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At least 73 records · Page 4

Ensuring Reliable Natural Gas-Fired Generation with Fuel Contracts and Storage - DOE/NETL-2017/1816

This report finds that natural gas-fired power plants purchase fuel both on the spot market and through firm supply contracts; there do not appear to be clear drivers propelling power plants toward one or the other type. Most natural gas-fired power generators are located near major natural gas transmission pipelines, and most natural gas contracts are currently procured on the spot market. Although there is some regional variation in the type of contract used, a strong regional pattern does not emerge. Whether gas prices are higher with spot or firm contracts varies by both region and year. Natural gas prices that push the generators higher in the supply curve would make them less likely to dispatch. Most of the natural gas generators discussed in this report would be unlikely to enter firm contracts if the agreed price would decrease their dispatch frequency. The price points at which these generators would be unlikely to enter a firm contract depends upon the region that the generator is in, and how dependent that region is on natural gas. The Electric Reliability Council of Texas (ERCOT) is more dependent on natural gas than either Eastern Interconnection or Western Interconnection. This report shows that above-ground storage is prohibitively expensive with respect to providing storage for an extended operational fuel reserve comparable to the amount of on-site fuel storage used for coal-fired plants. Further, both pressurized and atmospheric tanks require a significant amount of land for storage, even to support one day’s operation at full output. Underground storage offers the only viable option for 30-day operational storage of natural gas, and that is limited by the location of suitable geologic formations and depleted fields.

01 COAL, LIGNITE, AND PEAT↗

Supplement to M&V Guidelines: Measurement and Verification for Performance-Based Contracts Version 4.0

Measurement and verification (M&V) are key to determining and confirming the continued operation of, and savings associated with, performance-based contracts. The Federal Energy Management Program (FEMP) updates these guidelines to reflect the evolution of M&V to incorporate industry best practices and ensure that savings from these performance-based projects are properly planned, communicated, and realized. FEMP released M&V Guidelines: Measurement and Verification for Federal Energy Projects Version 3.0 in 2008. This document was developed with input from industry-government working groups, previous M&V guideline authors, and national laboratory subject matter experts. The document provided the methods and guidelines, with a focus on federal energy savings performance contracts (ESPCs). When FEMP released M&V Guidelines: Measurement and Verification for Performance-Based Contracts Version 4.0 in 2015, FEMP expanded the intended audience to include anyone (energy managers, procurement officers, and contractors) involved in implementing performance-based contracts. The streamlined M&V Guidelines Version 4.0 provided the procedures and guidelines needed to quantify savings resulting from installing energy-efficient equipment, water conservation, improved operation and maintenance (O&M), renewable energy, and cogeneration projects with a performance-based contract; however, it removed some of the associated details on topics such as developing regression models and sampling plans. The details and information provided in M&V Guidelines v. 3.0 are still pertinent to M&V for performance-based contracts. The objective is to keep FEMP M&V version 4.0 condensed, providing the reference document for specifying M&V methods and procedures and a resource for developing project-specific M&V plans; this supplement provides additional details. The content of this supplement has been updated to include pertinent revisions between M&V version 3.0 and M&V version 4.0 by providing details and updating the content to ensure relevancy.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Chemical and Biological Contract Manufacturing Services: Potential Proliferation Concerns and Impacts on Strategic Trade Controls

The use of contract manufacturing services in the chemical, pharmaceutical, and biotechnology industries has grown significantly in recent years, but the potential for such service providers to be exploited for chemical or biological weapons proliferation has garnered relatively little attention, despite the role of contract manufacturers in the A.Q. Khan nuclear proliferation network. Here, we examine the dual-use potential and global spread of chemical and biological contract manufacturing and their ramifications for related strategic trade controls (STCs). Hundreds of providers of dual-use contract services were found worldwide, but they were primarily located in jurisdictions with comprehensive STC regulations. This then provides some degree of protection against their misuse. However, the results outlined below also suggest that chemical and biological contract manufacturers are a critical community to target for STC outreach activities and efforts to increase industry compliance. Targeted outreach would help prevent contract manufacturing service providers from unwittingly contributing to the production and proliferation of chemical and biological weapons.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

A novel FPCL model producing directional contraction through induction of fibroblast alignment by biphasic pulse direct current electric field

Although parallel alignment of fibroblasts to the tension lines of scar has been evidenced in vivo, how scar contracture generates directional contraction remains largely unclear due to the lack of effective in vitro model. Fibroblast populated collagen lattice (FPCL), a widely used in vitro model, fails to mimic scar contracture since it produces concentric contraction with the random orientation of fibroblast. We hypothesized that a novel FPCL model with fibroblast alignment might produce directional contraction and then simulate scar contracture better. Here, we showed that although direct current electric fields (DCEFs) enabled fibroblasts aligned perpendicularly to the field vector, it also promoted electrotactic migration of fibroblast in FPCL. By contrast, biphasic pulse direct current electric fields (BPDCEFs), featured by reversal of the EF direction periodically, abolished the electrotactic migration, but induced fibroblast alignment in a pulse frequency dependent manner. Specifically, BPDCEF at a pulse frequency of 0.0002 Hz induced fibroblast alignment comparable to that induced by DCEF under the same field strength (300 mV/mm), leading to an enhanced contraction of FPCL along the direction of cell alignment. FPCL pretreated by BPDCEF showed an elliptical contraction whereas it was concentric in control FPCL. Further study revealed that F-actin redistributions acted as a key mechanism for the induction of fibroblasts alignment by BPDCEF. Cytochalasin D, an inhibitor of actin dynamics, abolished F-actins redistribution, and significantly suppressed the fibroblasts alignment and the directional contraction of FPCL. Importantly, BPDCEF significantly increased RhoA activity in fibroblasts, while this response was attenuated by C3 transferase pre-treatment, a potent inhibitor of RhoA, caused F-actin depolymerization and actin filament bundle randomly distributed. Taken together, our study suggests a crucial role for fibroblast orientation in scar contracture, and provides a novel FPCL model that may be feasible and effective for investigating scar contracture in vitro.

60 APPLIED LIFE SCIENCES↗

A Code Generator for High-Performance Tensor Contractions on GPUs

Tensor contractions are higher dimensional generalizations of matrix-matrix multiplication. They form the compute-intensive core for many applications in computational science and data science. Although high-performance library implementations are widely available for dense matrix-matrix multiplication on GPUs, the same is not true for contraction of dense tensors. In this paper, we describe a high- performance GPU code generator for arbitrary tensor contractions. It exploits domain-specific properties about data reuse in tensor contractions to devise an effective code generation schema, coupled with an effective model-driven search to determine parameters for mapping of computation to threads and staging of data through the GPU memory hierarchy. Experimental evaluation using a set of tensor contraction benchmarks demonstrates performance improvement and/or significantly reduced code generation time over other state-of-the-art tensor contraction libraries and code generators.

Kim, Jinsung↗

Effects of axisymmetric contractions on turbulence of various scales

Digitally acquired and processed results from an experimental investigation of grid generated turbulence of various scales through and downstream of nine matched cubic contour contractions ranging in area ratio from 2 to 36, and in length to inlet diameter ratio from 0.25 to 1.50 are reported. An additional contraction with a fifth order contour was also utilized for studying the shape effect. Thirteen homogeneous and nearly isotropic test flow conditions with a range of turbulence intensities, length scales and Reynolds numbers were generated and used to examine the sensitivity of the contractions to upstream turbulence. The extent to which the turbulence is altered by the contraction depends on the incoming turbulence scales, the total strain experienced by the fluid, as well as the contraction ratio and the strain rate. Varying the turbulence integral scale influences the transverse turbulence components more than the streamwise component. In general, the larger the turbulence scale, the lesser the reduction in the turbulence intensity of the transverse components. Best agreement with rapid distortion theory was obtained for large scale turbulence, where viscous decay over the contraction length was negligible, or when a first order correction for viscous decay was applied to the results.

Tan-Atichat, J.↗

How To Determine and Verify Operations and Maintenance Savings in Energy Savings Performance Contracts

Operations and maintenance (O&M) savings frequently occur in energy savings performance contracts (ESPCs). During FY 2022, 37% of reported annual cost savings for projects awarded under the U.S. Department of Energy (DOE) ESPC indefinite delivery indefinite quantity (IDIQ) contracts and in the performance period were due to O&M or other energy- and/or water-related cost savings, with the balance (63%) from utility cost savings (i.e., energy or water cost savings). Sometimes the energy- and water-related cost savings are acknowledged and included in payments within ESPCs; other times, for various reasons, they are not. As presented in this guide, FEMP recommends including energy- and water-related cost savings that are O&M (including related repair and replacement) savings in the financial aspects of an ESPC, to the extent such savings can be documented. Inclusion of these savings will help augment project scopes and/or lower interest costs (by shortening financing terms). However, there is a burden of proof as to what constitutes acceptability in O&M savings that needs to be carefully considered and documented in individual projects. Beyond promoting a key tenet used in U.S. federal performance contracting—that savings must be from actual budgets and therefore based on the level of O&M that is actually occurring, not what should have been performed—FEMP also recommends good practice in establishing and documenting O&M baselines, formulating the rationale for baseline adjustments during the performance period, and conducting ongoing verification activities. This document concludes with five examples of how O&M savings may be handled, in situations ranging from the partial displacement of O&M contracts to consolidation and “virtualization” of servers in data centers. A key theme that permeates this guide is the importance of thoroughly documenting all conditions and assumptions used in the development of and accounting for O&M costs and savings throughout the ESPC life cycle, from baseline-setting to measurement and verification (M&V) of the savings during each year of the performance period. Doing so not only prevents internal claims of non-performance (especially in the case of staff turnover during the contract term), but also simplifies ordering agency and energy service company (ESCO) response in the event of scrutiny from oversight organizations, such as government audits. While this guide focuses on federal ESPCs, it may also be applicable when O&M savings are included in utility energy service contracts (UESCs) and non-federal ESPCs.

Voss, Phil↗

Pressure drop in a prototypical 3D magnetohydrodynamic flow across contraction of a fusion blanket manifold

Predicting 3D magnetohydrodynamic (MHD) pressure losses associated with liquid metal flows in complex geometry ducts is required to design breeding blankets for fusion reactors. Of such components, manifolds exhibit major pressure losses. Recent correlations [T. Rhodeset al. Magnetohydrodynamic pressure drop and flow balancing of liquid metal flow in a prototypic fusion blanket manifold. Phys. Fluids. 2018; 30: 057101.] demonstrate promise for predicting pressure drops in electrically insulated inlet manifolds. In the present work, the extend to which these correlations can be applied to outlet manifolds, which feature sudden contractions, is investigated in both viscous-electromagnetic (VE) and inertial-electromagnetic (IE) regimes for Reynolds numbers 50 < Re < 1500, Hartmann numbers 2500 < Ha < 5475, and expansion/contraction ratio 10. Numerical computations have shown that the MHD pressure drops in the eutectic lead-lithium (PbLi) flows in contractions are almost identical to those in the flows featuring expansion with slightly higher magnitudes in the contraction cases. The small discripancy in the MHD pressure drop between contractions and expansions (<8%) suggests that the earlier obtained correlations for the 3D MHD pressure drop in a duct flow with a sudden expansion can also be applied to flows with a sudden contraction.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DETECTING ADIABATIC CONTRACTION IN ROTATION CURVES

We examine the structure of adiabatically contracted Einasto profiles, using the prescriptions of Blumenthal et al. and Gnedin et al., and its impact on rotation curves. Adiabatically contracted halos display a central power index of {approx}0.7 {+-} 0.1 for nearly all values of the Einasto shape parameter {alpha}, and are well fit inside {approx}< 1 kpc by double power laws. However, attempts to fit exponential disk and uncontracted halos to adiabatically contracted rotation curves yield disk masses and central power indices that are too large. We also determine whether or not the rotation curve of NGC 6503 displays evidence of adiabatic contraction using previously published bar formation constraints, and find that NGC 6503 most likely has a minimally contracted halo. However, this conclusion depends on the correct choice of circular velocity curve.

79 ASTRONOMY AND ASTROPHYSICS↗

CAST: Contraction Algorithm for Symmetric Tensors

Tensor contractions represent the most compute-intensive core kernels in ab initio computational quantum chemistry and nuclear physics. Symmetries in these tensor contractions makes them difficult to load balance and scale to large distributed systems. In this paper, we develop an efficient and scalable algorithm to contract symmetric tensors. We introduce a novel approach that avoids data redistribution in contracting symmetric tensors while also avoiding redundant storage and maintaining load balance. We present experimental results on two parallel supercomputers for several symmetric contractions that appear in the CCSD quantum chemistry method. We also present a novel approach to tensor redistribution that can take advantage of parallel hyperplanes when the initial distribution has replicated dimensions, and use collective broadcast when the final distribution has replicated dimensions, making the algorithm very efficient.

distributed memory↗

A Framework for Load Balancing of Tensor Contraction Expressions via Dynamic Task Partitioning

In this paper, we introduce the Dynamic Load-balanced Tensor Contractions (DLTC), a domain-specific library for efficient task parallel execution of tensor contraction expressions, a class of computation encountered in quantum chemistry and physics. Our framework decomposes each contraction into smaller unit of tasks, represented by an abstraction referred to as iterators. We exploit an extra level of parallelism by having tasks across independent contractions executed concurrently through a dynamic load balancing run- time. We demonstrate the improved performance, scalability, and flexibility for the computation of tensor contraction expressions on parallel computers using examples from coupled cluster methods.

Tensor contraction, domain-specific language, dyna↗

Salt Waste Processing Facility Project (SWPF) project management improvements: Working under a cost cap contract - 15523

The Salt Waste Processing Facility (SWPF), located at the Savannah River Site (SRS) in Aiken, South Carolina, is a multi-billion dollar LRW processing facility that represents the keystone for the U.S. Department of Energy (DOE)-EM clean-up mission at SRS. In June 2013, DOE and Parsons agreed to Contract Modification 0116 that definitized the remaining work to achieve Construction Complete with a target schedule and a cost cap contract structure. The SWPF project is currently 85 percent complete with construction, and approximately 10 percent complete with commissioning. To date there have been numerous lessons learned with regard to contract and project management, procurement, construction, safety and quality assurance approaches (both good practices and mistakes). These lessons learned are considered to be of significant value in improving the state of major project execution within the DOE-EM clean-up program as well as to the wider DOE complex. An overview of the current SWPF project status is provided, along with challenges associated with operating under a cost cap environment within a cost-plus contract structure. Key lessons learned will be discussed including contract management, baseline development and acceptance under DOE O 413.3, Program and Project Management for the Acquisition of Capital Assets requirements, cost and schedule control, change management and risk strategies. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Session 059 - Panel: Small Business Procurement and Contracting Opportunities within the US DOE Complex and USACE FUSRAP Sites (R1.7)

This panel session focused on small business procurement and contracting opportunities within the DOE Complex and USACE FUSRAP Sites. The federal government encourages prime contractors to obtain goods and services from small and disadvantaged businesses (Tier 2) and often tie these goals to contract award fee. Goods and services being considered for these procurements include decontamination and decommissioning, remediation, transportation and disposal of radioactive waste, health physics, emergency response planning and training, lab services, R and D products, waste treatment, maintenance, A/E and professional consulting. Panelists with presentations: Small Business Procurement and Contracting Opportunities within the US DOE Complex and USACE FUSRAP Program (Aaron Deckard; Subcontracting Opportunities with the DOE Primes (William Badger); Bechtel National, Inc. Small Business Opportunities (Lisa Tribuce-Leoung Tat); Small Business Procurement and Contracting Opportunities (Gina Joiner); Small Business Procurement and Contracting Opportunities - Flour (Katy Burnau); Environmental WORK, Formerly Utilized Sites Remedial Action Program (FUSRAP) (John Busse)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Relativity symmetries and Lie algebra contractions

We revisit the notion of possible relativity or kinematic symmetries mutually connected through Lie algebra contractions under a new perspective on what constitutes a relativity symmetry. Contractions of an SO(m,n) symmetry as an isometry on an m+n dimensional geometric arena which generalizes the notion of spacetime are discussed systematically. One of the key results is five different contractions of a Galilean-type symmetry G(m,n) preserving a symmetry of the same type at dimension m+n−1, e.g. a G(m,n−1), together with the coset space representations that correspond to the usual physical picture. Most of the results are explicitly illustrated through the example of symmetries obtained from the contraction of SO(2,4), which is the particular case for our interest on the physics side as the proposed relativity symmetry for “quantum spacetime”. The contractions from G(1,3) may be relevant to real physics.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Intrinsic activation energies for ring contraction of allylic cations in zeolites

Cyclic carbocations are important intermediates in zeolite-catalyzed chemistries such as methanol-to-hydrocarbons conversion, naphthenes ring opening, or coke formation. While information about their thermodynamic stability exists, little is known about the kinetics of formation and transformation of cyclic carbocations in zeolites. To fill this knowledge gap, ring contraction of the 1,3,5,5-tetramethylcyclohexenyl cation (C 10 H 17 + ), a representative of 6-membered ring allylic cations, was investigated by in situ UV–vis and IR spectroscopy. Protonic forms of zeolites served as catalysts, at temperatures from 80 °C to 135 °C. Significant oligomerization and hydride transfer in BEA and FAU hampered kinetics analysis, whereas ring contraction dominated in the channels of MOR. The reactant cation, characterized by an electronic absorption at 314 nm and an allylic stretch at 1549 cm −1 , contracted to both a 1,3-alkyl-substituted cyclopentenyl cation (287 nm and 1506 cm −1 ) and a 1,2,3-alkyl-substituted cyclopentenyl cation (297 nm and 1489 cm −1 ). Collection of time-resolved IR spectra and fitting of the intensities with various kinetic models revealed a third transformation, which is expected from thermodynamics: the 1,3-alkyl-substituted cyclopentenyl cation isomerizes to the 1,2,3-alkyl-substituted cyclopentenyl cation. Series of IR spectra recorded at different temperatures delivered intrinsic activation enthalpies (entropies) in MOR of 67 ± 2 kJ mol −1 (−130 ± 6 J mol −1 K −1 ) and 90 ± 3 kJ mol −1 (−70 ± 8 J mol −1 K −1 ) for the contraction to 1,3- and 1,2,3-substituted species, and of 88 ± 5 kJ mol −1 (−84 ± 12 J mol −1 K −1 ) for the isomerization. The findings characterize one path – via contraction of larger rings – to different cyclopentenyl species in zeolites; and the associated, moderate activation energies suggest such transformations contribute to many complex hydrocarbon reaction networks.

Acid catalysis↗

A new computational framework for spinor-based relativistic exact two-component calculations using contracted basis functions

Here, a new computational framework for spinor-based relativistic exact two-component (X2C) calculations is developed using contracted basis sets with a spin–orbit contraction scheme. Generally contracted, j-adapted basis sets of p-block elements using primitive functions in the correlation-consistent basis sets are constructed for the X2C Hamiltonian with atomic mean-field spin–orbit integrals (the X2CAMF scheme). The contraction coefficients are taken from atomic X2CAMF Hartree–Fock spinors, thereby following the simple concept of a linear combination of atomic orbitals. Benchmark calculations of spin–orbit splittings, equilibrium bond lengths, and harmonic vibrational frequencies demonstrate the accuracy and efficacy of the j-adapted spin–orbit contraction scheme.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Energy Storage Financing: Advancing Contracting in Energy Storage

The lack of standard financing contracts and supporting documents is inhibiting the growth of the energy storage industry. A number of firms are actively developing proprietary contract structures, resulting in a variety of unique attributes. This leaves the market disjointed for 3 rd party financing groups looking to scale their lending. Lack of commonality and harmonization between developer and lenders raises project execution costs and causes delays in financing. Of special concern, projects based on emerging technologies are finding an increasing uphill climb for equal consideration by developers and lenders, leaving their potential commercialization in peril. This study will evaluate the development of standardi7ed contracts to reduce the cost and contract approval time, learning from success in renewable energy project development. The goal of this study is to determine the key requirements for standard contracts in the emerging energy storage market, and suggest avenues for possible industry led development.

25 ENERGY STORAGE↗

Case Studies in Leveraging Performance Contracts for Resilience Projects

The resilience of federal facilities has become increasingly important among lawmakers, agency leadership, and the American public as high impact natural hazards occur more frequently over time. Resilience is broadly defined as the ability of a federal facility to withstand, respond to, and recover rapidly from disruptions to maintain critical functions. The Department of Energy (DOE) Federal Energy Management Program (FEMP) was codified to facilitate the strengthening of federal energy and water efficiency and resilience. Performance contracting is one of the mechanisms through which federal agencies can finance projects at their facilities, but resilience improvement measures do not always result in utility cost savings, which are the primary driver behind performance contracts. This report provides example cases where performance contracts, specifically energy savings performance contracts (ESPC) or utility energy service contracts (UESCs), were used to implement a resilience measure at a federal facility.

99 GENERAL AND MISCELLANEOUS↗