Fluorinated interphase enables reversible aqueous zinc battery chemistries
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99 GENERAL AND MISCELLANEOUS↗
SEARCH · Engineering Papers
Results for “Growth efficiency”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Highly supercooled riming and unusual triple-frequency radar signatures over McMurdo Station, Antarctica
Abstract. Riming of ice crystals by supercooled water droplets is an efficient ice growth process, but its basic properties are still poorly known. While it has been shown to contribute significantly to surface precipitation at mid-latitudes, little is known about its occurrence at high latitudes. In Antarctica, two competing effects can influence the occurrence of riming: (i) the scarcity of supercooled liquid water clouds due to the extremely low tropospheric temperatures and (ii) the low aerosol concentration, which may lead to the formation of fewer and larger supercooled drops potentially resulting in an enhanced riming efficiency. In this work, by exploiting the deployment of an unprecedented number of multiwavelength remote sensing systems (including triple-frequency radar measurements) in West Antarctica, during the Atmospheric Radiation Measurements West Antarctic Radiation Experiment (AWARE) field campaign, we evaluate the riming incidence at McMurdo Station and find that riming occurs at much lower temperatures when compared to previous results in the mid-latitudes. This suggests the possible occurrence of a common atmospheric state over Antarctica that includes a rather stable atmosphere inhibiting turbulent mixing, and a high riming efficiency driven by large cloud droplets. We then focus on a peculiar case study featuring a persistent layer with a particularly pronounced riming signature in triple-frequency radar data but only a relatively modest amount of supercooled liquid water. In-depth analysis of the radar observations suggests that such signatures can only be explained by the combined effects of moderately rimed aggregates or similarly shaped florid polycrystals and a narrow particle size distribution (PSD). Simulations of this case study performed with a one-dimensional bin model indicate that similar triple-frequency radar observations can be reproduced when narrow PSDs are simulated. Such narrow PSDs can in turn be explained by two key factors: (i) the presence of a shallow homogeneous droplet or humidified aerosol freezing layer aloft seeding an underlying supercooled liquid layer, and (ii) the absence of turbulent mixing throughout a stable polar atmosphere that sustains narrow PSDs, as hydrometeors grow from the nucleation region aloft to ice particles of several millimeters in size, by vapor deposition and then riming.
54 ENVIRONMENTAL SCIENCES↗
Polymer Composite Material Testing for a Cryotank Application
Composite cryotanks will play a key role in enabling the next generation of efficient aircraft. Carbon fiber reinforced polymer (CFRP) composites have the benefits of reduced weight and potentially higher structural strength compared to traditional metallic fuel tanks. A material screening study was conducted to inform material selection for liquid hydrogen (LH2) fuel storage. Three composite materials were considered because of their aerospace grade toughness, strength, and existing data to compare against. These materials were a thermoplastic low-melt polyaryletherketone (LM-PAEK)/carbon fiber (CF), thermoset/CF, and hybrid thermoset/thermoplastic polyurethane (TPU) veil/CF composite. Mechanical screening tests included tension, compression, in-plane shear (IPS), and tensile-tensile fatigue (TTF). Each material was tested at both a baseline (no liquid nitrogen/LN2 cycling) and 100 LN2-cycled conditions to determine the knockdown factor, if any, of each material when exposed to environmental loading effects in a cryotank. Results show minimal effects of the LN2-cycling compared against baseline values. The three materials behaved similarly in tension; however, the thermoplastic/CF had the highest IPS toughness. The hybrid thermoset/TPU/CF composite had the lowest IPS strength, compressive strength, and toughness. LN2-cycling had minimal effects on tensile-tensile fatigue performance of the thermoplastic/CF material. Mechanical data was captured to guide material down selection for future commercially viable hydrogen aircraft design. In its current state, there does not exist a consolidated, publicly available database for CFRP composite material performance data at cryogenic temperatures. The next step in this work is to test the thermoplastic and thermoset CFRP composites, as well as the neat resins, at LH2 relevant temperature (20 K) to capture this crucial material property data. These results are essential to inform cryotank design and modeling efforts. The process to start this next round of testing has begun. Planned mechanical tests include toughness (single-edge notched beam), tension (unidirectional and quasi-isotropic), thermal expansion, and thermal conductivity. Some tests will also be conducted at an intermediate temperature of 111 K relevant to liquid natural gas (LNG), another attractive fuel choice. The ultimate goal is to manufacture a sub-scale cryotank part that can pass relevant burst, fatigue, permeation, and thermal cycling tests. This work is a part of NASA’s Commercially viable Hydrogen Aircraft for Robust Growth in Efficiency (CHARGE) Project under the larger NASA Subsonic Vehicle Technologies and Tools (SVTT) Project.
composites↗
Automated Image Segmentation and Processing Pipeline Applied to X–Ray Computed Tomography Studies of Pitting Corrosion in Aluminum Wires
Understanding pitting corrosion is critical, yet its kinetics and morphology remain challenging to study from X-ray computed tomography (XCT) due to manual segmentation barriers. To address this, an automated pipeline leveraging deep learning for efficient large-scale XCT analysis is developed, revealing new corrosion insights. The pipeline enables pit segmentation, 3D reconstruction, statistical characterization, and a topological transformation for visualization. Here, the pipeline is applied to 87 648 XCT images capturing commercial purity aluminum (1100 Al) wire exposed to sodium chloride (NaCl) salt particles over a period of 122 h. The pipeline achieves complete feature extraction and statistical quantification across the entire XCT dataset, leveraging distributed computing environment for high efficiency. Global growth kinetics such as high-level stepwise sigmoidal volume loss patterns and granular individual pit developments are both captured for 36 detected pits. By combining automation, computer vision, and extensive XCT datasets, this research accelerates precise corrosion assessment to enable materials science discoveries at scale.
36 MATERIALS SCIENCE↗
Integrating Emerging Polymer Chemistries for the Advancement of Recyclable, Biodegradable, and Biocompatible Electronics
Abstract Through advances in molecular design, understanding of processing parameters, and development of non‐traditional device fabrication techniques, the field of wearable and implantable skin‐inspired devices is rapidly growing interest in the consumer market. Like previous technological advances, economic growth and efficiency is anticipated, as these devices will enable an augmented level of interaction between humans and the environment. However, the parallel growing electronic waste that is yet to be addressed has already left an adverse impact on the environment and human health. Looking forward, it is imperative to develop both human‐ and environmentally‐friendly electronics, which are contingent on emerging recyclable, biodegradable, and biocompatible polymer technologies. This review provides definitions for recyclable, biodegradable, and biocompatible polymers based on reported literature, an overview of the analytical techniques used to characterize mechanical and chemical property changes, and standard policies for real‐life applications. Then, various strategies in designing the next‐generation of polymers to be recyclable, biodegradable, or biocompatible with enhanced functionalities relative to traditional or commercial polymers are discussed. Finally, electronics that exhibit an element of recyclability, biodegradability, or biocompatibility with new molecular design are highlighted with the anticipation of integrating emerging polymer chemistries into future electronic devices.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Carbon source-induced changes in the transcriptional landscape of Novacetimonas hansenii
Novacetimonas hansenii is a model organism for bacterial cellulose (BC) production, a biopolymer with broad industrial applications. To better understand its carbon source-dependent metabolism, we conducted the first time-resolved transcriptomic analysis of N. hansenii ATCC 23769 grown on five carbon sources (glucose, fructose, mannitol, galactose, and sucrose) across five time points (24–120h). Glucose, fructose, and mannitol supported growth and efficient BC production, whereas galactose and sucrose resulted in poor yields, likely due to limited transport and enzymatic capacity. Solid-state NMR revealed that cellulose crystallinity and polymorphism were carbon source-dependent, with reduced bcsD expression correlating with lower crystallinity. Transcriptomic profiling showed distinct metabolic responses. Cultures containing glucose and mannitol activated core metabolic pathways, fructose induced a delayed adaptive shift, and galactose and sucrose triggered stress-related gene expression. These results highlight the metabolic plasticity of N. hansenii and offer insights for enhancing BC production through carbon source optomization.
Bacterial cellulose↗
Graupel Precipitating From Thin Arctic Clouds With Liquid Water Paths Less Than 50 g m -2
Rimed precipitation growth can efficiently remove moisture and aerosols from the boundary layer, yet thin low-level Arctic mixed-phase clouds are generally thought to precipitate pristine and aggregated ice crystals. Here we present automated surface photographic measurements showing that only 34% of precipitation particles exhibit negligible riming and that graupel particles ≥ in diameter commonly fall from clouds with liquid water paths less than 50 g m -2 . Analyses indicate that significant riming enhancement can occur provided sustained updrafts of 0.4 m s -1 , consistent with those measured in Arctic clouds. A Lagrangian numerical simulation that tracks falling particles suggests that similar updraft speeds can account for about one half of the observed riming enhancement. Riming enhancement appears particularly likely when weak temperature inversions are observed at cloud top, but a full explanation remains to be determined.
54 ENVIRONMENTAL SCIENCES↗
Universal and versatile morphology engineering via hot fluorous solvent soaking for organic bulk heterojunction
After explosive growth of efficiency in organic solar cells (OSCs), achieving ideal morphology of bulk heterojunction remains crucial and challenging for advancing OSCs into consumer market. Herein, by utilizing the amphiphobic nature and temperature-dependent miscibility of fluorous solvent, hot fluorous solvent soaking method is developed to optimize the morphology with various donor/acceptor combinations including polymer/small-molecule, all-polymer and all-small-molecule systems. By immersing blend film into hot fluorous solvent which is utilized as liquid medium with better thermal conductivity, the molecular reorganization is accelerated. Furthermore, fluorous solvent can be miscible with the residue of chloroform and chloronaphthalene above upper critical solution temperature. This mixed solvent diffuses around inside the active layer and selectively promotes molecular reorganization, leading to optimized morphology. Compared to widely-used thermal annealing, this approach processed under mild conditions achieves superior photovoltaic performance, indicating the practicality and universality for morphological optimization in OSCs as well as other optoelectronic devices.
14 SOLAR ENERGY↗
Predictions of rhizosphere microbiome dynamics with a genome-informed and trait-based energy budget model
Abstract Soil microbiomes are highly diverse, and to improve their representation in biogeochemical models, microbial genome data can be leveraged to infer key functional traits. By integrating genome-inferred traits into a theory-based hierarchical framework, emergent behaviour arising from interactions of individual traits can be predicted. Here we combine theory-driven predictions of substrate uptake kinetics with a genome-informed trait-based dynamic energy budget model to predict emergent life-history traits and trade-offs in soil bacteria. When applied to a plant microbiome system, the model accurately predicted distinct substrate-acquisition strategies that aligned with observations, uncovering resource-dependent trade-offs between microbial growth rate and efficiency. For instance, inherently slower-growing microorganisms, favoured by organic acid exudation at later plant growth stages, exhibited enhanced carbon use efficiency (yield) without sacrificing growth rate (power). This insight has implications for retaining plant root-derived carbon in soils and highlights the power of data-driven, trait-based approaches for improving microbial representation in biogeochemical models.
59 BASIC BIOLOGICAL SCIENCES↗
Advanced Building Construction (ABC) Research Opportunities Report: Industrializing Construction to Decarbonize Buildings
The DOE Building Technologies Office generally seeks to develop, demonstrate, and accelerate the adoption of cost-effective technologies, techniques, and tools in support of an equitable transition to a decarbonized building stock and energy system by 2050. This ABC Innovations Roadmap specifically focuses on and prioritizes innovations that support the industrialization of whole building retrofits and rapid growth of efficient new construction. The content relates to the integration of technologies and industrialization of processes associated with building construction and renovation. The ABC Innovations Roadmap cross-applies innovations in both the new and existing building sectors with a focus on widescale applicability. Installation flexibility is key to commoditizing solutions that are applicable for a wide variety of buildings (e.g., different building types, vintages, architectural details, and system configurations) and to help simplify decarbonization processes for the workforce.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
A high capacity satellite switched TDMA microwave switch matrix
A description is given of the conceptual design of a high-capacity satellite switched-time division multiple access (SS-TDMA) microwave switch matrix fabricated with GaAs monolithic microwave integrated circuits (MMICs), including integration of both microwave and control logic circuits into the monolithic design. The technology required for a 30/20 GHz communications system includes an on-board SS-TDMA switch matrix. A conceptual design study that has been completed for a wideband, high-capacity (typically 100 x 100) channel switch matrix using technology anticipated for 1987 is described, noting that the study resulted in a switch matrix design concept using a coupled crossbar architecture implemented with MMIC. The design involves basic building block MMIC, permitting flexible growth and efficient wraparound redundancy to increase reliability.
Cory, B. J.↗
Acid droplet generation in SRM exhaust clouds
A free energy analysis is applied to the co-condensation/evaporation of H2O and HCl vapors on wettable particles in open air in order to model droplet nucleation in solid rocket motor (SRM) exhaust clouds. Formulations are defined for the free energy change, the drop radius, the saturation ratio, the total number of molecules, and the mean molecular radius in solution, as well as the molecular volume and the concentration range. The free energy release in the phase transition for the AL2O3 nuclei in the SRM exhaust is examined as a function of the HCl molefraction and nucleating particle radius, based on Titan III launch exhaust cloud conditions 90 sec after ignition. The most efficient droplet growth is determined to occur at an HCl molefraction of 0.082 and a particle radius of 0.0000013 cm, i.e. a molality of 5.355.
Dingle, A. N.↗
Guidelines and Parameter Selection for the Simulation of Progressive Delamination
Turon s methodology for determining optimal analysis parameters for the simulation of progressive delamination is reviewed. Recommended procedures for determining analysis parameters for efficient delamination growth predictions using the Abaqus/Standard cohesive element and relatively coarse meshes are provided for single and mixed-mode loading. The Abaqus cohesive element, COH3D8, and a user-defined cohesive element are used to develop finite element models of the double cantilever beam specimen, the end-notched flexure specimen, and the mixed-mode bending specimen to simulate progressive delamination growth in Mode I, Mode II, and mixed-mode fracture, respectively. The predicted responses are compared with their analytical solutions. The results show that for single-mode fracture, the predicted responses obtained with the Abaqus cohesive element correlate well with the analytical solutions. For mixed-mode fracture, it was found that the response predicted using COH3D8 elements depends on the damage evolution criterion that is used. The energy-based criterion overpredicts the peak loads and load-deflection response. The results predicted using a tabulated form of the BK criterion correlate well with the analytical solution and with the results predicted with the user-written element.
Song, Kyongchan↗
A Composite Analysis of Snowfall Modes from Four Winter Seasons in Marquette, Michigan
Presented are four winter seasons of data from an enhanced precipitation instrument suite based at the National Weather Service (NWS) Office in Marquette (MQT), Michigan (250–500 cm of annual snow accumulation). In 2014 the site was augmented with a Micro Rain Radar (MRR) and a Precipitation Imaging Package (PIP). MRR observations are utilized to partition large-scale synoptically driven (deep)and surface-forced (shallow) snow events. Coincident PIP and NWS MQT meteorological surface observations illustrate different characteristics with respect to snow event category. Shallow snow events are often extremely shallow, with MRR-indicated precipitation heights of less than 1500 m above ground level. Large vertical reflectivity gradients indicate efficient particle growth, and increased boundary layer turbulence inferred from observations of spectral width implies increased aggregation in shallow snow events. Shallow snow events occur 2 times as often as deep events; however, both categories contribute approximately equally to estimated annual accumulation. PIP measurements reveal distinct regime-dependent snow microphysical differences, with shallow snow events having broader particle size distributions and comparatively fewer small particles and deep snow events having narrower particle size distributions and comparatively more small particles. In addition, coincident surface meteorological measurements indicate that most shallow snow events are associated with surface winds originating from the northwest (over Lake Superior), cold temperatures, and relatively high surface pressures, which are characteristics that are consistent with cold-air outbreaks. Deep snow events have meteorologically distinct conditions that are accordant with midlatitude cyclones and frontal structures, with mostly southwest surface winds, warmer temperatures approaching freezing, and lower surface pressures.
Claire Pettersen↗
Argentina Food Security & Agriculture: Crop Monitoring and Forecasting for Argentina using NASA Satellite Observations
Early harvest information helps guide agricultural commodity assessments in Argentina, providing valuable planning information to identify potentially food-insecure regions, anticipate transportation and storage demands, predict price fluctuations, and project commodity trends. However, crop yield estimates are currently subjective, based on interviews with qualified informants (i.e., farmers, agribusiness actors). In partnership with the Buenos Aires Grain Exchange, we leveraged Terra Moderate Resolution Imaging Spectroradiometer (MODIS), Soil Moisture Active Passive (SMAP), and Integrated Multi-satellitE Retrievals for Global Precipitation Measurement (GPM IMERG) NASA Earth observations to develop a Google Earth Engine (GEE) toolset to monitor vegetation growth. The first component of the toolset produces spatial and temporal maps of temperature, precipitation, soil moisture, and the Normalized Difference Vegetation Index (NDVI), allowing users to visualize the influence of the region’s climate and weather. Next, we developed an autoregressive model to predict NDVI several months in advance. Lastly, we created a linear regression model of crop yield and NDVI for soybeans, corn, and wheat, and input the forecasted NDVI to generate a predicted crop yield output. The NDVI forecasting model produced accurate predictions at two, four, and six months when examining the most recent growing season. In the crop yield model, soybeans exhibited moderately strong correlation, wheat had consistent weak correlation, and corn varied from weak to strong correlation depending on zone. This information is vital for vegetation growth monitoring by identifying areas of high growth and allocating resources to areas of lower growth to efficiently maximize crop yields.
DEVELOP Tech Paper↗
Stress and efficiency studies in edge-defined film-fed growth
The progress was reviewed for stress and efficiency studies of edge-defined film-fed growth (EFG) material. Effort was concentrated on the definition of condiitions that will reduce stress, on quantifying dislocation electrical activity and limits on solar cell efficiency, and on studying the effects of dopants on EFG characteristics.
Kalejs, J.↗
Size-related decline in dryland shrubs is related to reductions in hydraulic efficiency and carbon assimilation and not nonstructural carbohydrate depletion
Plant growth and survival are fundamentally constrained by water transport from roots to leaves, impacting carbon assimilation and associated labile carbon pools. However, physiological constraints on growth and survival vary with plant age, due to changes in metabolic sinks, and increases in hydraulic path length from rhizosphere to canopy. We investigated crown dieback, growth, hydraulics, carbon assimilation and carbohydrate storage in relation to increasing basal diameter of two dominant shrub species (Caragana korshinskii and Artemisia ordosica) at the southeastern edge of the Tengger Desert, China. The aim was to identify mechanisms of decreased performance with plant size in dryland shrubs. Clear contrasts in stomatal regulation of leaf water potentials were detected between species. Despite these contrasts, radial growth, hydraulic transport efficiency (Ks), and photosynthetic efficiency similarly declined in both species with increasing plant size, while non-structural carbohydrate (NSC) reserves remained unchanged. Xylem embolism (PLC) increased with plant size, resulting in significant reductions in carbon assimilation in both species. Results indicate that hydraulic, and potentially carbon assimilation constraints, rather than reductions in carbohydrate storage, govern growth-related dryland shrub decline. These findings improve our understanding of how population demography impacts dryland forest response to climate change.
Zhang, Hongxia↗
Proceedings of the Flat-Plate Solar Array Project Workshop on Crystal Gowth for High-Efficiency Silicon Solar Cells
A Workshop on Crystal Growth for High-Efficiency Silicon Solar Cells was held December 3 and 4, 1984, in San Diego, California. The Workshop offered a day and a half of technical presentations and discussions and an afternoon session that involved a panel discussion and general discussion of areas of research that are necessary to the development of materials for high-efficiency solar cells. Topics included the theoretical and experimental aspects of growing high-quality silicon crystals, the effects of growth-process-related defects on photovoltaic devices, and the suitability of various growth technologies as cost-effective processes. Fifteen invited papers were presented, with a discussion period following each presentation. The meeting was organized by the Flat-Plate Solar Array Project of the Jet Propulsion Laboratory. These Proceedings are a record of the presentations and discussions, edited for clarity and continuity.
Dumas, K. A.↗