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A statistical equilibrium analysis of interstellar CO toward zeta Ophiuchi as recorded by the Goddard High Resolution Spectrograph

High-resolution and high signal-to-noise ratio echelle observations made by the Goddard High Resolution Spectrograph (GHRS), aboard the Hubble Space Telescope, of molecular (12)C(16)O and (13)C(16)O in the absorbing gas toward zeta Oph are reported. A statistical equilibrium model, incorporating a different way of dealing with the radiation field in the interstellar clouds, is presented. Based upon previous observations, two velocity components of the gas at V(sub LSR) = - 0.79 and 0.39 km/s, corresponding to solar velocity = -14.6 and -13.4 km/s, together with three different sets of velocity dispersions are adopted in our models. The ratios of the computed emergent intensities (I(sub em)) resulting from the emission lines in the lowest transitions (J = 1 goes to 0, 2 goes to 1, 3 goes to 2) of ground state of CO are presented. The ratios for the two velocity components, (I(sub em)(1 goes to 0)(sub 1))/(I(sub em)(1 goes to 0)(sub 2)), and (I(sub em)(2 goes to 1)(sub 1))/I(sub em)(1 goes to 0)(sub 1)) are comparable to the observed corrected antenna temperature ratios. From the solutions to the statistical equilibrium equations including the six lowest rotational transitions of CO and from multiple Voigt profile fits, the observed (12)CO and (13)CO UV abroption features are successfully reproduced. Profile fitting and double cloud curve-of-growth analysis using the GHRS and Copernicus data indicate that the abundance of CO is (1.8 +/- 0.2) x 10(exp 15)/sq cm. The most recently measured wavelength of the (6 goes to 0) (13)CO band by Haridass & Huber (R(0) = 1370.616 A) shows that the tentative (13)CO features in the GHRS data are unquestionably identified. If there is no blending from any other unknown interstellar species, the isotope ratio of (12)CO/(13)CO is approximately 82 +/- 25. This result is close to the terrestrial value of 90 and implies that the CO is not substantially fractionated, and (12)C(16)O experiences little preferential self-shielding through the selective isotopic photodissociation process. This conclusion differs strongly with that of Sheffer et al. Other implications of the results are discussed.

Lyu, Cheng-Hsuan↗

Real-time measurements of endogenous CO production from vascular cells using an ultrasensitive laser sensor

Carbon monoxide (CO) has been implicated as a biological messenger molecule analogous to nitric oxide. A compact gas sensor based on a midinfrared laser absorption spectroscopy was developed for direct and real-time measurement of trace levels (in approximate pmol) of CO release by vascular cells. The midinfrared light is generated by difference frequency mixing of two nearinfrared lasers in a nonlinear optical crystal. A strong infrared absorption line of CO (4.61 microm) is chosen for convenient CO detection without interference from other gas species. The generation of CO from cultured vascular smooth muscle cells was detected every 20 s without any chemical modification to the CO. The sensitivity of the sensor reached 6.9 pmol CO. CO synthesis was measured from untreated control cells (0.25 nmol per 10(7) cells/h), sodium nitroprusside-treated cells (0.29 nmol per 10(7) cells/h), and hemin-treated cells (0.49 nmol per 10(7) cells/h). The sensor also detected decreases in CO production after the addition of the heme oxygenase (HO) inhibitor tin protoporphyrin-IX (from 0.49 to 0.02 nmol per 10(7) cells/h) and increases after the administration of the HO substrate hemin (from 0.27 to 0.64 nmol per 10(7) cells/h). These results demonstrate that midinfrared laser absorption spectroscopy is a useful technique for the noninvasive and real-time detection of trace levels of CO from biological tissues.

Non-NASA Center↗

L'CO/LFIR Relations with CO Rotational Ladders of Galaxies Across the Herschel SPIRE Archive

We present a catalog of all CO (carbon monoxide) (J (total angular momentum quantum number) equals 1-0 through J equals 13-12), [CI], and [NII] lines available from extragalactic spectra from the Herschel SPIRE (Spectral and Photometric Imaging Receiver) Fourier Transform Spectrometer (FTS) archive combined with observations of the low-J CO lines from the literature and from the Arizona Radio Observatory. This work examines the relationships between L (sub FIR (Far Infra Red)), L prime (sub CO), and L (sub CO) / L (sub CO, 1-0). We also present a new method for estimating probability distribution functions (PDFs) from marginal signal-to-noise ratio Herschel FTS spectra, which takes into account the instrumental "ringing" and the resulting highly correlated nature of the spectra. The slopes of Log (L (sub FIR)) versus Log (L prime (sub CO)) are linear for all mid- to high-J CO lines. The mid- to high-J CO luminosity relative to CO J equals 1-0 increases with increasing L (sub FIR), indicating higher excitement of the molecular gas, though these ratios do not exceed approximately 100. The luminosities relative to CO J equals 1-0 remain relatively at from J equals 6-5 through J equals13-2, across many orders of magnitude of L (sub FIR). Qualitative comparisons to current theoretical models do not match these flat SLED (spectral line energy distributions) shapes, indicating the need for more comprehensive modeling of the excitation processes of warm molecular gas in nearby galaxies.

Submillimeter Data↗

Collisional Dissociation of CO: ab initio Potential Energy Surfaces and Quasiclassical Trajectory Rate Coefficients

We have generated accurate global potential energy surfaces for CO+Ar and CO+O that correlate with atom-diatom pairs in their ground electronic states based on extensive ab initio electronic structure calculations and used these potentials in quasi-classical trajectory nuclear dynamics calculations to predict the thermal dissociation rate coefficients over 5000- 35000 K. Our results are not compatible with the 20-45 year old experimental results. For CO + Ar we obtain fairly good agreement with the experimental rate coefficients of Appleton et al. (1970) and Mick and Roth (1993), but our computed rate coefficients exhibit a stronger temperature dependence. For CO + O our dissociation rate coefficient is in close agreement with the value from the Park model, which is an empirical adjustment of older experimental results. However, we find the rate coefficient for CO + O is only 1.5 to 3.3 times larger than CO + Ar over the temperature range of the shock tube experiments (8000-15,000 K). The previously accepted value for this rate coefficient ratio is 15, independent of temperature. We also computed the rate coefficient for the CO + O ex- change reaction which forms C + O2. We find this reaction is much faster than previously believed and is the dominant process in the removal of CO at temperatures up to 16,000 K. As a result, the dissociation of CO is accomplished in two steps (react to form C+O2 and then O2 dissociates) that are endothermic by 6.1 and 5.1 eV, instead of one step that requires 11.2 eV to break the CO bond.

exchange rate coefficient↗

Isotopic Tracers for CO 2 Produced During A Planetary Impact Into Limestone Target Rocks

Terrestrial meteorite impacts have been directly linked with multiple mass extinction events throughout Earth’s history. Among these impacts, those that land in sedimentary target rocks are thought to generate large quantities of CO 2 via decarbonation. This injection of CO 2 into the atmosphere has the potential to alter the climate and threaten terrestrial habitability. The magnitude of this change depends upon the net amount of CO 2 released, which is controlled by how much CO 2 is produced by the impact, how much CO 2 is removed by back-reactions after the impact, and other post-impact CO 2 sinks. To interrogate the behavior of CO 2 release into the impact atmosphere, we present carbon (δ 13 C), oxygen (δ 18 O), and clumped (Δ 47 ) isotope results from carbonate clasts preserved within the impact breccia of the Steen River Impact Structure (SRIS) in Alberta, Canada. These clasts exhibit a ~65‰ range in δ 13 C and a ~5‰ variation in δ 18 O. However, while δ 13 C and δ 18 O are positively correlated, Δ 47 unexpectedly has a negative relationship with δ 13 C and δ 18 O. Based on prior assumptions, there would either be (1) no relationship with carbonate Δ 47 and the bulk ratios because Δ 47 would be reset at extreme impact temperatures, or (2) Δ 47 would have a positive correlation with the bulk ratios, reflecting gradual Δ 47 ‘resetting.’ To reconcile the SRIS result with these expectations, we conducted a series of in vacuo heating experiments at temperatures above calcite decomposition. As predicted by Rayleigh fractionation, these heating experiments generated depletions in δ 13 C and δ 18 O that increased with reaction time. Mimicking the SRIS results, these experiments also produced concomitant increases in Δ 47 . Using an adaptation of a mechanistic model for decomposition fractionation (Hayles & Killingsworth, 2022) we hypothesize that these exotic isotope trends are caused by Rayleigh fractionation and a Δ 47 kinetic isotope effect that results from the disproportionation of O to CaO and CO 2 during thermal decomposition. This high Δ 47 CO 2 subsequently exchanges with the residual CaCO 3 . This work highlights a potential pathway for identifying and quantifying CO 2 generation by impacts and builds on the relatively limited literature characterizing the behavior of carbonate clumped isotopes at very high geologic temperatures.

Multi-isotope systems↗

Pretreatment of CO oxidation catalysts

CO oxidation catalysts with high activity in the range of 25 C to 100 C are important for long-life, closed-cycle operation of pulsed carbon dioxide 2 lasers. A reductive pretreatment with either CO or H sub 2 was shown to significantly enhance the activity of a commerically-available platinum on tin (IV) oxide (Pt/SnO2) catalyst relative to an oxidative or inert pretreatment or no pretreatment. Pretreatment at temperatures of 175 C and above caused an initial dip in observed CO or O sub 2 loss or CO sub 2 formation in a test gas mixture of 1 percent CO and 0.5 percent O sub 2 in a He gas matrix before a steady-state yield was obtained. This dip was found to be caused by dehydration of the surface of the catalyst and was readily eliminated by humidifying the catalyst or the test gas mixture. It was also found that too much moisture resulted in a lower overall yield of CO sub 2. Under similar conditions, it is hypothesized that the effect of the humidification is to increase the concentration of OH groups on the surface of the catalyst. The effect of having high concentration of CO sub 2 in the test gas mixture upon the loss of CO and O sub 2 as well as the effect of periods of relaxation of the catalyst under non-test gas conditions was studied. The purpose of these studies was to gain an insight into the mechanism of CO oxidation on this type of catalyst.

Vannorman, John D.↗

Reevaluation of the NOAA/CMDL carbon monoxide reference scale and comparisons with CO reference gases at NASA-Langley and the Fraunhofer Institut

The carbon monoxide (CO) reference scale created by the National Oceanic and Atmospheric Administration/Climate Monitoring and Diagnostics Laboratory (NOAA/CMDL) is used to quantify measurements of CO in the atmosphere, calibrate standards of other laboratories and to otherwise provide reference gases to the community measuring atmospheric CO. This reference scale was created based upon a set of primary standards prepared by gravimetric methods at CMDL and has been propagated to a set of working standards. In this paper we compare CO mixing ratios assigned to the working standards by three approaches: (1) calibration against the original gravimetric standards, (2) calibration using only working standards as the reference gas, and (3) calibration against three new gravimetric standards prepared to CMDL. The agreement between these values was typically better than 1%. The calibration histories of CMDL working standards are reviewed with respect to expected rates of CO change in the atmosphere. Using a Monte Carlo approach to simulate the effect of drifting standards on calculated mixing ratios, we conclude that the error solely associated with the maintenance of standards will limit the ability to detect small CO changes in the atmosphere. We also report results of intercalibration experiments conducted between CMDL and the Diode Laser Sensor Group (DACOM) at the NASA Langley Research Center (Hampton, Virginia), and CMDL and the Fraunhofer-Institut (Garmisch-Partenkirchen, Germany). Each laboratory calibrated several working standards for CO using their reference gases, and these results were compared to calibrations conducted by CMDL. The intercomparison of eight standards (CO concentrations between approximately 100 and approximately 165 ppb) by CMDL and NASA agreed to better than +/- 2%. The calibration of six standards (CO concentrations between approximately 50 and approximately 210 ppb) by CMDL and the Fraunhofer-Institut agreed to within +/- 2% for four standards, and to within +/- 5% for all six standards.

Novelli, P. C.↗

A Climatology of Tropospheric CO over the Central and Southeastern United States and the Southwestern Pacific Ocean Derived from Space, Air, and Ground-based Infrared Interferometer Spectra

This final report summarizes all research activities and publications undertaken as part of NASA Atmospheric Chemistry and Modeling Analysis Program (ACMAP) Grant NAG-1-2022, 'A Climatology of Tropospheric CO over the Central and Southeastern United States and the Southwestern Pacific Ocean Derived from Space, Air, and Ground-based Infrared Interferometer Spectra'. Major project accomplishments include: (1) analysis of more than 300,000 AERI spectra from the ARM SGP site yielding a 5-year (1998-2002) timeseries of CO retrievals from the Lamont, OK AERI; (2) development of a prototype CO profile retrieval algorithm for AERI spectra; (3) validation and publication of the first CO retrievals from the Scanning High-resolution Interferometer Sounder (SHIS); and (4) development of a prototype AERI tropospheric O3 retrieval algorithm. Compilation and publication of the 5-year Lamont, OK timeseries is underway including a new collaboration with scientists at the Lawrence Berkeley National Laboratory. Public access to this data will be provided upon article submission. A comprehensive CO analysis of the archive of HIS spectra of remains as the only originally proposed activity with little progress. The greatest challenge faced in this project was motivating the University of Wisconsin Co-Investigators to deliver their archived HIS and AERIOO data along with the requisite temperature and water vapor profiles in a timely manner. Part of the supplied HIS dataset from ASHOE may be analyzed as part of a Master s Thesis under a separate project. Our success with the SAFARI 2000 SHIS CO analysis demonstrates the utility of such aircraft remote sensing data given the proper support from the instrument investigators. In addition to the PI and Co-I s, personnel involved in this CO climatology project include one Post Doctoral Fellow, one Research Scientist, two graduate students, and two undergraduate students. A total of fifteen presentations regarding research related to this project were delivered at eleven different scientific meetings. Thus far, three publications have resulted from this project with another five in preparation. No subject inventions resulted from this research project.

McMillian, W. Wallace↗

Regional and Global CO and Aerosol Correlations: An Integrated Approach of Surface, Satellite, and Aircraft Measurements and Model Simulations

We investigate regional and global CO and fine mode aerosol correlations by combining GOCART model simulations with various measurements from surface (CMDL /CO and AERONET / aerosol), satellite (MOPl3T / CO and MODIS / aerosol), and aircraft. CO mixing ratios and aerosol concentrations are examined using surface and aircraft measurements on several representative regions. Satellite observations provide the comparisons of CO column and aerosol fine model AOD at global scale. Numerical model simulation allows us to compare CO and aerosol properties without temporal and spatial limitation and with the capability to trace emissions by isolating different somces. Our zonal mean comparisons confirm the previous researches that the variations of CO and aerosol properties are out of phase by several month. over northern hemisphere middle latitudes where anthropogenic emissions dominate. Over the biomass burning dominating regions, such as southern hemisphere (SH) extra-tropical zone, the concentration and column properties of CO and aerosol show more agreement. Long- term transport and local chemistry drive the biggest phase shift of CO and aerosol properties over remote SH ocean regions. There are much more complicated relationships CO and aerosol properties over stations and small regions due to emission, transport, and local chemistry.

Bian-Hui-Sheng↗

Using CO2:CO Correlations to Improve Inverse Analyses of Carbon Fluxes

Observed correlations between atmospheric concentrations of CO2 and CO represent potentially powerful information for improving CO2 surface flux estimates through coupled CO2-CO inverse analyses. We explore the value of these correlations in improving estimates of regional CO2 fluxes in east Asia by using aircraft observations of CO2 and CO from the TRACE-P campaign over the NW Pacific in March 2001. Our inverse model uses regional CO2 and CO surface fluxes as the state vector, separating biospheric and combustion contributions to CO2. CO2-CO error correlation coefficients are included in the inversion as off-diagonal entries in the a priori and observation error covariance matrices. We derive error correlations in a priori combustion source estimates of CO2 and CO by propagating error estimates of fuel consumption rates and emission factors. However, we find that these correlations are weak because CO source uncertainties are mostly determined by emission factors. Observed correlations between atmospheric CO2 and CO concentrations imply corresponding error correlations in the chemical transport model used as the forward model for the inversion. These error correlations in excess of 0.7, as derived from the TRACE-P data, enable a coupled CO2-CO inversion to achieve significant improvement over a CO2-only inversion for quantifying regional fluxes of CO2.

Palmer, Paul I.↗

Representativeness of CO and O3 Along ATom Transects Derived from GEOS-5 and GMI-CTM Simulations

One major goal for the NASA Atmospheric Tomography Mission (ATom) is producing an observation-based chemical climatology to represent the atmospheric heterogeneity. In this study, we use CO and O3 observations and global atmospheric model simulations to examine the spatial representativeness of the ATom-1 and -2 transects within a 4D framework provided by the NASA GEOS-5 and GMI-CTM models. Based on the probability density functions, we find that the variability of CO and O3 along the flight tracks is well hindcast by the model when sampled per ATom flights. The CO variations along the ATom-transect are likely representative of the typical CO variations over the whole Pacific basin during both the ATom-1 and -2 periods, the northern Atlantic during the ATom-1 period, and the tropical Atlantic in the ATom-2 period. Over southern Atlantic, CO along the ATom-1 transects is likely less well mixed than that of the broader region, but is still representative of the median CO concentration. CO along the ATom-2 transect is likely higher than the median CO concentration over this region. For O3, the agreements between PDFs of O3 sampled along the ATom transects and over the broader regions are fair to good over all six regions (Scores > 0.65) with notable discrepancies over some regions. For example, in ATom-1 over the northern Pacific and Atlantic, the transect samples air masses with higher O3 levels. During ATom-2, the transect over-represents the occurrence of O3 plumes over tropical Pacific. Over the southern Pacific and Atlantic for both ATom-1 and -2, the transects have a less uniform distribution compared to the surrounding basins, but still represent the median O3 abundance. Overall, we conclude in most cases that ATom measurements represent the statistical variations of these two species over the ocean basins at the time of measurement. Higher-order statistics, including covariance of species, has not been tested in this study.

ozone↗

Electronic-to-vibrational energy transfer efficiency in the O/1 D/-N2 and O/1 D/-CO systems

With the aid of a molecular resonance fluorescence technique, which utilizes optical pumping from the v = 1 level of the ground state of CO by A 1 Pi-X 1 Sigma radiation, a study is made of the efficiency of E-V transfer from O(1 D) to CO. O(1 D) is generated at a known rate by O2 photodissociation at 1470 A in an intermittent mode, and the small modulation of the fluorescent signal associated with CO (v = 1) above the normal thermal background is interpreted in terms of E-V transfer efficiency. The CO (v = 1) lifetime in this system is determined mainly by resonance trapping of the IR fundamental band, and is found to be up to ten times longer than the natural radiative lifetime. For CO, (40 plus or minus 8)% of the O(1 D) energy is converted into vibrational energy. By observing the effect of N2 on the CO (v = 1) fluorescent intensity and lifetime, it is possible to obtain the E-V transfer efficiency for the system O(1 D)-N2 relative to that for O(1 D)-CO. The results indicate that the efficiency for N2 is (83 plus or minus 10)% of that for CO.

Slanger, T. G.↗

Vibrational and rotational excitation of CO in comets. Part 1: Non-equilibrium calculations. Part 2: Results of the calculation for standard bright comet, comet Iras-Araki-Alcock and comet Halley

The vibrational and rotational excitation of the CO molecule in cometary comae were investigated using a model which includes IR vibrational pumping by the solar flux, vibrational and rotational radiative decay, and collisional coupling among rotational states. Steady state was not assumed in solving the rate equations. The evolution of a shell of CO gas was monitored as it expanded from the nucleus into the outer coma. Collisional effects were treated using a kinetic temperature profile derived from theoretical work on the coma energy balance. The kinetic temperature was assumed to be extremely cold in the inner coma; this has significant consequences for the CO excitation. If optical depth effects are ignored, only low J transitions will be significantly excited in comets observed at high spatial resolution. Ground-based observations of CO co-vibrational and rotational transitions will be extremely difficult due to lack of sensitivity and/or terrestrial absorption. However, CO should be detectable from a large comet with favorable observing geometry if the CO is a parent molecule present at the 10% level (or greater) relative to H2O. Observations using cooled, spaceborne instruments should be capable of detecting CO emission from even moderately bright comets.

Chin, G.↗

Far-infrared emission lines of CO and OH in the Orion-KL molecular shock

Observations of far infrared rotational emission lines which arise in the shocked gas associated with Orion-Kl are presented, including detections of the CO J = 34 yields 33, J = 31 yields 30, J = 26 yields 25, and OH sup 2 PI sub (3/2) J sup P = 7/2(-) yields 5/2(+) emission lines, as well as improved measurements of the CO J = 22 yields 21 and OH sup 2 PI sub (3/2) J = 5/2 yields 3/2 lines. These lines are observed to have velocity widths of Del V approx. 20 to 30 km/sec, somewhat less than either the 2 micro H sub 2 lines or the high velocity plateau component of the millimeter wave CO lines seen in this object. An H sub 2 column density of approx. 3 x 10 to the 21st power, a total mass of approx. 1 solar mass and characteristic temperature and density T approx. 750 K and approx. 2 x 10 to the 6th power per cu cm can be derived from the CO intensities. The density is too low by at least an order of magnitude for the observed infrared H sub 2 and far infrared CO emission to be accounted for by a purely hydrodynamic shock, and support is lent to hydromagnetic shock models. From the present measurements, the relative abundance of CO is estimated to be CO H sub 2 = 1.2 x .0001, corresponding to 20% of the cosmic abundance of C existing in the form of CO. The average relative abundance of OH in the shocked gas is O/H sub 2 or = 5 x 10 to the -7th power. An upper limit to the intensity of the HD J = 1 yields 0 line is used to derive an upper limit of tau or = 3 for the D/H relative abundance in the Orion cloud core.

Watson, D. M.↗

Far-infrared emission lines of CO and OH in the Orion-KL molecular shock

Observations of far infrared rotational emission lines which arise in the shocked gas associted with Orion-Kl are presented, including detections of the CO J = 34 yields 33, J = 31 yields 30, J = 26 yields 25, and OH sup 2 PI sub (3/2) J sup P = 7/2(-) yields 5/2(+) emission lines, as well as improved measurements of the CO J = 22 yields 21 and OH sup 2 PI sub (3/2) J = 5/2 yields 3/2 lines. These lines are observed to have velocity widths of Del V approx. 20 to 30 km/sec, somewhat less than either the 2 micro H sub 2 lines or the high velocity plateau component of the millimeter wave CO lines seen in this object. An H sub 2 column density of aprox. 3 x 10 to the 21st power, a total mass of approx. 1 solar mass and characteristic temperature and density T approx. 750 K and approx. 2 x 10 to the 6th power per cu cm can be derived from the CO intensities. The density is too low by at least an order of magnitude for the observed infrared H sub 2 and far infrared CO emission to be accounted for by a purely hydrodynamic shock, and support is lent to hydromagnetic shock models. From the present measurements, the relative abundance of CO is estimated to be CO H sub 2 = 1.2 x .0001, corresponding to 20 percent of the cosmic abundance of C existing in the form of CO. The average relative abundance of OH in the shocked gas is O/H sub 2 or = 5 x 10 to the -7th power. An upper limit to the intensity of the HD J - 1 yields 0 line is used to derive an upper limit of tau or = 3 for the D/H relative abundance in the Orion cloud core.

Watson, D. M.↗

CO aperture synthesis of NGC 4038/9 (ARP 244)

Researchers present high-resolution (approx. 6 seconds) CO observations of the merging galaxies NGC 4038/9 made with the Owens Valley Radio Observatory (OVRO) Millimeter Wave Interferometer. The CO observations of Arp 244 were obtained between April and June 1988 using the OVRO Millimeter Wave Interferometer. Two fields with phase centers near the NGC 4039 nucleus and near the NGC 4038 nucleus were observed. The size of the synthesized beam is approximately 6.5 x 7 seconds at PA=72 degrees. The rms in a single cleaned channel map is 0.06 Jy beam(exp -1), corresponding to a brightness temperature of 0.12 K over the synthesized beam. Contour maps of the integrated CO intensity for both interferometer fields are shown. Three CO concentrations are evident. Two are centered near the nuclei of NGC 4038 and NGC 4039, closely correlated with H alpha and radio continuum maxima. A third CO emission region lies about 25 seconds northeast of the NGC 4039 nucleus. A number of radio continuum, H alpha, and 10 micron emission knots appear in this region. The total integrated intensity at the northern nuclear source, 302 K km/s, leads to a molecular mass of 8.3 by 10 to the 8th power solar mass assuming a Galactic CO to H2 conversion factor of 3.0 x 10 to the 20th power H2 cm(-2) (K km/s)(-1). The integrated CO intensity of the southern nuclear source leads to a molecular mass of 2.4 x 10 to the 8th solar mass. The extranuclear CO concentration contains 1.2 x 10 to the 9th power solar mass of molecular gas, extending over 170 km/s, and is resolved in a number of channels. Its large size, mass, and morphology strongly suggest that it is an agglomeration of several clumps.

Stanford, S. A.↗

CO observations of southern mergers

There are good reasons to believe that the formation of some elliptical galaxies result from the merging of two disk galaxies, as Toomre and Toomre first suggested (1972, Ap. J. 178, 623). Such a process strongly enhances the star-formation activity of the system, thus consuming its molecular gas. This might account for the low cold-gas content of elliptical galaxies compared to that of spirals. Researchers present here CO(1-0) and CO(2-1) observations of a sequence of three objects, NGC 1614, NGC 3256, and NGC 7252, that present characteristic features of merger remnants: single body and extended tidal tails. NGC 3256 and 7252 even exhibit the r(exp 1/4) radial light distribution that is the signature of elliptical galaxies, which indicates that their stellar bodies are in late stages of relaxation. Both NGC 1614 and NGC 3256 undergo extended bursts of star formation revealed by their large far-infrared luminosities, and by the presence in the near-infrared spectrum of the 3.28 microns feature (Morwood: 1986, A. A. 166, 4) attributed to polycyclic aromatic hydrocarbons. On the other hand, NGC 7252 has a milder activity of star formation, as suggested by a lower infrared luminosity, and thus seems to have gone past the starburst phase. The CO data were collected with the Swedish-ESO 15 m Submillimeter Telescope (SEST) (beamsize = 43 seconds at 115 GHz, 23 seconds at 230 GHz). For NGC 7252, researchers have only observed the central position in CO-12(1-0). The spectrum is displayed together with an HI spectrum obtained with the Nancay radiotelescope. Researchers mapped NGC 1614 and NGC 3256 in CO-12(1-0) and CO-12(2-1), and also observed the nucleus of NGC 3256 in CO-13(1-0). The various CO spectra obtained towards the nuclei of both galaxies are presented. Characteristics of the galaxies are gathered, with luminosities and masses in solar units and temperatures in Kelvins.

Casoli, F.↗

Savanna burning and convective mixing in southern Africa - Implications for CO emissions and transport

Atmospheric data from both remote and direct measurements were used to compute the carbon monoxide (CO) emissions and mass transport from Africa south of the equator. The Measurement of Air Pollution from Satellites (MAPS) experiment flew on the Space Shuttle during October 5-13, 1984; the highest CO mixing ratios from the entire mission were measured over southern Africa. In addition to the MAPS data, surface CO mixing ratios were measured in the boundary layer at Cape Point, South Africa. A calibration factor for the remote MAPS CO measurements was determined by computing the ratio of the surface measurements from Cape Point during unpolluted periods to coincident MAPS measurements. The adjusted MAPS CO data were then used to compute the mass flux of CO from biomass burning in southern Africa during the MAPS mission. The transport calculations were compared to the estimated CO emissions from biomass burning to examine the efficiency in which the continental tropical clouds redistribute CO in the troposphere.

Connors, Vickie S.↗