Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “ALS”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Evaluation of Pressurization Fatigue Life of 1441 Al-li Fuselage Panel

A study was conducted to evaluate the pressurization fatigue life of fuselage panels with skins fabricated from 1441 Al-Li, an attractive new Russian alloy. The study indicated that 1441 Al-Li has several advantages over conventional aluminum fuselage skin alloy with respect to fatigue behavior. Smooth 1441 Al-Li sheet specimens exhibited a fatigue endurance limit similar to that for 1163 Al (Russian version of 2024 Al) sheet. Notched 1441 Al-Li sheet specimens exhibited greater fatigue strength and longer fatigue life than 1163 Al. In addition, Tu-204 fuselage panels fabricated by Tupolev Design Bureau using Al-Li skin and ring frames with riveted 7000-series aluminum stiffeners had longer pressurization fatigue lives than did panels constructed from conventional aluminum alloys. Taking into account the lower density of this alloy, the results suggest that 1441 Al-Li has the potential to improve fuselage performance while decreasing structural weight.

Bird, R. Keith↗
NASA NTRSDate not supplied

The Chemical and Isotopic Signatures of the Hibonite-rich FUN Inclusion "HIDALGO" in Dar al Gani 027 (CO3)

Refractory Ca-Al-rich Inclusions (CAIs) with FUN (Fractionation with Unidentified Nuclear effects) characteristics are peculiar samples among all high-temperature components in chondritic meteorites. They are generally characterized by strong mass-dependent isotopic fractionations in several elements (e.g., O, Mg, Ca, Ti), large (~5-20‰) enrichments or depletions in neutron-rich isotopes (e.g., 48 Ca, 50 Ti, 54 Cr), and low inferred abundances of 26 Al ( 26 Al/ 27 Al < 1×10 −5 ). Understanding the origins of these features in FUN CAIs can shed light on the astrophysical environment and chemical processes that took place in the early Solar System. A large fraction (slightly less than 50%) of the ~20 FUN CAIs discovered so far are hibonite-rich (such as HAL, SHAL and DH-H1, collectively called HAL-type inclusions hereafter). According to their elemental and isotopic signatures and the results of evaporation experiments, HAL-type inclusions are thought to have formed as a distillation residue. However, questions regarding the timing of the formation of HAL-type inclusions (or FUN inclusions in general) relative to those of regular CAIs and the decoupling between the 26 Al abundances and nucleosynthetic anomalies remain poorly understood. In 2021, we reported the discovery of a new HAL-type inclusion, HIDALGO (Hibonite in Dar al Gani CO3) in the CO3 chondrite Dar al Gani 027 (DaG027), based on its (fractionated) oxygen isotopic compositions and low inferred 26 Al/ 27 Al ratio of (1.50±0.02)×10 −5 . Since then, more work on other short-lived and stable isotope systems and trace element abundances has been conducted. Here we report these new results and discuss the implications for the possible formation history of HIDALGO and origins of shortlived radionuclides (SLRs).

Meteorite↗
NASA NTRS1977

Evidence for Al-26 in the solar system

Evidence is reviewed for the presence of short-lived Al-26 (half-life of 720,000 years) in the early solar system. Large excesses of Mg-26 of up to 5% have been found in Ca-Al-rich inclusions of the Allende meteorite. The Mg excesses correlate well with Al-27/Mg-24 and in two cases they are found in high-purity separates of coarse-grained Al-rich minerals which tend to exclude Mg. The data demonstrate that Al-26 was present in the early solar system. Mechanisms for addition of Al-26 to the solar nebula or for production within an active solar system are required within a few million years of condensation of small (centimeter-sized) objects. The Al-26 abundance in Allende inclusions is high enough to provide for effective melting of kilometer-size bodies or larger, if such bodies accreted early enough (a few million years) to incorporate the Al-26.

Papanastassiou, D. A.↗
NASA NTRS1985

Angular distribution of interstellar Al-26

The angular distribution and local concentration of interstellar Al-26 are calculated for five theoretical models of its origin, as a guide for future observations. The models considered relate Al-26 to current star formation (with surface CO density as its indicator), treat Al-26 as a secondary-nucleosynthesis product on seed nuclei with the same metallicity gradient as O, assume the Al-26 ejection rate is proportional to present light output, make Al-26 synthesis depend on total H I + H2 gas density, or assume that Al-26 is formed mainly in novae. The local decay and production rates for the five models are found to lie within a factor of 2 of surface density 0.0003/sq cm s, corresponding to a present (Al-26)/(Al-27) ratio of 5 x 10 to the -6th averaged over H I and H2 phases.

Leising, M. D.↗
NASA NTRS2011

Effects of Annealing Process on the Formability of Friction Stir Welded Al-Li Alloy 2195 Plates

Large rocket cryogenic tank domes have typically been fabricated using Al-Cu based alloys like Al-Cu alloy 2219. The use of aluminum-lithium based alloys for rocket fuel tank domes can reduce weight because aluminum-lithium alloys have lower density and higher strength than Al-Cu alloy 2219. However, Al-Li alloys have rarely been used to fabricate rocket fuel tank domes because of the inherent low formability characteristic that make them susceptible to cracking during the forming operations. The ability to form metal by stretch forming or spin forming without excessive thinning or necking depends on the strain hardening exponent "n". The stain hardening exponent is a measure of how rapidly a metal becomes stronger and harder. A high strain hardening exponent is beneficial to a material's ability to uniformly distribute the imposed strain. Marshall Space Flight Center has developed a novel annealing process that can achieve a work hardening exponent on the order of 0.27 to 0.29, which is approximately 50% higher than what is typically obtained for Al-Li alloys using the conventional method. The strain hardening exponent of the Al-Li alloy plates or blanks heat treated using the conventional method is typically on the order of 0.17 to 0.19. The effects of this novel annealing process on the formability of friction stir welded Al-Li alloy blanks are being studied at Marshall Space Flight Center. The formability ratings will be generated using the strain hardening exponent, strain rate sensitivity and forming range. The effects of forming temperature on the formability will also be studied. The objective of this work is to study the deformation behavior of the friction stir welded Al-Li alloy 2195 blank and determine the formability enhancement by the new annealing process.

Chen, Po-Shou↗
NASA NTRS2016

Observations of the Minor Species Al and Fe in Mercury's Exosphere

We report here on the first observational evidence of Al and Fe in the exosphere of Mercury, based on measurements of resolved emission lines of these metals with Keck-1/HIRES. Al emission was observed on two separate runs, in 2008 and 2013, with tangent column densities of 3.1 +/- 1.0 and 4.0 +/-1.5 x 10(exp 7) Al atoms cm(exp - 2) at altitudes of 1185 and 1870 km (1.5 and 1.75 R(sub M). The Al radiative intensity was seen to increase where the slit crossed the planetary penumbral shadow, and then decrease monotonically with altitude. Fe emission has been observed once, in 2009, indicating an extended source. We also present observed 3- Sigma Ca(+) upper limits near Mercury's equatorial anti-solar limb, from which an abundance limit of 4.0 x 10(exp 6) cm(exp -2) at 1650 km altitude is derived for the Ca ion. A simple model for zenith column abundances of the neutral species yields 1.9 -5.2 x 10(exp 7) Al cm(exp -2) , and 8.2 x 10(exp 8) Fe cm(exp -2) . The observations appear to be consistent with production of these species by impact vaporization, with a large fraction of the Al ejecta in molecular form, and that for Fe in mixed atomic and molecular forms. The scale height of the Al gas is consistent with a kinetic temperature of 6100-8000 K. The apparent high temperature and low density of the Al gas would suggest that it may be produced by dissociation of molecules.

Mercury↗
NASA NTRS1980

Synthesis of Al-26 in explosive hydrogen burning

The possibility of Al-26 synthesis during the explosive processing of hydrogen-rich material in the outer layers of a supernova or in nova envelopes is investigated. It is found that in the peak temperature range of 1-3 x 10 to the 8th deg K and for expansion time scales of the order of 1-1000 s, values of (Al-26)/(Al-27) as high as 0.1-1 can be obtained for values of 0.001-100,000 for the product of the peak density in g/cu cm and the proton mass fraction. Such a level of Al-26 production is considerably higher than that of recent carbon/neon burning nucleosynthesis models, and is sufficient to account for the magnesium anomalies detected in certain inclusions from the Leoville and Allende meteorites. Al abundances resulting from a hydrodynamical calculation performed on the grounds of a 25 solar mass presupernova model are also presented, and the influence of uncertainties in the input physics is discussed; in particular, the rates of the (Mg-25)(p,gamma)(Al-26) and (Al-26)(p,gamma)(Si-27) key reactions are studied.

Arnould, M.↗
NASA NTRS1984

Solute transport and the prediction of breakaway oxidation in gamma + beta Ni-Cr-Al alloys

The Al transport and the condition leading to breakaway oxidation during the cyclic oxidation of gamma + beta NiCrAl alloys have been studied. The Al concentration/distance profiles were measured after various cyclic oxidation exposures at 1200 C. It was observed that cyclic oxidation results in a decreasing Al concentration at the oxide/metal interface, maintaining a constant flux of Al to the Al2O3 scale. It was also observed that breakaway oxidation occurs when the Al concentration at the oxide/metal interface approaches zero. A numerical model was developed to simulate the diffusional transport of Al and to predict breakaway oxidation in gamma + beta NiCrAl alloys undergoing cyclic oxidation. In a comparison of two alloys with similar oxide spalling characteristics, the numerical model was shown to predict correctly the onset of breakaway oxidation in the higher Al-content alloy.

Nesbitt, J. A.↗
NASA NTRS1985

Development of powder metallurgy 2XXX series Al alloy plate and sheet materials for high temperature aircraft structural applications, FY 1983/1984

The objective of this investigation is to fabricate and evaluate PM 2124 Al alloy plate and sheet materials according to NASA program goals for damage tolerance and fatigue resistance. Previous research has indicated the outstanding strength-toughness relationship available with PM 2124 Al-Zr modified alloy compositions in extruded product forms. The range of processing conditions was explored in the fabrication of plate and sheet gage materials, as well as the resultant mechanical and metallurgical properties. The PM composition based on Al-3.70 Cu-1.85 Mg-0.20 Mn with 0.60 wt. pct. Zr was selected. Flat rolled material consisting of 0.250 in. thick plate was fabricated using selected thermal mechanical treatments (TMT). The schedule of TMT operations was designed to yield the extreme conditions of grain structure normally encountered in the fabrication of flat rolled products, specifically recrystallized and unrecrystallized. The PM Al alloy plate and sheet materials exhibited improved strength properties at thin gages compared to IM Al alloys, as a consequence of their enhanced ability to inhibit recrystallization and grain growth. In addition, the PM 2124 Al alloys offer much better combinations of strength and toughnessover equivalent IM Al. The alloy microstructures were examined by optical metallographic texture techniques in order to establish the metallurgical basis for these significant property improvements.

Chellman, D. J.↗
NASA NTRS1989

Predicting minimum Al concentrations for protective scale fromation on Ni-base alloys. I - Isothermal oxidation. II - Cyclic oxidation

Criteria proposed to predict the minimum bulk Al concentration for the formation of protective Al2O3 scales on Ni-based alloys during isothermal oxidation (two criteria proposed by Wagner, 1952 and 1959) and cyclic oxidation (the criteria proposed by Wahl, 1983, and Whittle, 1972/Wahl, 1983) were applied to Ni-Al and Ni-Cr-Al(Zr) alloys, respectively. It is shown that the first Wagner (1952) criterion underpredicted, by a factor of 3, the experimentally observed minimum Al concentration for the formation of an external Al2O3 scale on Ni-Al alloys at 1200 C; the second Wagner criterion predicted a transition from internal oxidation to continuous Al2O3 formation in good agreement with experimentally observed concentrations. It was also found that the two criteria for an Al2O3 scale formation during cyclic oxidation of Ni-Cr-Al(Zr) alloys were inadequate to predict the minimum Al concentration necessary for repeated formation of an Al2O3 scale, regardless of the adherence of the scale.

Nesbitt, James A.↗
NASA NTRS2007

Solidification Behavior of gamma'-Ni3Al Containing Alloys in the Ni-Al-O System

The chemical activities of Al and Ni in gamma(prime)-Ni3Al-containing systems were measured using the multi-cell Knudsen effusion-cell mass spectrometry technique (multi-cell KEMS), over the composition range 8 - 32 at.%Al and temperature range T = 1400 - 1750 K. From these measurements a better understanding of the equilibrium solidification behaviour of gamma(prime)-Ni3Al-containing alloys in the Ni-Al-O system was established. Specifically, these measurements revealed that (1) gamma(prime)-Ni3Al forms via the peritectiod reaction, gamma + Beta (+ A12O3) = gamma (prime) (+ Al2O3), at 1633 +/- 1 K, (2) the {gamma + Beta + Al2O3} phase field is stable over the temperature range 1633 through 1640 K, and (3) equilibrium solidification occurs by the eutectic reaction, L (+ Al2O3) = gamma + Beta (+ Al2O3), at 1640 +/- 1 K and a liquid composition of 24.8 +/- 0.2 at.%Al (at an unknown oxygen content). When projected onto the Ni-Al binary, this behaviour is inconsistent with the current Ni-Al phase diagram and a new diagram is proposed. This new Ni-Al phase diagram explains a number of unusual steady-state solidification structures reported previously and provides a much simpler reaction scheme in the vicinity of the gamma(prime)-Ni3Al phase field.

Copland, Evan↗
NASA NTRS2011

Comment on "An Analysis of VLF Electric Field Spectra Measured in Titan's Atmosphere by The Huygens Probe" By J. A. Morente et al.

Morente et al. have recently revisited the VLF electric field measurements made with the Permittivity, Wave and Altimetry (PWA) instrument during the descent of the Huygens Probe through the atmosphere of Titan. They assert that they have identified several harmonics of the transverse resonance mode of the surface?]ionosphere cavity, which would prove the existence of an electrical activity in the atmosphere of the largest satellite of Saturn. We refute this finding on the basis that it results from an artifact due to an improper analysis of the data set. [2] The investigators of the Permittivity, Wave and Altimetry (PWA) experiment on the Huygens Probe have reported the extremely low frequency (ELF) and very low frequency (VLF) electric signals recorded during the descent through the atmosphere of Titan. The PWA data are archived in the Planetary Science Archive (PSA) of ESA, and an extensive description of the instrument is at the disposal of the scientific community. Morente and his coworkers have revisited this data set and reported the results of their investigations in two papers. In a first paper, they claim that they have detected in the ELF range (0.100 Hz) several harmonics of a global resonance allegedly generated by lightning activity in the spherical cavity guide formed by the surface of Titan and the inner boundary of the ionosphere, a phenomenon similar to the Schumann resonance observed at EartH In the second paper dedicated to the VLF electric signal recorded by PWA, in the range 0.10 kHz, they argue that they can also bring out the transverse resonance and its harmonics, a more local phenomenon that develops around the excitation source and whose frequency is controlled by the separation between Titan?fs surface and the inner ionospheric boundary. [3] The PWA investigators have analyzed the narrowband ELF signal at about 36 Hz effectively observed during the entire descent. They have not endorsed, however, the alternative approach of Morente et al. that discloses additional ELF narrow-band signals and numerous related harmonics. Hamelin et al. and Beghin et al. have questioned the work of Morente and his coworkers and demonstrated unambiguously that their findings are mere artifacts entirely due to a faulty procedure. Morente et al. refuted this critical analysis of their ELF paper in a rebuttal. The present comment draws a parallelism between the ELF and VLF papers and demonstrates that the VLF signal carries no evidence whatever of any transverse resonance. The analyses of the ELF and VLF signals by Morente and his coworkers are flawed, and their conclusions are shown here to be invalid. A more comprehensive and thorough assessment of the numerical approaches proposed by Morente et al. is given by Berthelin et al..

Grard, Rejean↗
NASA NTRS1972

The oxidation behavior of Ni-Cr-Al-2ThO2 alloys at 1093 and 1204 C.

A pack diffusion process has been developed which permits the introduction of nearly 6 wt % Al into solid solution in the near surface region of TDNiCr (Ni-20 wt % Cr-2 vol % ThO2) and Ni-20Cr. Alumina scales, adherent under cyclic heating and cooling conditions, were produced on TDNiCr-5.86Al upon exposure to an environment of 1330 N/sq m (10 torr) or 101,000 N/sq m (760 torr) air at temperatures of 1093 and 1204 C. While the same oxidation kinetics were observed in isothermal tests for Ni-14.6Cr-5.86Al as were obtained for the TDNiCr-5.86Al, the dispersion-strengthened alloy exhibited superior oxide scale adhesion during cyclic testing. At 1204 C, continuous weight gains were observed under all test conditions for TDNiCr-5.86Al, in contrast to the weight loss with time which occurred several hours after exposure of TDNiCr to an oxidizing environment. TDNiCr with an initial aluminum surface concentration of 4.95 wt % has nearly comparable oxidation resistance to the TDNiCr-5.86Al alloy.

Seltzer, M. S.↗
NASA NTRS1983

Reactions and diffusion between an Al film and a Ti substrate

The reaction between a 0.5 to 1.0 micron Al film and a thick Ti substrate to form TiAl3 occurs very rapidly on heating to 635 C and causes the Al to be confined to the surface region. After heating to 900 C, Ti3Al is formed with little release of Al into alpha-Ti. Further annealing at 900 C eventually causes the Ti3Al phase to decompose and a substantial amount of Al is released into alpha-Ti. The interdiffusion coefficient for Al in alpha-Ti at 900 C was found to increase by less than one order of magnitude as Al is varied from 0 to 20 at. pct. These data were obtained from the (101) X-ray diffraction intensity band using polycrystalline samples. Improvements in the analysis of X-ray diffraction data for the determination of composition profiles are discussed.

Rao, V. B.↗
NASA NTRS1986

The effects of gravity level during directional solidification on the microstructure of hypermonotectic Al-In-Sn alloys

Five hypermonotectic Al-In-Sn compositions were directionally solidified in a Bridgman-type furnace at normal gravity and during aircraft low-gravity maneuvers. The tendency of the Al-30In alloy to form an indium-rich band at the start of unidirectional growth (SUG) made it difficult to study the integration of L sub 2 into the solidification interface. Hypermonotectic compositions closer to monotectic slightly hypermonotectic caused only a partial band on L sub 2 to form at SUG and allowed the study of such variables as gravity, composition, and monotectic dome height on integration of excess L sub 2 into the solid plus L sub 2 interface. It was found that formation of aligned composite structures for the Al-In-Sn system is not only a function of G and R but also of the degree to which the composition varies from monotectic. Most of the aligned fibrous structures formed from hypermonotectic Al-In-Sn had spacings that were of the order of irregular fibrous structures reported for on monotectic Al-In-Sn. The spacings for the large fibers and aligned globules found for ground and low-gravity processed Al-In-18-Sn-22, respectively, were significantly larger than the others measured and were of the order expected for cell spacings under the growth conditions utilized. It was found that the integration into the solidification front of excess L sub 2 in low gravity was a function of the Sn composition of the alloy.

Curreri, P. A.↗
NASA NTRS1988

Diffusional transport during the cyclic oxidation of gamma + beta, Ni-Cr-Al(Y, Zr) alloys

The cyclic oxidation behavior of several cast gamma + beta, Ni-Cr-Al(Y, Zr) alloys and one low-pressure plasma spraying gamma + beta, Ni-Co-Cr-Al(Y) alloy was studied. Cyclic oxidation was found to result in a decreasing Al concentration at the oxide-metal interface due to a high rate of Al consumption coupled with oxide scale cracking and spalling. Diffusion paths plotted on the ternary phase diagram showed higher Ni concentrations with increasing cyclic oxidation exposures. The alloy with the highest rate of Al consumption and the highest Al content underwent breakaway oxidation following 500 1-hr cycles at 1200 C.

Nesbitt, J. A.↗
NASA NTRS1988

Iron-base superalloys - A phase analysis of the multicomponent system (Fe-Mn-Cr-Mo-Nb-Al-Si-C)

In the course of studies on the iron-rich multicomponent system Fe-Mn-Cr-Mo-Nb-Al-Si-C, work was concentrated on pertinent quinary and six-component combinations namely Fe-Mn-Al-Si-C, Fe-Cr-Al-Si-C and Fe-Mn-Cr-Al-Si-C which had been elaborated at 65, 72, and 80 wt pct Fe. Manganese acts as a strong stabilizer for the cementite carbide. Chromium seems to stabilize the iron aluminide Fe2Al5 which forms in a considerable amount within an alloy of nominal composition Fe(65)Mn(15)Cr(12)Al(5)Si(2)C(1) (percent by weight). Although the Mn3AlC carbide is, like Fe3AlC, a perovskite carbide, manganese does not appear to favor the formation of the perovskite carbide. Because of the relatively low sintering temperature (700 C), for al large portion of the samples equilibria conditions are not always reached.

Gupta, H.↗
NASA NTRS1991

Reaction of Ti and Ti-Al alloys with alumina

The reaction of single-crystal Al2O3 with pure Ti and Ti-Al alloys with different Al concentrations was examined in the temperature range of 1173 to 1573 K. Significant reaction occurred between Al2O3 and the Ti-Al alloys with Al concentrations lower than that corresponding to the gamma-TiAl phase. The reaction mechanism was determined to be simultaneous diffusion of Al and atomic oxygen from Al2O3 into Ti and the Ti-Al alloys.

Misra, Ajay K.↗