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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

High Pressure X-ray Diffraction and Equation of State of Hydrazine

Synchrotron X-ray diffraction has been used to investigate the structure and equation of state (EOS) of hydrazine (N 2 H 4 ) up to 54.3 GPa at 298 K. The diffraction patterns could be fit to a monoclinic unit-cell structure and put strong constraints on previously reported phase transitions documented by vibrational spectroscopy over this pressure range. Pressure–volume ( P–V ) data were fit using a Vinet EOS, yielding parameters: V 0 = 45.2 Å 3 /molecule (fixed), K 0 = 11.8(7) GPa, and K 0 ′ = 6.5(2). Previously measured high-pressure vibrational frequency shifts were used to estimate the vibrational free energy and model P–V–T isotherms from 0 to 1200 K. The results of the P–V–T isotherms are compared to existing shock Hugoniot data on hydrazine and 298 K isotherms for assemblages of possible decomposition products. This comparison suggests dissociation at high density under shock loading. Good correspondence was found between the static lattice EOS as calculated by the model and the previously reported EOS as calculated by density functional theory. Finally, these results resolve existing uncertainties about the EOS and crystal symmetry of hydrazine at high pressure and provide valuable baseline information on this important energetic material.

diffraction↗
NASA NTRS1961

THERMAL DECOMPOSITION OF HYDRAZINE

The Thermal Stability of Hydrazine has been studied in the temperature and pressure intervals of 175" to 250"C. and 300 to 430 p.s.i., Respectively. Previous studies of the decomposition of hydrazine indicated that several factors affect its stability (2, 5, 7). the rate of decomposition is increased by the presence of certain surfaces (especially metals and salts). pH, oxygen, and carbon dioxide. Further explosive decomposition Is attributable to the uncontrolled heterogeneous, gas-phase decomposition. These factors were considered in selecting the following experimental conditions: highly purified hydrazine was prepared in a nitrogen atmosphere, and this product was decomposed over triply distilled mercury in outgassed borosilicate glass tubes at ullages that were initially zero. This study also included the effects of added quantities of ammonia on the rate of decomposition and an investigation of the products of the decomposition.

Harold W. Lucien↗
NASA NTRS1973

Monopropellant hydrazine resistojet: Flight application design

The design, development, and testing of an engineering model nominal 20-millipound thrust monopropellant hydrazine resistojet program is directed toward the advanced development of an electrothermal hydrazine thruster (EHT). The EHT decomposes hydrazine thermally and expands the decomposition products through a nozzle to provide the impulse necessary to fulfill spacecraft propulsive requirements. The thruster is capable of operation at pulse widths from 0.050 second to steady state and delivers specific impulse values up to about 230 seconds depending on the duty cycle. The program is comprised of six tasks including analyses, the generation of specifications and other documentation, design, fabrication and test, data correlation, and recommendations for the design of flight units.

Kurch, C. K.↗
NASA NTRS1973

Monopropellant hydrazine resistoject: Engineering model fabrication and test task

The monopropellant hydrazine resistojet, termed the electrothermal hydrazine thruster (EHT) by TRW systems, thermally decomposes anhydrous hydrazine propellant to produce a high-temperature, low-molecular-weight gas for expulsion through a propulsive nozzle. The EHT developed for this program required about 3-5 watts of electrical power and produced 0.020 to 0.070 pound of thrust over the inlet pressure range of 100 to 400 psia. The thruster was designed for both pulsed and steady state operation. A summary of the GSFC original requirements and GSFC modified requirements, and the performance of the engineering model EHT is given. The experimental program leading to the engineering model EHT design, modifications necessary to achieve the required thruster life capability, and the results of the life test prgram. Other facets of the program, including analyses, preliminary design, specifications, data correlation, and recommendations for a flight model are discussed.

Murch, C. K.↗
NASA NTRS1978

Evaluation of the SSRCS engine with hydrazine as a fuel, phase 2

Test firing of the Space Shuttle Reaction Control Thruster (SSRCT) was conducted to determine the characteristic velocity and chamber throat temperatures when the fuel is changed from monomethylhydrazine (MMH) to hydrazine. Thruster performance with hydrazine was essentially as predicted. Characteristic velocity at a mixture ratio of 1.4 (equal volumetric flow) for hydrazine was 5180 feet/second compared with 5110 feet/second at a mixture of 1.6 for MMH. Specific impulse with 22:1 nozzle is calculated to be 280 lbf-sec/lbm. Thermal performance, as measured by chamber throat temperature, was dramatically different (colder) than predicted. Throat temperatures of 2330 F were predicted from a cooling model which assumed a reactive liquid cooling film. Throat temperatures of 800 - 1000 F were measured. An attempt to reconcile the differences between film cooling predictions and the measurements, indicated that an evaporation (nonreactive fluid) model rather than a decomposition (reactive fluid) model best fits the test data at 0/F = 1.4. At higher mixture ratios, a transition to temperatures typical of the reactive fluid model were observed.

Minton, S. J.↗
NASA NTRS1979

The monopropellant hydrazine propulsion subsystem for the Pioneer Venus spacecraft

The Pioneer Venus Orbiter and the Multiprobe spacecraft propulsion subsystems and their performance are presented. Monopropellant hydrazine subsystems on each spacecraft provided the capability to spin up the spacecraft after separation and perform all spin rate, velocity, and attitude changes required by the control subsystem to satisfy mission objectives. The propulsion subsystem provides thrust on demand by supplying anhydrous hydrazine from the propellant tanks through manifolds, filters and valves to the thrust chamber assemblies where the hydrazine is catalytically decomposed and expanded in a conical nozzle. The subsystems consist of seven 1 lbf thrusters for the Orbiter and six 1 lbf thrusters for the multiprobe which are isolated by two latch valves from the two propellant tanks so that two redundant thruster clusters are provided to ensure mission completion in the event of a single point failure. The propellant feed system is of all-welded construction to minimize weight and leakage and titanium is used as the primary material of construction. The multiprobe burned up on entering the Venus atmosphere with enough propellant left for the mission and the Orbiter was inserted into Venus orbit with enough propellant remaining for more than 2 earth years of orbital operations.

Barker, F. C.↗
NASA NTRS1982

Hydrazine-Compatible Elastomer

Hydrazine hardly reacts with ethylene propylene diene monomer, even at high temperatures. According to report to tests, EPDM is most hydrazine-compatible material among elastomers. Has strong potential as valve-seat and O-ring seal with hydrazine, especially at high temperatures.

Markles, O., F.↗
NASA NTRS1983

Hydrazine gas generator performance on Space Shuttle

The design, functions, performance, and applications of the hydrazine gas generators (GG) on the STS are detailed. The GGs provide gas horse power for the APUs that drive the hydraulic pumps on the SRBs, which have two cross-linked systems. The Orbiter has three-cross-linked APU systems, used for gimballing the main engine and booster nozzles, actuating the main engine fuel valves and the ET umbilical disconnect, actuation of the control surfaces, and powering the landing gear, brakes, and nose wheel steering. The major design components of the Orbiter GGs are an injector, a catalyst bed, a decomposition chamber, an exhaust nozzle, and an interface structure, with the main structural material being Hasteloy B. Hydrazine injected and dispersed into the catalyst bed decomposes into gas and exits for expansion in an APU turbine. Twenty-six GGs have flown on missions STS-1 through STS-6 with over three tons of hydrazine having been expended over 44 hr of operations, as no refurbishment to that point was necessary.

Patterson, I. J.↗
NASA NTRS1985

Explosive decomposition of hydrazine due to rapid gas compression

Results from tests which attempt to determine conditions which cause explosive decomposition of hydrazine from rapid gas compression are described. Hydrazine was initiated by pressure in combination with shock waves from the pressurant gas. A new test method was developed at the White Sands Test Facility which subjects a gas bubble in contact with liquid hydrazine to pure adiabatic compression. Results from this new test method are compared to those from the U-tube method.

Briles, O.↗
NASA NTRS1986

Treatment for hydrazine-containing waste water solution

The treatment for waste solutions containing hydrazine is presented. The invention attempts oxidation and decomposition of hydrazine in waste water in a simple and effective processing. The method adds activated charcoal to waste solutions containing hydrazine while maintaining a pH value higher than 8, and adding iron salts if necessary. Then, the solution is aerated.

Yade, N.↗
NASA NTRS1987

The catalysis of hydrazines

Hydrazine sulfate in a hot aqueous solution can be catalyzed in the direction of 3 N2H4 = 4 NH3 + N2. Free hydrazine in a hot aqueous solution dissociates in the presence of platinum in the following direction: 2 N2H4 = 2 NH3 + N2 + H2. In the presence of sodium hydroxide, the catalytic dissociation of hydrazine takes a third direction: 3 N2H4 = 2 NH3 + 2 N3 + 3 H2.

Tanatar, S.↗
NASA NTRS1988

Surface-catalyzed air oxidation reactions of hydrazines: Tubular reactor studies

The surface-catalyzed air oxidation reactions of hydrazine, monomethylhydrazine, unsymmetrical dimethylhydrazine, symmetrical dimethylhydrazine, trimethylhydrazine and tetramethylhydrazine were investigated in a metal-powder packed turbular flow reactor at 55 plus or minus 3 C. Hydrazine was completely reacted on all surfaces studied. The major products of monomethylhydrazine (MMH) oxidation were methanol, methane and methyldiazene. The di-, tri- and tetra-methyl hydrazines were essentially unreactive under these conditions. The relative catalytic reactivities toward MMH are: Fe greater than Al2O3 greater than Ti greater than Zn greater than 316 SS greater than Cr greater than Ni greater than Al greater than 304L SS. A kinetic scheme and mechanism involving adsorption, oxidative dehydrogenation and reductive elimination reactions on a metal oxide surface are proposed.

Kilduff, Jan E.↗
NASA NTRS1988

A diffuse reflectance infrared Fourier transform spectroscopic study of adsorbed hydrazines

Diffuse reflectance spectroscopy of fuel hydrazines adsorbed on silica, silica-alumina and alimina surfaces indicates that the primary surface-hydrazine interaction is hydrogen bonding. Hydrazine, on adsorption to a deuterated silica surface, undergoes a rapid H/D exchange with deuterated surface silanol (Si-OD) groups. Adsorption equilibria are rapidly established at room temperature. Monomethylhydrazine and unsymmetrical dimethylhydrazine are similarly adsorbed. On adsorption, the C-H stretching and methyl deformation modes of the methylhydrazines are shifted to higher frequencies by 10 to 20 cm(-1). These shifts are postulated to be due to changes in the lone-pair electro-density on the adjacent nitrogen atom and an electronegativity effect.

Davis, Dennis D.↗
NASA NTRS1992

Long life monopropellant hydrazine thruster evaluation for Space Station Freedom application - Test results

In support of propulsion system thruster development activity for Space Station Freedom (SSF), NASA Johnson Space Center (JSC) conducted a hydrazine thruster technology demonstration program. The goal of this program was to identify impulse life capability of state-of-the-art long life hydrazine thrusters nominally rated for 50 pounds thrust at 300 psia supply pressure. The SSF propulsion system requirement for impulse life of this thruster class is 1.5 million pounds-seconds, corresponding to a throughput of approximately 6400 pounds of propellant. Long life thrusters were procured from The Marquardt Company, Hamilton Standard, and Rocket Research Company, Testing at JSC was completed on the thruster designs to quantify life while simulating expected thruster firing duty cycles and durations for SSF. This paper presents a review of the SSF propulsion system hydrazine thruster requirements, summaries of the three long life thruster designs procured by JSC and acceptance test results for each thruster, the JSC thruster life evaluation test program, and the results of the JSC test program.

Popp, Christopher G.↗
NASA NTRS1999

Permeation Resistance of Chlorinated Polyethylene Against Hydrazine Fuels

The permeation resistance of chlorinated polyethylene (CPE) used in chemical protective clothing against the aerospace fuels hydrazine, monomethylhydrazine (MMH), and uns-dimethylhydrazine (UDMH) was determined by measuring breakthrough times and time-averaged vapor transmission rates using an ASTM F 739 permeation cell. Two exposure scenarios were simulated: a 2 hour (h) fuel vapor exposure, and a liquid fuel "splash" followed by a 2 h vapor exposure. To simulate internal suit pressure during operation, a positive differential pressure of 0.3 in. water (75 Pa) on the collection side of the permeation apparatus was used. Breakthrough was observed after exposure to liquid MMH, and to vapor and liquid UDMH. No breakthrough was observed after exposure to vapor and liquid hydrazine, or vapor MMH. A model was then used to calculate propellant concentrations inside a totally encapsulating chemical protective suit based on the ASTM permeation data obtained in the present study. Concentrations were calculated under conditions of fixed vapor transmission rate, variable breathing air flow rate, and variable splash exposure area. Calculations showed that the maximum allowable permeation rates of hydrazine fuels through CPE were of the order of 0.05 to 0.08 ng sq cm/min for encapsulating suits with low breathing air flow rates (of the order of 5 scfm or 140 L/min). Above these permeation rates, the 10 parts per billion (ppb) threshold limit value time - weighted average could be exceeded for chemical protective suits having a CPE torso. To evaluate suit performance at ppb level concentrations, use of a sensitive analytical method such as cation exchange high performance liquid chromatography with amperometric detection was found to be essential.

Waller, J. M.↗
NASA NTRS2007

A Process for Producing Highly Wettable Aluminum 6061 Surfaces Compatible with Hydrazine

NASA's Global Precipitation Measurement (GPM) mission is an ongoing Goddard Space Flight Center (GSFC) project whose basic objective is to improve global precipitation measurements. The space-based portion of the mission architecture consists of a primary or core spacecraft and a constellation of NASA and contributed spacecrafts. The efforts described in this paper refer to the core spacecraft (hereafter referred to as simply GPM) which is to be fabricated at GSFC. It has been decided that the GPM spacecraft is to be a "design-for-demise-spacecraft." This requirement resulted in the need for a propellant tank that would also demise or ablate to an appropriate degree upon re-entry. Composite overwrapped aluminum lined propellant tanks with aluminum propellant management devices (PMD) were shown by analyses to demise and thus became the baseline configuration for GPM. As part of the GPM tank development effort, long term compatibility and wettability testing with hydrazine was performed on Al6061 and 2219 coupons fabricated and cleaned by conventional processes. Long term compatibility was confirmed. However, the wettability of the aluminum as measured by contact angle produced higher than desired angles (greater than 30 deg.) with excessive scatter. The availability of PMD materials exhibiting consistently low contact angles aids in the design of simple PMDs. Two efforts performed by Angeles Crest Engineering and funded by GSFC were undertaken to reduce the risk of using aluminum for the GPM PMD. The goal of the first effort was to develop a cleaning or treatment process to produce consistently low contact angles. The goal of the second effort was to prove via testing that the processed aluminum would retain compatibility with hydrazine and retain low contact angle after long term exposure to hydrazine. Both goals were achieved. This paper describes both efforts and the results achieved.

Moore, N. R.↗
NASA NTRS2006

Determination of Silicon in Hydrazine

Inductively coupled plasma-mass spectrometry (ICP-MS) is a highly sensitive technique sometimes used for the trace determination of silicon at a mass-to-charge (m/z) ratio of 28, the most abundant natural isotope of silicon. Unfortunately, ICP-MS is unable to differentiate between other sources of m/z 28 and false positive results for silicon will result when other sources of m/z 28 are present. Nitrogen was a major source of m/z 28 and contributes to the m/z 28 signal when hydrazine sample or nitric acid preservative is introduced into the plasma. Accordingly, this work was performed to develop a sample preparation step coupled with an ICP-MS analysis that minimized non-silicon sources of m/z 28. In the preparatory step of this method, the hydrazine sample was first decomposed predominately to nitrogen gas and water with copper-catalyzed hydrogen peroxide. In the analysis step, ICP-MS was used without nitric acid preservative in samples or standards. Glass, a potential source of silicon contamination, was also avoided where possible. The method was sensitive, accurate, and reliable for the determination of silicon in monopropellant grade hydrazine (MPH) in AF-E-332 elastomer leaching tests. Results for silicon in MPH were comparable to those reported in the literature for other studies.

McClure, Mark B.↗