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At least 703 records · Page 39

Study of the water dynamics near hydrophilic, nanostructured CuO surfaces by quasielastic and inelastic neutron scattering

We have used quasielastic and inelastic neutron scattering to investigate the structure, dynamics, and phase transitions of water interacting with superhydrophilic CuO surfaces that not only possess a strong affinity for water but also a “grass-like” topography that is rough on both micro- and nanoscales. Here, we report quasielastic neutron scattering (QENS) measurements on two samples differing in water content at five temperatures below 280 K. The QENS spectra show water undergoing two different types of diffusive motion near the CuO surfaces: a “slow” translational diffusion occurring on a nanosecond time scale and a faster rotational motion. Further from the surfaces, there is “fast” translational diffusion comparable in rate to that of bulk supercooled water and the rotational motion occurring in the interfacial water. Analysis of the QENS spectra supports wetting of water to the CuO blades as seen in electron microscopy images. In addition, we observe an anomalous temperature dependence of the QENS spectra on cooling from 270 to 230 K with features consistent with a liquid–liquid phase transition. We suggest that the solvent-like properties of the coexisting bulk-like water in our CuO samples are a significant factor in determining the temperature dependence of the interfacial water’s dynamics. Our results are compared with those obtained from two well-studied substrate classes: (1) silicas that contain ordered cylindrical nanopores but have weaker hydrophilicity and (2) nanoparticles of other transition-metal oxides, such as TiO 2 , which share the strong hydrophilicity of our samples but lack their porosity.

36 MATERIALS SCIENCE↗

Reduced-Order Kalman Filtering for Processing Relative Measurements

A study in Kalman-filter theory has led to a method of processing relative measurements to estimate the current state of a physical system, using less computation than has previously been thought necessary. As used here, relative measurements signifies measurements that yield information on the relationship between a later and an earlier state of the system. An important example of relative measurements arises in computer vision: Information on relative motion is extracted by comparing images taken at two different times. Relative measurements do not directly fit into standard Kalman filter theory, in which measurements are restricted to those indicative of only the current state of the system. One approach heretofore followed in utilizing relative measurements in Kalman filtering, denoted state augmentation, involves augmenting the state of the system at the earlier of two time instants and then propagating the state to the later time instant.While state augmentation is conceptually simple, it can also be computationally prohibitive because it doubles the number of states in the Kalman filter. When processing a relative measurement, if one were to follow the state-augmentation approach as practiced heretofore, one would find it necessary to propagate the full augmented state Kalman filter from the earlier time to the later time and then select out the reduced-order components. The main result of the study reported here is proof of a property called reduced-order equivalence (ROE). The main consequence of ROE is that it is not necessary to augment with the full state, but, rather, only the portion of the state that is explicitly used in the partial relative measurement. In other words, it suffices to select the reduced-order components first and then propagate the partial augmented state Kalman filter from the earlier time to the later time; the amount of computation needed to do this can be substantially less than that needed for propagating the full augmented Kalman state filter.

Bayard, David S.↗

Pulse Energy and Pulse Duration Effects in the Ionization and Fragmentation of Iodomethane by Ultraintense Hard X Rays

The interaction of intense femtosecond x-ray pulses with molecules sensitively depends on the interplay between multiple photoabsorptions, Auger decay, charge rearrangement, and nuclear motion. Here, we report on a combined experimental and theoretical study of the ionization and fragmentation of iodomethane (CH 3 I) by ultraintense (~10 19 W/cm 2 ) x-ray pulses at 8.3 keV, demonstrating how these dynamics depend on the x-ray pulse energy and duration. We show that the timing of multiple ionization steps leading to a particular reaction product and, thus, the product’s final kinetic energy, is determined by the pulse duration rather than the pulse energy or intensity. While the overall degree of ionization is mainly defined by the pulse energy, our measurement reveals that the yield of the fragments with the highest charge states is enhanced for short pulse durations, in contrast to earlier observations for atoms and small molecules in the soft x-ray domain. Finally, we attribute this effect to a decreased charge transfer efficiency at larger internuclear separations, which are reached during longer pulses.

36 MATERIALS SCIENCE↗

Convection sensitivity and thermal analyses for indium and indium-lead mixing experiment (74-18)

Sounding rocket Experiment 74-18 was designed to demonstrate the effects of the Black Brandt rocket acceleration levels (during the low-g coast phase of its flight) on the motion of a liquid metal system to assist in preflight design. Some post flight analyses were also conducted. Preflight studies consisted of heat transfer analysis and convection sensitivity and convection modeling analyses which aided in the: (1) final selection of fluid materials (indium-lead melts rather than paraffins); (2) design and timing of heater and quench system; and (3) preflight predictions of the degree of lead penetration into the pure indium segment of the fluid. Postflight studies involved: (1) updating the convection sensitivity calculations by utilizing actual flight gravity levels; and (2) modeling the mixing in the flight samples.

Bourgeois, S. V.↗

Excitation of the Earth's Chandler wobble by southern oscillation/El Nino, 1900-1979

The southern oscillation/El Nino (ENSO) is the single most prominent interannual signal in global atmospheric/oceanic fluctuations. The following question is addressed: how important is the angular momentum carried by ENSO in exciting the Earth's Chandler wobble? The question is attacked through a statistical analysis of the coherence spectra (correlation as a function of frequency) between two data sets spanning 1900 to 1979-the southern oscillation index (SOI) time series and the excitation function psi (with x-component psi sub x and y-component psi sub y) of the Chandler wobble derived from the homogeneous ILS (International Latitude Service) polar motion data. The coherence power and phase in the Chandler frequency band (approx. 0.79 to 0.89 cpy) are studied. It is found that, during 1900 to 1979 the coherence between SOI and psi sub x is significant well over the 95% confidence threshold whereas that between SOI and psi sub y is practically nil. Quantitatively, the coherence study shows that ENSO provides some 20% of the observed Chandler wobble excitation power. Since earlier investigations have shown that the total atmospheric/oceanic variation can account for the Chandler wobble excitation at about 20% level, the implication is that ENSO maybe an important (interannual) part of the atmospheric/oceanic variation that is responsible for the Chandler wobble excitation during 1900 to 1979.

Chao, B. F.↗

Numerical simulation of plasma transport driven by the Io torus

The Rice convection model (RCM) has been modified to a form suitable for Jupiter (RCM-J) to study plasma interchange motion in and near the Io plasma torus. The net result of the interchange is that flux tubes, heavily loaded with torus plasma, are transported outward, to be replaced by tubes containing little low-energy (less than 1 keV) plasma. The process is numerically simulated in terms of time evolution from an initial torus that is longitudinally asymmetric and with gradually decreasing density outward from Io's orbit. In the simulations, the nonlinear stage of the instability characteristically exhibits outreaching fingers of heavily-loaded flux tubes that lengthen at an accelerating rate. The principal finding is that the primary geometrical form of outward transport of torus plasma in Jupiter's magnetosphere is through long, outward-moving fingers of plasma. In the simulations, the fingers mainly form in the active sector of the Io torus (the heavier side of the asymmetric torus), and they are spaced longitudinally roughly 20 deg apart.

Yang, Y. S.↗

Evaluation of inertial devices for the control of large, flexible, space-based telerobotic arms

Batch simulation studies which show that torque-wheels can reduce the overshoot in abrupt stop commands by 82 percent for a two-link arm are presented. For man-in-the-loop evaluation, a real-time simulator has been developed that samples a hand-controller, solves the nonlinear equations of motion, and graphically displays the resulting motion on a computer workstation. It is shown that, for a single-link arm, a reaction-mass/torque-wheel combination at the payload end can yield a settling time of 3 s for disturbances in the first flexible mode as opposed to 10 s utilizing only a hub motor.

Montgomery, Raymond C.↗

Ditching Tests with a 1/16-Size Model of the Navy XP2V-1 Airplane at the Langley Tank No. 2 Monorail

Tests were made with a 1/16 size dynamically similar model of the Navy XP2V-1 airplane to study its performance when ditched. The model was ditched in calm water at the Langley tank no. 2 monorail. Various landing attitudes, speeds, and conditions of damage were simulated. The performance of the node1 was determined and recorded from visual observations, by recording time histories of the longitudinal decelerations, and by taking motion pictures of the ditchings From the results of the tests with the model the following conclusions were drawn: 1. The airplane should be ditched at the normal landing attitude. The flaps should be fully extended to obtain the lowest possible landing speed; 2. Extensive damage will occur in a ditching and the airplane probably will dive violently after a run of about 2 fuselage lengths. Maximum longitudinal decelerations up to about 4g will be encountered; and 3. If a trapezoidal hydroflap 4 feet by 2 feet by 1 foot is attached to the airplane at station 192.4, diving will be prevented and the airplane will probably porpoise in a run of about 4 fuselage lengths with a maximum longitudinal deceleration of less than 3.5g.

Fisher, Lloyd J.↗

DVL Angular Velocity Recorder

In many studies, especially of nonstationary flight motion, it is necessary to determine the angular velocities at which the airplane rotates about its various axes. The three-component recorder is designed to serve this purpose. If the angular velocity for one flight attitude is known, other important quantities can be derived from its time rate of change, such as the angular acceleration by differentiations, or - by integration - the angles of position of the airplane - that is, the angles formed by the airplane axes with the axis direction presented at the instant of the beginning of the motion that is to be investigated.

Liebe, Wolfgang↗

Accuracy of High-Rate GPS for Seismology

We built a device for translating a GPS antenna on a positioning table to simulate the ground motions caused by an earthquake. The earthquake simulator is accurate to better than 0.1 mm in position, and provides the "ground truth" displacements for assessing the technique of high-rate GPS. We found that the root-mean-square error of the 1-Hz GPS position estimates over the 15-min duration of the simulated seismic event was 2.5 mm, with approximately 96% of the observations in error by less than 5 mm, and is independent of GPS antenna motion. The error spectrum of the GPS estimates is approximately flicker noise, with a 50% decorrelation time for the position error of approx.1.6 s. We that, for the particular event simulated, the spectrum of dependent error in the GPS measurements. surface deformations exceeds the GPS error spectrum within a finite band. More studies are required to determine whether a generally optimal bandwidth exists for a target group of seismic events.

Elosegui, P.↗

Relationship Between Optimal Gain and Coherence Zone in Flight Simulation

In motion simulation the inertial information generated by the motion platform is most of the times different from the visual information in the simulator displays. This occurs due to the physical limits of the motion platform. However, for small motions that are within the physical limits of the motion platform, one-to-one motion, i.e. visual information equal to inertial information, is possible. It has been shown in previous studies that one-to-one motion is often judged as too strong, causing researchers to lower the inertial amplitude. When trying to measure the optimal inertial gain for a visual amplitude, we found a zone of optimal gains instead of a single value. Such result seems related with the coherence zones that have been measured in flight simulation studies. However, the optimal gain results were never directly related with the coherence zones. In this study we investigated whether the optimal gain measurements are the same as the coherence zone measurements. We also try to infer if the results obtained from the two measurements can be used to differentiate between simulators with different configurations. An experiment was conducted at the NASA Langley Research Center which used both the Cockpit Motion Facility and the Visual Motion Simulator. The results show that the inertial gains obtained with the optimal gain are different than the ones obtained with the coherence zone measurements. The optimal gain is within the coherence zone.The point of mean optimal gain was lower and further away from the one-to-one line than the point of mean coherence. The zone width obtained for the coherence zone measurements was dependent on the visual amplitude and frequency. For the optimal gain, the zone width remained constant when the visual amplitude and frequency were varied. We found no effect of the simulator configuration in both the coherence zone and optimal gain measurements.

Gracio, Bruno Jorge Correia↗

Astronaut Kinematics and Injury Risk for Piloted Lunar Landings and Launches While Standing

During future lunar missions, astronauts may be required to pilot vehicles while standing, and the associated kinematic and injury response is not well understood. In this study we used human body modeling to predict unsuited astronaut kinematics and injury risk for piloted lunar launches and landings in the standing posture. Three pulses (2-5 g; 10–150 ms rise times) were applied in 10 directions (vertical; ± 10-degree offsets) for a total of 30 simulations. Across all simulations, motion envelopes were computed to quantify displacement of the astronaut’s head (max 9.0 cm forward, 7.0 cm backward, 2.1 cm upward, 7.3 cm downward, 2.4 cm lateral) and arms (max 25 cm forward, 35 cm backward, 15 cm upward, 20 cm downward, 20 cm lateral). All head, neck, lumbar, and lower extremity injury metrics were within NASA’s tolerance limits, except tibia compression forces (0–1543 N upper tibia; 0–1482 N lower tibia; tolerance—1350 N) and revised tibia index (0.04–0.58 upper tibia; 0.03–0.48 lower tibia; tolerance—0.43) for the 2.7 g/150 ms pulse. Pulse magnitude and duration contributed over 80% to the injury metric values, whereas loading direction contributed less than 3%. Overall, these simulations suggest piloting a lunar lander vehicle in the standing posture presents a low risk of injury to the astronaut, although risk of tibia injury is potentially outside NASA’s acceptance limits and warrants further investigation.

Mitesh Lalwala↗

Kinematic Evolution of Simulated Star-Forming Galaxies

Recent observations have shown that star-forming galaxies like our own Milky Way evolve kinematically into ordered thin disks over the last approximately 8 billion years since z = 1.2, undergoing a process of "disk settling." For the first time, we study the kinematic evolution of a suite of four state of the art "zoom in" hydrodynamic simulations of galaxy formation and evolution in a fully cosmological context and compare with these observations. Until now, robust measurements of the internal kinematics of simulated galaxies were lacking as the simulations suffered from low resolution, overproduction of stars, and overly massive bulges. The current generation of simulations has made great progress in overcoming these difficulties and is ready for a kinematic analysis. We show that simulated galaxies follow the same kinematic trends as real galaxies: they progressively decrease in disordered motions (sigma(sub g)) and increase in ordered rotation (V(sub rot)) with time. The slopes of the relations between both sigma(sub g) and V(sub rot) with redshift are consistent between the simulations and the observations. In addition, the morphologies of the simulated galaxies become less disturbed with time, also consistent with observations. This match between the simulated and observed trends is a significant success for the current generation of simulations, and a first step in determining the physical processes behind disk settling.

Evolution↗

The Epoch of Disk Settling: Z Approximately Equal to 1 to Now

We present evidence from a sample of 544 galaxies from the DEEP2 Survey for evolution of the internal kinematics of blue galaxies over 0.2 < z < 1.2. DEEP2 provides a large sample of high resolution galaxy spectra and dual-band Hubble imaging from which we measure emission-line kinematics and galaxy inclinations, respectively. Our large sample allows us to overcome scatter intrinsic to galaxy properties, in order to examine trends. At a fixed stellar mass, galaxies systematically decrease in disturbed motions and increase in rotation velocity and potential well depth with time. The most massive galaxies are the most well-ordered at all times, with higher rotation velocities and less disturbed motions compared to less massive galaxies. We quantify disturbed motions with an integrated gas velocity dispersion (sigma(sub g)), which is unlike the typical pressure-supported velocity dispersion measured for early type galaxies and galaxy bulges. Due to finite slit width and seeing, sigma(sub g) integrates over unresolved velocity gradients which can correspond to non-ordered gas kinematics such as small-scale velocity gradients, gas motions due to star-formation, or super-imposed clumps along the line-of-sight. We compile surveys of galaxy kinematics over 1.2 < z < 3.8 and do not find any trends with redshift, likely because these studies are biased toward the most highly star-forming systems. In summary, over the last approx 8 billion years since z = 1.2, blue galaxies evolve from disturbed to ordered systems as they settle to become the rotation-dominated disk galaxies observed in the Universe today, with the most massive galaxies always being the most evolved at any time.

Kassin, Susan A.↗

MD Simulation of Water Using a Rigid Body Description Requires a Small Time Step to Ensure Equipartition

In simulations of aqueous systems, it is common to freeze the bond vibration and angle bending modes in water to allow for a longer time step δt for integrating the equations of motion. Thus, δt = 2 fs is often used in simulating rigid models of water. We simulate the SPC/E model of water using δt from 0.5 to 3.0 fs and up to 4 fs using hydrogen mass repartitioning. In these simulations, we find that for all but δt = 0.5 fs, equipartition is not obtained between translational and rotational modes, with the rotational modes exhibiting a lower temperature than the translation modes. To probe the reasons for the lack of equipartition, we study the autocorrelation of the translational velocity of the center of mass and the angular velocity of the rigid water molecule, respectively. Here, we find that the rotational relaxation occurs on a timescale comparable to vibrational periods, calling into question the original motivations for freezing the vibrations. Furthermore, a time step with δt ≥ 1 fs is not able to capture accurately the fast rotational relaxation, which reveals its impact as an effective slowing-down of rotational relaxation. The fluctuation–dissipation relation then leads to the conclusion that the rotational temperature should be cooler for δt greater than the reference value of 0.5 fs. Consideration of fluctuation–dissipation in equilibrium molecular dynamics simulations also emphasizes the need to capture the temporal evolution of fluctuations with fidelity and the role of δt in this regard. The time step also influences the solution thermodynamic properties: both the mean system potential energies and the excess entropy of hydration of a soft repulsive cavity are sensitive to δt.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Response of space shuttle insulation panels to acoustic noise pressure

The response of reusable space shuttle insulation panels to random acoustic pressure fields are studied. The basic analytical approach in formulating the governing equations of motion uses a Rayleigh-Ritz technique. The input pressure field is modeled as a stationary Gaussian random process for which the cross-spectral density function is known empirically from experimental measurements. The response calculations are performed in both frequency and time domain.

Vaicaitis, R.↗

Dynamic radionuclide determination of regional left ventricular wall motion using a new digital imaging device

In 47 men with arteriographically defined coronary artery disease comparative studies of left ventricular ejection fraction and segmental wall motion were made with radionuclide data obtained from the image intensifier camera computer system and with contrast cineventriculography. The radionuclide data was digitized and the images corresponding to left ventricular end-diastole and end-systole were identified from the left ventricular time-activity curve. The left ventricular end-diastolic and end-systolic images were subtracted to form a silhouette difference image which described wall motion of the anterior and inferior left ventricular segments. The image intensifier camera allows manipulation of dynamically acquired radionuclide data because of the high count rate and consequently improved resolution of the left ventricular image.

Steele, P.↗

Analytical study of the time dependent spacecraft-plasma interaction

A study of the time dependent interaction of an initially uniform equilibrium plasma with a plane conducting surface was made in order to achieve a more complete understanding of the dynamics of the charging process and of the approach to the floating potential on the surface. Numerical solutions of the cold ion equations of motion in conjunction with equilibrium electrons and Poisson's equation show the formation of an ion-rich sheath near the surface and the coupling of the non-neutral region to the undisturbed plasma through a quasineutral rarefaction. Analytical treatment of the quasineutral region showed excellent agreement (within 1 percent) with the numerical results.

Cipolla, J. W., Jr.↗