Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “EMISSION SPECTRA”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Model emission spectra from primeval galaxies

The paper computes models of the UV luminosity produced by a distribution of supernova remnants resulting from a burst of star formation in primeval galaxies at large redshift. The evolution of low metal abundance remnants is described analytically, and their UV emission is found from a velocity grid of radiative shock models. The implications of these results for the detection of line emission from young galaxies and for the diffuse background radiation are discussed.

Shull, J. M.↗
NASA NTRS2006

Visible to Near Infrared Emission Spectra of Electron-Excited H2

The electron-impact induced fluorescence spectrum of H2 at 100 eV from 700 nm to 950 nm at a spectral resolution of between 0.2 nm to 0.3 nm has been measured. The laboratory spectrum has been compared with our theoretical simulated spectrum obtained by calculating the lines emission cross sections from the upper states of g symmetry (EF, GK, HH, P, O ; I, R, J, S ) towards the states of u symmetry (B, C, B', D) of H2. The nine above Born-Openheimer g-upper states have been coupled together as well as the four above Born-Openheimer u-lower states. The comparison seems adequate with few minor discrepancies.

Aguilar, A.↗
DOE OSTI2021

National Opacity Program: Analysis of Opacity-relevant X-ray Emission Spectra (Milestone Report ID 7121)

We have produced high energy density iron plasmas at temperatures above 1 keV and electron densities exceeding 1023 cm -3 (~ 1 g/cm 3 ) using the Orion laser at the Atomic Weapons Establishment. These plasmas were created by irradiating 50 µm diameter layered targets with frequency doubled (λ = 527 nm), 1 ps laser pulses focused to a 100 µm diameter producing an irradiance of ~ 2 x 10 18 W/cm 2 . The buried layer targets consist of 160 nm iron sulfide (FeS), 60 nm potassium chloride (KCl), and 15 nm carbon. The combined layers are tamped on both sides with 3 µm of parylene-N. The x-ray emission from the plasma was measured using two time-resolved, and four time-integrated Bragg crystal spectrometers, as well as one time-integrated imaging system. One time-resolved x-ray spectrometer measured emission from L-shell transitions in highly charged iron, the other from K-shell transitions in helium-like S 14+ and hydrogen-like S 15+ . The time-integrated spectrometers are intensity-calibrated and measured emission from K-shell transitions in sulfur, potassium, chlorine, and both K-shell and L-shell transitions in iron. The density and temperature of the plasma were determined by modeling the x-ray spectra using different spectral and hydrodynamic modeling packages. A brief overview of the uncertainties associated with the measurements and models are presented. We also give an overview of our 1-D HYDRA-DCA radiation-hydrodynamics model and improvements for future work. Our results aid in assessing experimental uncertainties associated with plasma uniformity and with x-ray emission employed as diagnostics in opacity experiments at temperatures and densities not achievable elsewhere and represent a significant step in creating and diagnosing plasmas near LTE. These results are summarized as part of the completion requirements for milestone 7121

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS2000

Thermal Emission Spectra of Phobos, Vesta, Ceres, and Pallas: A Comparison

Ultraviolet, visual, and near-infrared spectra of Phobos, obtained by Mariner 9 and Viking Orbiters, were interpreted to suggest a compositional similarity with carbonaceous chrondrites. Such a composition would be inconsistent with the moon's origin in the proto-Mars region, as Mars is composed chiefly of differentiated silicates. This interpretation was used to suggest that the moons originated in the main-asteroid belt, with subsequent capture and orbital evolution into their current locations. Interpretations of more recent visual and near-infrared spectra, obtained by Phobos-2 and Mars Pathfinder, have demonstrated that the Phobos spectrum is more similar to spectra of other classes of asteroids and lunar soils. If lunar mare soil is the correct analogy, then such a composition suggests a formation of Phobos from materials similar to that on Mars, i.e. basalts, and would not require a dynamically difficult capture and orbital evolution. During the science phasing orbits of the Mars Global Surveyor mission Thermal Emission Spectrometer (TES) observations of Phobos were acquired at each of four encounters. The spectral variability observed for localized surface regions on Phobos has been previously reported and is greatest near the northern wall of Stickney crater. Interpretation of the thermal infrared spectra of airless bodies, based upon most existing laboratory measurements, is complicated by the absence of interstitial gases on the celestial objects that would act to minimize potential thermal gradients in the upper layers of the surface. As an aid to interpretation of the TES Phobos spectra are compared to telescopic and airborne thermal infrared spectra of asteroids from several classes, including Ceres (G), Pallas (B), and Vesta (V). The asteroid spectra provide a direct analogy to the physical situation encountered at the surface of Phobos, albeit different thermal gradients may exist for each surface. This work is supported by NASA RTOP's 344-30-30-01 and 344-34-21-08.

Roush, Ted↗
NASA NTRS1973

Expected gamma-ray emission spectra from the lunar surface as a function of chemical composition

The gamma rays emitted from the moon or any similar body carry information on the chemical composition of the surface layer. The elements most easily measured are K, U, Th and major elements such as O, Si, Mg, and Fe. The expected fluxes of gamma ray lines were calculated for four lunar compositions and one chondritic chemistry from a consideration of the important emission mechanisms: natural radioactivity, inelastic scatter, neutron capture, and induced radioactivity. The models used for cosmic ray interactions were those of Reedy and Arnold and Lingenfelter. The areal resolution of the experiment was calculated to be around 70 to 140 km under the conditions of the Apollo 15 and 16 experiments. Finally, a method was described for recovering the chemical information from the observed scintillation spectra obtained in these experiments.

Reedy, R. C.↗
NASA NTRS1973

Expected gamma ray emission spectra from the lunar surface as a function of chemical composition.

The gamma rays emitted from the moon or any similar body carry information on the chemical composition of the surface layer. The elements most easily measured are K, U, Th, and major elements such as O, Si, Mg, and Fe. The expected fluxes of gamma ray lines are calculated for four lunar compositions and one chondritic chemistry from a consideration of the important emission mechanisms: natural radioactivity, inelastic scatter, neutron capture, and induced radioactivity. The models used for cosmic ray interactions are those of Reedy and Arnold (1972) and Lingenfelter et al. (1972). The areal resolution of the experiment is calculated to be around 70-140 km under the conditions of the Apollo 15 and 16 experiments. Finally, a method is described for recovering the chemical information from the observed scintillation spectra obtained in these experiments.

Reedy, R. C.↗
NASA NTRS1975

Infrared emission spectra of elastohydrodynamic contacts

A small diamond disk mounted as a window in a steel plate was covered with test fluid, and a weighted steel ball was rotated over the window so as to form a sliding elastohydrodynamic (EHD) contact region. Some of the radiant energy generated in this region, both in the fluid and at the boundaries, passed through the window into an infrared interferometer, giving rise to an emission spectrum. This spectrum could be separated into contributions from the fluid and from the ball surface, making it possible, by appropriate calibrations, to estimate their temperatures separately under operating conditions. Moreover, the shape of the discrete spectral bands of the fluid permitted some inferences on its state. Two fluids were studied under identical mechanical conditions, a polyester and a naphthenic oil, each containing an equal amount of polymethylstyrene as a spectral indicator. Differences of band intensity, band width, and frequency could, therefore, be attributed to differences in the behavior of the base fluid.

Lauer, J. L.↗
NASA NTRS1992

Emission spectra of selected SSME elements and materials

Stennis Space Center (SSC) is pursuing the advancement of experimental techniques and theoretical developments in the field of plume spectroscopy for application to rocket development testing programs and engine health monitoring. Exhaust plume spectral data for the Space Shuttle Main Engine (SSME) are routinely acquired. The usefulness of this data depends upon qualitative and quantitative interpretation of spectral features and their correlation with the engine performance. A knowledge of the emission spectral characteristics of effluent materials in the exhaust plume is essential. A study of SSME critical components and their materials identified 30 elements and 53 materials whose engine exhaust plume spectral might be required. The most important were evaluated using SSC's Diagnostic Testbed Facility Thruster (DTFT), a 1200-lbf, liquid oxygen/gaseous hydrogen rocket engine which very nearly replicates the temperature and pressure conditions of the SSME exhaust plume in the first Mach diamond. This report presents the spectral data for the 10 most important elements and 27 most important materials which are strongly to moderately emitting in the DTFT exhaust plume. The covered spectral range is 300 to 426 nm and the spectral resolution is 0.25 nm. Spectral line identification information is provided and line interference effects are considered.

Tejwani, Gopal D.↗
NASA NTRS2022

Mapping Phyllosilicates on the Asteroid Bennu Using Thermal Emission Spectra and Machine Learning Model Applications

Bennu, the target of the OSIRIS-REx mission, is an asteroid with compositions analogous to low petrologic type CI, CM, CR, and/or ungrouped carbonaceous chondrites. Asteroids like Bennu provide information about the building blocks of the early Solar System. Analysis of the mid-infrared remote sensing data informs mineral quantification. We apply a phyllosilicate specific model, developed by Breitenfeld et al. (2021) that distinguishes between Mg and Fe serpentines, to Baseball Diamond 1 (BBD1), Equatorial Station 3 (EQ3), and Touch-And-Go OSIRIS-REx Thermal Emission Spectrometer data. The average total phyllosilicate predictions are 73 (BBD1) and 72 vol% (EQ3). We observe higher Fe-cronstedtite and lower Mg-rich serpentine content in the equatorial region of Bennu than average. Mid-infrared spectral variability may be explained by sorting effects through mass movement.

Bennu↗
NASA NTRS2003

Package for Interactive Analysis of Line Emission (Analysis of UV-X-Ray High-Resolution Emission Spectra)

PINTofALE is an IDL based package to analyze high-resolution grating spectra. The first version was made available to the public on 3 February 2001. Since then we have carried out numerous changes, and the current release is version 1.5, released on 9 October 2002. The changes include upgrades to handle higher versions of IDL, the new version of the CHIANTI database (v4), major enhancements in user-friendliness, improved handling of response matrices, the ability to handle 24-bit color, access to the Atomic Plasma Emission Database (APED), and beta releases of Markov Chain Monte Carlo (MCMC) based DEM fitting routines. Plans for the future include: inclusion of MCMC techniques in the fitting programs, enhanced graphics capabilities, an overhaul of the line and continuum database structure, and bug fixes. In September 2002, we hired a data analyst (LiWei Lin) to work on PINTofALE. Mr.Lin is concentrating on incorporating MCMC as well as simpler Monte-Carlo techniques, fast RMF convolution, etc., into the code base, as well as reviewing the existing documentation and searching for bugs. A detailed description of the package, together with fairly detailed documentation, example walks-throughs, and downloadable tar files, are available on-line from http://hea-www. harvard.edu/PINTofALE/

Kashyap, Vinay↗
NASA NTRS2003

Thermal Emission Spectra of Silica-coated Basalt and Considerations for Martian Surface Mineralogy

Among the most important discoveries made during the Mars Global Surveyor (MGS) mission was that the rocky materials of Mars are broadly divisible into two distinct rock types. The geological significance of this finding is dependent on the mineralogy of these rock types as well as their geographic and stratigraphic positions. Much work has yet to be done to understand these relationships and the small-scale variability of these units. For now, it is worth considering various scenarios that could have resulted in Mars global-scale mineralogical dichotomy. Such work will make clearer what must be looked for in Thermal Emission Spectrometer (TES) and Thermal Imaging Spectrometer (THEMIS) data, what to test with other data sets, and what geological processes can be considered or ruled out as we advance with interpreting Martian geologic history. Here, we suggest that exogenic coatings of secondary silica on basaltic rocks may provide a plausible explanation for the newly discovered distribution of rock types.

Kraft, M. D.↗
NASA NTRS1976

Ion temperatures in HIP-1 and SUMMA from charge-exchange neutral optical emission spectra

Ion temperatures were obtained from observations of the H sub alpha, D sub alpha, and He 587.6 nm lines emitted from hydrogen, deuterium, and helium plasmas in the SUMMA and HIP-1 mirror devices at Lewis Research Center. Steady state discharges were formed by applying a radially inward dc electric field between cylindrical or annular anodes and hollow cathodes located at the peaks of the mirrors. The ion temperatures were found from the Doppler broadening of the charge-exchange components of spectral lines. A statistical method was developed for obtaining scaling relations of ion temperature as a function of current, voltage, and magnetic flux density. Derivations are given that take into account triangular monochromator slit functions, loss cones, and superimposed charge-exchange processes. In addition, the Doppler broadening was found to be sensitive to the influence of drift on charge-exchange cross section. The effects of finite ion-cyclotron radius, cascading, and delayed emission are reviewed.

Patch, R. W.↗
NASA NTRS1993

Near-surface temperature gradients and their effects on thermal-infrared emission spectra of particulate planetary surfaces

The infrared energy emitted from a planetary surface is generated within a finite depth determined by the material's absorption skin depth. This parameter varies significantly with wavelength in the infrared but has an average value of around 50 microns for most geologic materials. In solid rock, heat transfer is efficient enough so that this 50 micron zone of the near surface from which the radiation emanates will be more or less isothermal. In particulate materials, however, heat transfer is more complicated and occurs via a combination of mechanisms, including solid conduction within grains and across grain contacts, conduction through the interstitial gas, and thermal radiation within individual particles and across the void spaces in between grains. On planets with substantial atmospheres, the gas component dominates the heat transfer and tends to mitigate near-surface thermal gradients. However, on airless bodies, the gas component is absent and heat transfer occurs via solid conductions and radiation. If the particles are small relative to the average absorption skin depth, then the top 50-100 microns or so of the surface will be cooled by radiation to space allowing the creation of significant near-surface thermal gradients. In those regions of the spectrum where the absorption coefficient is low, the emission will come from the deeper, warmer parts of the medium, whereas in regions of high absorption, the emission will emanate from shallower, cooler parts of the medium. The resulting emission spectrum will show non-compositional features as a result of the thermal structure in the material. We have modeled the heat transfer in a particulate medium in order to determine the magnitude of near-surface thermal gradients for surfaces on airless bodies and on Mars. We use the calculated thermal structure to determine the effects it has on the infrared emission spectrum of the surface.

Henderson, B. G.↗
DOE OSTI2021

Visible emission spectra of thermographic phosphors under x-ray excitation

Thermographic phosphors have been employed for temperature sensing in challenging environments, such as on surfaces or within solid samples exposed to dynamic heating, because of the high temporal and spatial resolution that can be achieved using this approach. Typically, UV light sources are employed to induce temperature-sensitive spectral responses from the phosphors. However, it would be beneficial to explore x-rays as an alternate excitation source to facilitate simultaneous x-ray imaging of material deformation and temperature of heated samples and to reduce UV absorption within solid samples being investigated. Here, the phosphors BaMgAl 10 O 17 :Eu (BAM), Y 2 SiO 5 :Ce, YAG:Dy, La 2 O 2 S:Eu, ZnGa 2 O 4 :Mn, Mg 3 F 2 GeO 4 :Mn, Gd 2 O 2 S:Tb, and ZnO were excited using incident synchrotron x-ray radiation. These materials were chosen to include conventional thermographic phosphors as well as x-ray scintillators (with crossover between these two categories). X-ray-induced thermographic behavior was explored through the measurement of visible spectral response with varying temperature. The incident x-rays were observed to excite the same electronic energy level transitions in these phosphors as UV excitation. Similar shifts in the spectral response of BAM, Y 2 SiO 5 :Ce, YAG:Dy, La 2 O 2 S:Eu, ZnGa 2 O 4 :Mn, Mg 3 F 2 GeO 4 :Mn, and Gd 2 O 2 S:Tb were observed when compared to their response to UV excitation found in literature. Some phosphors were observed to thermally quench in the temperature ranges tested here, while the response from others did not rise above background noise levels. This may be attributed to the increased probability of non-radiative energy release from these phosphors due to the high energy of the incident x-rays. These results indicate that x-rays can serve as a viable excitation source for phosphor thermometry.

42 ENGINEERING↗
DOE OSTI2022

Development of advanced machine learning models for analysis of plutonium surrogate optical emission spectra

This work investigates and applies machine learning paradigms seldom seen in analytical spectroscopy for quantification of gallium in cerium matrices via processing of laser-plasma spectra. Ensemble regressions, support vector machine regressions, Gaussian kernel regressions, and artificial neural network techniques are trained and tested on cerium-gallium pellet spectra. A thorough hyperparameter optimization experiment is conducted initially to determine the best design features for each model. The optimized models are evaluated for sensitivity and precision using the limit of detection (LoD) and root mean-squared error of prediction (RMSEP) metrics, respectively. Gaussian kernel regression yields the superlative predictive model with an RMSEP of 0.33% and an LoD of 0.015% for quantification of Ga in a Ce matrix. This study concludes that these machine learning methods could yield robust prediction models for rapid quality control analysis of plutonium alloys.

Rao, Ashwin P. (ORCID:0000000319312568)↗
DOE OSTI2022

Typical Neutron Emission Spectra for Multi-Mission Radioisotope Thermoelectric Generator Fuel

The Dragonfly rotorcraft currently being designed by the Johns Hopkins Applied Physics Laboratory (APL) is a mission destined to explore, via autonomous flight, the Saturnian moon of Titan and currently scheduled to launch in 2027. This largest moon of Saturn contains a thick, dense atmosphere, that when coupled with the remote distance to the Sun, requires the use of a radioisotope power system (RPS). The multi-mission radioisotope thermoelectric generator (MMRTG) fueled at Idaho National Laboratory is currently the only flight-certified RPS still in production within the Department of Energy complex, thus, an MMRTG was chosen for the Dragonfly mission.

07 ISOTOPE AND RADIATION SOURCES↗