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At least 73 records · Page 4

From Fossil Fuels to Green Mines: Understanding Hydrogen-Shale Interactions for Secure Underground Storage

Hydrogen-powered mining trucks are rapidly gaining traction as a key driver of decarbonization in the mining industry. This surge necessitates a decisive shift towards renewable energy sources, primarily for hydrogen production. However, the inherent intermittency of renewables poses a challenge for continuous operations, demanding efficient storage solutions for hydrogen fuel. Hydrogen, derived from renewables, requires large-scale storage, with underground hydrogen storage (UHS) in depleted oil and gas reservoirs projected to provide this capacity. An impermeable seal (caprock) overlying depleted reservoirs is crucial for preventing leakage and ensuring secure storage. Shale, a potential caprock, has been recognized for its effectiveness in containing natural gas for geological time-periods. This study investigates the impact of hydrogen exposure on the matrix permeability of Marcellus shale, a key factor influencing its sealing capacity. A novel time-resolved approach was employed, measuring matrix permeability after each exposure to understand the dynamic interactions between hydrogen and the shale matrix. Samples were exposed to hydrogen in pressure reactions at realistic reservoir conditions at varying time durations. Preliminary results reveal an initial increase in permeability, while subsequent exposures show a decrease, indicating potential microstructural changes.

08 HYDROGEN↗

Fossil Fuel Transitions Framework: Case studies of the decision-making process for energy and economic development pathways

The Net Zero World Initiative leverages expertise across U.S. government agencies and the U.S. Department of Energy’s (DOE) national laboratories, in partnership with other governments and philanthropies, to accelerate the decarbonization of global energy systems. This whole-of-government approach supports countries committed to raising their climate ambitions by co-creating and implementing highly tailored, actionable technical and investment strategies that put just and sustainable net-zero solutions within reach. The Net Zero World Initiative enables country partners to harness the convening power and technical expertise of U.S. and international industry, think tanks, and technical institutions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

The position of gas turbine power plants with respect to the emission of nitrogen oxides by fossil-fueled energy installations

The amount of nitrogen oxides introduced into the atmosphere by gas turbines is very significant in relation to the total amount of nitrogen oxide emissions produced by chemical installations and combustion engines. Turbine manufacturers are therefore working to develop combustion chambers with sufficiently low nitrogen oxide emission concentrations. Attention is given to aspects of nitrogen oxide formation in gas turbines, the parameters which determine this formation, and suitable approaches to reducing nitrogen oxide emissions.

Kaiser, E.↗

Study of Systems and Technology for Liquid Hydrogen Production Independent of Fossil Fuels

Based on Kennedy Space Center siting and logistics requirements and the nonfossil energy resources at the Center, a number of applicable technologies and system candidates for hydrogen production were identified and characterized. A two stage screening of these technologies in the light of specific criteria identified two leading candidates as nonfossil system approaches. Conceptual design and costing of two solar-operated, stand alone systems, one photovoltaic based on and the other involving the power tower approach reveals their technical feasibility as sited as KSC, and the potential for product cost competitiveness with conventional supply approaches in the 1990 to 1210 time period. Conventional water hydrolysis and hydrogen liquefaction subsystems are integrated with the solar subsystems.

Sprafka, R. J.↗

Fossil fuel and biomass burning effect on climate - Heating or cooling?

The basic theory of the effect of pollution on cloud microphysics and its global implications is applied to compare the relative effect of a small increase in the consumption rate of oil, coal, or biomass burning on cooling and heating of the atmosphere. The characteristics of and evidence for the SO2 induced cooling effect are reviewed. This perturbation analysis approach permits linearization, therefore simplifying the analysis and reducing the number of uncertain parameters. For biomass burning the analysis is restricted to burning associated with deforestation. Predictions of the effect of an increase in oil or coal burning show that within the present conditions the cooling effect from oil and coal burning may range from 0.4 to 8 times the heating effect.

Kaufman, Yoram J.↗

Global Studies of the Sulfur Cycle Including the Influence of DMS and Fossil Fuel Sulfur on Climate and Climate Change

The indirect effect of anthropogenic aerosols, wherein aerosol particles are thought to increase cloud droplet concentrations and cloud lifetime, is the most uncertain component of climate forcing over the past 100 years. Here, for the first time, we use a mechanistic treatment of droplet nucleation and a prognostic treatment of the number of cloud droplets to study the indirect aerosol effect from changes in carbonaceous and sulfate aerosols. Cloud droplet nucleation is parameterized as a function of total aerosol number concentration, updraft velocity and a shape parameter, which takes into account the mechanism, of sulfate aerosol formation, while cloud droplet number depends on the nucleation as well as on droplet sinks. Whereas previous treatments have predicted annual average indirect effects between -1 and -2 W/sq m, we obtain an indirect aerosol effect between -0.14 W/sq m and -0.42 W/sq m in the global mean.

Penner, Joyce E.↗

Coupling of the Electricity and Transportation Sectors - Part I: Sector Overviews

“Sector coupling” is a concept that addresses potential designs for the future power industry. Traditionally, the energy sectors, i.e., electricity supply, transport, and industry, have functioned largely independently from one another. Thus, the concept of sector coupling means that the electricity sector would become the central pillar of the energy system, supplying the other sectors – transportation and industry – with energy in various ways, a scheme described by the term “Power-to-X”. This report delves into the ambitious goal set by the United States to achieve net-zero emissions by 2050, with a pivotal milestone of making half of all passenger vehicles sold in America zero-emission by 2030. Central to achieving this objective is the electrification of the transportation sector, resulting in complex interactions between this sector and the electric industry. As electric vehicles become more prevalent, a shift in the dependency on electricity for vehicle charging emerges, alongside a reduction in the electricity demand associated with maintaining the fossil fuel supply chain. Both the electricity and fossil fuel have been identified as critical infrastructure sectors, the transportation sector's historical reliance on fossil fuels, and the mature supply chain supporting them are explored. This study emphasizes the existing sectoral coupling between the electric energy and transportation sectors, extending beyond vehicle charging to essential operations at refineries, pipeline facilities, storage, and fuel extraction. Recognizing the critical dependency of fossil fuel supply chain operations on the electric sector, this research underscores the need for a comprehensive view of the evolving dynamics between the transportation and electric sectors. This study has been split into two segments, Part-I provides an overview of the existing fossil fuel supply chain architecture and the electrical sector. We provide an in-depth analysis of the grid-transportation sectoral coupling, its interactions, the vulnerabilities and essential take-aways that would help us to address them and apply towards an electrified transportation sector in the future. We engaged with stakeholders to understand their expectations in enabling an electrified transportation. We accumulate the understandings from the current fossil fuel-based system in developing a risk matrix, by identifying all the threats and vulnerabilities and how would they apply to both the current and future transportation systems in Part-II of this report.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Four-Stage Multi-Physics Simulations to Assist Temperature Sensor Design for Industrial-Scale Coal-Fired Boiler

The growth of renewable energy sources presents a pressing challenge to the operation and maintenance of existing fossil fuel power plants, given that fossil fuel remains the predominant fuel source, responsible for over 60% of electricity generation in the United States. One of the main concerns within these fossil fuel power plants is the unpredictable failure of boiler tubes, resulting in emergency maintenance with significant economic and societal consequences. A reliable high-temperature sensor is necessary for in situ monitoring of boiler tubes and the safety of fossil fuel power plants. In this study, a comprehensive four-stage multi-physics computational framework is developed to assist the design, optimization installation, and operation of the high-temperature stainless-steel and quartz coaxial cable sensor (SSQ-CCS) for coal-fired boiler applications. With the consideration of various operation conditions, we predict the distributions of flue gas temperatures within coal-fired boilers, the temperature correlation between the boiler tube and SSQ-CCS, and the safety of SSQ-CCS. With the simulation-guided sensor installation plan, the newly designed SSQ-CCSs have been employed for field testing for more than 430 days. The computational framework developed in this work can guide the future operation of coal-fired plants and other power plants for the safety prediction of boiler operations.

42 ENGINEERING↗

Investigation of O( 3 P) Initiated Oxidation Products of 2,3-Dimethylfuran Using Synchrotron Photoionization

Biofuels are an appealing alternative to augment conventional fossil fuels, given that traditional fossil fuels are finite in nature despite being the highest-consumed energy source. Furans have been studied as potential biofuels due to their renewability, high energy density, and ability to both blend with existing fossil fuels and serve as a stand-alone fuel. Although promising, more research efforts on the combustion of furan-based biofuels are needed. Here, in this study, the oxidation of 2,3-dimethylfuran (2,3-DMF) initiated by O( 3 P) was investigated using vacuum-ultraviolet synchrotron radiation from the Advanced Light Source at the Lawrence Berkeley National Laboratory. The reaction was studied at 550 K and 7 Torr. Major reaction products include 3-methyl-3-buten-2-one, 4,5-dimethyl-3(2H)-furanone, and 3-methyl-4-oxo-2(Z)-pentenal, with 3-methyl-3-buten-2-one being the most abundant.

CBS-QB3↗

Intergenerational equity and conservation

The issue of integenerational equity in the use of natural resources is discussed in the context of coal mining conversion. An attempt to determine if there is a clear-cut benefit to future generations in setting minimum coal extraction efficiency standards in mining is made. It is demonstrated that preserving fossil fuels beyond the economically efficient level is not necessarily beneficial to future generations even in terms of their own preferences. Setting fossil fuel conservation targets for intermediate products (i.e. energy) may increase the quantities of fossil fuels available to future generations and hence lower the costs, but there may be serious disadvantages to future generations as well. The use of relatively inexpensive fossil fuels in this generation may result in more infrastructure development and more knowledge production available to future generations. The value of fossil fuels versus these other endowments in the future depends on many factors which cannot possibly be evaluated at present. Since there is no idea of whether future generations are being helped or harmed, it is recommended that integenerational equity not be used as a factor in setting coal mine extraction efficiency standards, or in establishing requirements.

Otoole, R. P.↗