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At least 73 records · Page 4

Demonstrating non-isothermal vacuum membrane air dehumidification for efficient next-generation air conditioning

Vacuum membrane air dehumidification has gained significant interest in recent years as a highly efficient means of air dehumidification. Prior theoretical modeling work by the authors introduced the Active Membrane Energy Exchanger (AMX) concept, which combines active heat exchange and vacuum membrane dehumidification into one non-isothermal system, and found that it could outperform other air conditioning technologies under many conditions. However, no experimental literature exists on combining active heat exchangers and vacuum membrane dehumidification. Here, the goal of the present study is to evaluate the dehumidification (mass transfer) performance of the AMX concept relative to isothermal membrane dehumidification through three main methodologies: (1) membrane material-level characterization, (2) experimental prototype development and testing, and (3) computational fluid dynamics (CFD) simulations. The dense membranes used in this work showed up to a 40% increase in water vapor permeance at cooler temperatures, and the prototype system showed up to a 6% increase in humidity removal when the air was simultaneously cooled. Furthermore, the membrane module-integrated heat exchange tubes provided additional mixing and turbulence, leading to a 4–8% increase in humidity removal. The upper limit coefficient of performance was equal to approximately 2.2, necessitating advanced system designs to improve efficiency. This study is the first to highlight that combining the cooling and vacuum dehumidification processes can improve dehumidification performance.

30 DIRECT ENERGY CONVERSION↗

Heating performance of a vapor compression heat pump cascaded with a thermoelectric heat pump

Air source heat pumps (ASHPs) are widely utilized for heating and cooling in residential buildings; however, their effectiveness in heating mode is compromised during extreme weather conditions. Extensive research endeavors have been undertaken to develop, test, and assess a cost-effective vapor compression ASHP suitable for cold climate regions. Further, this study takes an innovative approach by developing component and system prototypes for a cold climate heat pump. This design combines a thermoelectric heat pump (TEHP) with a traditional residential split ASHP to augment heating capacity in low ambient temperature conditions. The component and system prototypes underwent experimental testing in the psychrometric chambers. The experimental findings revealed a 13.6% to 13.7% increase in total heat pump heating capacity, accompanied by a 3.1% to 5.0% decrease in the coefficient of performance (COP) at ambient temperatures of -15°C and -19°C, when compared to the original ASHP. The COP of the TEHP is relatively constant, ranging from 1.63 to 1.76. This prototype offers a solution to address the challenges associated with reduced heat pump capacity at low ambient temperatures. The experimental results indicated that the lower the ambient temperature, thermoelectric heat pump auxiliary heating can increase the heating efficiency 60% in comparison to electric resistance.

42 ENGINEERING↗

Experimental Investigation on Cooling performance of A Thermoelectric Freezer

Thermoelectric heat pumps (TEHPs) have found widespread use in the electronics cooling industry and portable refrigerators. However, there has been a lack of extensive research on the application of TEHPs in low-temperature refrigeration settings. To address this gap, various configurations of TEHPs were fabricated to assess their suitability for freezer applications. Key parameters such as cooling capacity and system performance of the TEHPs were crucial in evaluating these configurations. Three configurations, each with different numbers of cooling units and fan arrangements, were tested using a 300-liter freezer prototype under typical room conditions (21°C). A cooling unit is comprised of two-stage thermoelectric modules, an aluminum plate fin heat exchanger sink with fans positioned either on top or directing airflow through the center, and a cooling block with circulating icy water for heat dissipation. Across all configurations, the minimum temperature inside the freezer cabinet reached -16.0°C. The cooling capacity peaked at 74.7 W, with the thermoelectric coefficient of performance (COP) reaching a maximum of 0.45. System COP ranged from 0.23 to 0.28. Minimum TE power consumption was recorded at 138.8 W, with TE system power consumption at 174.4 W, indicating feasibility for practical residential freezer applications. This investigation lays the foundation for integrating TE freezers with ice thermal storage systems.

Hu, Yifeng↗

Technology Development and Field Monitoring in nZEB - US Country report IEA HPT Annex 49 Task 3

The International Energy Agency (IEA) Heat Pumping Technologies (HPT) Annex 49, “Design and Integration of Heat Pumps for Nearly Zero Energy Buildings,” deals with the application of heat pumps (HPs) as a core component of the HVAC system for nearly or net-zero energy buildings. This report covers the Task 3 activities of the US team. Three institutions are involved on the US team and have worked on the following projects. 1) Oak Ridge National Laboratory (ORNL) summarized development activities since the conclusion of IEA HPT Annex 40 for several integrated HP (IHP) systems - electric ground-source IHP and air-source IHP versions and engine-driven AS-IHP version. 2) The University of Maryland partnered with ORNL and Blue Bear Management to develop a personal cooling device called RoCo that can provide personalized conditioned air to occupants in inadequately or unconditioned environments. With RoCo, building facility management can elevate the HVAC thermostat settings without compromising occupants’ thermal comfort. Researchers have found that a 4°F increase in thermostat settings can save 12–30% energy savings. Therefore, RoCo is a promising technology that can help reduce building energy consumption and facilitate achievement of net-zero energy building performance. 3) The National Institute of Standards and Technology (NIST) is working on a field study effort on the NIST Net-Zero Energy Residential Test Facility. Two air-source split-system HPs were installed in a residential, net-zero energy home that was constructed as a laboratory on the NIST campus in Gaithersburg, Maryland. The first HP was a two-stage, 7 kW (2 ton), 15.8 seasonal energy efficiency ratio (SEER), 9.05 heating seasonal performance factor (HSPF) conventionally ducted system; the second HP was a variable-speed, 10.6 kW (3 ton), 14 SEER, 8.35 HSPF, high-velocity ducted system. These two systems operated side by side, using separate supply ducts and a common return duct, on a weekly alternating schedule to condition the home that was operated with very consistent simulated thermal loads. The team wanted to determine whether the high-velocity system could provide comparable energy-use efficiency to the conventional system. The results of this study showed that it did meet the required loads and had slightly greater efficiency; the average cooling coefficient of performance (COP) was (0.40 ± 0.11) higher, and the average heating COP was statistically equal. A new firmware was provided at the end of the heating season that greatly improved the performance of the high-velocity system; its average heating COP went from (1.8 ± 0.9) to (2.5 ± 1.1) at a 95% confidence level. The new firmware heating COP averaged (1.05 ± 0.23) higher than the old firmware over the same outdoor temperatures. The defrost performance is very different for these two systems, yet they consumed equivalent energy per HDD. The conventional system uses a timed-initiate, temperature-terminate algorithm with auxiliary electric resistive heating, whereas the high-velocity system uses calculated evaporator parameters with a hot-gas bypass before a full reverse-cycle defrost with no supplementary resistive heat.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Field Validation of Air-Source Heat Pumps for Cold Climates

Heating energy is the largest end-use for U.S. residential buildings accounting for approximately one-third of residential building energy consumption (EIA 2021). Historically, air-source heat pumps have been limited to temperate climates because of subpar performance at extremely cold outdoor air temperatures. However, recent advances to cold-climate air-source heat pump technology, which typically rely on inverter-driven, variable-speed compressors and variable-speed fans, have significantly improved low-temperature heat pump performance enabling the technology to save energy for many homes in cold climates. The primary objective of this project was to measure in-field performance of centrally ducted, variable-capacity air-source heat pumps in cold climates to validate performance and develop field-based performance maps. The project focused on quantifying heat pump performance at cold temperatures. The sites identified for the study were primarily located in the Northwest United States since homes in the region tend to have all-electric space heating systems and high-efficiency heat pumps have been incentivized in the region for several years. NREL partnered with Ecotope, Inc., a small energy consulting firm located in Seattle, WA, for site recruitment, monitoring equipment installation, data quality management. All the sites included in the study had previously installed a high-efficiency, central heat pump system. One site was in a Denver, CO suburb, which was the only dual fuel heat pump in the study. We used airside and power measurements, collected at 5-second intervals, to quantify heat pump capacity, coefficient of performance (COP), and auxiliary heater energy consumption. We developed algorithms to automatically determine the heat pump operating mode including defrost and auxiliary heating operation. A whole-house thermal and duct audit was completed during the initial site visit to estimate winter heating loads and assess heat pump sizing. Whole-home heating design loads were calculated at ASHRAE 99% design temperatures and compared to manufacturer-reported maximum capacities to assess the heat pump sizing at each site.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Decarbonization of Residential Building Energy Supply: Impact of Cogeneration System Performance on Energy, Environment, and Economics

Electrical and thermal loads of residential buildings present a unique opportunity for onsite power generation, and concomitant thermal energy generation, storage, and utilization, to decrease primary energy consumption and carbon dioxide intensity. This approach also improves resiliency and ability to address peak load burden effectively. Demand response programs and grid-interactive buildings are also essential to meet the energy needs of the 21st century while addressing climate impact. Given the significance of the scale of building energy consumption, this study investigates how cogeneration systems influence the primary energy consumption and carbon footprint in residential buildings. The impact of onsite power generation capacity, its electrical and thermal efficiency, and its cost, on total primary energy consumption, equivalent carbon dioxide emissions, operating expenditure, and, most importantly, thermal and electrical energy balance, is presented. The conditions at which a cogeneration approach loses its advantage as an energy efficient residential resource are identified as a function of electrical grid’s carbon footprint and primary energy efficiency. Compared to a heat pump heating system with a coefficient of performance (COP) of three, a 0.5 kW cogeneration system with 40% electrical efficiency is shown to lose its environmental benefit if the electrical grid’s carbon dioxide intensity falls below 0.4 kg CO 2 per kWh electricity.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Experimental characterization of a triply periodic minimal surface PCM-to-air thermal energy storage device

Here, the expansion of energy production has intensified research into thermal energy storage (TES) to manage variability and improve system efficiency. Heat exchanger design is critical to achieving high power densities in TES systems. This study presents a high-surface-area phase change material (PCM)-to-air heat exchanger fabricated via resin-based stereolithography with a novel gyroid-based geometry tailored for enhanced performance. Material properties of the commercial PCM and resin were characterized using analytical techniques. A controlled air loop was used to evaluate heat transfer and pressure drop at various flow rates and inlet temperatures. Results show a strong dependence on the inlet temperature difference (ΔT) relative to the PCM melting point. During charging at the highest flow rate, increasing the inlet air temperature from ΔT = 5 °C to 20 °C above the melting point increased the average heat transfer rate by 187%. During discharging, decreasing the inlet temperature by the same ΔT below the melting point led to a 232% increase. Notably, the high-surface-area design enabled nearly symmetric charging and discharging behavior, a novel result for PCM-based TES systems which are often restricted by natural convection and other effects. The overall heat transfer coefficient was calculated and compared to values from standard design correlations. The maximum thermal effectiveness reached 95% at ΔT = 20 °C and a moderate flow rate of 34 m 3 /h. Peak coefficients of performance (COP) of 7 during charging and 6.4 during discharging were observed at ΔT = 20 °C and a low flow rate of 20 m 3 /h. These results demonstrate the viability of additively manufactured geometries for advanced TES applications.

25 ENERGY STORAGE↗

Energy characteristics of multi-chiller load distribution algorithms in a large office building

Here, this study evaluates the energy efficiency of multi-chiller systems in large office buildings, focusing on their optimization across various climate zones as defined by ASHRAE. Using EnergyPlus for simulations, the research examines five different load distribution algorithms in multi-chiller systems that range from one to ten chillers, aiming to understand their effectiveness in 15 distinct climate zones. The primary objectives of the study include identifying the energy efficiency of multi-chiller systems in each climate zone, determining the appropriate number of chillers for each zone, and evaluating the performance of the load distribution algorithms. Based on the U.S. Department of Energy’s commercial building model, the results suggest that multi-chiller systems can significantly reduce cooling energy consumption in various climates. Among the algorithms evaluated, the Sequential Uniform Part Load Ratio (SUPLR) algorithm demonstrates notable efficiency, especially in the 4A climate zone (Baltimore), where it achieves substantial energy savings. Applying the SUPLR algorithm in a multi-chiller setup with four chillers in this zone leads to an estimated 24.5 % reduction in energy usage, equivalent to 183 MW annually. The research indicates that a range of 3 to 5 chillers is typically optimal for most climate zones. In-depth analysis in the 4A climate zone highlights the importance of minimizing operation hours at low Part Load Ratios (PLR) to ensure that chillers operate at a high Coefficient of Performance (COP). This strategy underscores the potential of well-designed multi-chiller systems to reduce cooling energy demand, particularly in climates with transitional seasons. This study provides an overview of the energy-saving potential of multi-chiller systems, applicable across a variety of climatic scenarios.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Development of a water source heat pump hardware-in-the-loop (HIL) testing facility for smart building applications

Over the last decade, the global fight against climate change through electrification has led to an increase in research on building heating, ventilation, and air conditioning (HVAC) systems that utilize intelligent control algorithms to provide demand-side grid service while maintaining the thermal comfort of building occupants. As the pivotalpoint between building electricity consumption and indoor thermal comfort, high-efficiency electrical heatpumps are at the center of these emerging studies, and various grid-interactive and occupant-comfort control algorithms have been developed for them. The impact of these algorithms on the heatpump operation andperformance under different weather, building load, and grid requests calls for investigation and verification via experimental tests with actual heat pumps integrated with real-time building and grid responses. This study presents a Water-Source Heat Pump Hardware-in-The-Loop (HIL) Test Facility developed with the capability to perform such tests. The hardware configuration for this testfacility introduces a hydronic system that emulates the conditions for the heat pump water-side, and a duct system that emulates conditions for the heat pump airside. Both data acquisition and emulator control are implemented through the National Instruments (NI) LabVIEW software running on an NI PXIplatform. The HIL mechanism based on the hardware-software integration that allows the testbed to communicate with a generic simulation environment is also discussed. Currently, the test facility setup includes a single heatpump and virtual building model in EnergyPlus coupled with an occupant behavioral model in MATLAB. Preliminary test results of the current setup demonstrate the building load emulator's ability to track the simulated gone temperature with a Root Mean Square Deviation (RSME) below 0.12°C (0.216°F). An uncertainty analysis based on sensor accuracies shows that the heat pump coefficient of performance (COP) can be measured with a relative uncertainty of 10.4% in cooling and 3.7% in heating. Apartfrom the current testing on a single heat pump, the test facility also provides the flexibility to include additional heat pumps to form a heat pump cluster, as well as coupling the heat pump with active thermal storage to provide enhanced demandflexibility.

Calfa, Caleb↗

Large room-temperature elastocaloric effect in a bulk polycrystalline Ni-Ti-Cu-Co alloy with low isothermal stress hysteresis

Creation of high-performance advanced elastocaloric materials is essential for the execution of elastocaloric refrigeration that can be an environment-friendly and high-efficiency substitute for the widely used traditional vapor-compression cooling technology. Here we have developed a bulk polycrystalline Ni-Ti-Cu-Co shape memory alloy exhibiting large elastocaloric effect, low stress hysteresis and room temperature working temperature, all of which are of great importance to and urgently demanded for high-efficiency room-temperature elastocaloric refrigeration. This newly developed (Ni 42.5 Ti 50 Cu 7.5 ) 99 Co 1 alloy shows a large room-temperature elastocaloric effect with directly measured adiabatic temperature change up to -14.4 K during unloading. The stress hysteresis of the isothermal superelastic stress-strain curve is as low as 60 MPa when the maximum tensile strain is 2.7%. Owing to the large elastocaloric effect and low stress hysteresis, a very high coefficient of performance up to 19 is achieved on the material level. This newly developed (Ni 42.5 Ti 50 Cu 7.5 ) 99 Co 1 alloy is a robust candidate for efficient elastocaloric refrigeration. Advanced in-situ synchrotron high-energy X-ray diffraction technique was employed to reveal the phase transformation sequence and to accurately determine the crystal structure of different phases, based on which the lattice compatibility between the transforming phases was evaluated and the phase transformation strain was predicted, providing in-depth fundamental understanding of the martensitic transformation in this newly developed alloy. This work could be useful for designing high-performance elastocaloric materials for solid-state cooling applications.

36 MATERIALS SCIENCE↗

Comparative Analysis of HEATNETS for Geothermal Network Performance: Preprint

Thermal energy networks (TENs), also known as 5th generation district energy systems, or more specifically geothermal networks when exchanging heat with geothermal boreholes, are an important technology for decarbonization. In these networks an ambient loop connects buildings and thermal sources, such as a borehole field, to exchange energy and maintain a desired loop temperature. Water-source heat pumps are used at the buildings to connect to the ambient or thermal loop to meet to the building heating and cooling loads and maintain comfort. A semi-transient, reduced-order technical model and techno-economic model, called HEATNETS, has been developed at NREL that captures the flow of energy around a TEN. In this work, a comparison of the HEATNETS technical model and a well-known coding platform used for modeling geothermal networks, TRNSYS, has been completed for a proposed geothermal network as a verification process. Hourly data provided from the TRNSYS simulation included building loads, pumping power, heat pump power, temperature entering and leaving the borehole field, and mass flow rates. The hourly borehole temperatures were used to create a linear regression model utilized in HEATNETS to estimate the borehole field heat exchange. The building loads and mass flow rates were direct inputs to HEATNETS while the pumping power, heat pump power, borehole temperatures, and coefficients of performance were all simulated and calculated by HEATNETS, allowing for direct comparison of the thermal energy transfer, rather than also comparing control systems responses. HEATNETS considers the full process from design inputs to economic outputs and can provide modeling options for high-level initial system design and operational optimization. This study shows that HEATNETS, while not intended to replace other modeling tools, can be a unique modeling tool for the performance of a full geothermal network system.

15 GEOTHERMAL ENERGY↗

Comparative Analysis of HEATNETS for Geothermal Network Performance

Thermal energy networks (TENs), also known as 5th generation district energy systems, or more specifically geothermal networks when exchanging heat with geothermal boreholes, are an important technology for decarbonization. In these networks an ambient loop connects buildings and thermal sources, such as a borehole field, to exchange energy and maintain a desired loop temperature. Water-source heat pumps are used at the buildings to connect to the ambient or thermal loop to meet to the building heating and cooling loads and maintain comfort. A semi-transient, reduced-order technical model and techno-economic model, called HEATNETS, has been developed at NREL that captures the flow of energy around a TEN. In this work, a comparison of the HEATNETS technical model and a well-known coding platform used for modeling geothermal networks, TRNSYS, has been completed for a proposed geothermal network as a verification and validation process. Hourly data provided from the TRNSYS simulation included building loads, pumping power, heat pump power, temperature entering and leaving the borehole field, and mass flow rates. The hourly borehole temperatures were used to create a linear regression model utilized in HEATNETS to estimate the borehole field heat exchange. The building loads and mass flow rates were direct inputs to HEATNETS while the pumping power, heat pump power, borehole temperatures, and coefficients of performance were all simulated and calculated by HEATNETS, allowing for direct comparison of the thermal energy transfer HEATNETS considers the full process from design inputs to economic outputs and can provide modeling options for high-level initial system design and operational optimization. This study focuses on a validation of HEATNETS using results from TRNSYS. HEATNETS is not intended to replace other modeling tools, but this work demonstrates, via a comparison with an industry standard code, that HEATNETS can be a unique, high-level and rapid modeling tool for estimating the performance of a full geothermal network system.

15 GEOTHERMAL ENERGY↗

Cost-Optimized Cold Climate Heat Pump Development and Field Test

Cold climate heat pumps (CCHPs) expand the heat pump market to climates where heating demand is dominant. They can achieve more than 70% energy savings compared with electric resistance heating and operate at lower cost than using tank-stored propane to fuel a furnace. A high-efficiency heat pump with a heating seasonal performance factor (HSPF)—as defined by the Air-Conditioning, Heating, and Refrigeration Institute (AHRI 2008)—greater than 10.0 would be more efficient than gas heating in terms of source energy. However, developing a cost-effective CCHP involves some challenges. A typical single-speed, air-source heat pump (ASHP) with an HSPF of 7.7 Btu/Wh does not work well under cold outdoor temperature conditions typical of cold climate locations for four major reasons: 1. Discharge temperature is too high—The low suction pressure and high compression pressure ratio at low ambient temperatures causes high compressor discharge temperatures in excess of the maximum limit for many of the compressors on the market. Furthermore, system charge of a heat pump is usually optimized in the cooling mode, which leads to overcharge conditions in the heating mode, further increasing the discharge temperature. 2. Heating capacity is insufficient if sized to meet the building design cooling load— Heating capacity of a single-speed heat pump decreases with ambient temperature. The heating capacity at -13°F (-25°C) typically decreases to 20%–40% of the rated heating capacity at 47°F (8.3°C) (~equivalent to the rated cooling capacity at 95°F [35°C]). Therefore, a single-speed heat pump, typically sized to match the building design cooling load, cannot provide adequate heating capacity to match the building heating load at low ambient temperatures. The capacity deficit is filled by inefficient resistance heat, thus lowering the system efficiency and significantly increasing power demand. 3. Cyclic loss is significant if sized to meet the building design heating load—If a single-speed heat pump is sized to meet the heating load, it will be significantly oversized relative to the cooling load in many cold climates. This will cause excessive on/off cyclic loss during the cooling and heating operations at moderately low ambient temperatures. Thus, capacity modulation capability (e.g., using a variable-speed or multi-stage compressor) is necessary for a CCHP, which uses its full capacity to meet the peak heating load and partial capacity to meet the cooling and part-load heating loads. 4. Coefficient of performance (COP) is low—Heating COP degrades significantly at low ambient temperatures owing to the large temperature difference between the heat source and sink. A target CCHP should be sized to meet the building design heating load while minimizing the cyclic loss for the cooling and heating operations at moderate ambient temperatures.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Mechanical and Electrochemical Implications of Drying Temperature on Lithium‐Ion Battery Electrodes

Abstract Lithium‐ion battery (LIB) electrodes are typically produced with n‐methyl‐2‐pyrrolidone, a toxic solvent that is a known carcinogen and reproductive hazard. Accordingly, aqueous processing has been an expanding area of research interest in the field of LIB manufacturing. Although aqueous processing has been widely successful in anode processing, serious challenges remain in processing the cathode. In this work, the drying mechanics of cathode processed with both solvents is investigated though implementation of a chemical‐engineering‐based model to better understand the utilization of heat provided by experimentally determining the heat and mass transfer coefficients. Electrochemical performance is also evaluated to determine the impact of drying temperature on cycling performance. Binder distribution is determined via various methods to confirm differences in binder homogeneity as a function of both solvent and drying temperature. Identified is the large difference in the efficiency in which the heat is used as well as an ideal drying temperature for both aqueous and non‐aqueous processed cathodes. Also identified is the increased sensitivity to processing temperature for aqueous processed electrodes compared to non‐aqueous processed counterparts, pointing to the possibility of tuned drying regimes which would capitalize on the potential cost savings of aqueous processing for cathodes.

25 ENERGY STORAGE↗

Integration of a thermoelectric subcooler with an air‑source heat pump to enhance heating capacity and dehumidification

This study presents an innovative configuration of a thermoelectric subcooler (TES) integrated with an air-source heat pump (ASHP). The TES is installed in the liquid line, where it absorbs heat from the refrigerant. On its hot side, it discharges heat to the return air in heating mode or to the supply air in cooling mode, enabling year-round operation. The ASHP–TES system was evaluated under various conditions to reduce supplemental heating needs and improve dehumidification. Experimental heating tests revealed that activating the TES increased the heating capacity by 12%–20%. However, this occurred with a 7.6%–10% reduction in heating coefficient of performance (COP). In cooling mode, TES operation significantly improved moisture removal. The TES reduced the sensible heat ratio (SHR) and enhanced dehumidification, removing 20%–50% more moisture than a conventional system when meeting the same sensible load. The TES can be turned off to use the refrigerant subcooler for reheat supply air or turned on to substantially boost dehumidification. When meeting the same latent load, the ASHP–TES system achieved up to 33% energy savings compared with a conventional ASHP using resistance heating. Relative to a conventional ASHP paired with a whole-house dehumidifier, the ASHP–TES system provided up to 20% energy savings. These findings underscore the potential of TES integration to improve latent load control and enhance overall energy efficiency in hybrid ASHP systems, especially in cold and humid climates.

Hu, Yifeng [ORNL] (ORCID:0000000242875185)↗

Dynamic modeling of near isothermal compressor for Transcritical carbon dioxide cycle to support efficiency improvement

Compressors are the primary components of energy consumption in vapor compression systems, drawing considerable research effort to reduce carbon emissions and improve energy efficiency. This work presents an isothermal compressor that integrates the compression chamber with the gas cooler to achieve near-isothermal compression, resulting in up to 30% energy reduction compared to traditional isentropic compression, according to the experiment results. A detailed dynamic model for the isothermal compression cycle of carbon dioxide (CO 2 ) is first presented, coupled with a liquid-piston model for chamber design. The model is experimentally validated on a 3.5 kW prototype, yielding a 6.2% relative error in chamber pressure and a 0.5 K deviation in chamber temperature. The liquid piston exhibits reduced frictional heating and geometric adaptability relative to the mechanical piston. Leveraging these attributes, the study further evaluates approaches that enhance the heat transfer to achieve isothermal compression by increasing the effective heat transfer area during compression. As a result, simulations demonstrated up to a 5% improvement in the coefficient of performance over the baseline case through chamber design, providing guidelines for design of isothermal compression cycle.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

On the elastocaloric effect in CuAlBe shape memory alloys: A quantitative phase-field modeling approach

We report the reversible stress-induced phase transformation in shape memory alloys (SMAs) is a dissipative process during which heat is absorbed or released. The inherent temperature variations inside the material has an elastocaloric effect (eCE) with appealing applications in solid-state cooling technology such as compact and efficient on-board refrigeration system for eletronic devices. In this manuscript, we conduct the first study of eCE of CuAlBe SMAs utilizing phase-field modeling. For an applied stress of 500 MPa, the results for polycrystalline Cu-Al11-2Be (at. %) show a minimum adiabatic unloading temperature change of -10 K over a pseudoelastic window of 40 K. In the absence of plastic deformation, the material demonstrates good reproducibility of the eCE over a few loading–unloading cycles. The presence of plastic deformation is found to cause functional fatigue that deteriorates the cooling capacity; however, the coefficient of performance only decreases from 9.04 to 8.03, which is still a very good value. These results place CuAlBe as a frontrunner SMA for solid-state cooling compared to the expensive NiTi.

36 MATERIALS SCIENCE↗