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At least 73 records · Page 4

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NASA NTRS1990

Effect of shock pressure on the structure and superconducting properties of Y-Ba-Cu-O in explosively fabricated bulk metal-matrix composites

While it is now well established that copper-oxide-based powder, or virtually any other ceramic superconductor powder, can be consolidated and encapsulated within a metal matrix by explosive consolidation, the erratic superconductivity following fabrication has posed a major problem for bulk applications. The nature of this behavior was found to arise from microstructural damage created in the shock wave front, and the residual degradation in superconductivity was demonstrated to be directly related to the peak shock pressure. The explosively fabricated or shock loaded YBa2Cu3Ox examples exhibit drastically altered rho (or R) - T curves. The deterioration in superconductivity is even more noticeable in the measurement of ac magnetic susceptibility and flux exclusion or shielding fraction which is also reduced in proportion to increasing peak shock pressure. The high-frequency surface resistance (in the GHz range) is also correspondingly compromised in explosively fabricated, bulk metal-matrix composites based on YBa2Cu3O7. Transmission electron microscopy (including lattice imaging techniques) is being applied in an effort to elucidate the fundamental (microstructural) nature of the shock-induced degradation of superconductivity and normal state conductivity. One focus of TEM observations has assumed that oxygen displaced from b-chains rather than oxygen-vacancy disorder in the basal plane of oxygen deficient YBa2Cu3Ox may be a prime mechanism. Shock-wave displaced oxygen may also be locked into new positions or interstitial clusters or chemically bound to displaced metal (possibly copper) atoms to form precipitates, or such displacements may cause the equivalent of local lattice cell changes as a result of stoichiometric changes. While the shock-induced suppression of T(sub c) is not desirable in the explosive fabrication of bulk metal-matrix superconductors, it may be turned into an advantage if the atomic-scale distortion can be understood and controlled as local flux pinning sites.

Murr, L. E.↗

NASA NTRS1985

Creep-fatigue behavior of NiCoCrAlY coated PWA 1480

This study of high-temperature fatigue and creep-fatigue behavior is part of a program to identify the basic features of the effects of temperature, creep, fatigue, and environment on the behavior of a single crystal superalloy, a bulk coating alloy, and a coated alloy system. A system was selected which has had considerable production experience: the Ni-base superalloy, PWA 1480, and the NiCoCrAlY coating, PWA 276. Isothermal behavior was studied first. A series of fatigue and creep fatigue tests of the types commonly designated as pp, cp, pc and cc were conducted. These tests were conducted at various constant total strain ranges. The creep-fatigue cycles employed constant stress dwells at the maximum and/or minimum load. Test results are given.

Miner, R. V.↗

NASA NTRS1971

Friction, wear, and lubrication in vacuum

A review of studies and observations on the friction, wear, and lubrication behavior of materials in a vacuum environment is presented. The factors that determine and influence friction and wear are discussed. They include topographical, physical, mechanical, and the chemical nature of the surface. The effects of bulk properties such as deformation characteristics, fracture behavior, and structure are included.

Buckley, D. H.↗

NASA NTRS2002

Surface Composition of NiPd Alloys

Surface segregation in Ni-Pd alloys has been studied using the BFS method for alloys. Not only does the method predict an oscillatory segregation profile but it also indicates that the number of Pd-enriched surface planes can vary as a function of orientation. The segregation profiles were computed as a function of temperature, crystal face, and composition. Pd enrichment of the first layer is observed in (111) and (100) surfaces, and enrichment of the top two layers occurs for (110) surfaces. In all cases, the segregation profile shows oscillations that are actually related to weak ordering tendencies in the bulk. An atom-by-atom analysis was performed to identify the competing mechanisms leading to the observed surface behaviors. Large-scale atomistic simulations were also performed to investigate the temperature dependence of the segregation profiles as well as for analysis of the bulk structures. Finally, the observed surface behaviors are discussed in relation to the bulk phase structure of Ni-Pd alloys, which exhibit a tendency to weakly order.

Noebe, Ronald D.↗

NASA NTRS1999

Bursting Bubbles from Combustion of Thermoplastic Materials in Microgravity

Many thermoplastic materials in common use for a wide range of applications, including spacecraft, develop bubbles internally as they burn due to chemical reactions taking place within the bulk. These bubbles grow and migrate until they burst at the surface, forceably ejecting volatile gases and, occasionally, molten fuel. In experiments in normal gravity, Kashiwagi and Ohlemiller observed vapor jets extending a few centimeters from the surface of a radiatively heated polymethylmethacrylate (PMMA) sample, with some molten material ejected into the gas phase. These physical phenomena complicated the combustion process considerably. In addition to the non-steady release of volatiles, the depth of the surface layer affected by oxygen was increased, attributed to the roughening of the surface by bursting events. The ejection of burning droplets in random directions presents a potential fire hazard unique to microgravity. In microgravity combustion experiments on nylon Velcro fasteners and on polyethylene wire insulation, the presence of bursting fuel vapor bubbles was associated with the ejection of small particles of molten fuel as well as pulsations of the flame. For the nylon fasteners, particle velocities were higher than 30 cm/sec. The droplets burned robustly until all fuel was consumed, demonstrating the potential for the spread of fire in random directions over an extended distance. The sequence of events for a bursting bubble has been photographed by Newitt et al.. As the bubble reaches the fluid surface, the outer surface forms a dome while the internal bubble pressure maintains a depression at the inner interface. Liquid drains from the dome until it breaks into a cloud of droplets on the order of a few microns in size. The bubble gases are released rapidly, generating vortices in the quiescent surroundings and transporting the tiny droplets. The depression left by the escaping gases collapses into a central jet, which rises with a high velocity and may break up, releasing one or more relatively large drops (on the order of a millimeter in these experiments). A better understanding of bubble development and bursting processes, the effects of bursting behavior on burning rate of the bulk material, and the circumstances under which large droplets are expelled, as well as their trajectories, sizes, and burning rates, is sought through computer modeling compared with experiment.

Butler, K. B.↗

NASA NTRS1994

Boundary-layer transition detection with infrared imaging emphasizing cryogenic applications

This paper reviews the technique of boundary-layer transition detection using infrared (IR) imaging, emphasizing cryogenic wind-tunnel testing. With the exception of the low-temperature effects on the IR radiation, the discussion is relevant to conventional wind-tunnel and flight testing as well. At low temperatures, IR imaging encounters a reduction in the radiated energy throughout the IR spectrum, combined with a shift to longer wavelengths of the bulk of the radiation. This radiation behavior affects the minimum resolvable temperature difference (MRTD) of the IR imaging system because of its fixed wave band sensitivity. In the absence of commercial long wavelength IR imaging systems, operating at wavelengths longer than 13 micron, some measures can be taken to alleviate the problem caused by the MRTD limitation. The thermal signature of transition can be enhanced by allowing a small and controlled temperature increase of the wind-tunnel flow that induces a transient heat transfer to the model. This action temporarily reveals the model area under the turbulent regime through its higher heating rate compared with the laminar regime. The contrast between the areas exposed to the two regimes can be enhanced by subtraction of thermograms (the equilibrium thermogram from the transient thermogram). Further visual improvement can be obtained through shade stretching or binary shading.

Gartenberg, Ehud↗

NASA NTRS1996

The Micromechanics of the Moving Contact Line

The proposed research is divided into three components concerned with molecular structure, molecular orientation, and continuum averages of discrete systems. In the experimental program, we propose exploring how changes in interfacial molecular structure generate contact line motion. Rather than rely on the electrostatic and electrokinetic fields arising from the molecules themselves, we augment their interactions by an imposed field at the solid/liquid interface. By controling the field, we can manipulate the molecular structure at the solid/liquid interface. In response to controlled changes in molecular structure, we observe the resultant contact line motion. In the analytical portion of the proposed research we seek to formulate a system of equations governing fluid motion which accounts for the orientation of fluid molecules. In preliminary work, we have focused on describing how molecular orientation affects the forces generated at the moving contact line. Ideally, as assumed above, the discrete behavior of molecules can be averaged into a continuum theory. In the numerical portion of the proposed research, we inquire whether the contact line region is, in fact, large enough to possess a well-defined average. Additionally, we ask what types of behavior distinguish discrete systems from continuum systems. Might the smallness of the contact line region, in itself, lead to behavior different from that in the bulk? Taken together, our proposed research seeks to identify and accurately account for some of the molecular dynamics of the moving contact line, and attempts to formulate a description from which one can compute the forces at the moving contact line.

Han, Minsub↗

NASA NTRS2003

The Polar Regions and Martian Climate: Studies with a Global Climate Model

Much of the interest in the polar regions centers on the fact that they likely contain the best record of Martian climate change on time scales from years to eons. This expectation is based upon the observed occurrence of weathering product deposits and volatile reservoirs that are coupled to the climate. Interpretation and understanding of these records requires understanding of the mechanisms that involve the exchange of dust, water, and carbon dioxide between the surface and atmosphere, and the atmospheric redistribution of these species. We will summarize our use of the GFDL Mars general circulation model (MGCM), to exploration aspects of the interaction between the global climate and the polar regions. For example, our studies have shown that while the northern polar cap is the dominant seasonal source for water, it can act as a net annual source or sink for water, depending upon the cap temperatures and the bulk humidity of the atmosphere. This behavior regulates the annual and global average humidity of the atmosphere, as the cap acts as a sink if the atmosphere is too wet and a source if it is too dry. We will then focus our presentation on the ability of the MGCM to simulate the observed diurnal variations of surface temperature. We are particularly interested in assessing the influence of dust aerosol and water ice clouds on simulated surface temperature and the comparison with observations. Surface thermal inertia and albedo are critical boundary inputs for MGCM simulations. Thermal inertia is also of intrinsic interest as it may be related to properties of the surface such as particle size and surface character.

Wilson, R. J.↗

NASA NTRS2005

PDSOI and Radiation Effects: An Overview

Bulk silicon substrates are a common characteristic of nearly all commercial, Complementary Metal-Oxide-Semiconductor (CMOS), integrated circuits. These devices operate well on Earth, but are not so well received in the space environment. An alternative to bulk CMOS is the Silicon-On-Insulator (SOI), in which a &electric isolates the device layer from the substrate. SO1 behavior in the space environment has certain inherent advantages over bulk, a primary factor in its long-time appeal to space-flight IC designers. The discussion will investigate the behavior of the Partially-Depleted SO1 (PDSOI) device with respect to some of the more common space radiation effects: Total Ionized Dose (TID), Single-Event Upsets (SEUs), and Single-Event Latchup (SEL). Test and simulation results from the literature, bulk and epitaxial comparisons facilitate reinforcement of PDSOI radiation characteristics.

Forgione, Joshua B.↗

NASA NTRS1998

Solid Lubrication Fundamentals and Applications. Properties of Clean Surfaces: Adhesion, Friction, and Wear

This chapter presents the adhesion, friction, and wear behaviors of smooth, atomically clean surfaces of solid-solid couples, such as metal-ceramic couples, in a clean environment. Surface and bulk properties, which determine the adhesion, friction, and wear behaviors of solid-solid couples, are described. The primary emphasis is on the nature and character of the metal, especially its surface energy and ductility. Also, the mechanisms of friction and wear for clean, smooth surfaces are stated.

Miyoshi, Kazuhisa↗

NASA NTRS1983

Compression, nonstoichiometry and bulk viscosity of wuestite

New and existing data on the elasticity of wuestite which indicate virtually no correlation between the bulk modulus and stoichiometry are summarized. There appears, however, to be a systematic difference between static and dynamic measurements. This behavior suggests the presence of a frequency dependence to the bulk modulus that can be formally ascribed to a finite bulk viscosity of Fe(1-x)O. Such an effect has not previously been described in oxide or silicate minerals, and it presumably is caused by pressure-induced changes in defect ordering and subsequent relaxation within the incommensurate structure of wuestite.

Jeanloz, R.↗

NASA NTRS1984

The role of material properties in adhesion

When two solid surfaces are brought into contact strong adhesive bond forces can develop between the materials. The magnitude of the forces will depend upon the state of the surfaces, cleanliness and the fundamental properties of the two solids, both surface and bulk. Adhesion between solids is addressed from a theoretical consideration of the electronic nature of the surfaces and experimentally relating bond forces to the nature of the interface resulting from solid state contact. Surface properties correlated with adhesion include, atomic or molecular orientation, reconstruction and segregation as well as the chemistry of the surface specie. Where dissimilar solids are in contact the contribution of each is considered as is the role of their interactive chemistry on bond strength. Bulk properties examined include elastic and plastic behavior in the surficial regions, cohesive binding energies, crystal structure, crystallographic orientation and state. Materials examined with respect to interfacial adhesive interactions include metals, alloys, ceramics, polymers and diamond. They are reviewed both in single and polycrystalline form. The surfaces of the contacting solids are studied both in the atomic or molecularly clean state and in the presence of selected surface contaminants.

Buckley, D. H.↗

NASA NTRS1984

Ceramic microstructure and adhesion

When a ceramic is brought into contact with a ceramic, a polymer, or a metal, strong bond forces can develop between the materials. The bonding forces will depend upon the state of the surfaces, cleanliness and the fundamental properties of the two solids, both surface and bulk. Adhesion between a ceramic and another solid are discussed from a theoretical consideration of the nature of the surfaces and experimentally by relating bond forces to interface resulting from solid state contact. Surface properties of ceramics correlated with adhesion include, orientation, reconstruction and diffusion as well as the chemistry of the surface specie. Where a ceramic is in contact with a metal their interactive chemistry and bond strength is considered. Bulk properties examined include elastic and plastic behavior in the surficial regions, cohesive binding energies, crystal structures and crystallographic orientation. Materials examined with respect to interfacial adhesive interactions include silicon carbide, nickel zinc ferrite, manganese zinc ferrite, and aluminum oxide. The surfaces of the contacting solids are studied both in the atomic or molecularly clean state and in the presence of selected surface contaminants.

Buckley, D. H.↗

NASA NTRS1985

Ceramic microstructure and adhesion

Buckley, D. H.↗

NASA NTRS2015

Structural CNT Composites: Developing a Carbon Nanotube Filament Winder - Part I

Carbon nanotube (CNT) based materials promise advances in the production of high strength and multifunctional components for aerospace and other applications. Specifically, in tension dominated applications, the latest CNT based filaments are yielding composite properties comparable to or exceeding composites from more established fibers such as Kevlar and carbon fiber. However, for the properties of these materials to be fully realized at the component level, suitable manufacturing processes have to be developed. These materials handle differently from conventional fibers, with different wetting characteristics and behavior under load. The limited availability of bulk forms also requires that the equipment be scaled down accordingly to tailor the process development approach to material availability. Here, the development of hardware and software for filament winding of carbon nanotube based tapes and yarns is described. This hardware features precision guidance of the CNT material and control of the winding tension over a wide range in an open architecture that allows for effective process control and troubleshooting during winding. Use of the filament winder to develop CNT based Composite Overwrapped Pressure Vessels (COPVs) shall also be discussed.

Sauti, Godfrey↗

NASA NTRS1989

Deformation behavior of NiAl-based alloys containing iron, cobalt, and hafnium

The effects of alloying additions on the mechanical properties of the B2 intermetallic NiAl have been investigated in both the melt-spun ribbon and consolidated, bulk form. The study is based on a matrix of NiAl-based alloys with up to 20 at. pct Co and Fe additions and with reduced Al levels in the range of 30-40 at. pct. Characterization of the melt-spun ribbon by optical and scanning electron microscopy indicates a range of microstructures, including single-phase beta, gamma-prime necklace phase surrounding either martensitic or beta grains, and a mixture of equiaxed martensitic and gamma-prime grains. Bend ductility is present in melt-spun and annealed ribbons exhibiting the gamma-prime necklace structure and in a single-phase beta material containing 20 at. pct Fe. The analysis of compressive flow behavior on consolidated, bulk specimens indicates that the single-phase beta alloys exhibit a continuous decrease in yield stress with increasing temperature and profuse microcracking at grain boundaries. In contrast, multiphase (gamma-prime + either martensite or beta) alloys tend to display a peak in flow stress between 600 and 800 K, with little or no signs of microcracking. In general, heat treatments which convert the martensitic grains to beta + gamma-prime result in improved strength at temperatures above 600 K and better resistance to crack initiation.

Pank, D. R.↗

NASA NTRS1981

Contribution to the knowledge of nickel hydroxide electrodes. 5. Analysis and electrochemical behavior of cadmium nickel hydroxides

Electrochemical experiments performed at sintered and bulk electrodes show that beta nickel hydroxide contains an electrochemically inactive proportion of cadmium hydroxide of up to 10%. The electrochemically ineffective cadmium hydroxide is homogeneously dissolved in beta nickel hydroxide.

Bode, H.↗

NASA NTRS1976

Simulation of a cometary conglomerate of frozen gases and dust in a zero-gravity environment: A critical evaluation of possible space experiments

It is proposed to use the Shuttle (OFT experiments) or eventually Spacelab to study, in the absence of gravity the low velocity accretion and the bulk properties of icy conglomerates simulating cometary material and their sedimentation and bulk properties in very small acceleration fields. Their behavior when exposed to the direct solar flux is also under consideration.

Delsemme, A. H.↗