet flames provide a robust thermal ignition source that allows the engine to operate agnostic of fuel composition, or flex-fuel. Computational fluid dynamics (CFD) modeling was used to assess critical design features of the PC while garnering insights into the ignition strategies that facilitate robust performance. A key finding was the ignition performance benefits of fuel-rich PC operation which yield exothermic jets. Based on the numerical findings, a prototype igniter was tested experimentally on both single and multi-cylinder engine platforms at a variety of operating conditions. The experimental results indicate flex-fuel PC-MCC is well capable of diesel-like combustion processes by demonstrating matched or improved gross thermal efficiencies and load variability within 2%. Fuel grade ethanol (E98) exhibited consistently lower NOx and immeasurable soot across the load space. E98 also demonstrated a significant improvement in thermal efficiency at light loads.

Zeman, Jared

Ignition Delay of Combustible Materials in Normoxic Equivalent Environments

Material flammability is an important factor in determining the pressure and composition (fraction of oxygen and nitrogen) of the atmosphere in the habitable volume of exploration vehicles and habitats. The method chosen in this work to quantify the flammability of a material is by its ease of ignition. The ignition delay time was defined as the time it takes a combustible material to ignite after it has been exposed to an external heat flux. Previous work in the Forced Ignition and Spread Test (FIST) apparatus has shown that the ignition delay in the currently proposed space exploration atmosphere (approximately 58.6 kPa and32% oxygen concentration) is reduced by 27% compared to the standard atmosphere used in the Space Shuttle and Space Station. In order to determine whether there is a safer environment in terms of material flammability, a series of piloted ignition delay tests using polymethylmethacrylate (PMMA) was conducted in the FIST apparatus to extend the work over a range of possible exploration atmospheres. The exploration atmospheres considered were the normoxic equivalents, i.e. reduced pressure conditions with a constant partial pressure of oxygen. The ignition delay time was seen to decrease as the pressure was reduced along the normoxic curve. The minimum ignition delay observed in the normoxic equivalent environments was nearly 30% lower than in standard atmospheric conditions. The ignition delay in the proposed exploration atmosphere is only slightly larger than this minimum. Interms of material flammability, normoxic environments with a higher pressure relative to the proposed pressure would be desired.

Ignition delay time

Effects of spatiotemporal plasma power distribution on the modeling of ignition kernel evolution in quiescent and turbulent methane/air mixtures

Abstract The present work improves a phenomenological plasma-assisted combustion model by integrating the spatiotemporal distribution of plasma power density, thereby considering the evolution of plasma streamers in the modeling, and subsequently, better predicting the ignition kernel evolution. The improved phenomenological model is validated against experiments representing the plasma discharge and post-discharge ignition kernel evolution. Specifically, the new model demonstrates a more accurate prediction of ultrafast gas heating and O 2 dissociation during the plasma discharge, compared to the original model. In addition, the new model is found to closely match the experimental pressure wave and heated channel profiles post-discharge without the need for tuning the energy deposition (unlike the original model), highlighting its accuracy of post-discharge ignition kernel dynamics. The improved phenomenological model is then employed to investigate ignition kernel evolution for a stoichiometric methane-air discharge across various discharge gap configurations. Simulations reveal a non-uniform temperature and streamer distribution progressing from the electrode tips toward the center, contrasting uniform cylindrical discharges previously described in the original model. Streamer propagation is observed to be faster for larger gaps when maintained at the same average electric field for different discharge gaps. The tendency of smaller gaps to produce detached toroidal ignition kernels is observed, while larger gaps promote cylindrical and attached ignition kernels. Interactions between successive ignition kernels from consecutive discharges varied significantly, with the smallest gap (1 mm) promoting the quenching of the preceding ignition kernel due to the initial kernel–kernel separation. The intermediate gap (2 mm) promotes detached kernel growth. In contrast, in the largest gap (4 mm), kernels consistently combine and expand attached to electrodes. The impact of homogeneous isotropic turbulence is also explored, showing the persistence of ignition kernels early on but eventually quenching due to enhanced radical and heat losses with pronounced turbulence intensity.

Johnson, Praise Noah