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At least 703 records · Page 39

Experimental studies of the vapor phase nucleation of refractory compounds. III - The condensation of silver

Measurements are reported of the critical supersaturation necessary to initiate the vapor phase nucleation of silver over the ambient temperature range 500-950 K at total pressures of 250 and 500 torr of hydrogen. The results are compared with the predictions of both classical nucleation theory and the theory of a physical spinodal developed by Rasmussen (1982), neither of which adequately describes the present observations. The nucleation of silver appears to be dependent on the total pressure of the system in a manner which suggests that three-body reactions are necessary in order to form the initial silver cluster (e.g., dimers) from the monoatomic vapor.

Nuth, J. A.↗

Simulation studies for surfaces and materials strength

Three different investigations based on computer simulations were carried out. Simulation calculations were performed using model potentials with two- and three-body interactions which were represented by the Mie and the Axilrod-Teller potentials, respectively. In the first part, to analyze stability criteria for simple crystals, a parametrical investigation was performed and stability regions for five different crystalline structures were determined with respect to potential energy parameters. To simulate some of the basic surface processes such as diffusion and nucleation, in the second and third parts, silicon surfaces were considered as a specific example. In these studies diffusion of adatoms on stepped surfaces were simulated and energetics associated with the formation of kink sites were calculated.

Halicioglu, Timur↗

Solar system dynamics

The rotational dynamics of irregularly shaped satellites and the origin of Kirkwood Gaps are discussed. The chaotic tumbling of Hyperion and the anomalously low eccentricity of Deimos are examined. The Digital Orrery is used to explore the phase space of the ellipic restricted three body problem near the principal commensurabilities (2/1, 5/2, 3/1, and 3/2). The results for the 3/1 commensurability are in close agreement with those found earlier with the algebraic mapping method. Large chaotic zones are associated with the 3/1, 2/1 and 5/2 resonances, where there are gaps in the distribution of asteroids. The region near the 3/2 resonance, where the Hilda group of asteroids is located, is largely devoid of chaotic behavior. Thus, there is a qualitative agreement between the character of the motion and the distribution of asteroids.

Wisdom, Jack↗

Orbital resonances, unusual configurations and exotic rotation states among planetary satellites

Several examples of satellite dynamics are presented where significant progress has been made in understanding a complex problem, where a long-standing problem has finally been solved, where newly discovered configurations have motivated novel descriptions or where an entirely new phenomenon has been revealed. The origin of orbital resonances in satellites and the solution of the problem of the origin and evolution of the three body Laplace resonance among the Galilean satellites are among the topics discussed.

Peale, S. J.↗

Spacecraft ram glow and surface temperature

Space shuttle glow intensity measurements show large differences when the data from different missions are compared. In particular, on the 41-G mission the space shuttle ram glow was observed to display an unusually low intensity. Subsequent investigation of this measurement and earlier measurements suggest that there was a significant difference in temperature of the glow producing ram surfaces. The highly insulating properties coupled with the high emissivity of the shuttle tile results in surfaces that cool quickly when exposed to deep space on the night side of the orbit. The increased glow intensity is consistent with the hypothesis that the glow is emitted from excited NO2. The excited NO2 is likely formed through three body recombination (OI + NO + M = NO2*) where ramming of OI interacts with weakly surface bound NO. The NO is formed from atmospheric OI and NI which is scavenged by the spacecraft moving through the atmosphere. It is postulated that the colder surfaces retain a thicker layer of NO thereby increasing the probability of the reaction. It has been found from the glow intensity/temperature data that the bond energy of the surface bound precursor, leading to the chemical recombination producing the glow, is approximately 0.14 eV. A thermal analysis of material samples of STS-8 was made and the postulated temperature change of individual material samples prior to the time of glow measurements above respective samples are consistent with the thermal effect on glow found for the orbiter surface.

Swenson, G. R.↗

Space at JPL

Various aspects of space R&D at JPL are reviewed and illustrated with photographs. The career and achievements of interplanetary-spacecraft designer Ronald Draper (beginning with work on Mariner 2 in 1961) are described, with emphasis on the ongoing development of the Galileo Jupiter spacecraft and the proposed Comet Rendezvous Asteroid Flyby spacecraft; the technological challenges posed by the Magellan mission to Venus (scheduled launch in 1989) are examined; and the histories of three mathematical problems with space applications are briefly recalled: the study of conic sections (applicable to orbits and trajectories), the development of formal logic (applicable to expert systems and artificial intelligence), and the restricted three-body problem of celestial mechanics.

Mclaughlin, William↗

S-matrix calculation of the triple-alpha reaction

An S-matrix formalism is developed which can be applied to reactions in which electron screening is important, including three-body reactions and reactions involving weak interactions. The various regimes of the triple-alpha reactions are systematically discussed, and a new nonresonant regime at high densities is identified. Using the S-matrix formalism, an analytic expression is obtained for the screened triple-alpha reactions which is accurate for all temperatures and densities. The results are compared with those of Cameron (1959) and Nomoto et al. (1985), and the latter's expression for the unscreened reaction rate is verified. However, it is shown that the reaction rate in the pycnonuclear regime cannot be obtained from the unscreened rate using a screening factor, and that the results of Nomoto et al. therefore cannot be used in this regime.

Fushiki, Ikko↗

Small Al clusters. II - Structure and binding in Al(n) (n = 2-6, 13)

The structure and stability of aluminum clusters containing up to six atoms have been studied using correlated wave functions and extended basis sets. The lowest energy structure is planar for Al4 and Al5, but three dimensional for Al6. The icosahedral, hcp, fcc, and two planar structures of Al13 were considered at the SCF level. The lowest energy structure is the icosahedron, but the planar structures are fairly low lying even in this case. A simplified description using two- and three-body interaction potentials is found to agree well with the ab initio structures and binding energies.

Pettersson, Lars G. M.↗

Friction and wear of ceramics

The adhesion, friction, wear, and lubricated behaviors of both oxide and non-oxide ceramics are reviewed. Ceramics are examined in contact with themselves, other harder materials, and metals. Elastic, plastic, and fracture behavior of ceramics in solid state contact is discussed. The contact load necessary to initiate fracture in ceramics is shown to be appreciably reduced with tangential motion. Both friction and wear of ceramics are anisotropic and relate to crystal structure as with metals. Grit size effects in two and three body abrasive wear are observed for ceramics. Both the free energy of oxide formation and the d valence bond character of metals are related to the friction and wear characteristics for metals in contact with ceramics. Surface contaminants affect friction and adhesive wear. For example, carbon on silicon carbide and chlorine on aluminum oxide reduce friction while oxygen on metal surfaces in contact with ceramics increases friction. Lubrication increases the critical load necessary to initiate fracture of ceramics both in indentation and with sliding or rubbing.

Buckley, Donald H.↗

Theoretical approaches to metal chemistry

Theoretical calculations on metals ranging from very accurate ab initio studies of diatomic and triatomic systems to model studies of larger clusters are presented. Recent improvements in the representation of one-particle and n-particle spaces have made possible the prediction that Al2 has a 3Pi(u) ground state, even though the 3Sigma(-)g state lies within 200/cm. Results suggest that cluster geometry varies dramatically with cluster size, and that rather large clusters are required before the bulk structure becomes optimal. Al cluster studies show that three-body terms are needed for quantitative agreement with ab initio calculations.

Bauschlicher, Charles W.↗

Speculative histories of the Uranian satellite system

The hypothetical histories presently considered for the Uranian satellite system are very sensitive to the assumed satellite masses, within the errors of their determinations, as well as to the Uranian tidal effective dissipation function. A determination is made of the resonances that could have been encountered in these histories, and of the orbital eccentricity constraints that would have led to certain capture. It is found that if the mass of Miranda were of the upper extreme value, it would have been locked in a long-term 2/1 orbital resonance with Ariel to form a Laplacelike, three-body resonance that encompassed Umbriel.

Peale, S. J.↗

X-ray binaries in globular clusters

X-ray and optical studies of compact binaries and globular clusters are reviewed. Topics covered include, the formation of compact binaries by three-body interactions and by tidal capture, studies of the 11 minute binary in NGC 6624 and the 8.5 hour binary in M 15 (AC211), and an evolutionary model for compact binary formation. Optical searches for X-ray binaries in globular clusters are examined including CCD surveys and studies of NGC 6712. In addition, globular clusters with central cusps in their surface brightness profiles, questions concerning the blue color of binaries, diffuse line emission from CVs, and the possibility that X-ray burst sources in the galactic bulge were formed by tidal capture in globular clusters which have since been disrupted are discussed.

Grindlay, Jonathan E.↗

A collisional model for the formation of ripples in early-type disk galaxies

Restricted three-body calculations of high-inclination low-impact-parameter encounters between a disk galaxy and its companion are used to demonstrate that the shell-like ripples noted in a number of disk galaxies are also collisional artifacts. It is suggested that some of the ripples may be the results of internal oscillations following such encounters. It is assumed that the target is an early-type disk with a sufficiently low gas fraction that recent star formation does not dominate the appearance of the disturbed disk.

Wallin, John F.↗

Monte Carlo studies of liquid semiconductor surfaces - Si and Ge

The liquid-vapor interface of Si and Ge, and of Si doped with impurities is studied using the empirical Stillinger-Weber two- and three-body potentials. The surface tension of the pure elements is calculated by use of a direct evaluation of the free energy required to create the surface. For Si, both the surface tension and its temperature derivative are in good agreement with experiment. To within numerical accuracy, the free surfaces of both Si and Ge have a monotonically decreasing density, with a 10-90 percent surface width of about 2.2 A in both cases. When large and small model impurities are introduced into pure liquid Si, they are found in the simulations to migrate, respectively, towards the surface and away from the surface. This behavior is consistent with the interpretation that impurities with atoms larger than Si tend to lower the surface tension.

Wang, Z. Q.↗

Tribological properties of structural ceramics

The tribological and lubricated behavior of both oxide and nonoxide ceramics are reviewed in this chapter. Ceramics are examined in contact with themselves, other harder materials and metals. Elastic, plastic and fracture behavior of ceramics in solid state contact is discussed. The contact load necessary to initiate fracture in ceramics is shown to be appreciably reduced with tangential motion. Both friction and wear of ceramics are anisotropic and relate to crystal structure as has been observed with metals. Grit size effects in two and three body abrasive wear are observed for ceramics. Both free energy of oxide formation and the d valence bond character of metals are related to the friction and wear characteristics for metals in contact with ceramics. Surface contaminants affect friction and adhesive wear. For example, carbon on silicon carbide and chlorine on aluminum oxide reduce friction while oxygen on metal surfaces in contact with ceramics increases friction. Lubrication increases the critical load necessary to initiate fracture of ceramics both in indentation and with sliding or rubbing. Ceramics compositions both as coatings and in composites are described for the high temperature lubrication of both alloys and ceramics.

Buckley, Donald H.↗

Design aspects of long range supersonic LFC airplanes with highly swept wings

The achievement of natural LFC in SST configurations featuring externally braced, very highly swept, high structural aspect ratio wing planforms results in outstandingly high cruise L/D ratios while maintaining low sonic-boom overpressures. A conceptual design study has been conducted with a view to range capability maximization in SSTs. A three-body configuration employing a highly swept, strut-braced planform, in which a central fuselage and two smaller outboard bodies alleviate structural wing bending and torsion, is noted to allow further increases in wingspan and aspect ratio which commensurately reduce lift-induced wave-plus-vortex drag and volume-induced wave drag.

Pfenninger, Werner↗

The varieties of symmetric stellar rings and radial caustics in galaxy disks

Numerical, restricted three-body and analytic calculations are used to study the formation and propagation of cylindrically symmetric stellar ring waves in galaxy disks. It is shown that such waves can evolve in a variety of ways, depending on the amplitude of the perturbation and the potential of the target galaxy. Rings can thicken as they propagate outward, remain at a nearly constant width, or be pinched off at large radii. Multiple, closely spaced rings can result from a low-amplitude collision, while an outer ring can appear well-separated from overlapping inner rings or an apparent lens structure in halo-dominated potentials. All the single-encounter rings consist of paired fold caustics. The simple, impulsive, kinematic oscillation equations appear to provide a remarkably accurate model of the numerical simulations. Simple analytic approximations to these equations permit very good estimates of oscillation periods and amplitudes, the evolution of ring widths, and ring birth and propagation characteristics.

Struck-Marcell, Curtis↗

Selection of component modes for the simulation of flexible multibody spacecraft

This paper describes a procedure for the selection of component modes employed in discretization of component deformation in a flexible multibody spacecraft. The emphasis is placed on the selection of modes which adequately represent the interaction of the various on-board control systems with the vehicle structural flexibility. The method combines the component mode synthesis approaches of Craig-Bampton (1968), MacNeal (1971) and Rubin (1975), and Benfield-Hruda (1971) with the modal balancing method of Moore (1981) and Gregory (1984). The procedure, which is applicable to both articulating and nonarticulating systems, was used to develop a low-order model of the three-body articulating Galileo spacecraft.

Spanos, John T.↗