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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1971

An upper limit on the hardness of the nonthermal electron spectra produced during the flash phase of solar flares.

The observations of impulsive solar-flare X-rays above 10 keV made with OGO-5 satellite have been analyzed in order to study the variation of the nonthermal electron spectrum from one flare to another. The X-ray spectrum at the maxima of 129 impulsive X-ray bursts is represented by KE to the minus-gamma power photons per sq cm per sec per keV, and the frequency of occurrence of bursts with different values of gamma is studied. It is found that for gamma less than 4.0 the frequency of bursts rapidly decreases with the decrease in the value of gamma. The probability of occurrence of a burst with gamma less than 2.3 is extremely small.

Kane, S. R.↗
NASA NTRS2003

High Energy Cosmic Ray Electron Spectra measured from the ATIC Balloon Experiment

The Advanced Thin Ionization Calorimeter Balloon Experiment (ATIC) is specifically designed for high energy cosmic ray ion detection. From simulation and a CERN beam test exposure we find that the design consisting of a graphite target and an energy detection device, a totally active calorimeter of BGO scintillator, gives us sufficient information to distinguish electrons from protons up to the TeV energy range. Balloon observations were successfully carried out over Antarctica in both 2000/2001 and 2002/2003 for a total of more than 35 days. This paper presents preliminary results on the spectrum of high energy electrons observed in the first ATIC flight.

Chang, J.↗
DOE OSTI2022

Electronic spectra with paramagnon fractionalization in the single-band Hubbard model

We examine spectral properties of a recently proposed theory of the intermediate temperature pseudogap metal phase of the cuprates. We show that this theory can be obtained from the familiar paramagnon theory of nearly antiferromagnetic metals by fractionalizing the paramagnon into two “hidden” layers of S = 1 / 2 spins. The first hidden layer of spins hybridizes with the electrons as in a Kondo lattice heavy Fermi liquid, whereas the second hidden layer of spins forms a spin liquid with fractionalized spinon excitations. Here, we compute the imaginary part of the electronic self-energy induced by the spinon excitations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Electronic spectra of 2- and 3-tolunitrile in the gas phase. I. A study of methyl group internal rotation via rovibronically resolved spectroscopy

Rotationally resolved fluorescence excitation spectra of the origin bands in the S{sub 1}←S{sub 0} transition of 2-tolunitrile (2TN) and 3-tolunitrile (3TN) have been recorded in the collision-free environment of a molecular beam. Analyses of these data provide the rotational constants of each molecule and the potential energy curves governing the internal rotation of the attached methyl groups in both electronic states. 2TN exhibits much larger barriers along this coordinate than 3TN. Interestingly, the electronic transition dipole moment in both molecules is markedly influenced by the position of the attached methyl group rather than the position of the cyano group; possible reasons for this intriguing behavior are discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1990

Photophysical behavior of doubly bridged d7-d7 metal-metal bonded compounds - The crystal structure and the excited- and ground-state electronic spectra of Re2(CO)6(dmpm)2 (dmpm = bis/dimethylphosphino/ methane)

Re2(CO)6(dmpm)2 shows photophysical behavior in a rigid medium that differs dramatically from that observed in fluid solution. In a hydrocarbon glass at 77 K, metal-metal bond homolysis is suppressed and an intense phosphorescence is observed. The transient absorption spectrum, which shows only weak transitions to the red of the ground state 1(sigma-sigma asterisk) transition, permits assignment of the emitting state to a 3(sigma-sigma asterisk) transition. The crystal structure of Re2(CO)6(dmpm)2 is also reported. The ground-state electronic structure is discussed relative to the structural data.

Milder, Steven J.↗
DOE OSTI2015

Electronic spectra and excited state dynamics of pentafluorophenol: Effects of low-lying πσ{sup ∗} states

Multiple fluorine atom substitution effect on photophysics of an aromatic chromophore has been investigated using phenol as the reference system. It has been noticed that the discrete vibronic structure of the S{sub 1}←S{sub 0} absorption system of phenol vapor is completely washed out for pentafluorophenol (PFP), and the latter also shows very large Stokes shift in the fluorescence spectrum. For excitations beyond S{sub 1} origin, the emission yield of PFP is reduced sharply with increase in excess vibronic energy. However, in a collisional environment like liquid hydrocarbon, the underlying dynamical process that drives the non-radiative decay is hindered drastically. Electronic structure theory predicts a number of low-lying dark electronic states of πσ{sup ∗} character in the vicinity of the lowest valence ππ{sup ∗} state of this molecule. Tentatively, we have attributed the excitation energy dependent non-radiative decay of the molecule observed only in the gas phase to an interplay between the lowest ππ{sup ∗} and a nearby dissociative πσ{sup ∗} state. Measurements in different liquids reveal that some of the dark excited states light up with appreciable intensity only in protic liquids like methanol and water due to hydrogen bonding between solute and solvents. Electronic structure theory methods indeed predict that for PFP-(H{sub 2}O){sub n} clusters (n = 1-11), intensities of a number of πσ{sup ∗} states are enhanced with increase in cluster size. In contrast with emitting behavior of the molecule in the gas phase and solutions of nonpolar and polar aprotic liquids, the fluorescence is completely switched off in polar protic liquids. This behavior is a chemically significant manifestation of perfluoro effect, because a very opposite effect occurs in the case of unsubstituted phenol for which fluorescence yield undergoes a very large enhancement in protic liquids. Several dynamical mechanisms have been suggested to interpret the observed photophysical behavior.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

The intensity of forbidden torsional transitions in electronic spectra of molecules with a 6-fold barrier: Application to toluenes

Franck-Condon forbidden transitions involving methyl rotor modes are seen in the S{sub 1} ← S{sub 0} spectrum of toluene and toluene-like molecules. The strongest of these rotor transitions (m{sup ″} = 1 → m{sup ′} = 2, m{sup ″} = 0 → m{sup ′} = 3a{sub 1}{sup ″}, and m{sup ″} = 1 → m{sup ′} = 4) have been shown by Walker et al. [J. Chem. Phys. 102, 8718 (1995)] to gain intensity through the rotor equivalent of the Herzberg-Teller mechanism. Despite the m{sup ″} = 0 → m{sup ′} = 3a{sub 2}{sup ″} transition being forbidden in this formalism, it is sporadically observed. We show that this transition derives oscillator strength from incomplete mixing of the −3 and +3 free rotor basis states due to torsion-rotation coupling. Calculations demonstrate that this mechanism quantitatively explains the intensities observed for toluene, including their temperature dependence. Because the −3/+3 mixing is weakest when the torsional barrier height, V{sub 6}, is small, the m{sup ″} = 0 → m{sup ′} = 3a{sub 2}{sup ″} transition increases in intensity as |V{sub 6}| decreases. The temperature and |V{sub 6}| dependencies explain why reports of the 0 → 3a{sub 2}{sup ″} transition have been intermittent. The torsion-rotation coupling mechanism is predicted to also give significant intensity to m = 0 → m = 6a{sub 2}{sup ′} transitions relative to m = 0 → m = 6a{sub 1}{sup ′} transitions and to provide intensity to 0 → 3a{sub 2} transitions in molecules with a 3-fold (V{sub 3}) barrier. Comparison between the observed and calculated rotor band contours shows, unexpectedly, that the 3a{sub 1}{sup ″} constants fail to predict the 3a{sub 2}{sup ″} contour despite these two states being derived from the same free rotor basis states. Comparison with the observed spectrum also reveals differences in the separation of the S{sub 1} 3a{sub 2}{sup ″} and 3a{sub 1}{sup ″} levels. The V{sub 6} value determined from analysis of the high resolution, rotationally resolved m{sup ″} = 0 → m{sup ′} = 3a{sub 1}{sup ″} spectrum overestimates the 3a{sub 2}{sup ″}–3a{sub 1}{sup ″} separation by 0.6 cm{sup −1}. We postulate that this may be due to torsion-vibration coupling. The observed toluene torsion-rotation contours have been modeled to provide estimates of the rotational constants for several of the torsional states.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1979

Energetic particle precipitation into the high-latitude ionosphere and the auroral electrojets. I - Definition of electrojet boundaries using energetic electron spectra and ground-based magnetometer data

Magnetometric data are used to define the poleward and equatorward borders of the eastward electrojet in the evening sector. The relationship between central plasma sheet (cps) and boundary plasma sheet (bps) and the auroral electrojet region is explored. This relationship is used to infer the electric field configuration in the cps and bps regions. It is shown that in the evening sector the cps is threaded by field lines carrying current flowing into the ionosphere, while the bps is threaded by field lines carrying current flowing out of the ionosphere.

Winningham, J. D.↗