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NASA NTRS1975

Zinc depolarized electrochemical CO2 concentration

Two zinc depolarized electrochemical carbon dioxide concentrator concepts were analytically and experimentally evaluated for portable life support system carbon dioxide (CO2) removal application. The first concept, referred to as the zinc hydrogen generator electrochemical depolarized CO2 concentrator, uses a ZHG to generate hydrogen for direct use in an EDC. The second concept, referred to as the zinc/electrochemical depolarized concentrator, uses a standard EDC cell construction modified for use with the Zn anode. The Zn anode is consumed and subsequently regenerated, thereby eliminating the need to supply H2 to the EDC for the CO2 removal process. The evaluation was based primarily on an analytical evaluation of the two ZnDCs at projected end item performance and hardware design levels. Both ZnDC concepts for PLSS CO2 removal application were found to be noncompetitive in both total equivalent launch weight and individual extravehicular activity mission volume when compared to other candidate regenerable PLSS CO2 scrubbers.

Woods, R. R.↗
NASA NTRS2015

Airborne Measurements in Support of the NASA Atmospheric Carbon and Transport - America (ACT-America) Mission

NASA announced the research opportunity Earth Venture Suborbital -2 (EVS-2) mission in support of the NASA's science strategic goals and objectives in 2013. Penn State University, NASA Langley Research Center (LaRC), and other academic institutions, government agencies, and industrial companies together formulated and proposed the Atmospheric Carbon and Transport -America (ACT -America) suborbital mission, which was subsequently selected for implementation. The airborne measurements that are part of ACT-America will provide a unique set of remote and in-situ measurements of CO2 over North America at spatial and temporal scales not previously available to the science community and this will greatly enhance our understanding of the carbon cycle. ACT -America will consist of five airborne campaigns, covering all four seasons, to measure regional atmospheric carbon distributions and to evaluate the accuracy of atmospheric transport models used to assess carbon sinks and sources under fair and stormy weather conditions. This coordinated mission will measure atmospheric carbon in the three most important regions of the continental US carbon balance: Northeast, Midwest, and South. Data will be collected using 2 airborne platforms (NASA Wallops' C-130 and NASA Langley's B-200) with both in-situ and lidar instruments, along with instrumented ground towers and under flights of the Orbiting Carbon Observatory (OCO-2) satellite. This presentation provides an overview of the ACT-America instruments, with particular emphasis on the airborne CO2and backscatter lidars, and the, rationale, approach, and anticipated results from this mission.

Meadows, Byron↗
NASA NTRS2003

Treatment of Spacecraft Wastewater Using a Hollow Fiber Membrane Biofilm Redox Control Reactor

The purpose of this project was to develop and evaluate design concepts for biological treatment reactors for the purification of spacecraft wastewater prior to reverse osmosis treatment. The motivating factor is that wastewater recovery represents the greatest single potential reduction in the resupply requirements for crewed space missions. Spacecraft wastewater composition was estimated from the characteristics of the three major component streams: urine/flush water, hygiene water, and atmospheric condensate. The key characteristics of composite spacecraft wastewater are a theoretical oxygen demand of 4519 mg/L, of which 65% is nitrogenous oxygen demand, in a volume of 11.5 liter/crew-day. The organic carbon to nitrogen ratio of composite wastewater is 0.86. Urine represents 93% of nitrogen and 49% of the organic carbon in the composite wastestream. Various bioreaction scenarios were evaluated to project stoichiometric oxygen demands and the ability of wastewater carbon to support denitrification. Ammonia nitrification to the nitrite oxidation state reduced the oxygen requirement and enabled wastewater carbon to provide nearly complete denitrification. A conceptual bioreactor design was established using hollow fiber membranes for bubbleless oxygen transfer in a gravity-free environment, in close spatial juxtaposition to a second interspaced hollow fiber array for supplying molecular hydrogen. Highly versatile redox control and an enhanced ability to engineer syntrophic associations are stated advantages. A prototype reactor was constructed using a microporous hollow fiber membrane module for aeration. Maintaining inlet gas pressure within 0.25 psi of the external water pressure resulted in bubble free operation with no water ingress into hollow fiber lumens. Recommendations include the design and operational testing of hollow fiber bioreactors using: 1) Partial nitrification/nitrite predenitrification; 2) Limited aeration for simultaneous nitrification/denitrification or for nitrite reduction/ammonia oxidation; 3) Hydrogenotrophic denitrification.

Smith, Daniel P.↗
NASA NTRS2006

Laboratory Spectroscopy of Large Carbon Molecules and Ions in Support of Space Missions. A New Generation of Laboratory & Space Studies

Polycyclic Aromatic Hydrocarbons (PAHs) are an important and ubiquitous component of carbon-bearing materials in space. A long-standing and major challenge for laboratory astrophysics has been to measure the spectra of large carbon molecules in laboratory environments that mimic (in a realistic way) the physical conditions that are associated with the interstellar emission and absorption regions [1]. This objective has been identified as one of the critical Laboratory Astrophysics objectives to optimize the data return from space missions [2]. An extensive laboratory program has been developed to assess the properties of PAHs in such environments and to describe how they influence the radiation and energy balance in space. We present and discuss the gas-phase electronic absorption spectra of neutral and ionized PAHs measured in the UV-Visible-NIR range in astrophysically relevant environments and discuss the implications for astrophysics [1]. The harsh physical conditions of the interstellar medium characterized by a low temperature, an absence of collisions and strong VUV radiation fields - have been simulated in the laboratory by associating a pulsed cavity ringdown spectrometer (CRDS) with a supersonic slit jet seeded with PAHs and an ionizing, penning-type, electronic discharge. We have measured for the {\it first time} the spectra of a series of neutral [3,4] and ionized [5,6] interstellar PAHs analogs in the laboratory. An effort has also been attempted to quantify the mechanisms of ion and carbon nanoparticles production in the free jet expansion and to model our simulation of the diffuse interstellar medium in the laboratory [7]. These experiments provide {\it unique} information on the spectra of free, large carbon-containing molecules and ions in the gas phase. We are now, for the first time, in the position to directly compare laboratory spectral data on free, cold, PAH ions and carbon nano-sized carbon particles with astronomical observations in the UV-NIR range (interstellar UV extinction, DIBs in the NUV-NIR range). This new phase offers tremendous opportunities for the data analysis of current and upcoming space missions geared toward the detection of large aromatic systems Le., the "new frontier space missions" (Spitzer, HST, COS, JWST, SOFIA,...).

Salama, Farid↗
NASA NTRS1976

Development of a prototype regenerable carbon dioxide absorber

Design information was obtained for a new, regenerable carbon dioxide control system for extravehicular activity life support systems. Solid potassium carbonate was supported in a thin porous sheet form and fabricated into carbon dioxide absorber units. Carbon dioxide and water in the life support system atmosphere react with the potassium carbonate and form potassium bicarbonate. The bicarbonate easily reverts to the carbonate by heating to 150 deg C. The methods of effectively packing the sorbent material into EVA-sized units and the effects of inlet concentrations, flowrate, and temperature upon performance were investigated. The cycle life of the sorbent upon the repeated thermal regenerations was demonstrated through 90 cycles.

Onischak, M.↗
NASA NTRS2004

Full-waveform, Laser Altimeter Measurements of Vegetation Vertical Structure and Sub-canopy Topography in Support of the North American Carbon Program

Full-waveform, scanning laser altimeters (i.e. lidar) provide a unique and precise view of the vertical and horizontal structure of vegetation across wide swaths. These unique laser altimeters systems are able to simultaneously image sub-canopy topography and the vertical structure of any overlying vegetation. These data reveal the true 3-D distribution of vegetation in leaf-on conditions enabling important biophysical parameters such as canopy height and aboveground biomass to be estimated with unprecedented accuracy. An airborne lidar mission was conducted in the summer of 2003 in support of preliminary studies for the North America Carbon Program. NASA's Laser Vegetation Imaging Sensor (LVIS) was used to image approximately 2,000 sq km in Maine, New Hampshire, Massachusetts and Maryland. Areas with available ground and other data were included (e.g., experimental forests, FLUXNET sites) in order to facilitate numerous bio- and geophysical investigations. Data collected included ground elevation and canopy height measurements for each laser footprint, as well as the vertical distribution of intercepted surfaces (i.e. the return waveform). Data are currently available at the LVIS website (http://lvis.gsfc.nasa.gov/). Further details of the mission, including the lidar system technology, the locations of the mapped areas, and examples of the numerous data products that can be derived from the return waveform data products are available on the website and will be presented. Future applications including potential fusion with other remote sensing data sets and a spaceborne implementation of wide-swath, full-waveform imaging lidar will also be discussed.

Blair, B.↗
NASA NTRS2016

Global Carbon Budget 2016

Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere the global carbon budget is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and methodology to quantify all major components of the global carbon budget, including their uncertainties, based on the combination of a range of data, algorithms, statistics, and model estimates and their interpretation by a broad scientific community. We discuss changes compared to previous estimates and consistency within and among components, alongside methodology and data limitations. CO2 emissions from fossil fuels and industry (EFF) are based on energy statistics and cement production data, respectively, while emissions from land-use change (ELUC), mainly deforestation, are based on combined evidence from land-cover change data, fire activity associated with deforestation, and models. The global atmospheric CO2 concentration is measured directly and its rate of growth (GATM) is computed from the annual changes in concentration. The mean ocean CO2 sink (SOCEAN) is based on observations from the 1990s, while the annual anomalies and trends are estimated with ocean models. The variability in SOCEAN is evaluated with data products based on surveys of ocean CO2 measurements. The global residual terrestrial CO2 sink (SLAND) is estimated by the difference of the other terms of the global carbon budget and compared to results of independent dynamic global vegetation models. We compare the mean land and ocean fluxes and their variability to estimates from three atmospheric inverse methods for three broad latitude bands. All uncertainties are reported as +/- 1(sigma), reflecting the current capacity to characterize the annual estimates of each component of the global carbon budget. For the last decade available (2006-2015), EFF was 9.3+/-0.5 GtC/yr, ELUC 1.0+/-0.5 GtC/yr,GATM 4.5+/-0.1 GtC/yr, SOCEAN 2.6+/-0.5 GtC/yr, and SLAND 3.1+/-0.9 GtC/yr. For year 2015 alone, the growth in EFF was approximately zero and emissions remained at 9.9+/-0.5 GtC/yr, showing a slowdown in growth of these emissions compared to the average growth of 1.8/yr that took place during 2006-2015.Also, for 2015, ELUC was 1.3+/-0.5 GtC/yr, GATM was 6.3+/-0.2 GtC/yr, SOCEAN was 3.0+/-0.5 GtC/yr, and SLAND was 1.9+/-0.9 GtC/yr. GATM was higher in 2015 compared to the past decade (2006-2015), reflecting a smaller SLAND for that year. The global atmospheric CO2 concentration reached 399.4+/-0.1 ppm averaged over 2015. For 2016, preliminary data indicate the continuation of low growth in EFF with +0.2% (range of -1.0 to +1.8% ) based on national emissions projections for China and USA, and projections of gross domestic product corrected for recent changes in the carbon intensity of the economy for the rest of the world. In spite of the low growth of EFF in 2016, the growth rate in atmospheric CO2 concentration is expected to be relatively high because of the persistence of the smaller residual terrestrial sink (SLAND) in response to El Nino conditions of 2015-2016. From this projection of EFF and assumed constant ELUC for 2016, cumulative emissions of CO2 will reach 565+/-55 GtC (2075+/-205 GtCO2) for 1870-2016, about 75% from EFF and 25% from ELUC. This living data update documents changes in the methods and data sets used in this new carbon budget compared with previous publications of this data set.

Quéré, Corinne Le↗
NASA NTRS2007

Oxygen Generation from Carbon Dioxide for Advanced Life Support

The partial electrochemical reduction of CO2 using ceramic oxygen generators (COGs) is well known and has been studied. Conventional COGs use yttria-stabilized zirconia (YSZ) electrolytes and operate at temperatures greater than 700 C (1, 2). Operating at a lower temperature has the advantage of reducing the mass of the ancillary components such as insulation. Moreover, complete reduction of metabolically produced CO2 (into carbon and oxygen) has the potential of reducing oxygen storage weight if the oxygen can be recovered. Recently, the University of Florida developed ceramic oxygen generators employing a bilayer electrolyte of gadolinia-doped ceria and erbia-stabilized bismuth oxide (ESB) for NASA s future exploration of Mars (3). The results showed that oxygen could be reliably produced from CO2 at temperatures as low as 400 C. These results indicate that this technology could be adapted to CO2 removal from a spacesuit and other applications in which CO2 removal is an issue. This strategy for CO2 removal in advanced life support systems employs a catalytic layer combined with a COG so that the CO2 is reduced completely to solid carbon and oxygen. First, to reduce the COG operating temperature, a thin, bilayer electrolyte was employed. Second, to promote full CO2 reduction while avoiding the problem of carbon deposition on the COG cathode, a catalytic carbon deposition layer was designed and the cathode utilized materials shown to be coke resistant. Third, a composite anode was used consisting of bismuth ruthenate (BRO) and ESB that has been shown to have high performance (4). The inset of figure 1 shows the conceptual design of the tubular COG and the rest of the figure shows schematically the test apparatus. Figure 2 shows the microstructure of a COG tube prior to testing. During testing, current is applied across the cell and initially CuO is reduced to copper metal by electrochemical pumping. Then the oxygen source becomes the CO/CO2. This presentation details the results of testing the COG.

Bishop, s. R.↗
NASA NTRS2019

Global Carbon Budget 2019

Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere – the “global carbon budget” – is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and methodology to quantify the five major components of the global carbon budget and their uncertainties. Fossil CO2 emissions (E(FF)) are based on energy statistics and cement production data, while emissions from land use change (E(LUC)), mainly deforestation, are based on land use and land use change data and bookkeeping models. Atmospheric CO2 concentration is measured directly and its growth rate (G(ATM)) is computed from the annual changes in concentration. The ocean CO2 sink (S(OCEAN)) and terrestrial CO2 sink (S(LAND)) are estimated with global process models constrained by observations. The resulting carbon budget imbalance (B(IM)), the difference between the estimated total emissions and the estimated changes in the atmosphere, ocean, and terrestrial biosphere, is a measure of imperfect data and understanding of the contemporary carbon cycle. All uncertainties are reported as ±1σ. For the last decade available (2009–2018), E(FF) was 9.5±0.5 GtC/yr, E(LUC) 1.5±0.7 GtC/yr, G(ATM) 4.9±0.02 GtC/yr (2.3±0.01 ppm/yr), S(OCEAN) 2.5±0.6 GtC/yr, and S(LAND) 3.2±0.6 GtC/yr, with a budget imbalance B(IM) of 0.4 GtC/yr indicating overestimated emissions and/or underestimated sinks. For the year 2018 alone, the growth in E(FF) was about 2.1 % and fossil emissions increased to 10.0±0.5 GtC/yr, reaching 10 GtC/yr for the first time in history, E(LUC) was 1.5±0.7 GtC/yr, for total anthropogenic CO2 emissions of 11.5±0.9 GtC/yr (42.5±3.3 GtCO2). Also for 2018, G(ATM) was 5.1±0.2 GtC/yr (2.4±0.1 ppm/yr), S(OCEAN) was 2.6±0.6 GtC/yr, and S(LAND) was 3.5±0.7 GtC/yr, with a B(IM) of 0.3 GtC. The global atmospheric CO2 concentration reached 407.38±0.1 ppm averaged over 2018. For 2019, preliminary data for the first 6–10 months indicate a reduced growth in E(FF) of +0.6 % (range of −0.2 % to 1.5 %) based on national emissions projections for China, the USA, the EU, and India and projections of gross domestic product corrected for recent changes in the carbon intensity of the economy for the rest of the world. Overall, the mean and trend in the five components of the global carbon budget are consistently estimated over the period 1959–2018, but discrepancies of up to 1 GtC/yr persist for the representation of semi-decadal variability in CO2 fluxes. A detailed comparison among individual estimates and the introduction of a broad range of observations shows (1) no consensus in the mean and trend in land use change emissions over the last decade, (2) a persistent low agreement between the different methods on the magnitude of the land CO2 flux in the northern extra-tropics, and (3) an apparent underestimation of the CO2 variability by ocean models outside the tropics. This living data update documents changes in the methods and data sets used in this new global carbon budget and the progress in understanding of the global carbon cycle compared with previous publications of this data set (Le Quéré et al., 2018a, b, 2016, 2015a, b, 2014, 2013).

global carbon budget 2019↗
NASA NTRS2012

Performance Evaluation of Staged Bosch Process for CO2 Reduction to Produce Life Support Consumables

Utilizing carbon dioxide to produce water and hence oxygen is critical for sustained manned missions in space, and to support both NASA's cabin Atmosphere Revitalization System (ARS) and In-Situ Resource Utilization (ISRU) concepts. For long term missions beyond low Earth orbit, where resupply is significantly more difficult and costly, open loop ARS, like Sabatier, consume inputs such as hydrogen. The Bosch process, on the other hand, has the potential to achieve complete loop closure and is hence a preferred choice. However, current single stage Bosch reactor designs suffer from a large recycle penalty due to slow reaction rates and the inherent limitation in approaching thermodynamic equilibrium. Developmental efforts are seeking to improve upon the efficiency (hence reducing the recycle penalty) of current single stage Bosch reactors which employ traditional steel wool catalysts. Precision Combustion, Inc. (PCI), with support from NASA, has investigated the potential for utilizing catalysts supported over short-contact time Microlith substrates for the Bosch reaction to achieve faster reaction rates, higher conversions, and a reduced recycle flows. Proof-of-concept testing was accomplished for a staged Bosch process by splitting the chemistry in two separate reactors, first being the reverse water-gas-shift (RWGS) and the second being the carbon formation reactor (CFR) via hydrogenation and/or Boudouard. This paper presents the results from this feasibility study at various operating conditions. Additionally, results from two 70 hour durability tests for the RWGS reactor are discussed.

Vilekar, Saurabh A.↗
NASA NTRS1992

Evolution of a phase separated gravity independent bioreactor

The evolution of a phase-separated gravity-independent bioreactor is described. The initial prototype, a zero head-space manifold silicone membrane based reactor, maintained large diffusional resistances. Obtaining oxygen transfer rates needed to support carbon-recycling aerobic microbes is impossible if large resistances are maintained. Next generation designs (Mark I and II) mimic heat exchanger design to promote turbulence at the tubing-liquid interface, thereby reducing liquid and gas side diffusional resistances. While oxygen transfer rates increased by a factor of ten, liquid channeling prevented further increases. To overcome these problems, a Mark III reactor was developed which maintains inverted phases, i.e., media flows inside the silicone tubing, oxygen gas is applied external to the tubing. This enhances design through changes in gas side driving force concentration and liquid side turbulence levels. Combining an applied external pressure of 4 atm with increased Reynolds numbers resulted in oxygen transfer intensities of 232 mmol O2/l per hr (1000 times greater than the first prototype and comparable to a conventional fermenter). A 1.0 liter Mark III reactor can potentially deliver oxygen supplies necessary to support cell cultures needed to recycle a 10-astronaut carbon load continuously.

Villeneuve, Peter E.↗
NASA NTRS2022

Global Carbon Budget 2022

Accurate assessment of anthropogenic carbon dioxide (CO 2 ) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere in a changing climate is critical to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe and synthesize data sets and methodologies to quantify the five major components of the global carbon budget and their uncertainties. Fossil CO 2 emissions (E FOS ) are based on energy statistics and cement production data, while emissions from land-use change (E LUC ), mainly deforestation, are based on land use and land-use change data and bookkeeping models. Atmospheric CO 2 concentration is measured directly, and its growth rate (G ATM ) is computed from the annual changes in concentration. The ocean CO 2 sink (S OCEAN ) is estimated with global ocean biogeochemistry models and observation-based data products. The terrestrial CO 2 sink (S LAND ) is estimated with dynamic global vegetation models. The resulting carbon budget imbalance (B IM ), the difference between the estimated total emissions and the estimated changes in the atmosphere, ocean, and terrestrial biosphere, is a measure of imperfect data and understanding of the contemporary carbon cycle. All uncertainties are reported as ±1σ. For the year 2021, E FOS increased by 5.1 % relative to 2020, with fossil emissions at 10.1 ± 0.5 GtC yr −1 (9.9 ± 0.5 GtC yr −1 when the cement carbonation sink is included), and E LUC was 1.1 ± 0.7 GtC yr −1 , for a total anthropogenic CO 2 emission (including the cement carbonation sink) of 10.9 ± 0.8 GtC yr −1 (40.0 ± 2.9 GtCO 2 ). Also, for 2021, G ATM was 5.2 ± 0.2 GtC yr −1 (2.5 ± 0.1 ppm yr −1 ), S OCEAN was 2.9 ± 0.4 GtC yr −1 , and S LAND was 3.5 ± 0.9 GtC yr −1 , with a B IM of −0.6 GtC yr −1 (i.e. the total estimated sources were too low or sinks were too high). The global atmospheric CO 2 concentration averaged over 2021 reached 414.71 ± 0.1 ppm. Preliminary data for 2022 suggest an increase in E FOS relative to 2021 of +1.0 % (0.1 % to 1.9 %) globally and atmospheric CO 2 concentration reaching 417.2 ppm, more than 50 % above pre-industrial levels (around 278 ppm). Overall, the mean and trend in the components of the global carbon budget are consistently estimated over the period 1959–2021, but discrepancies of up to 1 GtC yr −1 persist for the representation of annual to semi-decadal variability in CO 2 fluxes. Comparison of estimates from multiple approaches and observations shows (1) a persistent large uncertainty in the estimate of land-use change emissions, (2) a low agreement between the different methods on the magnitude of the land CO 2 flux in the northern extratropics, and (3) a discrepancy between the different methods on the strength of the ocean sink over the last decade. This living data update documents changes in the methods and data sets used in this new global carbon budget and the progress in understanding of the global carbon cycle compared with previous publications of this data set. The data presented in this work are available at https://doi.org/10.18160/GCP-2022 (Friedlingstein et al., 2022b).

Pierre Friedlingstein↗
NASA NTRS2019

Global Ocean Primary Production Trends in the Modern Ocean Color Satellite Record (1998-2015)

Ocean primary production (PP), representing the uptake of inorganic carbon through photosynthesis, supports marine life and affects carbon exchange with the atmosphere. It is difficult to ascertain its magnitude, variability, and trends due to our inability to measure it directly at large scales. Yet it is paramount for understanding changes in marine health, fisheries, and the global carbon cycle. Using assimilation of ocean color satellite data into an ocean biogeochemical model, we estimate that global net ocean PP has experienced a small but significant decline −0.8 PgC/y (−2.1%) per decade (P < 0.05) in the 18-year satellite record from 1998 to 2015. This decline is associated with shallowing surface mixed layer depth (−2.4% per decade) and decreasing nitrate concentrations (−3.2% per decade). Relative contributions to PP by various types of ocean phytoplankton have changed, with decreases in production by intermediate-sized phytoplankton represented by chlorophytes (−14.3% per decade). This is partially compensated by increases from the unique, more nutrient-efficient, coccolithophores (8.4% per decade). Geographically, the North and Equatorial Indian Oceans are responsible for much of the decline in PP, falling 0.16 and 0.69 PgC/y per decade, respectively. Reduced production by large, fast-growing diatoms along with chlorophytes characterizes the decline here. In contrast, increases in PP are found in the North and North Central Pacific. The increases here are led by chlorophytes in the North Pacific and the small cyanobacteria in the North Central Pacific. These results suggest that the multi-decadal satellite observational record, coupled with an underlying representation of marine biodiversity in a model, can monitor the uptake of carbon by phytoplankton and that changes, although small, are occurring in the global oceans.

Watson W Gregg↗
NASA NTRS2003

Carbon balance in bioregenerative life support systems: some effects of system closure, waste management, and crop harvest index

In Advanced Life Support (ALS) systems with bioregenerative components, plant photosynthesis would be used to produce O2 and food, while removing CO2. Much of the plant biomass would be inedible and hence must be considered in waste management. This waste could be oxidized (e.g., incinerated or aerobically digested) to resupply CO2 to the plants, but this would not be needed unless the system were highly closed with regard to food. For example, in a partially closed system where some of the food is grown and some is imported, CO2 from oxidized waste when combined with crew and microbial respiration could exceed the CO2 removal capability of the plants. Moreover, it would consume some O2 produced from photosynthesis that could have been used by the crew. For partially closed systems it would be more appropriate to store or find other uses for the inedible biomass and excess carbon, such as generating soils or growing woody plants (e.g., dwarf fruit trees). Regardless of system closure, high harvest crops (i.e., crops with a high edible to total biomass ratio) would increase food production per unit area and O2 yields for systems where waste biomass is oxidized to recycle CO2. Such interlinking effects between the plants and waste treatment strategies point out the importance of oxidizing only that amount of waste needed to optimize system performance. Published by Elsevier Science Ltd on behalf of COSPAR.

NASA Discipline Life Support Systems↗
NASA NTRS2006

Laboratory Spectroscopy of Large Carbon Molecules and Ions in Support of Space Missions

One of the major objectives of Laboratory Astrophysics is the optimization of data return from space missions by measuring spectra of atomic and molecular species in laboratory environments that mimic interstellar conditions (WhitePaper (2002, 2006)). Among interstellar species, PAHs are an important and ubiquitous component of carbon-bearing materials that represents a particularly difficult challenge for gas-phase laboratory studies. We present the absorption spectra of jet-cooled neutral and ionized PAHs and discuss the implications for astrophysics. The harsh physical conditions of the interstellar medium have been simulated in the laboratory. We are now, for the first time, in the position to directly compare laboratory spectra of PAHs and carbon nanoparticles with astronomical observations. This new phase offers tremendous opportunities for the data analysis of current and upcoming space missions geared toward the detection of large aromatic systems (HST/COS, FUSE, JWST, Spitzer).

Salana, Farid↗
NASA NTRS2023

Damage Tolerance Comparison of IM7/8552 and T1100/3960 Carbon Fiber/Epoxy Sandwich Structure in Support of the Space Launch System Payload Adapter Fitting

As technology evolves and improves within the science of composite materials, new fiber/ resin systems are being developed for improved properties given certain loading and environmental scenarios. Improving the room temperature damage tolerance capabilities has long been one of the goals in the carbon fiber/polymer composite industry. Recently a new fiber/epoxy system has been introduced that is claimed to have superior damage tolerance capabilities. To examine if this new carbon fiber/epoxy composite material would be of benefit to a program to manufacture a Payload Adapter Fitting (PAF) for NASA’s Space Launch System (SLS) rocket, the question was asked as to just how much damage tolerance could be realized if this new system were used. Compression after impact (CAI) strength of sandwich structure is one of the leading metrics being used to evaluate materials for the PAF program. As a result, a comparison of this new fiber/resin system with a very common (and planned baseline) fiber/resin system with respect to CAI was considered in this study. While it was already known that the older, baseline carbon fiber structure would not have as good damage tolerance characteristics as the newer carbon fiber system, the quantitative difference in damage tolerance was sought in this study since no other CAI data could be found in open literature on sandwich structures made with this new fiber/resin system.

A.T. Nettles↗
NASA NTRS2016

Game Changing Development Program - Next Generation Life Support Project: Oxygen Recovery From Carbon Dioxide Using Ion Exchange Membrane Electrolysis Technology

This report summarizes the Phase I research and development work performed during the March 13, 2015 to July 13, 2016 period. The proposal for this work was submitted in response to NASA Research Announcement NNH14ZOA001N, "Space Technology Research, Development, Demonstration, and Infusion 2014 (SpaceTech-REDDI-2014)," Appendix 14GCD-C2 "Game Changing Development Program, Advanced Oxygen Recovery for Spacecraft Life Support Systems Appendix" The Task Agreement for this Phase I work is Document Control Number: GCDP-02-TA-15015. The objective of the Phase I project was to demonstrate in laboratories two Engineering Development Units (EDU) that perform critical functions of the low temperature carbon dioxide electrolysis and the catalytic conversion of carbon monoxide into carbon and carbon dioxide. The low temperature carbon dioxide electrolysis EDU was built by the University of Delaware with Dr. Feng Jiao as the principal investigator in charge of this EDU development (under NASA Contract NNC15CA04C). The carbon monoxide catalytic conversion EDU was built by the NASA Glenn Research Center with Kenneth Burke as the principal investigator and overall project leader for the development of both EDUs. Both EDUs were successfully developed and demonstrated the critical functions for each process. The carbon dioxide electrolysis EDU was delivered to the NASA Johnson Space Center and the carbon monoxide catalytic conversion EDU was delivered to the NASA Marshall Spaceflight Center.

Oxygen Recovery↗