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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS2000

Preventing Damaging Pressure Gradients at the Walls of an Inflatable Space System

An inflatable structural system to deploy a space system such as a solar shield, an antenna or another similar instrument, requires a stiffening element after it is extended by the inflated gas pressure. The stiffening element has to be packaged in a folded configuration before the deployment. It must be relatively small, lightweight, non-damaging to the inflated system, and be able to become stiff in a short time. One stiffening method is to use a flexible material inserted in the deployable system, which, upon a temperature curing, can become stiff and is capable to support the entire structure. There are two conditions during the space operations when the inflated volume could be damaged: during the transonic region of the launch phase and when the curing of the rigidizing element occurs. In both cases, an excess of pressure within the volume containing the rigid element could burst the walls of the low-pressure gas inflated portion of the system. This paper investigates those two conditions and indicates the vents, which will prevent those damaging overpressures. Vent openings at the non-inflated volumes have been calculated for the conditions existing during the launch. Those vents allow the initially folded volume to exhaust the trapped atmospheric gas at approximately the same rate as the ambient pressure drops. That will prevent pressure gradients across the container walls which otherwise could be as high as 14.7 psi. The other condition occurring during the curing of the stiffening element has been investigated. This has required the testing of the element to obtain the gas generation during the curing and the transformation from a pliable material to a rigid one. The tested material is a composite graphite/epoxy weave. The outgassing of the uncured sample at 121C was carried with the Cahn Microbalance and with other outgassing facilities including the micro-CVCM ASTM E-595 facility. The tests provided the mass of gas evolved during the test. That data, including the chemical nature of the evolved gas, provided the data for the calculation of the pressure produced within the volume. The evaluation of the areas of the vents that would prevent excessive pressures and provide a rapid release of the gas away from contamination sensitive surfaces has been carried out. The pressure decay with time has been indicated.

Scialdone, John J.↗
NASA NTRS2000

Preventing Damaging Pressure Gradients at the Walls of an Inflatable Space System

An inflatable structural system to deploy a space system such as a solar shield, an antenna or another similar instrument requires a stiffening element after it is extended by the inflated gas pressure. The stiffening element has to be packaged in folded configuration before the deployment. It must be relatively small, lightweight, non-damaging to the inflated system and be able to become stiff in a short time. One stiffening method is to use a flexible material inserted in the deployable system, which, upon a temperature curing, can become stiff and is capable of supporting the entire structure. There are two conditions during the space operations when the inflated volume could be damaged: during the transonic region of the launch phase and when the curing of the rigidizing element occurs. In both cases, an excess of pressure within the volume containing the rigid element could burst the walls of the low-pressure gas inflated portion of the system. This paper investigates those two conditions and indicates the vents, which will prevent those damaging overpressures. Vent openings at the non-inflated volumes have been calculated for the conditions existing during the launch. Those vents allow the initially folded volume to exhaust the trapped atmospheric gas at approximately the same rate as the ambient pressure drops. That will prevent pressure gradients across the container walls which otherwise could be as high as 14.7 psi. The other condition occurring during the curing of the stiffening element has been investigated. This has required the testing of the element to obtain the gas generation during the curing and the transformation from a pliable material to a rigid on The tested material is a composite graphite/epoxy weave. The outgassing of the uncured sample at 121 deg Celcius was carried with the Cahn Microbalance and with other outgassing facilities including the micro-CVCM ASTM E-595 facility. The test provided the mass of gas evolved during the test. That data, including the chemical nature of the evolved gas, provided the data for the calculation of the pressure produced within the volume. The evaluation of the areas of the vents that would prevent excessive pressures and provide a rapid release of the gas away from contamination sensitive surfaces has be carried out. The pressure decay with time has been indicated.

Scialdone, John J.↗
NASA NTRS2000

Material Total Mass Loss in Vacuum Obtained From Various Outgassing Systems

Several instruments including the Cahn Microbalance, the Knudsen Cell, the micro-CVCM, and the vacuum Thermogravimetric Analyzer (TGA) were used in the testing of a graphite/epoxy (GR/EP) composite that is proposed for use as a rigidizing element of an inflatable deployment system. This GR/EP will be cured in situ. The purpose of this testing is to estimate the gaseous production resulting from the curing of the GR/EP composite, to predict the resulting pressure, and to calculate the required venting. Every test was conducted under vacuum at 125 degrees C for 24 hours. Upon comparison of the results, the ASTM E-595 was noted to have given readings that were consistently lower than those obtained using the other instruments, which otherwise provided similar results. The GR/EP was tested using several different geometric arrangements. This paper describes the analysis evaluating the molecular and continuum flow of the outgassing products issuing from the exit port of the ASTM E-595 system. The effective flow conductance provided by the physical dimensions of the vent passage of the ASTM E-595 system and that of the material sample among other factors were investigated to explain the reduced amount of outgassing released during the 24-hour test period.

Scialdone, John↗
NASA NTRS2000

Outgassing Total Mass Loss Obtained with Micro-CVCM and Other Vacuum Systems

Several instruments including the Cahn Microbalance, the Knudsen Cell, the micro-CVCM, and the vacuum Thermogravimetric Analyzer (TGA) were used in the testing of a graphite epoxy (GR/EP) composite that is proposed for use as a rigidizing element of an inflatable deployment system. This GR/EP will be cured in situ. The purpose of this testing is to estimate the gaseous production resulting from the curing of the GR/EP composite, to predict the resulting pressure, and to calculate the required venting. Every test was conducted under vacuum at 125 C for 24 hours. Upon comparison of the results, the ASTM E-595 was noted to have given readings that were consistently lower than those obtained using the other instruments, which otherwise provided similar results. The GR/EP was tested using several different geometric arrangements. This paper describes the analysis evaluating the molecular and continuum flow of the outgassing products issuing from the exit port of the ASTM E-595 system. The effective flow conductance provided by the physical dimensions of the vent passage of the ASTM E-595 system and that of the material sample among other factors were investigated to explain the reduced amount of outgassing released during the 24-hour test period,

Scialdone, John↗
NASA NTRS2002

Material Outgassing, Identification and Deposition, MOLIDEP System

The outgassing tests are performed employing a modified vacuum operated Cahn analytical microbalance, identified as the MOLIDEP system. The test measures under high vacuum, the time varying Molecular mass loss of a material sample held at a chosen temperature; it Identifies the outgassing molecular components using an inline SRS 300 amu Residual Gas Analyzer (RGA) and employs a temperature controlled 10 MHz Quartz Crystal Microbalance (QCM) to measure the condensable DEPosits. Both the QCM and the RGA intercept within the conductive passage the outgassing products being evacuated by a turbomolecular pump. The continuous measurements of the mass loss, the rate of loss, the sample temperature, the rate of temperature change, the QCM temperature and the QCM recorded condensable deposits or rate of deposits are saved to an Excel spreadsheet. A separate computer controls the RGA.

Scialdone, John J.↗
NASA NTRS2003

Initial Measurement of the Vapor Pressures of Simple Refractory Materials: Cu and Fe

It has become increasingly clear over the past decade that high temperature processes played important roles in the Primitive Solar Nebula. Unfortunately, basic data, such as the vapor pressures of iron or SiO have not been measured over the appropriate temperature range (near T approximately equal to 2000K), but must be extrapolated from lower temperature measurements often made more than 50 years ago. The extrapolation of the available data to higher temperatures can be quite complex and can depend on other factors such as the oxygen fugacity or the presence of hydrogen gas. Moreover, modern technology has made possible more accurate measurements of such quantities over a wider temperature range. We recently acquired a commercial Thermo-Cahn Thermogravimetric system capable of vacuum operation to 1700 C and measurement of mass change with microgram accuracy in a 100g sample or smaller. In this paper, we will report our progress in learning to make vapor pressure measurements using this system.

Nuth, Joseph A., III↗
NASA NTRS2004

Effusion Cell Measurements of the Vapor Pressure of Cobalt at Temperatures up to 2000K; Comparisons with Iron and Nickel

It has become increasingly clear over the past decade that high temperature processes played important roles in the Primitive Solar Nebula. Unfortunately, basic data, such as the vapor pressures of Fe, Ni, Co or SiO have not been measured over the appropriate temperature range (near T approx. 2000K), but must be extrapolated from lower temperature measurements often made more than 50 years ago. The extrapolation of the available data to higher temperatures can be quite complex (e.g., see [1] for SiO vapor pressures) and can depend on other factors such as the oxygen fugacity or the presence of hydrogen gas not accounted for in the original measurements. Moreover, modern technology has made possible more accurate measurements of such quantities over a wider temperature range. We have acquired a commercial Thermo-Cahn Thermogravimetric system capable of vacuum operation to 1700C and measurement of a 10g change in sample mass using up to a 100g sample, with microgram accuracy. With this new system we have initiated a series of basic vapor pressure measurements on simple metals such as Fe[2] and Ni[3] with the intention to extend such measurements to more complex systems once we gain sufficient experience.

Nuth, J. A.↗
NASA NTRS2005

The Vapor Pressure of Palladium at Temperatures up to 1973K

Understanding high-temperature processes is imperative for modeling the formation of the solar system. It is unfortunate that since the 1950 s little has been done in the area of thermodynamics to continue gaining information on metals such as iron (Fe), nickel (Ni), cobalt (Co), palladium (Pd) and many others. Although the vapor pressures of these metals can be extrapolated to higher temperatures, the data is often limited to temperature ranges too low to be applicable to processes that occur during the formation of the solar system (T approx. 2000K). Experimental techniques inhibited the data in the past by restricting the testing of metals to temperatures below their melting point. Today, higher temperature testing is possible by using a Thermo- Cahn Thermogravimetric system that is able to reach temperatures up to 1973K in vacuo and measure a 10 gram change in a sample with mass of up to 100 grams.

Gardner, K. G.↗
NASA NTRSDate not supplied

A General Model for the Electrochemical Double Layer in Solids

It has long been clear that electrochemical double layer / space charge zone in the vicinity of interfaces and other extended defects greatly influences transport and reactivity. Over the past several years, multiple microscopic measurements of defect concentrations in the vicinity of solid-solid interfaces made clear that dilute-case thermodynamic theories to describe the behavior of charged species in space charge zones are untenable. Inhomogeneous thermodynamics – i.e., phase field models – have delivered the most success in describing both microscopic and macroscopic experiments. We still need a generalized approach that quantitatively reproduces the microscopic and macroscopic evidence, while remaining accessible to a wide range of researchers and engineers. In my talk I will present such a framework, which builds on the previously introduced Poisson-Cahn theory but utilizes data science methods which come into the thermodynamic framework in a well-defined way. I will review recent applications to both microscopic and macroscopic datasets while previewing our plans for connecting the theory to atomistic / first principles calculations and experiment simultaneously. I will also review plans for releasing open source code that runs on desktop-level computational resources.

David Mebane↗
DOE OSTI2026

Parity-odd four-point correlation function from the DESI data release 1 luminous red galaxy sample

The parity-odd four-point function provides a unique probe of fundamental symmetries and potential new physics in the large-scale structure of the Universe. We present measurements of the parity-odd four-point function using the Dark Energy Spectroscopic Instrument (DESI) DR1 luminous red galaxy (LRG) sample and assess its detection significance. Our analysis considers both auto- and cross-correlations, using two complementary approaches to the covariance: (i) the full analytic covariance matrix applied to the uncompressed data vector, and (ii) a compressed data vector combined with a hybrid covariance matrix constructed from simulations and analytic estimates. When using the full analytic covariance matrix without corrections, we observe apparent auto-correlation signals with significance up to 4⁢𝜎. However, this excess is also consistent with a mismatch between the statistical fluctuations estimated from the simulations and those present in the real data. Our findings therefore suggest that the parity-odd signal in the current DESI DR1 LRG sample is consistent with zero. We note, however, that the low completeness of this sample may have a non-negligible impact on the detection sensitivity. Future data releases with improved completeness will be crucial for further investigation.

Hou, Jiamin [Ludwig-Maximilians-Universität; Unive↗
DOE OSTI2025

Review of Particle Physics - Scalar Mesons below 1 GeV

The summarizes much of particle physics and cosmology. Using data from previous editions, plus 2,717 new measurements from 869 papers, we list, evaluate, and average measured properties of gauge bosons and the recently discovered Higgs boson, leptons, quarks, mesons, and baryons. We summarize searches for hypothetical particles such as supersymmetric particles, heavy bosons, axions, dark photons, etc. Particle properties and search limits are listed in Summary Tables. We give numerous tables, figures, formulae, and reviews of topics such as Higgs Boson Physics, Supersymmetry, Grand Unified Theories, Neutrino Mixing, Dark Energy, Dark Matter, Cosmology, Particle Detectors, Colliders, Probability and Statistics. Most of the 120 reviews are updated, including many that are heavily revised. The is divided into two volumes. Volume 1 includes the Summary Tables and 97 review articles. Volume 2 consists of the Particle Listings and contains also 23 reviews that address specific aspects of the data presented in the Listings. The complete (both volumes) is published online on the website of the Particle Data Group () and in a journal. Volume 1 is available in print as the . A with the Summary Tables and essential tables, figures, and equations from selected review articles is available in print, as a web version optimized for use on phones, and as an Android app. The 2024 edition of the Review of Particle Physics should be cited as: S. Navas et al. (Particle Data Group), Phys. Rev. D 110, 030001 (2024)© 20242024

Navas, S. [Universidad de Granada]↗
DOE OSTI2023

A chloroplast protein atlas reveals punctate structures and spatial organization of biosynthetic pathways

Chloroplasts are eukaryotic photosynthetic organelles that drive the global carbon cycle. Despite their importance, our understanding of their protein composition, function, and spatial organization remains limited. Here, we determined the localizations of 1,034 candidate chloroplast proteins using fluorescent protein tagging in the model alga Chlamydomonas reinhardtii. The localizations provide insights into the functions of poorly characterized proteins; identify novel components of nucleoids, plastoglobules, and the pyrenoid; and reveal widespread protein targeting to multiple compartments. We discovered and further characterized cellular organizational features, including eleven chloroplast punctate structures, cytosolic crescent structures, and unexpected spatial distributions of enzymes within the chloroplast. We also used machine learning to predict the localizations of other nuclear-encoded Chlamydomonas proteins. The strains and localization atlas developed here will serve as a resource to accelerate studies of chloroplast architecture and functions.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Onion-Like nanoparticles of the metal–organic framework UiO-66 synthesized by sequential spike crystal growth

Reproducible size and morphology of metal–organic framework (MOF) particles are essential for tuning these materials for applications like heterogeneous catalysis. Particle size measurements from electron micrographs provide information about the impact of changing synthetic parameters on MOF growth, but reported data are usually limited to averages and statistical distributions. Further elucidating synthetic control parameters could facilitate studies of facet-dependent and non-classical growth mechanisms. Here, in this work, phase-pure nanoparticles of the MOF UiO-66 were synthesized using alternating spikes of zirconium and hafnium-based nodes, forming an onion-like structure with alternating layers of Zr-UiO-66 and Hf-UiO-66. In conventional, bright-field transmission electron micrographs, Hf-UiO-66 and Zr-UiO-66 layers appeared darker and lighter, respectively. Alternating layers of Hf-UiO-66 and Zr-UiO-66 were also apparent in elemental maps obtained using scanning transmission electron microscopy with energy-dispersive X-ray spectroscopy. Average particle sizes increased monotonically with each spike, and no Zr-only or Hf-only particles were observed after the first spike, indicating that new material was consistently incorporated onto existing seeds. Surface area of the onion-like particles and their uptake of Ni 2+ from solution were both between the values measured for Zr-UiO-66 and Hf-UiO-66. Results demonstrate the use of sequential spikes of nodes in monitoring crystal growth in MOFs.

36 MATERIALS SCIENCE↗
DOE OSTI2021

1q21.1 distal copy number variants are associated with cerebral and cognitive alterations in humans

Low-frequency 1q21.1 distal deletion and duplication copy number variant (CNV) carriers are predisposed to multiple neurodevelopmental disorders, including schizophrenia, autism and intellectual disability. Human carriers display a high prevalence of micro- and macrocephaly in deletion and duplication carriers, respectively. The underlying brain structural diversity remains largely unknown. We systematically called CNVs in 38 cohorts from the large-scale ENIGMA-CNV collaboration and the UK Biobank and identified 28 1q21.1 distal deletion and 22 duplication carriers and 37,088 non-carriers (48% male) derived from 15 distinct magnetic resonance imaging scanner sites. With standardized methods, we compared subcortical and cortical brain measures (all) and cognitive performance (UK Biobank only) between carrier groups also testing for mediation of brain structure on cognition. We identified positive dosage effects of copy number on intracranial volume (ICV) and total cortical surface area, with the largest effects in frontal and cingulate cortices, and negative dosage effects on caudate and hippocampal volumes. The carriers displayed distinct cognitive deficit profiles in cognitive tasks from the UK Biobank with intermediate decreases in duplication carriers and somewhat larger in deletion carriers—the latter potentially mediated by ICV or cortical surface area. These results shed light on pathobiological mechanisms of neurodevelopmental disorders, by demonstrating gene dose effect on specific brain structures and effect on cognitive function.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2023

An improved synthetic signal injection routine for the Haloscope At Yale Sensitive To Axion Cold dark matter (HAYSTAC)

Microwave cavity haloscopes are among the most sensitive direct detection experiments searching for dark matter axions via their coupling to photons. When the power of the expected microwave signal due to axion–photon conversion is on the order of 10 −24 W, having the ability to validate the detector response and analysis procedure by injecting realistic synthetic axion signals becomes helpful. Here, we present a method based on frequency hopping spread spectrum for synthesizing axion signals in a microwave cavity haloscope experiment. It allows us to generate a narrow and asymmetric shape in frequency space that mimics an axion’s spectral distribution, which is derived from a Maxwell–Boltzmann distribution. In addition, we show that the synthetic axion’s power can be calibrated with reference to the system noise. Further, compared to the synthetic axion injection in the Haloscope At Yale Sensitive to Axion Cold dark matter (HAYSTAC) Phase I, we demonstrated synthetic signal injection with a more realistic line shape and calibrated power.

47 OTHER INSTRUMENTATION↗
DOE OSTI2023

Large-scale analysis of structural brain asymmetries in schizophrenia via the ENIGMA consortium

Left–right asymmetry is an important organizing feature of the healthy brain that may be altered in schizophrenia, but most studies have used relatively small samples and heterogeneous approaches, resulting in equivocal findings. We carried out the largest case–control study of structural brain asymmetries in schizophrenia, with MRI data from 5,080 affected individuals and 6,015 controls across 46 datasets, using a single image analysis protocol. Asymmetry indexes were calculated for global and regional cortical thickness, surface area, and subcortical volume measures. Differences of asymmetry were calculated between affected individuals and controls per dataset, and effect sizes were meta-analyzed across datasets. Small average case–control differences were observed for thickness asymmetries of the rostral anterior cingulate and the middle temporal gyrus, both driven by thinner left-hemispheric cortices in schizophrenia. Analyses of these asymmetries with respect to the use of antipsychotic medication and other clinical variables did not show any significant associations. Assessment of age- and sex-specific effects revealed a stronger average leftward asymmetry of pallidum volume between older cases and controls. Case–control differences in a multivariate context were assessed in a subset of the data (N = 2,029), which revealed that 7% of the variance across all structural asymmetries was explained by case–control status. Subtle case–control differences of brain macrostructural asymmetry may reflect differences at the molecular, cytoarchitectonic, or circuit levels that have functional relevance for the disorder. Reduced left middle temporal cortical thickness is consistent with altered left-hemisphere language network organization in schizophrenia.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2025

Mitigation of DESI fiber assignment incompleteness effect on two-point clustering with small angular scale truncated estimators

We present a method to mitigate the effects of fiber assignment incompleteness in two-point power spectrum and correlation function measurements from galaxy spectroscopic surveys, by truncating small angular scales from estimators. We derive the corresponding modified correlation function and power spectrum windows to account for the small angular scale truncation in the theory prediction. We validate this approach on simulations reproducing the Dark Energy Spectroscopic Instrument (DESI) Data Release 1 (DR1) with and without fiber assignment. We show that we recover unbiased cosmological constraints using small angular scale truncated estimators from simulations with fiber assignment incompleteness, with respect to standard estimators from complete simulations. Additionally, we present an approach to remove the sensitivity of the fits to high k modes in the theoretical power spectrum, by applying a transformation to the data vector and window matrix. We find that our method efficiently mitigates the effect of fiber assignment incompleteness in two-point correlation function and power spectrum measurements, at low computational cost and with little statistical loss.

79 ASTRONOMY AND ASTROPHYSICS↗