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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Turbulent mixing layers in the interstellar medium of galaxies

It is proposed that turbulent mixing layers are common in the ISM of the Milky Way and selected external galaxies, with many layers per kiloparsec along typical lines of sight. All of the diffuse C I 1550-A background emission and a significant fraction of the diffuse H-alpha background at high latitude can be explained by mixing layers cooling at pressure of about 3000/cu cm K. These models also produce the correct ratio of semiforbidden C IV 15500 III 1663-A emission. Only 10 percent of the disk H-alpha is likely to arise from mixing layers. The observed Galactic absorption-line column densities of C IV, N V, Si IV, and O VI are roughly consistent with mixing-layer models with an intermediate temperature of about 10 exp 5.3 K and depleted abundances.

Slavin, Jonathan D.↗
NASA NTRS1992

On the modeling of scalar diffusion in isotropic turbulence

The objectives of the study were to establish the behavior of conditional scalar dissipation and diffusion at the extreme values of mass fraction and to derive and evaluate closure models for these terms using the scalar probability density function. The conditional scalar dissipation, its derivative with respect to mass fraction, and conditional scalar diffusion are all found to be zero at extreme values of mass fraction. A model for conditional scalar dissipation is derived which exhibits the correct behavior at the extreme values of scalar concentration.

Girimaji, Sharath S.↗
NASA NTRS1994

Calculation of Propulsive Nozzle Flowfields in Multidiffusing Chemically Reacting Environments

An advanced engineering model has been developed to aid in the analysis and design of hydrogen/oxygen chemical rocket engines. The complete multispecies, chemically reacting and multidiffusing Navier-Stokes equations are modelled, including the Soret thermal diffusion and the Dufour energy transfer terms. In addition to the spectrum of multispecies aspects developed, the model developed in this study is also conservative in axisymmetric flow for both inviscid and viscous flow environments and the boundary conditions employ a viscous, chemically reacting, reference plane characteristics method. Demonstration cases are presented for a 1030:1 area ratio nozzle, a 25 lbf film cooled nozzle, and a transpiration cooled plug and spool rocket engine. The results indicate that the thrust coefficient predictions of the 1030:1 and the 25 lbf film cooled nozzle are within 0.2 to 0.5 percent, respectively, of experimental measurements when all of the chemical reaction and diffusion terms are considered. Further, the model's predictions agree very well with the heat transfer measurements made in all of the nozzle test cases. The Soret thermal diffusion term is demonstrated to have a significant effect on the predicted mass fraction of hydrogen along the wall of the nozzle in both the laminar flow 1030:1 nozzle and the turbulent flow plug and spool nozzle analysis cases performed. Further, the Soret term was shown to represent an important fraction of the diffusion fluxes occurring in a transpiration cooled rocket engine.

Kacynski, Kenneth John↗
NASA NTRS1993

The prediction of nozzle performance and heat transfer in hydrogen/oxygen rocket engines with transpiration cooling, film cooling, and high area ratios

An advanced engineering computational model has been developed to aid in the analysis and design of hydrogen/oxygen chemical rocket engines. The complete multi-species, chemically reacting and diffusing Navier-Stokes equations are modelled, finite difference approach that is tailored to be conservative in an axisymmetric coordinate system for both the inviscid and viscous terms. Demonstration cases are presented for a 1030:1 area ratio nozzle, a 25 lbf film cooled nozzle, and transpiration cooled plug-and-spool rocket engine. The results indicate that the thrust coefficient predictions of the 1030:1 nozzle and the film cooled nozzle are within 0.2 to 0.5 percent, respectively, of experimental measurements when all of the chemical reaction and diffusion terms are considered. Further, the model's predictions agree very well with the heat transfer measurements made in all of the nozzle test cases. The Soret thermal diffusion term is demonstrated to have a significant effect on the predicted mass fraction of hydrogen along the wall of the nozzle in both the laminar flow 1030:1 nozzle and the turbulent plug-and-spool rocket engine analysis cases performed. Further, the Soret term was shown to represent a significant fraction of the diffusion fluxes occurring in the transpiration cooled rocket engine.

Kacynski, Kenneth J.↗
NASA NTRS1997

Soot Volume Fraction Maps for Normal and Reduced Gravity Laminar Acetylene Jet Diffusion Flames

The study of soot particulate distribution inside gas jet diffusion flames is important to the understanding of fundamental soot particle and thermal radiative transport processes, as well as providing findings relevant to spacecraft fire safety, soot emissions, and radiant heat loads for combustors used in air-breathing propulsion systems. Compared to those under normal gravity (1-g) conditions, the elimination of buoyancy-induced flows is expected to significantly change the flow field in microgravity (O g) flames, resulting in taller and wider flames with longer particle residence times. Work by Bahadori and Edelman demonstrate many previously unreported qualitative and semi-quantitative results, including flame shape and radiation, for sooting laminar zas jet diffusion flames. Work by Ku et al. report soot aggregate size and morphology analyses and data and model predictions of soot volume fraction maps for various gas jet diffusion flames. In this study, we present the first 1-g and 0-g comparisons of soot volume fraction maps for laminar acetylene and nitrogen-diluted acetylene jet diffusion flames. Volume fraction is one of the most useful properties in the study of sooting diffusion flames. The amount of radiation heat transfer depends directly on the volume fraction and this parameter can be measured from line-of-sight extinction measurements. Although most Soot aggregates are submicron in size, the primary particles (20 to 50 nm in diameter) are in the Rayleigh limit, so the extinction absorption) cross section of aggregates can be accurately approximated by the Rayleigh solution as a function of incident wavelength, particles' complex refractive index, and particles' volume fraction.

Greenberg, Paul S.↗
NASA NTRS1973

Ultrafiltration by a compacted clay membrane. I - Oxygen and hydrogen isotopic fractionation. II - Sodium ion exclusion at various ionic strengths.

Laboratory experiments were carried out to determine the magnitude of the isotopic fractionation of distilled water and of 0.01N NaCl forced to flow at ambient temperature under a hydraulic pressure drop of 100 bars across a montmorillonite disk compacted to a porosity of 35% by a pressure of 330 bars. The ultrafiltrates in both experiments were depleted in D by 2.5% and in O-18 by 0.8% relative to the residual solution. No additional isotopic fractionation due to a salt-filtering mechanism was observed at NaCl concentrations up to 0.01N. Adsorption is most likely the principal mechanism which produces isotopic fractionation, but molecular diffusion may play a minor role. The results suggest that oxygen and hydrogen isotopic fractionation of ground water during passage through compacted clayey sediments should be a common occurrence, in accord with published interpretations of isotopic data from the Illinois and Alberta basins. It is shown how it is possible to proceed from the ion exchange capacity of clay minerals and, by means of the Donnan membrane equilibrium concept and the Teorell-Meyer-Siever theory, develop a theory to explain why and to what extent ultrafiltration occurs when solutions of known concentration are forced to flow through a clay membrane.

Coplen, T. B.↗
NASA NTRS1994

Solar wind noble gases and nitrogen in metal from lunar soil 68501

Noble gases and N were analyzed in handpicked metal separates from lunar soil 68501 by a combination of step-wise combustions and pyrolyses. Helium and Ne were found to be unfractionated with respect to one another when normalized to solar abundances, for both the bulk sample and for all but the highest temperature steps. However, they are depleted relative to Ar, Kr and Xe by at least a factor of 5. The heavier gases exhibit mass-dependent fractionation relative to solar system abundance ratios but appear unfractionated, both in the bulk metal and in early temperature steps, when compared to relative abundances derived from lunar ilmenite 71501 by chemical etching, recently put forward as representing the abundance ratios in solar wind. Estimates of the contribution of solar energetic particles (SEP) to the originally implanted solar gases, derived from a basic interpretation of He and Ne isotopes, yield values of about 10%. Analysis of the Ar isotopes requires a minimum of 20% SEP, and Kr isotopes, using our preferred composition for solar wind Kr, yield a result that overlaps both these values. It is possible to reconcile the data from these gases if significant loss of solar wind Ar, Kr and presumably Xe has occurred relative to the SEP component, most likely by erosive processes that are mass independent, although mass-dependent losses (Ar greater than Kr greater than Xe) cannot be excluded. If such losses did occur, the SEP contribution to the solar implanted gases must have been no more than a few percent. Nitrogen is a mixture of indigenous meteoritic N, whose isotopic composition is inferred to be relatively light, and implanted solar N, which has probably undergone diffusive redistribution and fractionation. If the heavy noble gases have not undergone diffusive loss, then N/Ar in the solar wind can be inferred to be at least several times the accepted solar ratio. The solar wind N appears, even after correction for fractionation effects, to have a minimum delta N-15 value equal to or greater than +150% and a more probable value equal to or greater than +200%.

Becker, Richard H.↗
NASA NTRS1995

Hubble Space Telescope FOS spectroscopy of the ultrashort-period dwarf nova WZ Sagittae: The underlying degenerate

Two consecutive Hubble Space Telescope (HST) Faint Object Spectrograph (FOS) spectra of the exposed white dwarf in the ultrashort-period, high-amplitude, dwarf nova WZ Sge, reveal a rich absorption line spectrum of neutron carbon and ionized metals, the Stark-broadened Lyman-alpha absorption wing, the H2 quasi-molecular Lyman-alpha 'satellite' absorption line, and a double-peaked C IV emission line which is variable with orbital phase. A synthetic spectral analysis of the white dwarf yields T(sub eff) = 14,900 K +/- 250 K, log g = 8.0. In order to fit the strongest C I absorption lines and account for the weakness of the silicon absorption lines, the abundance of carbon in the photosphere must be approximately 0.5 solar, silicon abundance is 5 x 10(exp -3) solar, with all other metal species appearing to be 0.1-0.001 times solar. The H2 quasi-molecular absorption is fitted very successfully. The photospheric metals have diffusion timescales of fractions of a year, and thus they must have been accreted long after the 1978 December outburst. The source of the most abundance metal, carbon, is considered. If the time-averaged accretion rate during quiescence is low enough for diffusive equilibrium to prevail, then the equilibrium accretion rate pf neutron carbon is 7 x 10(exp -16) solar mass/yr. A convective dredge-up origin for the concentration of carbon is extremely unlikely, given that the white dwarf atmosphere is H-rich while in single degenerates showing carbon and hydrogen, the C and H are trace elements in a helium background. Additional implications are explored.

Sion, Edward M.↗
NASA NTRS1985

High-latitude H I structure and the soft X-ray background

The paper presents 21 cm observations made with the NRAO 43 m (140 foot) telescope of 20 randomly selected intermediate and high galactic latitude regions. The data are examined for evidence of the neutral gas clumping required by models in which a substantial fraction of the diffuse soft X-ray background (hv = 0.1 - 0.284 keV) originates outside the galactic disk and is absorbed by interstellar gas. No such evidence is found, and it is concluded that the degree of clumping required by such models must, if it exists, have characteristic angular scales less than 14 arcmin. Furthermore, an analysis of other data indicates that the required clumping does not exist on smaller size scales. It is therefore unlikely that a significant fraction of the X-ray flux originates in a galactic corona, unless some other explanation of the anomalously small apparent absorption can be found.

Jahoda, K.↗
DOE OSTI2020

The role of geography in the complex diffusion of innovations

The urban–rural divide is increasing in modern societies calling for geographical extensions of social influence modelling. Improved understanding of innovation diffusion across locations and through social connections can provide us with new insights into the spread of information, technological progress and economic development. In this work, we analyze the spatial adoption dynamics of iWiW, an Online Social Network (OSN) in Hungary and uncover empirical features about the spatial adoption in social networks. During its entire life cycle from 2002 to 2012, iWiW reached up to 300 million friendship ties of 3 million users. We find that the number of adopters as a function of town population follows a scaling law that reveals a strongly concentrated early adoption in large towns and a less concentrated late adoption. We also discover a strengthening distance decay of spread over the life-cycle indicating high fraction of distant diffusion in early stages but the dominance of local diffusion in late stages. The spreading process is modelled within the Bass diffusion framework that enables us to compare the differential equation version with an agent-based version of the model run on the empirical network. Although both model versions can capture the macro trend of adoption, they have limited capacity to describe the observed trends of urban scaling and distance decay. We find, however that incorporating adoption thresholds, defined by the fraction of social connections that adopt a technology before the individual adopts, improves the network model fit to the urban scaling of early adopters. Controlling for the threshold distribution enables us to eliminate the bias induced by local network structure on predicting local adoption peaks. Finally, we show that geographical features such as distance from the innovation origin and town size influence prediction of adoption peak at local scales in all model specifications.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS1992

Experimental dehydration of natural obsidian and estimation of DH2O at low water contents

Water diffusion experiments were carried out by dehydrating rhyolitic obsidian from Valles Caldera (New Mexico, USA) at 510-980 degrees C. The starting glass wafers contained approximately 0.114 wt% total water, lower than any glasses previously investigated for water diffusion. Weight loss due to dehydration was measured as a function of experiment duration, which permits determination of mean bulk water diffusivity, mean Dw. These diffusivities are in the range of 2.6 to 18 X 10(-14) m2/s and can be fit with the following Arrhenius equation: ln mean Dw (m2/s) = -(25.10 +/- 1.29) - (46,480 +/- 11,400) (J/mol) / RT, except for two replicate runs at 510 degrees C which give mean Dw values much lower than that defined by the above equation. When interpreted according to a model of water speciation in which molecular H2O is the diffusing species with concentration-independent diffusivity while OH units do not contribute to the transport but react to provide H2O, the data (except for the 510 degrees C data) are in agreement with extrapolation from previous results and hence extend the previous data base and provide a test of the applicability of the model to very low water contents. Mean bulk water diffusivities are about two orders of magnitude less than molecular H2O diffusivities because the fraction of molecular H2O out of total water is very small at 0.114 wt% total water and less. The 510 degrees C experimental results can be interpreted as due to slow kinetics of OH to H2O interconversion at low temperatures.

NASA Program Exobiology↗
DOE OSTI2022

Direct Correlation of the Salt-Reduced Diffusivities of Organic Solvents with the Solvent’s Mole Fraction

We report that lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) in organic solvents (especially propylene carbonate) has demonstrated extraordinary pseudocapacitive performance as an electrolyte in the supercapacitor configuration. However, the influence of the solvated ions on the diffusivity of the solvent molecules is yet to be understood. We examine the impact of LiTFSI on the diffusivity in five organic solvents: acetonitrile (ACN), tetrahydrofuran (THF), methanol (MeOH), dimethyl sulfoxide (DMSO), and propylene carbonate (PC) using a combination of neutron scattering, conductivity measurements, and molecular dynamics simulations. The extent of the diffusivity reduction in the concentration regime of ≤1 M directly correlates with the solvent mole fraction at which the solvation shells around Li + ions are of similar size in all the solvents, resulting in a universal ~50% reduction in the solvent diffusivity. These results provide guidance for formulation of the new electrolytes to enhance the performance of energy storage devices.

conductivity↗
NASA NTRS1980

The contribution of young galaxies to the X-ray background

The contribution of young galaxies to the diffuse X-ray background is estimated and two mechanisms by which young galaxies may emit hard X-rays are considered. The first mechanism is direct thermal bremsstrahlung emission from a hot galactic wind powered by supernovae. Estimating mass-loss rates from galaxies by arguments based on metallicity and on the X-ray spectroscopic observations of rich clusters, it is shown that galactic winds may contribute substantially to the background. The second mechanism relies on the decreased metallicity of young galaxies to increase the number of supergiant stars and hence the numbers of hard X-ray binaries. This effect quantitatively explains the relatively large X-ray luminosity of the Magellanic clouds and also indicates that binaries in young galaxies may contribute a significant fraction of the diffuse X-ray background. Both mechanisms require that the epoch of galaxy formation be recent (redshift less than 2-3) in order to account for the observed spectral temperature (45 keV) of the hard X-ray background.

Bookbinder, J.↗
DOE OSTI2023

Observation of two different cool flame regimes of diethyl ether in a counterflow burner

This short communication reports, for the first time, the existence of two different self-sustaining cool flame regimes of diethyl ether (DEE) in a diffusion counterflow burner: a weaker autoignition-assisted cool flame near the fuel burner and a normal diffusion cool flame near the stagnation plane. Here, the results show that the normal diffusion cool flame extinction limit increases monotonically with the fuel mole fraction, while the autoignition-assisted cool flame approaches a plateau and can exist at a fuel mole fraction below the normal diffusion cool flame. It is shown that both flame regimes are governed by the same low-temperature chain-branching reaction pathway of DEE. By using in situ laser diagnostics, entrainment of unburned fuel stream to oxygen stream at the outer edge of the fuel burner is identified as the governing physical mechanism causing a partially premixed self-sustained hollow cool flame structure. The results reveal that when a fuel with high low-temperature reactivity, two different cool flame regimes can be observed in a counterflow flame experiment. Future studies with high-reactivity fuels in a counterflow burner must ensure to distinguish between the two self-sustaining cool flame regimes. Moreover, the existence of these different cool flame regimes needs to be examined so that they would not trigger an uncontrolled combustion phasing in advanced engines fed with high low-temperature reactivity fuels.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2021

Performance of microchannel plate based detectors for <25 keV x rays: Monte Carlo simulations and comparisons with experimental results

We present the results of Monte Carlo simulations of the microchannel plate (MCP) response to x rays in the 250 eV to 25 keV energy range as a function of both x-ray energy and impact angle and their comparisons with the experimental results from the X8A beamline at the National Synchrotron Light Source at Brookhaven National Laboratory. Incoming x rays interact with the lead glass of the microchannel plate, producing photoelectrons. Transport of the photoelectrons is neglected in this model, and it is assumed that photoelectrons deposit all their energy at the point they are created. This deposition leads to the generation of many secondary electrons, some fraction of which diffuse to the MCP pore surface where they can initiate secondary electron cascades in the pore under an external voltage bias. X-ray penetration through multiple MCP pore walls is increasingly important above 5 keV, and the effect of this penetration on MCP performance is studied. In agreement with past measurements, we find that the dependence of MCP sensitivity with angle relative to the pore bias changes from a cotangent dependence to angular independence and then proceeds to a secant dependence as the x-ray energy increases. We also find that with the increasing x-ray energy, the MCP gain sensitivity as a function of bias voltage decreases. The simulations also demonstrate that for x rays incident normal to the MCP surface, spatial resolution shows little dependence on the x-ray energy but degrades with the increasing x-ray energy as the angle of incidence relative to the surface normal increases. This agrees with experimental measurements. Simulation studies have also been completed for MCPs gated with a subnanosecond voltage pulse. In this work, we find that the optical gate profile width increases as the x-ray energy is increased above 5 keV, a consequence of increased x-ray penetration at energies >5 keV. Simulations of the pulsed dynamic range show that the dynamic range varies between ~100 and 1000 depending on x-ray energy and peak voltage.

47 OTHER INSTRUMENTATION↗