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Advanced Sensors and Instrumentation (ASI) Program Plan. Nuclear Energy Enabling Technologies (NEET)

The U.S. Department of Energy Office of Nuclear Energy (DOE-NE) sponsors a crosscutting technology development (CTD) program addressing common instrumentation & controls (I&C) needs in all DOE-NE sponsored programs. In 2012, DOE-NE initiated the Nuclear Energy Enabling Technology (NEET) Program to conduct research, development, and demonstration (RD&D) in crosscutting technologies that directly support and enable the development of existing, new and advanced reactor designs, and fuel cycle technologies. These technologies will advance the state of nuclear technology, improve its competitiveness, and promote continued contribution to meeting our Nation’s energy and environmental challenges. The NEET Program has spurred innovation in the field of sensors and instrumentation, advanced methods for manufacturing, and cyber security. The Advanced Sensors and Instrumentation (ASI) program is one element of the NEET CTD that has spurred innovation in the measurement science field by funding research on sensors, instrumentation and controls, communication, and advanced analytics that measure system parameters, gauge component control input, and provide power plant owners and operators critical awareness so they can plan and safely manage operational evolutions. The NEET ASI Program has carried out research and development (R&D) required to develop and deploy innovative and advanced sensors, and instrumentation and control capabilities for current and future nuclear energy systems, and to enable the advanced technologies essential to NE’s R&D efforts needed to realize mission goals. The concept of technology readiness assessment is helpful for the classification of instrumentation technology as part of the program strategy. A technology readiness assessment evaluates technology maturity using the Technology Readiness Level (TRL) scale and was pioneered by the National Aeronautics and Space Administration in the 1980s for space technology. It has recently been adopted to advance fuels and materials. The NEET ASI program objective is to mature instruments technology to TRL 6, which is “demonstration of the technology in relevant environment.” While there may be instances in which a different strategy is justified, the aim of the program is to respond to DOE program and stakeholder needs for nuclear instrumentation then hand off the technology after demonstration for integration in a more complex system, for example an irradiation test, experimental loop or a plant component such as the core, primary system or heat exchanger. A mechanism to continue some level of support from NEET ASI during and after the adoption (for example, to maintain fabrication and calibration capabilities) will be defined as the first example of technology hand off comes to fruition. In addition, several paths exist within DOE to complement NEET ASI activities to extend the maturity beyond TRL, for example through GAIN, technology commercialization funding, and small-business programs. Role of NEET ASI CINR projects in the TRL space, and integration with direct funded demonstration.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

High Performance Alloy Technology to Market Support

The goal of the Technology to Market Assessment for Advanced Alloys is to identify non-technical support needs of research teams that could accelerate a path toward commercialization. The successful adoption of new technology into the market has positive impacts on direct stakeholders, taxpayers, and is important to showcase the strength of the United States (U.S.) Department of Energy (DOE) National Energy Technology Laboratory (NETL) Crosscutting High Performance Materials program. This assessment leverages a series of proven frameworks developed by NETL support contractor innovation specialists to determine which projects within NETL’s Crosscutting Advanced Alloys portfolio are in the best position for commercialization. The projects were then assessed for specific non-technical support needs.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Grid Energy Storage: Supply Chain Deep Dive Assessment

The report “America’s Strategy to Secure the Supply Chain for a Robust Clean Energy Transition” lays out the challenges and opportunities faced by the United States in the energy supply chain as well as the Federal Government plans to address these challenges and opportunities. It is accompanied by several issue-specific deep dive assessments, including this one, in response to Executive Order 14017 “America’s Supply Chains,” which directs the Secretary of Energy to submit a report on supply chains for the energy sector industrial base. The Executive Order is helping the Federal Government to build more secure and diverse U.S. supply chains, including energy supply chains. To combat the climate crisis and avoid the most severe impacts of climate change, the U.S. is committed to achieving a 50 to 52 percent reduction from 2005 levels in economy-wide net greenhouse gas pollution by 2030, creating a carbon pollution-free power sector by 2035, and achieving net zero emissions economy-wide by no later than 2050. The U.S. Department of Energy (DOE) recognizes that a secure, resilient supply chain will be critical in harnessing emissions outcomes and capturing the economic opportunity inherent in the energy sector transition. Potential vulnerabilities and risks to the energy sector industrial base must be addressed throughout every stage of this transition. The DOE energy supply chain strategy report summarizes the key elements of the energy supply chain as well as the strategies the U.S. Government is starting to employ to address them. Additionally, it describes recommendations for Congressional action. DOE has identified technologies and crosscutting topics for analysis in the one-year time frame set by the Executive Order. Along with the capstone policy report, DOE is releasing 11 deep dive assessment documents, including this one, covering the following technology sectors: carbon capture materials; electric grid including transformers and high voltage direct current (HVDC); energy storage; fuel cells and electrolyzers; hydropower including pumped storage hydropower (PSH); neodymium magnets; nuclear energy; platinum group metals and other catalysts; semiconductors; solar photovoltaics (PV); and wind. DOE is also releasing two deep dive assessments on the following crosscutting topics: Commercialization and competitiveness; and cybersecurity and digital components. More information can be found at www.energy.gov/policy/supplychains.

25 ENERGY STORAGE↗

Understanding and Predictability of Integrated Mountain Hydroclimate (Workshop Report)

Mountainous systems cover approximately 23% of Earth’s land and are distributed across all continents. They can capture and store atmospheric moisture that is then cycled through the terrestrial surface and subsurface system, released to downstream communities, and cycled back to the atmosphere. Mountain hydroclimate—characterized by steep gradients, geological, ecological, and biogeochemical diversity—is influenced by topographic forcing and elevated warming and susceptible to large subseasonal to multidecadal variability and rapid changes. Terrestrial hydrological and biogeochemical cycles also experience cascading effects from global warming impacts, such as multidecadal declines in mountain snowpack, longer growing seasons, and increased frequency and severity of extreme events like droughts and wildfires. However, little is known about the effects of these impacts and their feedbacks on climate systems and surface-subsurface compartments. Also unknown are the full implications of changing hydroclimate and extreme events on hydro biogeochemical cycles across atmosphere, terrestrial, and human systems in mountain regions and beyond. This knowledge gap is critical, given human reliance on mountain systems for stable water supply and quality. Mountain systems’ increasing vulnerability to climate change and human perturbations motivates the need to improve understanding of integrated mountain hydroclimate (IMHC) systems and their feedbacks and impacts on humans across scales. However, due to large heterogeneity and strong gradients, coupled natural-human processes in mountain regions present significant challenges for observations, modeling, predictions, and projections. Motivated by gaps in mountain hydroclimate understanding, observations, and modeling and the need for credible projections of future changes, the U.S. Department of Energy’s (DOE) Biological and Environmental Research (BER) program organized a virtual workshop on “Understanding and Predictability of Integrated Mountain Hydroclimate.” Sponsored by BER’s Earth and Environmental Systems Sciences Division (EESSD), the workshop aimed to inform and catalyze EESSD’s growing interests in enhancing predictive understanding of IMHC. Organizers structured the workshop to identify (1) knowledge gaps, (2) observational and modeling challenges, (3) short-term (1 to 3 years) and long-term (10 years and beyond) research opportunities, and (4) strategies for fostering collaboration and coordination. To address the outstanding challenges of IMHC, the workshop included two sessions organized by disciplinary, cross-disciplinary, and crosscutting science topics. The disciplinary and cross-disciplinary topics focused on essential IMHC elements: atmosphere, terrestrial, and human systems and their interactions. Breakout sessions on disciplinary and cross-disciplinary topics facilitated identification of crosscutting topics and central emerging themes. Session 1 focused on connecting existing DOE investments to accelerate progress related to scientific challenges in understanding mountain hydroclimate. In Session 2, participants further explored key Session 1 takeaways through the lens of multiagency collaborations and coordination.

54 ENVIRONMENTAL SCIENCES↗

A SUBSTRUCTURE INSIDE SPIRAL ARMS, AND A MIRROR IMAGE ACROSS THE GALACTIC MERIDIAN

Though the galactic density wave theory is over 50 years old and is well known in science, it has been difficult to say whether it fits our own Milky Way disk. Here we show a substructure inside the spiral arms. This substructure is reversing with respect to the Galactic Meridian (longitude zero), and crosscuts of the arms at negative longitudes appear as mirror images of crosscuts of the arms at positive longitudes. Four lanes are delineated: a mid-arm (extended {sup 12}CO gas at the mid-arm, H i atoms), an in-between offset by about 100 pc (synchrotron, radio recombination lines), an in-between offset by about 200 pc (masers, colder dust), and an inner edge (hotter dust seen in mid-IR and near-IR)

79 ASTRONOMY AND ASTROPHYSICS↗

NASA Accountability Report

NASA is piloting fiscal year (FY) 1997 Accountability Reports, which streamline and upgrade reporting to Congress and the public. The document presents statements by the NASA administrator, and the Chief Financial Officer, followed by an overview of NASA's organizational structure and the planning and budgeting process. The performance of NASA in four strategic enterprises is reviewed: (1) Space Science, (2) Mission to Planet Earth, (3) Human Exploration and Development of Space, and (4) Aeronautics and Space Transportation Technology. Those areas which support the strategic enterprises are also reviewed in a section called Crosscutting Processes. For each of the four enterprises, there is discussion about the long term goals, the short term objectives and the accomplishments during FY 1997. The Crosscutting Processes section reviews issues and accomplishments relating to human resources, procurement, information technology, physical resources, financial management, small and disadvantaged businesses, and policy and plans. Following the discussion about the individual areas is Management's Discussion and Analysis, about NASA's financial statements. This is followed by a report by an independent commercial auditor and the financial statements.

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NASA Procedures and Guidance 7120.5A: An Overview

The 1998 NASA Strategic Plan states that we are to deliver world-class programs and cutting-edge technology through a revolutionized NASA. Process and requirements must change to insure success in delivering those world-class programs. The 1996 Strategic Management Handbook defines the Agency's crosscutting processes: "Manage Strategically," "Provide Aerospace Products and Capabilities," "Generate Knowledge" and "Communicate Knowledge." The focus of this overview, and for the development of programs and projects, is the "Provide Aerospace Products and Capabilities" process. NASA Policy Document 7120.4A specifies the management system policy for the development and operation of programs and projects. NPG 7120.5A describes the next tier of requirements, integrating those crosscutting processes and process-focused requirements, making sure we can be flexible and efficient, providing the right kind of product delivery that meets user requirements.

Griner, Carolyn S.↗

NASA Performance Report

Introduction NASA's mission is to advance and communicate scientific knowledge and understanding of Earth, the solar system, and the universe; to advance human exploration, use, and development of space; and to research, develop, verify, and transfer advanced aeronautics, space, and related technologies. In support of this mission, NASA has a strategic architecture that consists of four Enterprises supported by four Crosscutting Processes. The Strategic Enterprises are NASA's primary mission areas to include Earth Science, Space Science, Human Exploration and Development of Space, and Aerospace Technology. NASA's Crosscutting Processes are Manage Strategically, Provide Aerospace Products and Capabilities, Generate Knowledge and Communicate Knowledge. The implementation of NASA programs, science, and technology research occurs primarily at our Centers. NASA consists of a Headquarters, nine Centers, and the Jet Propulsion Laboratory, as well as several ancillary installations and offices in the United States and abroad. The nine Centers are as follows: (1) Ames Research Center, (2) Dryden Flight Research Center (DFRC), (3) Glenn Research Center (GRC), (4) Goddard Space Flight Center (GSFC), (5) Johnson Space Center, (6) Kennedy Space Center (KSC), (7) Langley Research Center (LaRC), (8) Marshall Space Flight Center (MSFC), and (9) Stennis Space Center (SSC).

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Quantifying Exact Motions Along Lineaments on Europa

Evaluating the precise motions along lineaments on the surface of Jupiter's icy moon, Europa, is a valuable tool for interpreting the development and history of lineaments of various morphologies. Such morphologies include strike-slip faults, dilational bands, ridges, and convergence zones. However, the exact mode of origin and kinematic behavior of these various lineaments are not obvious based on morphology alone. In fact, the apparent motions implied by displaced crosscut features can provide misleading indications of true motions along lineaments. Identifying the precise motions (combinations of sliding and opening/closing) is critical to the accurate characterization and interpretation of each of these lineament types. Lineaments of interest (i.e., those having displaced relatively older features in some manner) are identified on Galileo spacecraft images and measurements are made of the total offset, the separation, and relative orientations of crosscut features with respect to the lineament of interest. Specifically, by using these measured quantities and a series of trigonometric equations, the precise motions (i.e., dilation, convergence, strike-slip, or a combination of strike-slip and dilation or convergence) can be determined. These measurements are, however, limited by the resolution of the available images. This study focuses on motion analysis techniques for Europan lineaments and the precise characterization of fault-orthogonal and/or strike-slip motion along lineaments of varying morphologies. We highlight potential pitfalls of cursory analyses of motion indicators. For example, lineaments with obvious lateral offsets have typically been identified simply as strike-slip faults. This assumption may actually be incorrect, as fault-orthogonal motions may contribute to apparent lateral displacements (offsets or separations). Also, variability in the amount of fault motion along the trace length should theoretically be identifiable using the outlined technique. Strike-slip faults on Europa have conventionally been presumed to have a constant slip magnitude along their lengths; however, we posit that variable distributions of slip may be common, as is typical along terrestrial strike-slip faults.

Vetter, J. C.↗

NASA Technology Demonstrations Missions Program Overview

The National Aeronautics and Space Administration (NASA) Fiscal Year 2010 (FY10) budget introduced a new strategic plan that placed renewed emphasis on advanced missions beyond Earth orbit. This supports NASA s 2011 strategic goal to create innovative new space technologies for our exploration, science, and economic future. As a result of this focus on undertaking many and more complex missions, NASA placed its attention on a greater investment in technology development, and this shift resulted in the establishment of the Technology Demonstrations Missions (TDM) Program. The TDM Program, within the newly formed NASA Office of the Chief Technologist, supports NASA s grand challenges by providing a steady cadence of advanced space technology demonstrations (Figure 1), allowing the infusion of flexible path capabilities for future exploration. The TDM Program's goal is to mature crosscutting capabilities to flight readiness in support of multiple future space missions, including flight test projects where demonstration is needed before the capability can transition to direct mission The TDM Program has several unique criteria that set it apart from other NASA program offices. For instance, the TDM Office matures a small number of technologies that are of benefit to multiple customers to flight technology readiness level (TRL) 6 through relevant environment testing on a 3-year development schedule. These technologies must be crosscutting, which is defined as technology with potential to benefit multiple mission directorates, other government agencies, or the aerospace industry, and they must capture significant public interest and awareness. These projects will rely heavily on industry partner collaboration, and funding is capped for all elements of the flight test demonstration including planning, hardware development, software development, launch costs, ground operations, and post-test assessments. In order to inspire collaboration across government and industry, more than 70% of the TDM funds will be competitively awarded as a result of yearly calls for proposed flight demonstrators and selected based on possible payoff to NASA, technology maturity, customer interest, cost, and technical risk reduction. This paper will give an overview of the TDM Program s mission and organization, as well as its current status in delivering advanced space technologies that will enable more flexible and robust future missions. It also will provide several examples of missions that fit within these parameters and expected outcomes.

Turner, Susan↗

Proceedings of the NASA Technical Interchange Meeting on Active Optical Systems for Supporting Science, Exploration, and Aeronautics Measurements Needs

Active optical (Laser/Lidar) measurement techniques are critical for the future National Aeronautics and Space Administration (NASA) Earth, Planetary Science, Exploration, and Aeronautics measurements. The latest science decadal surveys recommend a number of missions requiring active optical systems to meet the science measurement objectives and the aeronautics community continues to use Laser/Lidar technologies to meet the aeronautics measurement objectives. With these drivers, the NASA Agency Program Management Council (APMC), chaired by the NASA Associate Administrator, has tasked the NASA Sensors and Instrumentation (S&I) Capability Leadership Team (CLT) Leader to determine if the Agency has the necessary expertise and capabilities to execute successfully the active optical-based systems necessary to make the required measurements for Science, Exploration, and Aeronautics. This NASA Technical Interchange Meeting (TIM) was a forum to exchange perspectives on the current state of the discipline’s technologies and the direction NASA needs to take in the future to raise the Technical Readiness Level (TRL) of the measurement technologies to meet these measurement needs in the applications domains. The information developed at this TIM was used in formulating the Agency-level strategy and solutions for advancing high-risk Laser/Lidar technologies that are not currently being sufficiently planned, developed, or risk-reduced to meet NASA’s mission requirements. Given the crosscutting synergies in critical Active Optical measurements for NASA Science, Exploration, and Aeronautics, a strategic approach is needed to identify areas where NASA should “lead, leverage or collaborate” with existing national and international industries to meet its future needs. The TIM aimed at focusing NASA’s directions to attain the necessary TRLs to meet the Agency-level priority Active Optical measurements in Space and Aeronautics. The TIM presentations and strategic inputs were synthesized by the NASA Active Optical Tiger Team for presentation to the NASA APMC with a suggested strategy to address the Agency’s needs in a crosscutting, synergistic and cost-effective manner.

Singh, Upendra N↗

Demonstrating integration of CBP and ASCEM simulation tools - 15627

DOE-EM is supporting two crosscutting projects to develop software and conduct targeted experiments to enhance performance and risk assessment capabilities: the Cementitious Barriers Partnership (CBP) and the Advanced Simulation Capability for Environmental Management (ASCEM). The CBP is a smaller-scale project of coordinated software development and experimentation focused on cementitious materials. ASCEM is a larger-scale project aimed at developing next-generation, science-based, reactive flow and transport simulation capabilities and supporting modeling tool-sets within a high-performance computing framework to address DOE-EM's waste management and environmental cleanup challenges. Complementary integration of CBP and ASCEM software tool-sets has been demonstrated through a joint simulation of radionuclide release and transport in a representative tank closure scenario. Specialized CBP capabilities for simulating reactive transport in cementitious materials were utilized in a near-field simulation of radionuclide leaching from the engineered system. The high-performance computing (HPC) capabilities of the ASCEM Amanzi simulator were utilized to simulate far-field flow and transport in the natural environment outside the closed tank. The ASCEM flow simulation provided boundary conditions to the CBP near-field model, which in turn provided radionuclide source terms to the ASCEM far-field transport simulation. The joint demonstration illustrates how the two crosscutting projects can be used in a complementary manner to enhance DOE performance and risk assessment. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Wind Energy Technologies Office Multi-Year Program Plan Fiscal Years 2021—2025

WETO's Multi-Year Program Plan outlines the Office’s research priorities and plans through the year 2025. With the objectives of reducing the cost of wind energy, enabling the integration of substantial amounts of wind energy into the evolving national energy system, and creating siting and environmental solutions to reduce environmental impacts, the Plan provides insight into DOE’s wind energy research priorities, and will guide planning and execution of future R&D activities. It is organized in six sections: offshore wind, land-based wind, distributed wind, systems integration, modeling and analysis, and crosscutting initiatives.

17 WIND ENERGY↗

Oxidation of manganese in an ancient aquifer, Kimberley formation, Gale crater, Mars

We report that the Curiosity rover observed high Mn abundances (>25 wt % MnO) in fracture-filling materials that crosscut sandstones in the Kimberley region of Gale crater, Mars. The correlation between Mn and trace metal abundances plus the lack of correlation between Mn and elements such as S, Cl, and C, reveals that these deposits are Mn oxides rather than evaporites or other salts. On Earth, environments that concentrate Mn and deposit Mn minerals require water and highly oxidizing conditions; hence, these findings suggest that similar processes occurred on Mars. In conclusion, based on the strong association between Mn-oxide deposition and evolving atmospheric dioxygen levels on Earth, the presence of these Mn phases on Mars suggests that there was more abundant molecular oxygen within the atmosphere and some groundwaters of ancient Mars than in the present day.

36 MATERIALS SCIENCE↗

Solvent-Free Manufacturing of Lithium-Ion Battery Electrodes via Cold Plasma

Slurry casting has been used to fabricate lithium-ion battery electrodes for decades, which involves toxic and expensive organic solvents followed by high-cost vacuum drying and electrode calendering. This work presents a new manufacturing method using a nonthermal plasma to create inter-particle binding without using any polymeric binding materials, enabling solvent-free manufacturing electrodes with any electrochemistry of choice. The cold-plasma-coating technique enables fabricating electrodes with thickness (>200 μm), high mass loading (>30 mg cm -2 ), high peel strength, and the ability to print lithium-ion batteries in an arbitrary geometry. This crosscutting, chemistry agnostic, platform technology would increase energy density, eliminate the use of solvents, vacuum drying, and calendering processes during production, and reduce manufacturing cost for current and future cell designs. Here, lithium iron phosphate and lithium cobalt oxide were used as examples to demonstrate the efficacy of the cold-plasma-coating technique. It is found that the mechanical peel strength of cold-plasma-coating-manufactured lithium iron phosphate is over an order of magnitude higher than that of slurry-casted lithium iron phosphate electrodes. Full cells assembled with a graphite anode and the cold-plasma-coating-lithium iron phosphate cathode offer highly reversible cycling performance with a capacity retention of 81.6% over 500 cycles. For the highly conductive cathode material lithium cobalt oxide, an areal capacity of 4.2 mAh cm -2 at 0.2 C is attained. We anticipate that this new, highly scalable manufacturing technique will redefine global lithium-ion battery manufacturing providing significantly reduced plant footprints and material costs.

25 ENERGY STORAGE↗

3D pore analysis of gasoline particulate filters using X-ray tomography: impact of coating and ash loading

Since particulate emissions control technologies are dependent on filtration technologies, development of porous materials with optimized pore structures is crucial to improve filtration efficiency and pressure drop across filters. Despite increasing attention to 3D measurements of porous materials, there are few reports of pore structure investigations of diesel/gasoline particulate filters (D/GPFs) using 3D visualization techniques. Here, GPF 3D pore structures were examined using X-ray tomography (XRT) to identify the impacts of catalyst coating or ash loading. Voxel resolution of 2.93 mu m made it impossible to distinguish coating or ash materials from the cordierite substrate or to recognize smaller pores than the voxel resolution. However, pores up to 200 mu m, which are responsible for the most pore volume, were successfully analyzed. Coating and ash loading resulted in lowering average pore diameter, total porosity, and open porosity, as the peak density of pore diameter at 60 mu m decreased, while pores below 20 mu m increased. Also, the visualized closed pores, which were homogeneously distributed throughout the bare filter, tended to get larger from inlet to outlet sides and more likely to be on the surface inlet due to coating and ash loading, indicating gas pathways originally existing in open pores were blocked due to coating and ash loading, leading to increased pressure drop. The ash impact was found to be more noticeable on mid and back positions than on front position. In addition, the investigation of areal porosity along the direction of gas flow suggested that while ash penetration could reach the outlet side as noted from increased closed pore population, most ash particles would be contained up to 150 mu m. Lastly, the 2D crosscut microscopic analysis that requires destructive procedures with the limited examination area could provide underestimation of ash penetration, whereas the 3D XRT analysis seems to provide more accurate information of pore structure changes due to ash loading at different locations.

36 MATERIALS SCIENCE↗

Heterogeneous Creep Deformations and Correlation to Microstructures in Fe-30Cr-3Al Alloys Strengthened by an Fe 2 Nb Laves Phase

We have develooped a new Fe-Cr-Al (FCA) alloy system with good oxidation resistance and creep strength at high temperature. The alloy system is a candidate for use in future fossil-fueled power plants. The creep strength of these alloys at 973 K (700 °C) was found to be comparable with traditional 9 pct Cr ferritic–martensitic steels. A few FCA alloys with general composition of Fe-30Cr-3Al-.2Si-xNb (x = 0, 1, or 2) with a ferrite matrix and Fe 2 Nb-type Laves precipitates were prepared. The detailed microstructural characterization of samples, before and after creep rupture testing, indicated precipitation of the Laves phase within the matrix, Laves phase at the grain boundaries, and a 0.5 to 1.5 μm wide precipitate-free zone (PFZ) parallel to all the grain boundaries. In these alloys, the areal fraction of grain boundary Laves phase and the width of the PFZ controlled the cavitation nucleation and eventual grain boundary ductile failure. Finally, we used a phenomenological model to compare the creep strain rates controlled by the effects of the particles on the dislocations within the grain and at grain boundaries. (The research sponsored by US-DOE, Office of Fossil Energy, the Crosscutting Research Program).

36 MATERIALS SCIENCE↗

Hydration state of calcium sulfates in Gale crater, Mars: Identification of bassanite veins

In-situ analyses reveal the presence of hydrogen within calcium sulfate veins crosscutting the sediments found in Gale crater. Laboratory experiments were performed to calibrate the hydrogen signal measured by laser induced breakdown spectroscopy (LIBS) in a range applicable to martian data. The analyses indicate that all veins targeted so far at Gale consist predominantly of bassanite which most likely formed by dehydration of gypsum. This scenario thus suggests that the percolating water produced gypsum, possibly by hydration of anhydrite in aqueous solution, and remained at temperatures below ~60 °C at that time. Desiccating conditions followed, consistent with a hyperarid climate and favored by burial or impacts. In addition, anhydrite with lesser bassanite has been found by XRD in samples of sediments hosting the veins. Our result suggests bassanite is likely found in the veins and anhydrite may be more common as a fine-grained component within the sediments.

58 GEOSCIENCES↗