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At least 703 records · Page 39

Filling the Gaps: A Bayesian Mixture Model for Imputing Missing Soil Water Content Data

ABSTRACT Soil water content (SWC) data are central to evaluating how soil moisture varies over time and space and influences critical plant and ecosystem functions, especially in water‐limited drylands. However, sensors that record SWC at high frequencies often malfunction, leading to incomplete timeseries and limiting our understanding of dryland ecosystem dynamics. We developed an analytical approach to impute missing SWC data, which we tested at six eddy flux tower sites along an elevation gradient in the southwestern United States. We impute missing data as a mixture of linearly interpolated SWC between the observed endpoints of a missing data gap and SWC simulated by an ecosystem water balance model (SOILWAT2). Within a Bayesian framework, we allowed the relative utility (mixture weight) of each component (linearly interpolated vs. SOILWAT2) to vary by depth, site and gap characteristics. We explored “fixed” weights versus “dynamic” weights that vary as a function of cumulative precipitation, average temperature, and time since the start of the gap. Both models estimated missing SWC data well ( R 2 = 0.70–0.88 vs. 0.75–0.91 for fixed vs. dynamic weights, respectively), but the utility of linearly interpolated versus SOILWAT2 values depended on site and depth. SOILWAT2 was more useful for more arid sites, shallower depths, longer and warmer gaps and gaps that received greater precipitation. Overall, the mixture model reliably gap‐fills SWC, while lending insight into processes governing SWC dynamics. This approach to impute missing data could be adapted to accommodate more than two mixture components and other types of environmental timeseries.

Ogle, Kiona [School of Informatics, Computing, and↗

Effects of Spaceflight Relevant Carbon Dioxide Levels on Pathogenesis Related Microbial Characteristics

BACKGROUND Multiple stressors in the spaceflight environment have the potential to alter microbial pathogenesis and virulence characteristics, including microgravity, radiation, and hostile/confined conditions. This combination of factors may lead to a stacking of risks, potentially creating unexpected increase in the risk of infectious disease. One understudied variable is the higher CO2 atmospheric concentration. The current Spaceflight Maximum Allowance Concentration (SMAC) for 24-hour average CO2 is 0.4% (3 mm Hg). These elevated ambient CO2 levels aboard the ISS could potentially influence the diversity and phenotypic responses of the resident microbial communities from both the spacecraft environment (air, surface, water) and crewmembers (gut, nasal, skin microbiomes). METHODS For these studies, we will evaluate the response of Staphylococcus aureus, Streptococcus pneumoniae and Enterobacter aerogenes, which are opportunistic pathogens that are of medical significance and have been or are likely to be found aboard spacecraft. These microorganisms will be cultured in both spaceflight analog and control conditions at CO2levels representing terrestrial atmospheric concentration of 0.04% (0.3 mmHg), ISS elevated concentration of 0.4% (3 mm Hg), and an unexpected elevated concentration of 1 % (7.6 mmHg) to represent a worst case scenario. DISCUSSION Overwhelming evidence from studies performed in food microbiology, marine biology and terrestrial environmental biology suggest altered gene expression, selective bacterial inhibition, increased growth and diversity, and increased antibiotic resistance of bacterial communities individually and in biofilm formation when exposed to increased levels of CO2. While many of these findings are based on levels of CO2 higher than would be found during spaceflight exploration missions, the potential for subtle changes in CO2 levels to exacerbate infectious disease risks warrants an evaluation of pathogen responses to spaceflight CO2 conditions. Our study will provide answers to spaceflight relevant atmospheric conditions, as described in the Risk of Adverse Health Effects Due to Host-Microorganism Interaction (GapMicro 103).

A A Medina-Colorado↗

Unified Wind-Wave Growth and Spectrum Functions for All Water Depths: Field Observations and Model Results

Abstract Wind-wave development is governed by the fetch- or duration-limited growth principle that is expressed as a pair of similarity functions relating the dimensionless elevation variance (wave energy) and spectral peak frequency to fetch or duration. Combining the pair of similarity functions, the fetch or duration variable can be removed to form a dimensionless function of elevation variance and spectral peak frequency, which is interpreted as the wave energy evolution with wave age. The relationship is initially developed for quasi-neural stability and quasi-steady wind forcing conditions. Further analyses show that the same fetch, duration, and wave-age similarity functions are applicable to unsteady wind forcing conditions, including rapidly accelerating and decelerating mountain gap wind episodes and tropical cyclone (TC) wind fields. Here it is shown that with the dimensionless frequency converted to dimensionless wavenumber using the surface wave dispersion relationship, the same similarity function is applicable in all water depths. Field data collected in shallow to deep waters and mild to TC wind conditions and synthetic data generated by spectrum model computations are assembled to illustrate the applicability. For the simulation work, the finite-depth wind-wave spectrum model and its shoaling function are formulated for variable spectral slopes. Given wind speed, wave age, and water depth, the measured and spectrum-computed significant wave heights and the associated growth parameters are in good agreement in forcing conditions from mild to TC winds and in all depths from deep ocean to shallow lake. Significance Statement This paper presents a growth function and spectrum model to describe wind-wave development in all water depths. Their applicability covers a wide range of wind forcing conditions including steady, accelerating, decelerating, and tropical cyclone events. Support for the unified spectrum model and growth function is presented with field observations and numerical computations.

Hwang, Paul A.↗

Temperature Effect on Photoelectrochemical Water Splitting: A Model Study Based on BiVO 4 Photoanodes

Photoelectrochemical (PEC) water splitting is typically studied at room temperature. In this work, the temperature effect on PEC water splitting is studied using crystalline BiVO4 thin film photoanode as a model system. Systematic temperature-dependent electrochemical study demonstrates that the PEC activity is boosted at elevated electrolyte temperatures and indicates that thermal energy plays a main role in improving charge carrier transport in the bulk of BiVO 4 . Irreversible surface reconstruction is observed after PEC reactions at elevated temperature in the presence of hole scavengers, with regularly spaced stripes emerging on BiVO4 grains. The surface-reconstructed photoanode exhibits up to 40% improvement in photocurrent densities and ~0.25 V shift of photocurrent onset to favorable direction. Detailed investigation shows the formation of amorphous layer without stoichiometric change at the reconstructed surface. Furthermore, this work provides insights of temperature effect on photoelectrode in solar water splitting and reveals the non-negligible effect of hole scavengers in photoelectrochemical measurement.

36 MATERIALS SCIENCE↗

Mass removal efficiencies in water and consequences after a river diversion into coastal wetlands: second thoughts

Abstract Salinity control, nutrient additions, and sediment supply were directly or indirectly the rationale for a $220 million coastal wetland restoration project (Davis Pond River Diversion) that began in 2002. We sampled Mississippi River water going in and out of the receiving basin from 1999 to 2018 to understand why wetland loss increased after it began. There was a reduction in inorganic sediments, nitrogen (N), and phosphorus (P) concentrations within the ponding area of 77%, 39% and 34%, respectively, which is similar to that in other wetlands. But the average sediment accumulation of 0.6 mm year −1 inadequately balances the present-day 5.6 mm year −1 sea level rise or the 7.9 ± 0.13 mm year −1 accretion rates in these organic soils. Nutrients added likely reduced live belowground biomass and soil strength, and increased decomposition of the organic matter necessary to sustain elevations. The eutrophication of the downstream aquatic system from the diversion, principally by P additions, increased Chl a concentrations to a category of ‘poor’ water quality. We conclude that this diversion, if continued, will be a negative influence on wetland area and will eutrophy the estuary. It is a case history example for understanding the potential effects arising from proposed river diversions.

Turner, R. Eugene (ORCID:0000000307767506)↗

Identification of Noise Sources During Rocket Engine Test Firings and a Rocket Launch Using a Microphone Phased-Array

A 70 microphone, 10-foot by 10-foot, microphone phased array was built for use in the harsh environment of rocket launches. The array was setup at NASA Wallops launch pad 0A during a static test firing of Orbital Sciences' Antares engines, and again during the first launch of the Antares vehicle. It was placed 400 feet away from the pad, and was hoisted on a scissor lift 40 feet above ground. The data sets provided unprecedented insight into rocket noise sources. The duct exit was found to be the primary source during the static test firing; the large amount of water injected beneath the nozzle exit and inside the plume duct quenched all other sources. The maps of the noise sources during launch were found to be time-dependent. As the engines came to full power and became louder, the primary source switched from the duct inlet to the duct exit. Further elevation of the vehicle caused spilling of the hot plume, resulting in a distributed noise map covering most of the pad. As the entire plume emerged from the duct, and the ondeck water system came to full power, the plume itself became the loudest noise source. These maps of the noise sources provide vital insight for optimization of sound suppression systems for future Antares launches.

acoustics↗

Origin of tungsten and geochemical controls on its occurrence and mobilization in shallow sediments from Fallon, Nevada, USA

In this study, tungsten (W) occurrence and speciation was investigated in sediments collected from Fallon, Nevada where previous studies have linked elevated W levels in human body fluids to an unusual cluster of childhood leukemia cases. The speciation of sedimentary W was determined by μ-XRF mapping and μ-XANES. The W content of the analyzed surface sediments ranged between 81 and 25,908 mg/kg, which is significantly higher than the W content in deeper sediments which ranged from 37 to 373 mg/kg at 30 cm depth. The μ-XANES findings reveal that approximately 20–50% of the total W in the shallow sediment occurs in the metallic form (W 0 ); the rest occurs in the oxide form (W VI O 3 ). Because W 0 does not occur naturally, its elevated concentrations in surface sediments point toward a possible local anthropogenic origin. The oxidation of metallic W 0 with meteoric waters likely leads to the formation of W VI O 3 . The chief water-soluble W species was identified as WO 4 2– by chromatographic separation and speciation modeling. These results led us to postulate that W 0 particles from a currently unknown but local source(s) is (are) deposited onto the soils and/or surface sediments. The W 0 in interaction with meteoric water is oxidized to W VI O 3 , and as these sediment-water interactions progress, WO 4 2– is formed in the water at pH ~7. Under pH < 7, and sufficient W concentrations, tungstate tends to polymerize, and polymerized species are less likely to adsorb onto sediments. Polymerized species have lower affinity than monomers, which leads to enhanced mobility of W.

58 GEOSCIENCES↗

Analysis of alternative climate datasets and evapotranspiration methods for the Upper Mississippi River Basin using SWAT within HAWQS

This study reports the application of Soil andWater Assessment Tool (SWAT) within the Hydrologic andWater Quality System(HAWQS) on-line platform, for the UpperMississippi River Basin (UMRB). TheUMRB is an important ecosystem located in the north central U.S. that is experiencing a range of ecological stresses. Specifically, testing of SWAT was performed for: (1) Hargreaves (HG) and Penman-Monteith (PM) PET methods, and (2) Livneh, National Climatic Data Center (NCDC) and Parameter-elevation Regressions on Independent Slopes Model (PRISM) climate datasets. The Livneh-PM combination resulted in the highest average annual water yield of 380.6 mm versus the lowest estimated water yield of 193.9 mm for the Livneh-HG combination, in response to 23-year uncalibrated simulations. Higher annual ET and PET values were predicted with HG method versus the PM method for all three weather datasets in response to the uncalibrated simulations, due primarily to higher HG-based estimates during the growing season. Based on these results, it was found that the HG method is the preferred PET option for the UMRB. Initial calibration of SWAT was performed using the Livneh data and HGmethod for threeMississippi Rivermain stem gauge sites, which was followed by spatial validation at 10 other gauge sites located within the UMRB streamnetwork. Overall satisfactory results were found for the calibration and validation gauge sites, with the majority of R2 values ranging between 0.61 and 0.82, Nash- Sutcliffe modeling efficiency (NSE) values ranging between 0.50 and 0.79, and Kling-Gupta efficiency (KGE) values ranging between 0.61 and 0.84. The results of an additional experimental suite of six scenarios,which represented different combinations of climate data sets and calibrated parameters, revealed that suggested statistical criteria were again satisfied by the different scenario combinations. Overall, the PRISM data exhibited the strongest reliability for the UMRB.

54 ENVIRONMENTAL SCIENCES↗

Optimum frequencies of passive microwave radiometer for tropospheric path-length correction

Radio-astronomical observations require accurate calibration of tropospheric path length. Such calibration can be achieved by microwave radiometers operating near the 22-GHz water vapor line. However, the performances of current passive microwave radiometers are meteorology-profile dependent. This is due mainly to incorrect frequency combinations and to saturation of brightness temperatures. By properly selecting an optimum frequency pair and removing the saturation effect, the dependency is alleviated and can be further adjusted by surface measurements alone. Hence, a universal calibration equation is applicable to all environmental conditions. Optimum frequency pairs are systematically searched. Simulation analysis indicates that calibration for the tropospheric water-vapor path-length error is better than 0.3 cm at zenith and better than 2 cm for an elevation angle as low as 10 deg.

Wu, S.-C.↗

Verification and transfer of thermal pollution model. Volume 4: User's manual for three-dimensional rigid-lid model

The theory of a three dimensional (3-D) mathematical thermal discharge model and a related one dimensional (1-D) model are described. Model verification at two sites, a separate user's manual for each model are included. The 3-D model has two forms: free surface and rigid lid. The former allows a free air/water interface and is suited for significant surface wave heights compared to mean water depth, estuaries and coastal regions. The latter is suited for small surface wave heights compared to depth because surface elevation was removed as a parameter. These models allow computation of time dependent velocity and temperature fields for given initial conditions and time-varying boundary conditions. The free surface model also provides surface height variations with time.

Lee, S. S.↗

Real Time Monitoring of Flooding from Microwave Satellite Observations

We have developed a new method for making high-resolution flood extent maps (e.g., at the 30-100 m scale of digital elevation models) in real-time from low-resolution (20-70 km) passive microwave observations. The method builds a "flood-potential" database from elevations and historic flood imagery and uses it to create a flood-extent map consistent with the observed open water fraction. Microwave radiometric measurements are useful for flood monitoring because they sense surface water in clear-or-cloudy conditions and can provide more timely data (e.g., compared to radars) from relatively wide swath widths and an increasing number of available platforms (DMSP, ADEOS-II, Terra, NPOESS, GPM). The chief disadvantages for flood mapping are the radiometers' low resolution and the need for local calibration of the relationship between radiances and open-water fraction. We present our method for transforming microwave sensor-scale open water fraction estimates into high-resolution flood extent maps and describe 30-day flood map sequences generated during a retrospective study of the 1993 Great Midwest Flood. We discuss the method's potential improvement through as yet unimplemented algorithm enhancements and expected advancements in microwave radiometry (e.g., improved resolution and atmospheric correction).

Galantowicz, John F.↗

Deviation of Long-Period Tides from Equilibrium: Kinematics and Geostrophy

New empirical estimates of the long-period fortnightly (Mf) tide obtained from TOPEX/Poseidon (T/P) altimeter data confirm significant basin-scale deviations from equilibrium. Elevations in the low-latitude Pacific have reduced amplitude and lag those in the Atlantic by 30 deg or more. These interbasin amplitude and phase variations are robust features that are reproduced by numerical solutions of the shallow-water equations, even for a constant-depth ocean with schematic interconnected rectangular basins. A simplified analytical model for cooscillating connected basins also reproduces the principal features observed in the empirical solutions. This simple model is largely kinematic. Zonally averaged elevations within a simple closed basin would be nearly in equilibrium with the gravitational potential, except for a constant offset required to conserve mass. With connected basins these offsets are mostly eliminated by interbasin mass flux. Because of rotation, this flux occurs mostly in a narrow boundary layer across the mouth and at the western edge of each basin, and geostrophic balance in this zone supports small residual offsets (and phase shifts) between basins. The simple model predicts that this effect should decrease roughly linearly with frequency, a result that is confirmed by numerical modeling and empirical T/P estimates of the monthly (Mm) tidal constituent. This model also explains some aspects of the anomalous nonisostatic response of the ocean to atmospheric pressure forcing at periods of around 5 days.

Egbert, Gary D.↗

A Theoretical Investigation of Oxidation Efficiency of a Volatile Removal Assembly Reactor Under Microgravity Conditions

Volatile Removal Assembly (VRA) is a subsystem of the Closed Environment Life Support System (CELSS) installed in the International Space Station. It is used for removing contaminants (volatile organics) in the wastewater produced by the space station crews. The major contaminants are formic acid, ethanol, and propylene glycol. The VRA contains a slim packbed reactor (3.5 cm diameter and four 28 cm long tubes in series) to perform catalyst oxidation of wastewater at elevated pressure and temperature under microgravity conditions. In the reactor, the contaminants are burned with oxygen gas (O2) to form water and carbon dioxide (CO2) that dissolves in the water stream. Optimal design of the reactor requires a thorough understanding about how the reactor performs under microgravity conditions. The objective of this study was to develop a mathematical model to interpret experimental data obtained from normal and microgravity conditions, and to predict the performance of VRA reactor under microgravity conditions. Catalyst oxidation kinetics and the total oxygen-water contact area control the efficiency of catalyst oxidation for mass transfer, which depends on oxygen gas holdup and distribution in the reactor. The process involves bubbly flow in porous media with chemical reactions in microgravity environment. This presents a unique problem in fluid dynamics that has not been studied. Guo et al. (2004) developed a mathematical model that predicts oxygen holdup in the VRA reactor. No mathematical model has been found in the literature that can be used to predict the efficiency of catalyst oxidation under microgravity conditions.

Guo, Boyun↗

Oxy-fuel combustion and power generation system

Integration of an oxyfuel combustion boiler at elevated pressures and a heat exchanger is achieved to produce carbon dioxide by feeding flue gas comprising carbon dioxide and water from the oxyfuel combustion boiler to a direct contact cooler column wherein water is condensed at a temperature of 0 to 10° C. lower than its dew point; feeding a portion of the condensed water from the direct contact cooler column to the oxyfuel combustion boiler; feeding a portion of the carbon dioxide from the direct contact cooler column to the oxyfuel combustion boiler; and recovering a portion of the carbon dioxide from the direct contact cooler column.

Alekseev, Alexander↗

Impacts of Topography-Based Subgrid Scheme and Downscaling of Atmospheric Forcing on Modeling Land Surface Processes in the Conterminous US

The effects of small-scale topography-induced land surface heterogeneity are not well represented in current Earth System Models (ESMs). In this study, a new topography-based subgrid structure referred to as topographic units (TGU) designed to better capture subgrid topographic effects, and methods to downscale atmospheric forcing to the land TGUs have been implemented in the Energy Exascale Earth System Model (E3SM) Land Model (ELM). Effects of the subgrid scheme and downscaling methods on ELM simulated land surface processes are evaluated over the conterminous United States (CONUS). For this purpose, ELM simulations are performed using two configurations without (NoD ELM) and with (D ELM) downscaling, both using TGUs derived for the 0.5-degree grids and the same land surface parameters. Simulations using the two ELM configurations are compared over the CONUS domain, regional levels, and at observational sites (e.g., SNOTEL). The CONUS-level results suggest that D ELM simulates more snowfall and snow water equivalent (SWE), higher runoff, and less ET during spring and summer. Regional-level results suggest more pronounced impacts of downscaling over regions dominated by higher elevation TGUs and regions with maximum precipitation occurring during cool seasons. Results at the SNOTEL sites suggest that D ELM has superior capability of reproducing the observed SWE at 83% of the sites, with more pronounced performance over topographically heterogeneous TGUs with their maximum precipitation occurring during cool seasons. The results highlight the importance of improving representation of small-scale surface heterogeneity in ESMs and motivate future research to understand their effects on land-atmosphere interactions, streamflow, and water resources management over mountainous regions.

54 ENVIRONMENTAL SCIENCES↗

Anhydrous vs Hydrated f-Element Acetate Polymers Dictated by the Stoichiometry of Protic Acidic/Basic Azole Mixtures

Continuing our investigations of ionic liquid (IL) based routes to a library of f-element/soft donor complexes which could be studied crystallographically, we have explored the dissolution of f-element salts in protic imidazole-based ILs containing only soft donors at high temperatures to drive off volatiles, including water and carboxylic or mineral acids. Here we present our results, reacting acidic and basic azoles in 1:3 or 1:1 stoichiometric compositions at elevated temperature, followed by saturation with Nd(OAc) 3 ·xH 2 O or Ce(OAc) 3 ·xH 2 O, which led to 13 new metal–acetate polymeric complexes identified by single-crystal X-ray diffraction. We found that the diversity in coordination modes of the simple acetate ligand that interfere with substitution of the softer N donors led to several readily crystallizable complexes forming two distinct groups with respect to f-element interaction with the ionic liquid precursors. When the acidic/basic azole ratio was 1:3, acetate and a neutral basic azole were found to be coordinated to the metal centers but no water, although in one case (2) water was observed in the secondary coordination sphere: [Ce(μ 2 -OAc) 3 (C 1 im)] n (1, C 1 im = 1-methylimidazole), [Nd(μ 2 -(OAc) 3 (C 1 im)] n ·nH 2 O (2), [Ce(μ 2 -OAc) 3 (C 2 im)] n (3, C 2 im = 1-ethylimidazole), [Ln(μ 2 -OAc) 3 DMF] n (Ln = Nd (4), Ce (5); dimethylformamide (DMF) was substituted for the azole mixture), and [Nd(μ 2 -OAc) 3 (C 4 im)] n (6, C 4 im = 1-butylimidazole). However, when the stoichiometric ratio was 1:1, water was always observed coordinated to the metal ions with the acidic azole included in the structure as a solvate or cocrystal, despite a higher reaction temperature: [Nd(μ 2 -OAc) 3 (OH 2 )] n ·n(1,2,3-Taz) (7, 1,2,3-Taz = 1,2,3-triazole), [Ln(μ 2 -OAc) 3 (OH 2 )] n ·n(4,5-DCim) (Ln = Nd (8), Ce (9), 4,5-DCim = 4,5-dicyanoimidazole), [Ln(μ 2 -OAc) 3 (OH 2 )] n ·n(3,5-diNH 2 -1,2,4-Taz) (Ln = Nd (10), Ce (11), 3,5-diNH 2 -1,2,4-Taz = 3,5-diamino-1,2,4-triazole), [Ce(μ 2 -OAc) 3 (OH 2 )] n ·n(3-NH 2 -1,2,4-Taz) (12, 3-NH 2 -1,2,4-Taz = 3-amino-1,2,4-triazole), and [Nd(μ 2 -OAc) 3 (OH 2 )] n ·n(5-NH 2 -Tz) (13, 5-NH2-Tz = 5-aminotetrazole). All of the compounds retain the Ln:OAc– ratio of 1:3 and form 1D polymeric chains; however, they exhibit a variety of coordination modes affecting the degree of chain condensation. The isolation of both hydrated and anhydrous products revealed different abilities of the investigated soft N-donors to compete with O-donors finding their place in the coordination sphere of the lanthanide or in the crystal lattice.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Kinetics of the Temperature-Dependent e aq - and ·OH Radical Reactions with Cr(III) Ions in Aqueous Solutions

The reactivity of chromium(III) species with the major oxidizing and reducing radiolysis products of water was investigated in aqueous solutions at temperatures up to 150 °C. The reaction between the hydrated electron (e aq - ) and Cr(III) species showed a positive temperature dependence over this temperature range. The reaction was also studied in pH 2.5 and 3.5 solutions for the first time. This work also studied the reaction between acidic Cr(III) species and the hydroxyl radical (·OH). It was found that Cr 3+ did not react significantly with the ·OH radical, but the first hydrolysis species, Cr(OH) 2+ , did with a rate coefficient of k= (7.2±0.3)×10 8 M -1 s -1 at 25 °C. The oxidation of Cr(OH) 2+ by the ·OH radical formed an absorbing product species that ultimately oxidized to give Cr(VI). In conclusion, these newly measured reaction rates allow for the development of improved models of aqueous chromium speciation for the effective remediation of liquid high-level nuclear waste via vitrification processes.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

The Mars water cycle at other epochs - Recent history of the polar caps and layered terrain

A numerical model is presented of the integrated role of seasonal water cycle on the evolution of polar deposits on Mars over the last 10 million years. From the model, it is concluded that the only major difference between the polar caps which affects their long-term behavior is ultimately the difference in their elevations. Because of that difference, there is a preference for CO2 frost to stay longer on the northern polar cap. The average difference in sublimation at the caps results in a net south-to-north transport of water ice over long time scales. Superimposed on any long-term behavior is a transfer of water ice between the caps on the 10 exp 5 - 10 exp 6 yr time scales. The amount of water exchanged is small compared to the total ice content of the polar deposits.

Jakosky, Bruce M.↗