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All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

Multi-property modeling of ocean basin carbon fluxes

The objectives of this project were to elucidate the causal mechanisms in some of the most important features of the global ocean/atomsphere carbon system. These included the interaction of physical and biological processes in the seasonal cycle of surface water pCo2, and links between productivity, surface chlorophyll, and the carbon cycle that would aid global modeling efforts. In addition, several other areas of critical scientific interest involving links between the marine biosphere and the global carbon cycle were successfully pursued; specifically, a possible relation between phytoplankton emitted DMS and climate, and a relation between the location of calcium carbonate burial in the ocean and metamorphic source fluxes of CO2 to the atmosphere. Six published papers covering the following topics are summarized: (1) Mass extinctions, atmospheric sulphur and climatic warming at the K/T boundary; (2) Sensitivity of climate and atmospheric CO2 to deep-ocean and shallow-ocean carbonate burial; (3) Controls on CO2 sources and sinks in the earthscale surface ocean; (4) pre-anthropogenic, earthscale patterns of delta pCO2 between ocean and atmosphere; (5) Effect on atmospheric CO2 from seasonal variations in the high latitude ocean; and (6) Limitations or relating ocean surface chlorophyll to productivity.

Volk, Tyler↗
NASA NTRS2015

Development of Double and Triple-Pulsed 2-micron IPDA Lidars for Column CO2 Measurements

Carbon dioxide (CO2) is an important greenhouse gas that significantly contributes to the carbon cycle and globalradiation budget on Earth. CO2 role on Earth’s climate is complicated due to different interactions with various climatecomponents that include the atmosphere, the biosphere and the hydrosphere. Although extensive worldwide efforts formonitoring atmospheric CO2 through various techniques, including in-situ and passive sensors, are taking place highuncertainties exist in quantifying CO2 sources and sinks. These uncertainties are mainly due to insufficient spatial andtemporal mapping of the gas. Therefore it is required to have more rapid and accurate CO2 monitoring with higheruniform coverage and higher resolution. CO2 DIAL operating in the 2-μm band offer better near-surface CO2measurement sensitivity due to the intrinsically stronger absorption lines. For more than 15 years, NASA LangleyResearch Center (LaRC) contributed in developing several 2-m CO2 DIAL systems and technologies. This paperfocuses on the current development of the airborne double-pulsed and triple-pulsed 2-m CO2 integrated pathdifferential absorption (IPDA) lidar system at NASA LaRC. This includes the IPDA system development andintegration. Results from ground and airborne CO2 IPDA testing will be presented. The potential of scaling suchtechnology to a space mission will be addressed.

Singh, Upendra N.↗
NASA NTRS2021

Drivers of Air-Sea CO2 Flux Seasonality and its Long-Term Changes in the NASA-GISS Model CMIP6 Submission.

Climate change will affect both the mean state and seasonality of marine physical and biogeochemical properties, with important implications for the oceanic sink of atmospheric CO2. Here, we investigate the seasonal cycle of the air-sea exchange of CO2 and pCO2,sw (surface seawater pCO2) and their long term changes using the CMIP6 submission of the NASA-GISS modelE (GISS-E2.1-G). In comparison to the CMIP5 submission (GISS-E2-R), we find that on the global scale, the seasonal cycles of the CO2 flux and NPP have improved, while the seasonal cycles of DIC, alkalinity, and macronutrients have deteriorated. Moreover, for all ocean biogeochemietry fields, changes in skill between E2.1-G and E2-R display large regional variability. For E2.1-G, we find similar modeled and observed CO2 flux seasonal cycles in the subtropical gyres, where seasonal anomalies of pCO2,sw and the flux are temperature-driven, and the Southern Ocean, where anomalies are DIC-driven. Biases in these seasonal cycles are largest in the subpolar and equatorial regions, driven by a combination of biases in temperature, DIC, alkalinity, and wind speed. When comparing the historical simulation to a simulation with an idealized increase in atmospheric pCO2, we find that the seasonal amplitudes of the CO2 flux and pCO2,sw generally increase. These changes are produced by increases in the sensitivity of pCO2,sw to its respective drivers. These findings are consistent with the notion that the sensitivity of pCO2,sw is expected to increase due to the increase of atmospheric pCO2, with changes in the seasonality of temperature, DIC, and alkalinity having secondary influences.

Air-Sea CO2↗
NASA NTRS2007

Evaluating the Capacity of Global CO2 Flux and Atmospheric Transport Models to Incorporate New Satellite Observations

As we enter the new era of satellite remote sensing for CO2 and other carbon cyclerelated quantities, advanced modeling and analysis capabilities are required to fully capitalize on the new observations. Model estimates of CO2 surface flux and atmospheric transport are required for initial constraints on inverse analyses, to connect atmospheric observations to the location of surface sources and sinks, and ultimately for future projections of carbon-climate interactions. For application to current, planned, and future remotely sensed CO2 data, it is desirable that these models are accurate and unbiased at time scales from less than daily to multi-annual and at spatial scales from several kilometers or finer to global. Here we focus on simulated CO2 fluxes from terrestrial vegetation and atmospheric transport mutually constrained by analyzed meteorological fields from the Goddard Modeling and Assimilation Office for the period 1998 through 2006. Use of assimilated meteorological data enables direct model comparison to observations across a wide range of scales of variability. The biospheric fluxes are produced by the CASA model at lxi degrees on a monthly mean basis, modulated hourly with analyzed temperature and sunlight. Both physiological and biomass burning fluxes are derived using satellite observations of vegetation, burned area (as in GFED-2), and analyzed meteorology. For the purposes of comparison to CO2 data, fossil fuel and ocean fluxes are also included in the transport simulations. In this presentation we evaluate the model's ability to simulate CO2 flux and mixing ratio variability in comparison to in situ observations at sites in Northern mid latitudes and the continental tropics. The influence of key process representations is inferred. We find that the model can resolve much of the hourly to synoptic variability in the observations, although there are limits imposed by vertical resolution of boundary layer processes. The seasonal cycle and its interannual variations generally respond adequately, but discrepancies in the tropics suggest the need for a refinement of the soil moisture dependence of the respiration flux in CASA. Examples and inferences for interpretation of satellite data will be discussed. In general, the fidelity of these simulations leads us to anticipate incorporation of real-time, highly resolved remote sensing and other observations into quantitative analyses that will reduce uncertainty in the terrestrial CO2 sink and revolutionize our understanding of the key processes controlling atmospheric CO2 and its evolution with time.

Kawa, S. R.↗
NASA NTRS2013

Surface Ocean pCO2 Seasonality and Sea-Air CO2 Flux Estimates for the North American East Coast

Underway and in situ observations of surface ocean pCO2, combined with satellite data, were used to develop pCO2 regional algorithms to analyze the seasonal and interannual variability of surface ocean pCO2 and sea-air CO2 flux for five physically and biologically distinct regions of the eastern North American continental shelf: the South Atlantic Bight (SAB), the Mid-Atlantic Bight (MAB), the Gulf of Maine (GoM), Nantucket Shoals and Georges Bank (NS+GB), and the Scotian Shelf (SS). Temperature and dissolved inorganic carbon variability are the most influential factors driving the seasonality of pCO2. Estimates of the sea-air CO2 flux were derived from the available pCO2 data, as well as from the pCO2 reconstructed by the algorithm. Two different gas exchange parameterizations were used. The SS, GB+NS, MAB, and SAB regions are net sinks of atmospheric CO2 while the GoM is a weak source. The estimates vary depending on the use of surface ocean pCO2 from the data or algorithm, as well as with the use of the two different gas exchange parameterizations. Most of the regional estimates are in general agreement with previous studies when the range of uncertainty and interannual variability are taken into account. According to the algorithm, the average annual uptake of atmospheric CO2 by eastern North American continental shelf waters is found to be between 3.4 and 5.4 Tg C/yr (areal average of 0.7 to 1.0 mol CO2 /sq m/yr) over the period 2003-2010.

interannual variability↗
NASA NTRS2006

The Orbiting Carbon Observatory: Sampling Approach and Anticipated Data Products

This viewgraph presentation reviews the mission and the architecture of NASA's Orbiting Carbon Observatory (OCO). It also discusses the method of making precise measurements of CO2 from space. Due to be launched in September of 2008, the OCO will fly 12 minutes ahead of the EOS Aqua platform in the Earth Observing System (EOS) Afternoon Constellation (A-Train). The OCO's mission is to identify the sources and sinks for atmospheric CO2.

CO2↗
NASA NTRS2006

Space-Based Near-Infrared CO2 Measurements: Testing the Orbiting Carbon Observatory Retrieval Algorithm and Validation Concept Using SCIAMACHY Observations over Park Falls, Wisconsin

Space-based measurements of reflected sunlight in the near-infrared (NIR) region promise to yield accurate and precise observations of the global distribution of atmospheric CO2. The Orbiting Carbon Observatory (OCO) is a future NASA mission, which will use this technique to measure the column-averaged dry air mole fraction of CO2 (XCO2) with the precision and accuracy needed to quantify CO2 sources and sinks on regional scales (approx.1000 x 1000 sq km and to characterize their variability on seasonal timescales. Here, we have used the OCO retrieval algorithm to retrieve XCO2 and surface pressure from space-based Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) measurements and from coincident ground-based Fourier transform spectrometer (FTS) measurements of the O2 A band at 0.76 mm and the 1.58 mm CO2 band for Park Falls,Wisconsin. Even after accounting for a systematic error in our representation of the O2 absorption cross sections, we still obtained a positive bias between SCIAMACHY and FTS XCO2 retrievals of approx.3.5%. Additionally, the retrieved surface pressures from SCIAMACHY systematically underestimate measurements of a calibrated pressure sensor at the FTS site. These findings lead us to speculate about inadequacies in the forward model of our retrieval algorithm. By assuming a 1% intensity offset in the O2 A band region for the SCIAMACHY XCO2 retrieval, we significantly improved the spectral fit and achieved better consistency between SCIAMACHY and FTS XCO2 retrievals. We compared the seasonal cycle of XCO2 at Park Falls from SCIAMACHY and FTS retrievals with calculations of the Model of Atmospheric Transport and Chemistry/Carnegie-Ames-Stanford Approach (MATCH/CASA) and found a good qualitative agreement but with MATCH/CASA underestimating the measured seasonal amplitude. Furthermore, since SCIAMACHY observations are similar in viewing geometry and spectral range to those of OCO, this study represents an important test of the OCO retrieval algorithm and validation concept using NIR spectra measured from space. Finally, we argue that significant improvements in precision and accuracy could be obtained from a dedicated CO2 instrument such as OCO, which has much higher spectral and spatial resolutions than SCIAMACHY. These measurements would then provide critical data for improving our understanding of the carbon cycle and carbon sources and sinks.

carbon dioxide↗
DOE OSTI2022

Annual carbon sequestration and loss rates under altered hydrology and fire regimes in southeastern USA pocosin peatlands

Peatlands drained for agriculture or forestry are susceptible to the rapid release of greenhouse gases (GHGs) through enhanced microbial decomposition and increased frequency of deep peat fires. We present evidence that rewetting drained subtropical wooded peatlands (STWPs) along the southeastern USA coast, primarily pocosin bogs, could prevent significant carbon (C) losses. To quantify GHG emissions and storage from drained and rewetted pocosin we used eddy covariance techniques, the first such estimates that have been applied to this major bog type, on a private drained (PD) site supplemented by static chamber measurements at PD and Pocosin Lakes National Wildlife Refuge. Net ecosystem exchange measurements showed that the loss was 21.2 Mg CO2 ha –1 year –1 (1 Mg = 10 6 g) in the drained pocosin. Under a rewetted scenario, where the annual mean water table depth (WTD) decreased from 60 to 30 cm, the C loss was projected to fall to 2 Mg CO 2 ha –1 year –1 , a 94% reduction. If the WTD was 20 cm, the peatlands became a net carbon sink (–3.3 Mg CO2 ha –1 year –1 ). Hence, net C reductions could reach 24.5 Mg CO 2 ha –1 year –1 , and when scaled up to the 4000 ha PD site nearly 100,000 Mg CO 2 year –1 of creditable C could be amassed. We conservatively estimate among the 0.75 million ha of southeastern STWPs, between 450 and 770 km 2 could be rewet, reducing annual GHG emissions by 0.96–1.6 Tg (1 Tg = 10 12 g) of CO 2 , through suppressed microbial decomposition and 1.7–2.8 Tg via fire prevention, respectively. Despite covering <0.01% of US land area, rewetting drained pocosin can potentially provide 2.4% of the annual CO 2 nationwide reduction target of 0.18 Pg (1 Pg = 10 15 g). Finally, suggesting pocosin restoration can contribute disproportionately to the US goal of achieving net-zero emission by 2050.

58 GEOSCIENCES↗
NASA NTRSDate not supplied

Observation of Trace Gases Seasonal Variability in the Marine Boundary Layer over the Atlantic Ocean during the ACTIVATE Field Campaign

High resolution in-situ measurements of carbon monoxide (CO), carbon dioxide (CO2), methane (CH4), and water vapor (H2O) were made onboard the NASA HU-25 aircraft during the ACTIVATE (Aerosol Cloud meteorology Interactions oVer the western Atlantic Experiment) campaign during 2020 and 2021 in different seasons (winter through summer) over the mid-latitude western Atlantic Ocean. As most of the flights focused on the marine boundary layer (MBL) during the campaign, these trace gas observations are an excellent data set to examine seasonal variability of trace gas background values in the MBL without the influence of localized point sources. We will describe the variability of these trace gases in the MBL background by filtering out concentrated point sources using back trajectory analysis along with trace gas ratios. Additionally, the ocean is a significant sink of anthropogenic CO2 capturing about one quarter of total anthropogenic carbon. By looking at the MBL CO2 variation as a function of season, we discuss observed changes in CO2 uptake over the ocean. These high accuracy observations of trace gas backgrounds in the MBL along with characterizing seasonal effects on oceanic sequestering of anthropogenic CO2 will improve the understanding of seasonal variations and change in climate and inverse modelling over the ocean.

Yonghoon Choi↗
NASA NTRS2019

Characteristics of Total Column CO2 Retrievals from the OCO Missions: Biases, Information Content and Implications for Flux Inversions

The Orbiting Carbon Observatory-2 and Orbiting Carbon Observatory-3, launched in 2015 and 2019, respectively, are intended to collect and deliver high-resolution observations of CO2 with unprecedented space and time coverage. Observations of CO2 from these remote-sensing missions (also known as XCO2, or column-based average, dry air mole fraction of CO2) are then used by the global carbon cycle community to answer a wide range of science questions, from the distribution and quantification of global and regional CO2 source-sink patterns to quantification of anthropogenic sources at urban scales. Even though we have had the OCO-2 mission flying for a few years now, the retrieval algorithms are continuously evolving and improving to deliver XCO2 retrievals with very high precision and high accuracy (or low biases). In this presentation, we will discuss a simple yet effective quantitative framework that has been developed by the OCO-2 flux team to evaluate the information content of these XCO2 retrievals as soon as they are released, i.e., with lower latency than full-scale flux inversions. This framework serves as a precursor to advanced inverse modeling frameworks and is intended to provide an early but accurate assessment of the signal present in the satellite retrievals, the robustness of that signal, and the ability of these retrievals to resolve patterns in CO2 surface fluxes that cannot be resolved by our current network of surface sites. Specific results will tackle a tiered set of questions that are being addressed using this framework: (a) what are the distribution of retrievals in the different modes of operation and how do they vary in space and time? (b) what is the information that is being given to the inverse modeling frameworks from the space-based data, information above and beyond what is provided by the in-situ data? and (c) how do these factors influence our choices for doing flux inversions with the satellite retrievals? While the primary focus of the results will be on application of this technique to mature OCO-2 retrievals, we will show early results for a couple of months of OCO-3 retrievals. For the time-period that the retrievals from the two missions overlap, we will highlight how this framework allows us to effortlessly put the information from OCO-3 and OCO-2 on an equal footing, thus enabling easy comparison between the two pioneering missions.

Chatterjee, Abhishek↗
NASA NTRS2013

Ocean Biological Pump Sensitivities and Implications for Climate Change Impacts

The ocean is one of the principal reservoirs of CO2, a greenhouse gas, and therefore plays a crucial role in regulating Earth's climate. Currently, the ocean sequesters about a third of anthropogenic CO2 emissions, mitigating the human impact on climate. At the same time, the deeper ocean represents the largest carbon pool in the Earth System and processes that describe the transfer of carbon from the surface of the ocean to depth are intimately linked to the effectiveness of carbon sequestration.The ocean biological pump (OBP), which involves several biogeochemical processes, is a major pathway for transfer of carbon from the surface mixed layer into the ocean interior. About 75 of the carbon vertical gradient is due to the carbon pump with only 25 attributed to the solubility pump. However, the relative importance and role of the two pumps is poorly constrained. OBP is further divided to the organic carbon pump (soft tissue pump) and the carbonate pump, with the former exporting about 10 times more carbon than the latter through processes like remineralization.Major uncertainties about OBP, and hence in the carbon uptake and sequestration, stem from uncertainties in processes involved in OBP such as particulate organicinorganic carbon sinkingsettling, remineralization, microbial degradation of DOC and uptakegrowth rate changes of the ocean biology. The deep ocean is a major sink of atmospheric CO2 in scales of hundreds to thousands of years, but how the export efficiency (i.e. the fraction of total carbon fixation at the surface that is transported at depth) is affected by climate change remains largely undetermined. These processes affect the ocean chemistry (alkalinity, pH, DIC, particulate and dissolved organic carbon) as well as the ecology (biodiversity, functional groups and their interactions) in the ocean. It is important to have a rigorous, quantitative understanding of the uncertainties involved in the observational measurements, the models and the projections of future changes.

particulates↗
NASA NTRS2001

Modeling Biogeochemical-Physical Interactions and Carbon Flux in the Sargasso Sea (Bermuda Atlantic Time-series Study site)

An ecosystem-carbon cycle model is used to analyze the biogeochemical-physical interactions and carbon fluxes in the Bermuda Atlantic Time-series Study (BATS) site for the period of 1992-1998. The model results compare well with observations (most variables are within 8% of observed values). The sea-air flux ranges from -0.32 to -0.50 mol C/sq m/yr, depending upon the gas transfer algorithm used. This estimate is within the range (-0.22 to -0.83 mol C/sq m/yr) of previously reported values which indicates that the BATS region is a weak sink of atmospheric CO2. The overall carbon balance consists of atmospheric CO2 uptake of 0.3 Mol C/sq m/yr, upward dissolved inorganic carbon (DIC) bottom flux of 1.1 Mol C/sq m/yr, and carbon export of 1.4 mol C/sq m/yr via sedimentation. Upper ocean DIC levels increased between 1992 and 1996 at a rate of approximately 1.2 (micro)mol/kg/yr, consistent with observations. However, this trend was reversed during 1997-1998 to -2.7 (micro)mol/kg/yr in response to hydrographic changes imposed by the El Nino-La Nina transition, which were manifested in the Sargasso Sea by the warmest SST and lowest surface salinity of the period (1992-1998).

Signorini, Sergio R.↗
NASA NTRS2004

CO2 and CO Simulations and Their Source Signature Indicated by CO/CO2

Three years (2000-2002) atmospheric CO2 and CO fields are simulated by a Chemistry Transport Model driven by the assimilated meteorological fields from GEOS-4. The simulated CO2 and CO are evaluated by measurements from surface (CMDL), satellite (MOPITT/CO), and aircraft. The model-observation comparisons indicate reasonable agreement in both source and remote regions, and in the lower and upper troposphere. The simulation also captures the seasonality of CO2 and CO variations. The ratios of CO/CO2 are analyzed over different representative regions to identify the source signature, since the anthropogenic CO comes fiom the same combustion processes as CO2. This work enables us to improve satellite inversion estimates of CO2 sources and sinks by simultaneously using satellite CO measurement.

Kawa, Randy↗
NASA NTRS2018

Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS): Final Report of the ASCENDS Ad Hoc Science Definition Team

Improved remote sensing observations of atmospheric carbon dioxide (CO2) are critically needed to quantify, monitor, and understand the Earth's carbon cycle and its evolution in a changing climate. The processes governing ocean and terrestrial carbon uptake remain poorly understood,especially in dynamic regions with large carbon stocks and strong vulnerability to climate change,for example, the tropical land biosphere, the northern hemisphere high latitudes, and the Southern Ocean. Because the passive spectrometers used by GOSAT (Greenhouse gases Observing SATellite) and OCO-2 (Orbiting Carbon Observatory-2) require sunlit and cloud-free conditions,current observations over these regions remain infrequent and are subject to biases. These short comings limit our ability to understand and predict the processes controlling the carbon cycle on regional to global scales.In contrast, active CO2 remote-sensing techniques allow accurate measurements to be taken day and night, over ocean and land surfaces, in the presence of thin or scattered clouds, and at all times of year. Because of these benefits, the National Research Council recommended the National Aeronautics and Space Administration (NASA) Active Sensing of CO2 Emissions over Nights,Days, and Seasons (ASCENDS) mission in the 2007 report Earth Science and Applications from Space: National Imperatives for the Next Decade and Beyond. The ability of ASCENDS to collect low-bias observations in these key regions is expected to address important gaps in our knowledge of the contemporary carbon cycle.The ASCENDS ad hoc Science Definition Team (SDT), comprised of carbon cycle modeling and active remote sensing instrument teams throughout the United States (US), worked to develop the mission's requirements and advance its readiness from 2008 through 2018. Numerous scientific investigations were carried out to identify the benefit and feasibility of active CO2 remote sensing measurements for improving our understanding of CO2 sources and sinks. This report summarizes their findings and recommendations based on mission modeling studies, analysis of ancillary meteorological data products, development and demonstration of candidate technologies, anddesign studies of the ASCENDS mission concept.

Kawa, S. Randolph↗
NASA NTRS2018

Improving NASA GEOS Atmospheric CO2 Simulations by Calibrating CASA Surface Fluxes with an Empirical Sink

With the adoption of the Paris climate accord, efforts to monitor and understand both anthropogenic and natural carbon sources and sinks are increasing across the world. Given their low latency and global coverage, satellite observations of atmospheric carbon dioxide (CO2) are poised to make important contributions to this field. The combination of satellite data and high resolution global models can be used to monitor changes in carbon fluxes and to evaluate the consistency of nationally reported emissions estimates in support of multiple stakeholder communities. However, a consistent challenge to such work has been the high latency of surface carbon flux estimates, which are often not available for a year or more. This presentation describes the construction of surface carbon flux estimates meant to improve the near real time simulation of atmospheric CO2 with NASA's Goddard Earth Observing System (GEOS) general circulation model. The surface flux estimates begin with a collection of bottom-up fluxes which incorporate satellite measurements in their construction, e.g. vegetation indices in the Carnegie-Ames-Stanford Approach (CASA) and nighttime lights in the Open-source Data Inventory for Anthropogenic CO2 (ODIAC). From there, we take the additional step of using an empirical sink to calibrate terrestrial net biospheric exchange (NBE) to estimated values from atmospheric inversion systems. This approach removes a known, systematic bias in predicted atmospheric mixing ratios. Using these fluxes in a free running simulation, the model is able to reproduce in situ measurements with the same skill as when it uses gridded fluxes from a flux inversion system. Using these fluxes as a prior in an assimilation system, e.g. one incorporating retrievals of column CO2 from the Orbiting Carbon Observatory 2 (OCO-2), allows the analysis to capture variability in CO2 on scales that would be missed otherwise. This approach supports NASA's capability to forecast atmospheric CO2 up to two weeks in advance by leveraging a GEOS system used to produce quasi-operational weather analyses and forecasts, providing a valuable new tool to the carbon monitoring research and applications communities.

Weir, B.↗
NASA NTRS2015

An Inversion Analysis of Recent Variability in Natural CO2 Fluxes Using GOSAT and In Situ Observations

About one-half of the global CO2 emissions from fossil fuel combustion and deforestation accumulates in the atmosphere, where it contributes to global warming. The rest is taken up by vegetation and the ocean. The precise contribution of the two sinks, and their location and year-to-year variability are, however, not well understood. We use two different approaches, batch Bayesian synthesis inversion and variational data assimilation, to deduce the global spatiotemporal distributions of CO2 fluxes during 2009-2010. One of our objectives is to assess different sources of uncertainties in inferred fluxes, including uncertainties in prior flux estimates and observations, and differences in inversion techniques. For prior constraints, we utilize fluxes and uncertainties from the CASA-GFED model of the terrestrial biosphere and biomass burning driven by satellite observations and interannually varying meteorology. We also use measurement-based ocean flux estimates and two sets of fixed fossil CO2 emissions. Here, our inversions incorporate column CO2 measurements from the GOSAT satellite (ACOS retrieval, filtered and bias-corrected) and in situ observations (individual flask and afternoon-average continuous observations) to estimate fluxes in 108 regions over 8-day intervals for the batch inversion and at 3 x 3.75 weekly for the variational system. Relationships between fluxes and atmospheric concentrations are derived consistently for the two inversion systems using the PCTM atmospheric transport model driven by meteorology from the MERRA reanalysis. We compare the posterior fluxes and uncertainties derived using different data sets and the two inversion approaches, and evaluate the posterior atmospheric concentrations against independent data including aircraft measurements. The optimized fluxes generally resemble those from other studies. For example, the results indicate that the terrestrial biosphere is a net CO2 sink, and a GOSAT-only inversion suggests a shift in the global sink from the tropics south to the north relative to the prior and to an in-situ-only inversion. We also find a smaller terrestrial sink in higher-latitude northern regions in boreal summer of 2010 relative to 2009.

Carbon dioxide↗
NASA NTRS1984

Some aspects of understanding changes in the global carbon cycle

The collective character of carbon exchanges between the atmosphere and other pools is partially revealed by comparing the record of CO2 concentration beginning in 1958 with estimates of the releases from fossil fuels during this period. In analyzing the secular increase in CO2 concentration induced by fossil fuel use, the atmosphere is generally treated as a single well-mixed reservoir; however, to study finer structure in the CO2 records, the influence of atmospheric circulation must be more carefully considered. The rate of carbon uptake by the oceans, the primary sink for fossil fuel CO2, is assessed more reliably than influences on the atmosphere due to interactions with other pools. Models of the global carbon cycle are being substantially refined while data that reflect the response of the cycle to fossil fuel use and other perturbations are being extended.

Emanuel, W. R.↗
NASA NTRS2018

Measuring Atmospheric Carbon Dioxide from the NASA Orbiting Carbon Observatory-2 (OCO-2)

Fossil fuel combustion, deforestation, and other human activities are now adding almost 40 billion tons of carbon dioxide (CO2) to the atmosphere each year. These emissions are superimposed on an active natural carbon cycle that adds about 20 times as much CO2 to the atmosphere annually, and then reabsorbs a comparable amount, along with over half of the CO2 contributed by human activities. Interestingly, the identity and location of the natural “sinks” in the land biosphere and ocean that are responsible for absorbing this anthropogenic CO2 are still poorly understood. Because of this, it is impossible to accurately predict how these sinks will respond to a warming climate. Space based remote sensing provides new tools for studying the sources and sinks of CO2. The NASA Orbiting Carbon Observatory-2 (OCO-2) was launched in July 2014 and was inserted at the head of the 705-km Afternoon Constellation (A-Train) a month later.

Crisp, David↗