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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Energy Storage Grand Challenge - RFI response

Idaho National Laboratory (INL) is operated by Battelle Energy Alliance LLC for the U.S. Department of Energy (DOE). INL conducts research in energy storage (ES) and ancillary fields for several DOE offices including, EERE, NE, FE, and OE. In addition, INL conducts related research for DOD, DHS, state agencies, utilities, and technology developers. INL has developed significant expertise in ES. In July 2020, DOE released the Energy Storage Grand Challenge (ESGC) Roadmap and in conjunction, a Request for Information (RFI) regarding the content of the roadmap. INL is qualified to provide a response to the RFI.

13 HYDRO ENERGY↗

Compilation and Evaluation of Data from Groundwater Impounded within the U12n and U12t Tunnels, Rainier and Aqueduct Mesas, Nevada National Security Site

The Department of Defense (DOD) Defense Threat Reduction Agency (DTRA) and the U.S. Department of Energy (DOE) Office of Environmental Management Nevada Program (EM NV) conducted routine physical and geochemical monitoring of water impounded behind impermeable structures placed within the U12n and U12t tunnels on the Nevada National Security Site (NNSS) (formerly the Nevada Test Site [NTS]). Desert Research Institute (DRI) conducted a semiquantitative evaluation of pressure data to determine the extent to which the tunnels have been inundated and a qualitative evaluation of monitored geochemical parameters to determine if trends exist that were indicative of hydrologic and/or geochemical processes operating behind the tunnel plugs. Data were also evaluated to determine if monitored radiological parameters exceeded primary standards associated with the Environmental Protection Agency’s (EPA) Safe Drinking Water Act (SDWA) (40 C.F.R. § 141.66).

54 ENVIRONMENTAL SCIENCES↗

Long-Duration Energy Storage: Resiliency for Military Installations

This report provides a quantitative techno-economic analysis of a long-duration energy storage (LDES) technology, when coupled to on-base solar photovoltaics (PV), to meet the U.S. Department of Defense's (DoD's) 14-day requirement to sustain critical electric loads during a power outage and significantly reduce an installation's carbon footprint. The LDES modeled is Antora Energy's battery energy storage system (BESS). It is currently at a technology readiness level (TRL) of 7 and not ready for full-scale deployment. To support decisions on the value of near-term demonstrations, this analysis looked at the potential value of Antora Energy's BESS if deployed in the future.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Considerations for Department of Defense Implementation of Zero-Emission Vehicles and Charging Infrastructure

This guide provides a roadmap to comply with Executive Order (EO) 14057 requirements and transition to a zero-emission vehicle (ZEV) fleet efficiently and quickly. EO 14057 on Catalyzing Clean Energy Industries and Jobs Through Federal Sustainability requires the Department of Defense (DoD) to transition its non-tactical vehicles to a 100% ZEV fleet, including 100% of light-duty acquisitions by 2027 and 100% of medium- and heavy-duty acquisitions by 2035. The report covers planning for ZEVs and electric vehicle supply equipment (EVSE), roles and responsibilities of key stakeholders in designing EVSE, and execution issues including acquisition, installation, and ongoing fleet management.

33 ADVANCED PROPULSION SYSTEMS↗

Concentrated Solar Air Conditioning for Buildings Project

This slide presentation reviews project to implement the use of solar power to provide air conditioning for NASA buildings. Included is an overall conceptual schematic, and an diagram of the plumbing and instrumentation for the project. The use of solar power to power air conditioning in buildings, particularly in the Southwest, could save a significant amount of money. DOD studies have concluded that air conditioning accounts for 30-60% of total energy expenditures.

McLaughlin, Rusty↗

Understanding processes that control dust spatial distributions with global climate models and satellite observations

Dust aerosol is important in modulating the climate system at local and global scales, yet its spatiotemporal distributions simulated by global climate models (GCMs) are highly uncertain. In this study, we evaluate the spatiotemporal variations of dust extinction profiles and dust optical depth (DOD) simulated by the Community Earth System Model version 1 (CESM1) and version 2 (CESM2), the Energy Exascale Earth System Model version 1 (E3SMv1), and the Modern-Era Retrospective analysis for Research and Applications version 2 (MERRA-2) against satellite retrievals from Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP), Moderate Resolution Imaging Spectroradiometer (MODIS), and Multi-angle Imaging SpectroRadiometer (MISR). We find that CESM1, CESM2, and E3SMv1 underestimate dust transport to remote regions. E3SMv1 performs better than CESM1 and CESM2 in simulating dust transport and the northern hemispheric DOD due to its higher mass fraction of fine dust. CESM2 performs the worst in the Northern Hemisphere due to its lower dust emission than in the other two models but has a better dust simulation over the Southern Ocean due to the overestimation of dust emission in the Southern Hemisphere. DOD from MERRA-2 agrees well with CALIOP DOD in remote regions due to its higher mass fraction of fine dust and the assimilation of aerosol optical depth. The large disagreements in the dust extinction profiles and DOD among CALIOP, MODIS, and MISR retrievals make the model evaluation of dust spatial distributions challenging. Our study indicates the importance of representing dust emission, dry/wet deposition, and size distribution in GCMs in correctly simulating dust spatiotemporal distributions.

54 ENVIRONMENTAL SCIENCES↗

Bipolar plate flow channel designs for vanadium redox flow battery: a review

Vanadium redox flow battery is one of the preferred systems for grid scale energy storage due to long service life (>20000 cycles), higher efficiency (>85 %), deep discharge capability (>95 % DoD), and inherent scalability and safety. Among system components, flow field is most critical as it governs electrolyte distribution, mass transport and hydraulic performance. Here, this review examines emerging flow channel geometries, highlighting the impact of channel width (0.66 to 1.5 mm), depth (1 to 1.5 mm) and land width (0.5 to 1.5 mm) can reduce pressure drop to <10 kPa while enabling power densities above 600 mW.cm -2 . A key finding is that low channel width to depth ratio (<1) enhances voltage and energy efficiencies by improving under rib convection. The review also provides an overview of progress and perspective in bipolar plate materials, manufacturability, and shunt current mitigation strategies for stack scaling up. Cost analysis emphasizes the influence of flow field designs on the levelized cost of storage and pathways towards the US DOE's $\$$0.05 per kWh energy generation cost target. In addition, opportunities for AI/ML/DT tools assisted design and data driven optimization strategies are also outlined to accelerate next generation flow field development.

Efficiency optimization↗

Sustainability assessment of alternative jet fuel for the U.S. Department of Defense

The United States Department of Defense (DoD) is considering replacing the 2.8 billion gallons of petroleum jet fuel consumed within the continental United States (CONUS) annually with alternative jet fuels to reduce vulnerability to price and supply fluctuations and improve sustainability. We evaluate the feasibility of replacing DoD CONUS jet fuel with alternative jet fuel from domestic feedstocks and assess the cost, greenhouse gas (GHG) emissions, energy balance, land, water, and fertilizer impacts of nine alternative jet fuel pathways. The feedstocks include terrestrial crops (soy, corn, wood, and grass), marine microalgae, and by-products (forestry residue, municipal solid waste, and waste oil) converted by extraction, fermentation, or thermo-chemical conversion, paired with upgrading steps. We found that domestic biomass feedstocks can meet the DoD CONUS jet fuel demand without significantly affecting food supply. Alternative pathways cost more than petroleum jet fuel ($0.78 l -1 and emitting 89 g CO 2 equivalent (CO 2e ) MJ -1 ), but many lowered GHG emissions. The forestry residue and waste oil pathways yielded the lowest costs ($\$0.92$ and $\$0.82$ l -1 , respectively), decreased emissions (23 and 35 g CO 2 e MJ -1 , respectively), and had negligible effects on land, water, and fertilizer resources. Finally, tradeoffs among sustainability metrics are further explored with a sensitivity analysis and by evaluating carbon-cost scenarios.

09 BIOMASS FUELS↗

Analysis of Pulsed Lidar Measurements of Atmospheric CO2 Column Absorption During the ASCENDS 2009-2011 Airborne Campaigns

We have developed a pulsed lidar technique for measuring the tropospheric CO2 concentrations as a candidate for NASA's ASCENDS mission and have demonstrated the CO2 and O2 measurements from aircraft. Our technique uses two pulsed lasers allowing simultaneous measurement of a single CO2 absorption line near 1572 nm, O2 extinction in the Oxygen A-band, surface height and backscatter profile. The lasers are stepped in wavelength across the CO2 line and an O2 line doublet during the measurement. The column densities for the CO2 and O2 are estimated from the differential optical depths (DOD) of the scanned absorption lines via the IPDA technique. For the 2009 ASCENDS campaign we flew the CO2 lidar on a Lear-25 aircraft, and measured the absorption line shapes of the CO2 line using 20 wavelength samples per scan. Measurements were made at stepped altitudes from 3 to 12.6 km over the Lamont OK, central Illinois, North Carolina, and over the Virginia Eastern Shore. Although the received signal energies were weaker than expected for ASCENDS, clear CO2 line shapes were observed at all altitudes. Most flights had 5-6 altitude steps with 200-300 seconds of recorded measurements per step. We averaged every 10 seconds of measurements and used a cross-correlation approach to estimate the range to the scattering surface and the echo pulse energy at each wavelength. We then solved for the best-fit CO2 absorption line shape, and calculated the DOD of the fitted CO2 line, and computed its statistics at the various altitude steps. We compared them to CO2 optical depths calculated from spectroscopy based on HITRAN 2008 and the column number densities calculated from the airborne in-situ readings. The 2009 measurements have been analyzed and they were similar on all flights. The results show clear CO2 line shape and absorption signals, which follow the expected changes with aircraft altitude from 3 to 13 km. They showed the expected nearly the linear dependence of DOD vs altitude. The measurements showed ~ 1 ppm random errors for 8-10 km altitudes and ~30 sec averaging times. For the 2010 ASCENDS campaigns we flew the CO2lidar on the NASA DC-8 and added an 02lidar channel. During July 2010 we made measurements of CO2 and O2 column absorption during longer flights over Railroad Valley NV, the Pacific Ocean and over Lamont OK. CO2 measurements were made with 30 steps/scan, 300 scans/sec and improved line resolution and receiver sensitivity. Analysis of the 2010 CO2 measurements shows the expected ~linear change of DOD with altitude. For measurements at altitudes> 6 km the random errors were 0.3 ppm for 80 sec averaging times. For the summer 2011 ASCENDS campaigns we made further improvements to the lidar's CO2 line scan and receiver sensitivity. We demonstrated measurements over the California Central Valley, to stratus cloud tops over the Pacific Ocean, over mountain regions with snow, and over several areas with broken clouds. Details of the lidar measurements and their analysis will be described in the presentation.

Abshire, J. B.↗

Pulsed Lidar Measurements of Atmospheric CO2 Column Absorption and Range During the ASCENDS 2009-2011 Airborne Campaigns

We have developed a pulsed lidar technique for measuring the tropospheric CO2 concentrations as a candidate for NASA's ASCENDS mission and have demonstrated the CO2 and O2 measurements from aircraft. Our technique uses two pulsed lasers allowing simultaneous measurement of a single CO2 absorption line near 1572 nm, O2 extinction in the Oxygen A-band, surface height and backscatter profile. The lasers are stepped in wavelength across the CO2 line and an O2 line doublet during the measurement. The column densities for the CO2 and O2 are estimated from the differential optical depths (DOD) of the scanned absorption lines via the IPDA technique. For the 2009 ASCENDS campaign we flew the CO2 lidar only on a Lear-25 aircraft, and measured the absorption line shapes of the CO2 line using 20 wavelength samples per scan. Measurements were made at stepped altitudes from 3 to 12.6 km over the Lamont OK, central Illinois, North Carolina, and over the Virginia Eastern Shore. Although the received signal energies were weaker than expected for ASCENDS, clear C02 line shapes were observed at all altitudes. Most flights had 5-6 altitude steps with 200-300 seconds of recorded measurements per step. We averaged every 10 seconds of measurements and used a cross-correlation approach to estimate the range to the scattering surface and the echo pulse energy at each wavelength. We then solved for the best-fit CO2 absorption line shape, and calculated the DOD of the fitted CO2 line, and computed its statistics at the various altitude steps. We compared them to CO2 optical depths calculated from spectroscopy based on HITRAN 2008 and the column number densities calculated from the airborne in-situ readings. The 2009 measurements have been analyzed in detail and they were similar on all flights. The results show clear CO2 line shape and absorption signals, which follow the expected changes with aircraft altitude from 3 to 13 km. They showed the expected nearly the linear dependence of DOD vs altitude. The measurements showed -1 ppm random errors for 8-10 km altitudes and -30 sec averaging times. For the 2010 ASCENDS campaigns we flew the CO2 lidar on the NASA DC-8 and added an O2 lidar channel. During July 2010 we made measurements of CO2 and O2 column absorption during longer flights over Railroad Valley NV, the Pacific Ocean and over Lamont OK. CO2 measurements were made with 30 steps/scan, 300 scans/sec and improved line resolution and receiver sensitivity. Analysis of the 2010 CO2 measurements shows the expected -linear change of DOD with altitude. For measurements at altitudes> 6 km the random errors were 0.3 ppm for 80 sec averaging times. For the summer 2011 ASCENDS campaigns we made further improvements to the lidar's CO2 line scan and receiver sensitivity. The seven flights in the 2011 Ascends campaign were flown over a wide variety of surface and cloud conditions in the US, which produced a wide variety of lidar signal conditions. Details of the lidar measurements and their analysis will be described in the presentation.

Abshire, J. B.↗

H2@Airports (Workshop Summary Report)

This report serves as the proceedings of the H2@Airports Workshop held virtually by the U.S. Department of Energy (DOE) in collaboration with the U.S. Department of Transportation (DOT) and Department of Defense (DOD), November 4-6, 2020. Presentations from the workshop can be found at H2@Airports Workshop: https://www.energy.gov/eere/fuelcells/h2airports-workshop. The workshop was held to assess the state of the art for electric aircraft and airport applications specifically using hydrogen fuel cells, to discuss operational requirements and lessons learned on early fuel cell aviation and airport projects, to understand current technology gaps, to identify collaborative research and development (R&D) opportunities, to highlight codes, standards, safety, and regulatory challenges, and to identify potential actions that address them. Experts and stakeholders from industry, government, and academia met to discuss the current state of the art of hydrogen and fuel cell technologies and the requirements for using these technologies in aviation applications and land-based applications at airports. This report summarizes the discussions and diverse opinions expressed at the workshop.

08 HYDROGEN↗

Vehicle/Atmosphere Interaction Glows: Far Ultraviolet, Visible, and Infrared

Spacecraft glow information has been gathered from a number of spacecraft including Atmospheric and Dynamic satellites, and Space Shuttles (numerous flights) with dedicated pallet flow observations on STS-39 (DOD) and STS-62 (NASA). In addition, a larger number of laboratory experiments with low energy oxygen beam studies have made important contributions to glow understanding. The following report provides information on three engineering models developed for spacecraft glow including the far ultraviolet to ultraviolet (1400-4000 A), and infrared (0.9-40 microns) spectral regions. The models include effects resulting from atmospheric density/altitude, spacecraft temperature, spacecraft material, and ram angle. Glow brightness would be predicted as a function of distance from surfaces for all wavelengths.

Swenson, G.↗

K-Modules

K-Modules are capacitive energy modules designed to be stacked together to form a capacitor bank (aka a Marx bank). Discharging the stack produces a single, high voltage, high current pulse that when coupled to an X-ray (or electron) tube, produces energetic X-rays (or an intense electron beam, E-beam). The energetic X-rays are used in Flash X-ray Radiography (FXR), a technique to image objects moving at extremely high speed to measure their speed, shape and internal density profiles. The images help validate computer models for materials behavior under extreme pressure and temperature. FXR is a technology critical to dynamic experiments for the national security mission, and most users are DOE and DOD labs. Febetrons, the X-ray generating devices, are used at these sites and rely on capacitive energy modules for their operation. A stack of the newly developed K-modules will significantly extend the capabilities of these Febetrons

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Performance Characterization of High Energy Commercial Lithium-ion Cells

The NASA Glenn Research Center Electrochemistry Branch performed characterization of commercial lithium-ion cells to determine the cells' performance against Exploration Technology Development Program (ETDP) Key Performance Parameters (KPP). The goals of the ETDP Energy Storage Project require significant improvements in the specific energy of lithium-ion technology over the state-of-the-art. This work supports the high energy cell development for the Constellation customer Lunar Surface Systems (LSS). In support of these goals, testing was initiated in September 2009 with high energy cylindrical cells obtained from Panasonic and E-One Moli. Both manufacturers indicated the capability of their cells to deliver specific energy of at least 180 Wh/kg or higher. Testing is being performed at the NASA Glenn Research Center to evaluate the performance of these cells under temperature, rate, and cycling conditions relevant to the ETDP goals for high energy cells. The cell-level specific energy goal for high energy technology is 180 Wh/kg at a C/10 rate and 0 C. The threshold value is 165 Wh/kg. The goal is to operate for at least 2000 cycles at 100 percent DOD with greater than 80 percent capacity retention. The Panasonic NCR18650 cells were able to deliver nearly 200 Wh/kg at the aforementioned conditions. The E-One Moli ICR18650J cells also met the specific energy goal by delivering 183 Wh/kg. Though both cells met the goal for specific energy, this testing was only one portion of the testing required to determine the suitability of commercial cells for the ETDP. The cells must also meet goals for cycle life and safety. The results of this characterization are summarized in this report.

Schneidegger, Brianne T.↗

Economic Comparison Between a Battery and Supercapacitor for Hourly Dispatching Wave Energy Converter Power: Preprint

This paper demonstrates a successful dispatching scheme of slider-crank wave energy converter (WEC) production using two different kinds of energy storage systems, namely, (i) Li-ion battery and (ii) Supercapacitors (SC). The performance of two energy storage systems has been compared in order to develop the most economical energy storage system for WEC hourly dispatching scheme. The cost optimization of the energy storage system considering both cycling and calendar aging expenses is made based on its usage of depth of discharge (DOD). In this study, the extensive simulation is conducted in MATLAB/Simulink platform, and it is found that SC is a better candidate than Li-ion battery in terms of economic assessment for hourly dispatching WEC power.

50 EE - Wind and Water Power Program - Water (EE-4↗

Development and demonstration of a telerobotic excavation system

Oak Ridge National Laboratory is developing remote excavation technologies for the Department of Energy's Office (DOE) of Technology Development, Robotics Technology Development Program, and also for the Department of Defense (DOD) Project Manager for Ammunition Logistics. This work is being done to meet the need for remote excavation and removal of radioactive and contaminated buried waste at several DOE sites and unexploded ordnance at DOD sites. System requirements are based on the need to uncover and remove waste from burial sites in a way that does not cause unnecessary personnel exposure or additional environmental contamination. Goals for the current project are to demonstrate dexterous control of a backhoe with force feedback and to implement robotic operations that will improve productivity. The Telerobotic Small Emplacement Excavator is a prototype system that incorporates the needed robotic and telerobotic capabilities on a commercially available platform. The ability to add remote dexterous teleoperation and robotic operating modes is intended to be adaptable to other commercially available excavator systems.

Burks, Barry L.↗

Isothermal Microcalorimetric Analysis of Li/CF x Battery Discharge

Lithium/carbon monofluoride (Li/CF x ) batteries generate substantial amounts of heat during discharge in part due to the large deviation of the loaded voltage from the measured and thermodynamically predicted open circuit voltage. Here, in this study, we further analyze this system by estimating the equilibrium voltage (V eq ) and its temperature dependence (dV eq /dT) over the entire discharge range. Based on these results, the ohmic and entropic heat contributions to the overall heat flow are calculated from experimental data. The ohmic heat flow is consistent with an electrochemical impedance spectroscopy model and electrode density measurements, indicating decreasing porosity of the electrode during discharge. Entropic heating increases during discharge as the cell reaction becomes increasingly entropically unfavorable. The total energy dissipated by the cell (electrical and thermal) remains similar over the entire discharge, evidence for a two-phase reaction with a constant, and rate-independent, ΔG rxn of about -465 kJ mol -1 . However, near the end of discharge (>90% DOD), ΔG rxn changes significantly indicating possible secondary reactions.

25 ENERGY STORAGE↗

All Solid State Batteries Enabled by Multifunctional Electrolyte Materials

Solid Power has teamed with University of California San Diego to develop a high energy, long life, low cost, and safe all-solid-state-battery (ASSB). The battery is enabled by a multifunctional solid state electrolyte (SSE). The project enables scalable production of large format solid state batteries required by the vehicle market and building domestic battery manufacturers as leaders in the global vehicle ASSB production. In the project, the multifunctional SSE materials have been developed and optimized with ionic conductivity ≥ 5 mS/cm and electrochemical stability 0 – 4.5V. SSE separator films have been coated by using a roll-to-roll process with thickness ≤ 40 µm. All-solid-state NMC-Li pouch cells containing the developed SSE have been assembled. A cycle life of > 750 at 100% DOD and 45 °C has been demonstrated in a full pouch cell.

25 ENERGY STORAGE↗