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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 703 records · Page 39

Defect-Engineered High-Entropy Spinel Oxide@Onion-Like Carbon Catalysts for High-Areal-Energy Rechargeable Zinc–Air Batteries

Rechargeable zinc-air batteries (ReZAB) have emerged as the next-generation batteries with several advantages over the conventional lithium-ion battery. In this work, single nanocrystals of inverse-type high-entropy spinel oxides (HESOx, particle size of 10−12 nm) confined in highly curved defective onion-like carbons (HESOx/OLC AT ) as efficient electrocatalysts for oxygen evolution reaction (OER), oxygen reduction reaction (ORR), and ReZAB, have been synthesized. The HESOx materials were thoroughly characterized using several analytical techniques, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning transmission electron microscopy (STEM), Raman, and electron paramagnetic resonance (EPR). HESOx/OLC AT catalyst was tested for ReZAB using literature-recommended parameters that would allow for real technological application. These parameters include a current loading of 10 mA cm −2 and a discharge areal energy density of 35 mWh cm geometric −2 , which maps a Li-ion battery pack-level specific energy of 120 Wh kg pack −1 . HESOx/OLC AT electrocatalysts allowed for continuous discharging and charging at a current loading of 10 mA cm −2 with discharge areal energy densities between 37 and 74 mWh cm geometric −2 , thus outperforming the recommended threshold of 35 mWh cm geometric −2 . Considering that most studies (>90%) hardly meet the recommended threshold for technological application of ReZAB, the present work represents one of the top-performing electrocatalysts for ReZAB. The excellent electrocatalytic properties of defect-rich HESOx/OLC AT toward ORR/OER and ReZAB are governed by the strong electronic modulation arising from d-π hybridization, the availability of multiple catalytic sites for intermediates, and weakened d-band centers of the rate-determining intermediates (i.e., *O adsorption for ORR and *OOH formation for OER) compared to the pristine HESOx. This work introduces an effective approach for the design and synthesis of single nanocrystals of high-entropy electrocatalysts for the development of low-cost, robust, and technologically relevant rechargeable zinc−air batteries.

25 ENERGY STORAGE↗

A Systematic Comparison for Consistent Scenario Development Using Microscopic Simulation Software

This study aims to explore a methodology that enables the development of consistent traffic micro simulation for emerging traffic and vehicle control technologies for improved mobility and energy efficiency across different modeling platforms. Researchers might study the same application on different platforms and have the need to benchmark across platforms. However, there lacks a systematic study on simulation software comparison, especially for emerging mobility and energy efficiency applications. For this, a systematic scenario development and evaluation approach is presented and demonstrated to compare scenarios generated in different traffic microsimulation platforms. Network-level and vehicle-level trip performance results of the traffic scenario are evaluated in three microscopic simulation platforms - VISSIM, AIMSUN, and SUMO. The results indicate that the network-level performance is consistent among the three software suites except when the demand is high, where the energy consumption performance varies.

Saroj, Abhilasha [ORNL] (ORCID:0000000191178063)↗

M4SF-20LL010301042: Updated Thermodynamic Database for Use in Generic Disposal System Assessment

This progress report (Level 4 Milestone Number M4SF-20LL010301042) summarizes research conducted at Lawrence Livermore National Laboratory (LLNL) within the Argillite Activity Number SF-20LL010301041. LLNL is leading efforts in the development of thermodynamic databases in support of the Spent Fuel and Waste Science Technology (SFWST) program. Thermodynamic models provide the basis for understanding the stability of solid phases and speciation of aqueous species and modeling the evolution of repository conditions. The LLNL effort is being performed in coordination with other US database development efforts. The effort includes a review of available thermochemical databases and a path forward for database integration. International coordination with the NEA-TDB is supported through crystalline international work package.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

SUPCRTNE Thermodynamic Database Engine

This progress report (Level 4 Milestone Number M4SF-21LL010301052) summarizes research conducted at Lawrence Livermore National Laboratory (LLNL) within the Argillite Activity Number SF-21LL01030105. LLNL is leading efforts in the development of thermodynamic databases in support of the Spent Fuel and Waste Science Technology (SFWST) program. Thermodynamic models provide the basis for understanding the stability of solid phases and speciation of aqueous species and modeling the evolution of repository conditions. The LLNL effort is being performed in coordination with other US database development efforts. The effort includes a review of available thermochemical databases and a path forward for database integration. International coordination with the NEA-TDB is supported through crystalline international work package.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Modeling Power Plant Siting Opportunities and Constraints in the Eastern Interconnection

The electrical transmission grid is a critical part of the U.S. national infrastructure, and its modernization is a U.S. Department of Energy (DOE) priority. We describe the Energy Zones Mapping Tool (EZMT), a unique, powerful, and public web-based system with multi-criteria decision analysis (MCDA) models for more than 20 power plant technologies and many other capabilities. Through a case study on natural gas combined cycle (NGCC) power plants in the Eastern Interconnection (EI), we provide an example of incorporating an EZMT MCDA model into a larger planning context, with projections of interconnection-level capacity expansion, thermoelectric power plant retirements, and water availability. Our results provide insights on candidate NGCC site distributions and the criteria influencing them. The case study provides both an efficient methodology for performing similar analyses and hundreds of candidate NGCC power plant sites that can be studied in more detail as potential project sites.

20 FOSSIL-FUELED POWER PLANTS↗

Transformational Sorbent-Based Process for a Substantial Reduction in the Cost of CO2 Capture

Adsorption processes have the potential to significantly reduce the CO2 capture cost from power plants and industrial flue gases. InnoSepra has developed several sorbent-based technologies to obtain very high CO2 recovery and high purity CO2 while meeting the EOR/sequestration product specifications. A first-generation process was shown to achieve CO2 recoveries greater than 94% at CO2 purities in the range of 98.5-99.5%. The absolute heat energy required for the process was not only 40% lower than MEA but also was needed at a much lower temperature. This work will present the performance of the second-generation InnoSepra process which is based on a breakthrough sorbent regeneration method. This process has a projected 45% lower capital cost compared to MEA, less than 16% loss in plant output for CO2 capture and compression, and a CO2 capture cost at least 55% lower than MEA. Lab scale testing and the process simulations indicate a CO2 capture performance similar to or better than the first-generation process. Pilot scale drying and breakthrough tests were carried out at the Technology Centre Mongstad (TCM), Norway, and lab-scale cyclic tests were carried out at InnoSepra to confirm the process improvement. During these tests, InnoSepra’s flue gas purification technology was also tested at TCM. It can provide a low-cost option for the removal of NO2 and SOX to sub-ppm levels as well as a significant reduction in aerosol emissions.

08 HYDROGEN↗

Advanced CO 2 Capture Solvent Systems for Dynamic Power Generation

RTI International, in collaboration with Pacific Northwest National Laboratory (PNNL), Carbon Capture Simulation for Industry Impact (CCSI 2 ), Electricity Power Research Institute (EPRI), and West Virginia University (WVU), successfully completed a joint research effort in developing a cost-effective, resilient, load-following advanced CO 2 capture technology for natural gas power plants. The project’s objective was to develop a CO 2 capture process that maximizes the net present value (NPV) of the electricity sale by minimizing the levelized cost of electricity (LCOE) under dynamic plant loads and high renewable penetration environments. The two key innovations developed in this project were the use of (i) advanced water-lean solvents (WLSs) and (ii) process intensification equipment, such as a rotating packed bed (RPB) absorber and dual-stage flash regeneration. The process’s low CO 2 capture cost is realized through WLSs’ low energy required for solvent regeneration, which lowers the operating cost while RPBs intensify the absorption process and reduces the power plant capital cost. A suite of advanced computational and simulation packages was implemented to guide the process design, validate the dynamic response of the capture plant, evaluate system-wide performance, and maximize the power plant’s profit. The project also engaged with power producers and other stakeholders to ensure its technical relevance and techno-economic viability. The development of this highly disruptive CO 2 capture technology could accelerate the industry adoption and thereby lower the greenhouse gas emissions of the U.S. power sector. Deployment of this technology can increase the reliability and decrease the cost of electricity generation in the U.S. by enabling the use of low-carbon fossil fuels to balance fluctuations of renewable energy availability.

03 NATURAL GAS↗

Model validation for inferred hot-spot conditions in National Ignition Facility experiments

Progress toward ignition requires accurately diagnosing current conditions and assessing proximity metrics for implosion experiments on the National Ignition Facility. Hot-spot conditions are not directly measured, but rather inferred, often using simple 0- and 1D models [P. Patel et al., Phys. Plasmas 27, 050901 (2020)]. In this work, we present a detailed accuracy validation exercise using a set of ~20,000 2D simulations encompassing a variety of performance and degradation levels. We find good agreement between the model-inferred pressure and the simulated burn-weighted pressure at peak neutron production and also present results on the precision of inferred quantities using a Markov-Chain Monte Carlo algorithm.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

New Concepts in Electrolytes

Over the past decades, Li-ion battery (LIB) has turned into one of the most important advances in the history of technology due to its extensive and in-depth impact on our life. Its omnipresence in all electric vehicles, consumer electronics and electric grids relies on the precisely tuned electrochemical dynamics and interactions among the electrolytes and the diversified anode and cathode chemistries therein. Furthermore, with consumers' demand for battery performance ever increasing, more and more stringent requirements are being imposed upon the established equilibria among these LIB components, and it became clear that the state-of-the-art electrolyte systems could no longer sustain the desired technological trajectory. Driven by such gap, researchers started to explore more unconventional electrolyte systems. From superconcentrated solvent-in-salt electrolytes to solid-state electrolytes, the current research realm of novel electrolyte systems has grown to unprecedented levels. In this review, we will avoid discussions on current state-of-the-art electrolytes but instead focus exclusively on unconventional electrolyte systems that represent new concepts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Holistic Transportation and Energy Modeling

This project advances the development and application of the TEMPO transportation energy systems model to support DOE analysis of evolving mobility futures. Recent work has focused on improving model transparency, performance, and fidelity through a redesigned software architecture and updated technology adoption scenarios aligned with the latest data and assumptions. Ongoing efforts aim to expand TEMPO's ability to assess transportation affordability and consumer decision-making, including vehicle ownership dynamics and distributional impacts across households. These enhancements position TEMPO to better inform policy and R&D decisions by providing more behaviorally realistic and policy-relevant insights into transportation energy use, technology adoption, and system-level outcomes.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Energy Master Planning for Resilient Public Communities—Best Practices from U.S. Military Installations

Until recently, most planners at military installations addressed energy systems for new facilities on an individual facility basis without consideration of community-wide goals relevant to energy sources, renewables, storage, or future energy generation needs. Building retrofits of public buildings typically do not address energy needs beyond the minimum code requirements making it difficult, if not impossible, to achieve community-level targets on a building-by-building basis. Planning on the basis of cost and general reliability may also fail to deliver community-level resilience. For example, many building code requirements focus on hardening to specific threats, but in a multi-building community, only a few of these buildings may be mission-critical. Over the past two decades, the frequency and duration of regional power outages and water utility disruptions from weather, man-made events, and aging infrastructure have increased. Major disruptions of electric and thermal energy have degraded critical mission capabilities and caused significant economic impacts. In 2016, the U.S. Department of Defense issued guidance that each Service (Army, Navy, Air Force, Marines) complete comprehensive energy plans for the installations that consumed 75% of total building energy. Guidance was updated in 2017 to include metrics for energy resilience, and in some cases, water. This paper describes how community level quantitative and qualitative resilience analysis and metrics have been incorporated into community energy and water planning best practices for military installations in three geographically diverse locations. It is based on research performed under the International Energy Agency’s “Energy in Buildings and Communities Program Annex 73,” focusing on development of guidelines and tools that support the planning of Net Zero Energy Resilient Public Communities as well as research performed under the Department of Defense Environmental Security Technology Certification Program project EW18-D1- 5281, “Technologies Integration to Achieve Resilient, Low- Energy Military Installations.” The first case study reviews progress made on an energy and water planning study conducted at Fort Bliss, Texas. The second and third describes planning conducted at Fort Bragg, North Carolina and the Joint Region Marianas, Guam, respectively, under the updated guidance from 2017 regarding energy and water resilience. Analysis methods, key metrics, and key infrastructure and operational constraints are described, as well as technical, economic and business concepts used during the planning process.

Urban, Angela B.↗

CyclusJS: A Distributed Web-based Fuel Cycle Visual Analytics. Research Performance (Final Report)

The overall aim of the CyclusJS project has been to design novel approaches that support fuel cycle simulations and empower decision-makers and researchers with better tools to compare and contrast results from multiple simulations to understand the landscape of potential outcomes better. In particular, nuclear fuel cycle simulations focus on modeling the nuclear industry and ecosystem at a macroscopic level, and the analysis tools connect such simulations with decision support systems. As a demonstration of the novelty and effectiveness of the proposed approach, we study scenarios for transitioning from one technology, Light Water Reactors (LWR), to a newer Sodium-cooled Fast breeder Reactor (SFR) technology.

60 APPLIED LIFE SCIENCES↗

Reduction of the Waste Occupied Area by Nuclide Separation and Horizontal Emplacement of the Waste Packages - 20422

Two of the key objectives for realizing the advanced nuclear fuel cycle are to reduce the volume of high-level radioactive waste and to reduce the foot-print of the geological repository. To achieve these objectives, research and development on nuclide separation technologies is a prerequisite. In this context, it is necessary to consider the vitrification conditions and the design of the geological repository where separation technologies would be implemented to achieve effective reductions in the volume of vitrified waste and the foot-print of the geological repository. In this study, the effects of the vitrification conditions on the number of vitrified waste units and the disposal area were evaluated, based on the assumption that separation of Cs and Sr from the spent nuclear fuel had been performed. In addition, with reference to the design of the geological repository, the impact on the foot-print of the repository for different emplacement methods of the waste packages was examined. As a result, it was clarified that the waste-occupied area could be reduced by horizontal emplacement of the vitrified waste with low heat generation. In addition, it was demonstrated that a low waste-loaded vitrified waste contributed to a reduction in the foot-print of the geological repository in the case of horizontal emplacement, although the number of vitrified waste units increased. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

On the stability and stationarity of the Super H-mode combined with an ion transport barrier in the core

The Super H-mode, a regime with high pedestal pressure and stored energy, is explored on DIII-D and combined with an ion transport barrier in the plasma core to increase performance. A significant improvement of ion temperatures and confinement is facilitated by favorable conditions such as high rotational shear and high ion pedestal temperatures. As a result of a rise in density and simultaneous decrease in rotation, the ion transport barrier disappears during the discharge evolution, leading to a transition from a very high confinement state at early times, to a reduced but still high confinement phase. Additionally, in many discharges, a global MHD event consistent with the coupling of a destabilized internal mode to an edge localized mode (ELM) causes a large energy loss and leads to a reorganization of the plasma into a lower temperature, higher density state. Depending on the magnitude of the global MHD event, the plasma edge collisionality can increase significantly and shift the operational boundary from the peeling to the ballooning side, which can be understood as a drop out of the Super H-mode channel into standard H-mode. Hence, in Super H-mode discharges with ion transport barriers, both the improved pedestal height and rotational shear contribute to the high stored energy. Here, at very low levels of rotation, the confinement factor for SH modes is still expected to exceed standard H-mode by 20-30 %. With their overall stationarity and high-performance levels, Super H-mode discharges provide an attractive regime for ITER and may enable a more compact design of future fusion power plants.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Review of Ultrafast Switching Power Modules: Trends, Challenges, and Technical Solutions

Benefiting from the superior properties of wide-bandgap semiconductor materials, wide-bandgap power devices demonstrate exceptional switching performance, enabling more efficient and compact power electronics systems. However, ultrafast switching poses challenges to the reliability of the system in terms of severe oscillations and voltage overshoot, electromagnetic interference, and increased risk of partial discharge. By developing advanced power module packaging for fast-switching power devices, the above-mentioned challenges can be mitigated at the packaging level, enabling the full utilization of the fast-switching capability of wide-bandgap devices. Meanwhile, such technology also lays the groundwork for packaging next-generation power devices with even higher blocking voltage and faster switching speed. In this paper, a comprehensive review of ultrafast switching power modules has been made, including the benefits and status of ultrafast switching power modules, challenges brought by ultrafast switching, and promising technologies to address these challenges. In addition, future development trends and research gaps are also discussed in this paper. Furthermore, this review can serve as a reference for future wide-bandgap power module packaging design.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Bistatic Synthetic Aperture Radar - Issues Analysis and Design

The physical separation of the transmitter from the receiver into perhaps separate flight vehicles (with separate flight paths) in a bistatic Synthetic Aperture radar system adds considerable complexity to an already complex system. Synchronization of waveform parameters and timing attributes become problematic, and notions of even the synthetic aperture itself take on a new level of abstractness. Consequently, a high-performance, fine-resolution, and reliable bistatic SAR system really needs to be engineered from the ground up, with tighter specifications on a number of parameters, and entirely new functionality in other areas. Nevertheless, such a bistatic SAR system appears viable.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Scoping Study of Integrated Geothermal CO 2 Heat Pump and Water Well System in Cold Climate Region

This study evaluates the feasibility of using ground-source heat pumps (GSHPs) integrated with water wells for residential heating demands in cold regions of the United States. Four different heat pump systems were evaluated and compared: a CO 2 air-source heat pump (ASHP), a R-410A ASHP, a CO 2 GSHP integrated with well water, and a R-410A GSHP integrated with well water. Simulations were conducted at both equipment and building integration levels, followed by a nationwide analysis across 10 selected cities. Results indicate that integrating GSHP technology with existing water wells (e.g., artesian, bedrock, drilled, and collector wells) is a feasible heating solution because of their high flow rates, good water quality, stable temperatures, and low environmental impact. Although R-410A systems demonstrate higher efficiency, CO 2 systems are more suitable for heating from contamination-free and energy security perspective. The CO 2 GSHPs maintain better performance in colder climates compared with that of ASHPs, providing higher coefficient of performance and environmental benefits because CO 2 refrigerant leakage would not contaminate well water. A national analysis confirms that CO 2 GSHPs outperform furnaces, especially in cold climates, making them a promising solution for residential heating.

99 GENERAL AND MISCELLANEOUS↗

Scoping Study of Integrated Geothermal CO 2 Heat Pump and Water Well System in Cold Climate Region (CRADA Final Report)

This study evaluates the feasibility of using ground-source heat pumps (GSHPs) integrated with water wells for residential heating demands in cold regions of the United States. Four different heat pump systems were evaluated and compared: a CO 2 air-source heat pump (ASHP), a R-410A ASHP, a CO 2 GSHP integrated with well water, and a R-410A GSHP integrated with well water. Simulations were conducted at both equipment and building integration levels, followed by a nationwide analysis across 10 selected cities. Results indicate that integrating GSHP technology with existing water wells (e.g., artesian, bedrock, drilled, and collector wells) is a feasible heating solution because of their high flow rates, good water quality, stable temperatures, and low environmental impact. Although R-410A systems demonstrate higher efficiency, CO 2 systems are more suitable for heating from contamination-free and energy security perspective. The CO 2 GSHPs maintain better performance in colder climates compared with that of ASHPs, providing higher coefficient of performance and environmental benefits because CO 2 refrigerant leakage would not contaminate well water. A national analysis confirms that CO 2 GSHPs outperform furnaces, especially in cold climates, making them a promising solution for residential heating.

15 GEOTHERMAL ENERGY↗