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DOE OSTI2024

Catalyst design for small molecule activation of energy consequence

This project targets the conversion of ubiquitous small molecules (e.g. NO, CO, H 2 O) into viable precursors to synthetic fuels. Current state of the art catalyst design has not directly targeted transition metal complexes capable of mediating the multi-electron redox processes necessary to reduce the overpotential (energy loss) required achieve efficient activation of small molecule substrates. In this vein, a new strategy has been developed for the assembly of polynuclear architectures; allowing for the construction of tunable polymetallic centers that assemble easily within a pre-organized template (conferring stability, selectivity and tunability) that can effect multi-electron redox processes for reactions. Catalyst development has commenced with the following target design elements: (1) catalysts featuring multiple transition metal ions in the same reaction space to greatly expand accessible molecular redox capabilities; (2) catalysts are assembled in a polynucleating ligand framework that permits control over the cluster morphology as well as the local steric and electronic environment of the transition metal ions within the cluster. The high-tunability of the catalyst composition (metal content) and geometric flexibility has permitted a rigorous assessment of electronic-structure-to-function relationship to be developed, further guiding synthetic efforts to realize more potent catalysts. The numerous permutations possible showcase the high degree of generality to this approach with many synthetic handles to tune redox and reaction chemistry. Trinuclear complexes have been synthesized featuring homo- and hetero-trinuclear cores featuring a variety of first row transition metal ions (Cr→Ni). The molecular clusters have been shown to successfully mediate multi-electron redox processes in a cooperative fashion without requiring strong chemical reductants or oxidants. The reactive molecular complexes are being utilized to activate and breakdown the robust bonds within typical waste stream small molecules (e.g., greenhouse gases) and convert them into value-added commodity chemicals. Ultimately, the catalysts developed by this approach will be required to convert energy acquired via renewable resources (e.g., solar or wind) into synthetic fuels as an energy storage mechanism.

10 SYNTHETIC FUELS↗

DOE OSTI2024

Electron Influence on the Parallel Proton Firehose Instability in 10-moment, Multifluid Simulations

Instabilities driven by pressure anisotropy play a critical role in modulating the energy transfer in space and astrophysical plasmas. For the first time, we simulate the evolution and saturation of the parallel proton firehose instability using a multifluid model without adding artificial viscosity. These simulations are performed using a 10-moment, multifluid model with local and gradient relaxation heat-flux closures in high-β proton–electron plasmas. When these higher-order moments are included and pressure anisotropy is permitted to develop in all species, we find that the electrons have a significant impact on the saturation of the parallel proton firehose instability, modulating the proton pressure anisotropy as the instability saturates. Even for lower β's more relevant to heliospheric plasmas, we observe a pronounced electron energization in simulations using the gradient relaxation closure. Our results indicate that resolving the electron pressure anisotropy is important to correctly describe the behavior of multispecies plasma systems.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS1993

Two-dimensional radiative transfer in cloudy atmospheres - The spherical harmonic spatial grid method

A new two-dimensional monochromatic method that computes the transfer of solar or thermal radiation through atmospheres with arbitrary optical properties is described. The model discretizes the radiative transfer equation by expanding the angular part of the radiance field in a spherical harmonic series and representing the spatial part with a discrete grid. The resulting sparse coupled system of equations is solved iteratively with the conjugate gradient method. A Monte Carlo model is used for extensive verification of outgoing flux and radiance values from both smooth and highly variable (multifractal) media. The spherical harmonic expansion naturally allows for different levels of approximation, but tests show that the 2D equivalent of the two-stream approximation is poor at approximating variations in the outgoing flux. The model developed here is shown to be highly efficient so that media with tens of thousands of grid points can be computed in minutes. The large improvement in efficiency will permit quick, accurate radiative transfer calculations of realistic cloud fields and improve our understanding of the effect of inhomogeneity on radiative transfer in cloudy atmospheres.

Evans, K. F.↗

NASA NTRS2002

Facility and Methods Developed for Simulated Space Vacuum Ultraviolet Exposure Testing of Polymer Films

Vacuum ultraviolet (VUV) radiation of wavelengths between 115 and 200 nm produced by the Sun in the space environment can degrade polymer films, producing changes in their optical, mechanical, and chemical properties. These effects are particularly important for thin polymer films being considered for ultralightweight space structures, because, for most polymers, VUV radiation is absorbed in a thin surface layer. The NASA Glenn Research Center has developed facilities and methods for long-term ground testing of polymer films to evaluate space environmental VUV radiation effects. VUV exposure can also be used as part of combined or sequential simulated space environmental exposures to determine combined damaging effects with other aspects of the space environment, which include solar ultraviolet radiation, solar flare x-rays, electron and proton radiation, atomic oxygen (for low-Earth-orbit missions), and temperature effects. Because the wavelength sensitivity of VUV damage is not well known for most materials, Glenn's VUV facility uses a broad-spectrum deuterium lamp with a magnesium fluoride window that provides output between 115 and 200 nm. Deuterium lamps of this type were characterized by the National Institute of Standards and Technology and through measurements at Glenn. Spectral irradiance measurements show that from approximately 115 to 160 nm, deuterium lamp irradiance can be many times that of air mass zero solar irradiance, and as wavelength increases above approximately 160 nm, deuterium lamp irradiance decreases in comparison to the Sun. The facility is a cryopumped vacuum chamber that achieves a system pressure of approximately 5310(exp -6) torr. It contains four individual VUV-exposure compartments in vacuum, separated by water-cooled copper walls to minimize VUV radiation and any sample contamination cross interactions between compartments. Each VUV-exposure compartment contains a VUV deuterium lamp, a motor-controlled sample stage coupled with a moveable cesium iodide VUV phototube, and two thermocouples for temperature measurement. The vacuum chamber and exterior equipment is shown. Each VUV lamp is located at the top of the chamber with its projection-tube pushed through an O-ring compression fitting. The lamp assemblies are located on ports that can be isolated from the rest of the vacuum chamber, permitting maintenance or replacement of the lamps without breaking vacuum in the main chamber where the samples are located. A view of two of the four interior VUV-exposure compartments, including the moveable sample stages and detector holders is also shown. Glenn is using this facility to support testing of Next Generation Space Telescope sunshield materials that is being led by the NASA Goddard Space Flight Center and to develop an understanding of the wavelength, intensity, and temperature dependence of VUV-induced polymer degradation.

Dever, Joyce A.↗

NASA NTRS1989

Evidence for a high-mass white dwarf in nova V1500 Cygni 1975

Time-resolved spectroscopy of V1500 Cyg are presented from 1981, when the nebular lines from the nova ejecta had faded sufficiently to permit reliably radial velocity measurements on emission lines from the binary remnant. The spectra possess a typical AM Herculis signature. The wavelength region 3800-5100 A contains a number of strong lines, in particular the Balmer series and He II 4686 A. All lines show periodic velocity changes with the same period as the photometric variations. On the first night the lines are relatively weak and narrow, are in phase with the photometric cycle, and suffer extreme modulation; two months later they are strong and broad, are roughly 90 deg out of phase with the photometric cycle, and have relatively less variation in their line fluxes. These features support the suggestion that the remnant is an AM Her system. The observed radial velocity of the secondary is 193 + or - 9 km/s. Various constraints suggest that the magnetic white dwarf in this system has a mass over 0.9 solar.

Horne, Keith↗

NASA NTRS1997

Direct Aerosol Radiative Forcing: Calculations and Measurements from the Tropospheric

Radiative forcing is defined as the change in the net (downwelling minus upwelling) radiative flux at a given level in the atmosphere. This net flux is the radiative power density available to drive climatic processes in the earth-atmosphere system below that level. Recent research shows that radiative forcing by aerosol particles is a major source of uncertainty in climate predictions. To reduce those uncertainties, TARFOX was designed to determine direct (cloud-free) radiative forcing by the aerosols in one of the world's major industrial pollution plumes--that flowing from the east coast of the US over the Atlantic Ocean. TARFOX measured a variety of aerosol radiative effects (including direct forcing) while simultaneously measuring the chemical, physical, and optical properties of the aerosol particles causing those effects. The resulting data sets permit a wide variety of tests of the consistency, or closure, among the measurements and the models that link them. Because climate predictions use the same or similar model components, closure tests help to assess and reduce prediction uncertainties. In this work we use the TARFOX-determined aerosol, gas, and surface properties to compute radiative forcing for a variety of aerosol episodes, with inadvisable optical depths ranging from 0.07 to 0.6. We calculate forcing by several techniques with varying degrees of sophistication, in part to test the range of applicability of simplified techniques--which are often the only ones feasible in climate predictions by general circulation models (GCMs). We then compare computed forcing to that determined from: (1) Upwelling and downwelling fluxes (0.3-0.7 mm and 0.7-3.0 mm) measured by radiometers on the UK MRF C-130. and (2) Daily average cloud-free absorbed solar and emitted thermal radiative flux at the top of the atmosphere derived from the AVHRR radiometer on the NOAA- 14 satellite. The calculations and measurements all yield aerosol direct radiative forcing in the range -50 to -190 W sq m per unit inadvisable optical depth. The magnitudes are about 15 to 100 times larger than the global-average direct forcing expected for the global-average sulfate aerosol optical depth of 0.04. The reasons for the larger forcing in TARFOX include the relatively large optical depths and the focus on cloud-free, daytime conditions over the dark ocean surface. These are the conditions that produce the actual major radiative forcing events that contribute to any global-average climate effect. Detailed comparisons of calculated and measured forcings for specific events are used for more refined tests of closure.

Russell, P. B.↗

NASA NTRS1971

San Marco-C Explorer

On or about 24 April 1971, the San Marco-C spacecraft will be launched from the San Marco Range located off the coast of Kenya, Africa, by a Scout launch vehicle. The launch will be conducted by an Italian crew. The San Marco-C is the third cooperative satellite project between Italy and the United States. The first such cooperative project resulted in the San Marco-1 satellite which was launched into orbit from the Wallops Island Range with a Scout vehicle on 15 December 1964. The successful launch demonstrated the readiness of the Italian Centro Ricerche Aerospaziuli (CRA) launch crews to launch the Scout vehicle and qualified the basic spacecraft design. The second in the series of cooperative satellite launches was the San Marco-II which was successfully launched into orbit from the San Marco Range on 26 April 1967. This was the first Scout launch from the San Marco Range. The San Marco-II carried the same accelerometer as San Marco-1, but the orbit permitted the air drag to be studied in detail in the equatorial region. The successful launch also served to qualify the San Marco Range as a reliable facility for future satellite launches, and has since been used for the successful launch of SAS-A (Explorer 42). This cooperative project has been implemented jointly by the Italian Space Commission and NASA. The CRA provided the spacecraft, its subsystems, and an air drag balance; Goddard Space Flight Center (GSFC) provided an omegatron and a neutral mass spectrometer, technical consultation and support. In addition, NASA provided the Scout launch vehicle. The primary scientific objective of the San Marco-C is to obtain, by measurement, a description of the equatorial neutral-particle atmosphere in terms of its density, com- position, and temperature at altitudes of 200 km and above, and to obtain a description of variations that result from solar and geomagnetic activities. The secondary scientific objective is to investigate the interdependence of three neutral-density-measurement techniques from one spacecraft: direct particle detection, direct drag, and integrated drag.

Source record↗

DOE OSTI2022

Transient reshaping of intraband transitions by hot electrons

Hot electrons, far above the lattice temperature of a material, present opportunities for enhanced solar energy harvesting or performance of otherwise unfavorable chemistry. The spectroscopic signatures and dynamics of hot carrier absorption and emission have been extensively studied in bulk and nanoscopic semiconductors, but the effects on intraband transitions are largely unexplored. In this work, the effect of hot electrons on the properties of colloidal quantum wells made of cadmium selenide is examined using ultrafast spectroscopy. Similar to expitaxial quantum wells, these atomically precise materials support intersubband transitions (a class of intraband transitions in 1D and 2D materials) in the near-infrared spectral window. Using energy-dependent photoexcitation, it is shown that electrons reach effective temperatures of 2000 K or greater. This results in a substantial transient shift in the oscillator strength of the instersubband transition to lower energies on a sub-picosecond time-scale. Similar heating of electrons is achieved under mid-infrared re-excitation, which permits ultrafast transmittance modulation throughout the near-infrared.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

NASA NTRS2010

The Origins and Evolution of Molecules in Icy Solids

Astronomical observations of the past few decades have revealed the existence of a variety of molecules in extraterrestrial ices. These molecules include H2O, CO, and CO2, and organics such as CH4, CH30H, and C2H6. Some ices are dominated by polar molecules, while non-polar species appear to dominate others. Observations, mainly in the radio and IR regions, have allowed the inference of other solid-phase molecules whose formation remains difficult to explain by gas-phase chemistry alone. Several laboratory research groups have reported on extensive experiments on the solid-phase reaction chemistry of icy materials, generally as initiated by either ionizing radiation or vacuum-UV photons. These experiments not only permit molecular identifications to be made from astronomical observations, but also allow predictions of yet unidentified molecules. This laboratory approach has evolved over more than 30 years with much of the earliest work focusing on complex mixtures thought to represent either cometary or interstellar ices. Although those early experiments documented a rich solid-state photo- and radiation chemistry, they revealed few details of reactions for particular molecules, partly due to the multi-component nature of the samples. Since then, model systems have been examined that allow the chemistry of individual species and specific reactions to be probed. Reactions involving most of the smaller astronomical molecules have now been studied and specific processes identified. Current laboratory work suggests that a variety of reactions occur in extraterrestrial ices, including acid-base processes, radical dimerizations, proton transfers, oxidations, reductions, and isomerizations. This workshop presentation will focus on chemical reactions relevant to solar system and interstellar ices. While most of the work will be drawn from that to which the speaker has contributed, results from other laboratories also will be included. Suggestions for future studies will be made, with an emphasis on some present deficiencies. The speaker's work has been generously supported by these NASA research programs: Cassini Data Analysis, Exobiology, Mars Fundamental Research, Outer Planets Research, Planetary Atmospheres, Planetary Geology and Geophysics, and the NASA Astrobiology Institute.

Hudson, Reggie L.↗

DOE OSTI2021

Supercritical Carbon Dioxide Primary Power Large-Scale Pilot Plant

The United States electrical power generation fleet encompasses a wide range of technologies, ranging from traditional combustion-based power generation, to nuclear power, to renewable energy. While the distribution of these assets continues to shift due to economic and regulatory influences, coal combustion continues to be a key part of the US energy portfolio. Despite the relative maturity of coal combustion technology, improvements in overall fuel-to-power efficiency and generation flexibility are still possible and will improve both the economic and environmental factors of coal combustion. Echogen Power Systems proposes to lead a world-class team including the University of Missouri, Electric Power Research Institute and Louis Perry Associates in the design, construction and operation of a 10MWe coal-fired supercritical carbon dioxide (sCO 2 ) large-scale pilot. This transformational technology uses sCO 2 as a working fluid instead of water to achieve high thermodynamic efficiencies that can significantly exceed advanced steam-Rankine cycles. Further, the compact nature of sCO 2 turbomachinery offers capital cost and footprint advantages, and the low maintenance of a water-free power cycle can significantly reduce operation and maintenance (O&M) costs over conventional steam-Rankine systems. Recent integration studies of sCO 2 with coal combustion power plants highlight the significant improvements in plant efficiency that sCO 2 can offer relative to even advanced steam Rankine cycles. At commercial scales, coal-sCO 2 plant net efficiency is predicted to be 39-44.0% (HHV), or 10-20% higher output than conventional steam-Rankine systems, which will significantly improve the competitiveness of coal-fired generation. This proposal builds upon projects previously funded by the Department of Energy, including DE-FE0025959 (High-Efficiency Thermal Integration of Closed Supercritical CO 2 Brayton Power Cycles with Oxy-Fired Heaters) and DE-NE0008470 (Conceptual Design for sCO 2 Power Cycle Test Facility). An appropriately-scaled and properly designed and operated pilot project is essential to overcome the natural risk-aversion of the power generation industry and project financing community. The 10 MWe coal-fired sCO 2 pilot power plant proposed herein will reduce the technical and economic risk of this transformational technology, enabling commercial deployment at the conclusion of the project. For the second phase of this project, Echogen lead a team that completed and refined the pilot system conceptual system and key component designs resulting in the completion of a front-end-engineering-design (FEED) study, completed the NEPA review process, completed the permitting process for construction and operation, refined the techno-economic analysis of the proposed system at commercial scale and received commitments for Phase III cost share. The end result of the program will be to demonstrate the technical and economic superiority of the sCO 2 power cycle for coal-fired operation. Major risk elements will have been retired with sufficient operation at high power to enable the power generation industry to move forward with the first commercial deployment of this transformational system.

01 COAL, LIGNITE, AND PEAT↗

NASA NTRS1991

Outer planets and icy satellites

The resources offered by the outer bodies in the Solar System, starting with the main belt asteroids and Jovian System, are not only larger and more diverse but may even be easier to reach than, say, those of Mars. The use of their material, including water and organic matter, depends exclusively on the general strategy of exploration of the Solar System. Of major interest in this respect are the large ice satellites - Titan, Ganymede, and Callisto. Motion through the planetary magnetospheres excites in their ice envelopes megampere currents which, in the presence of rocky, etc., inclusions with electronic conduction should lead to the bulk electrolysis of ice and accumulation in it of 2H2 + O2 in the form of a solid solution. With the concentration of 2H2 + O2 reaching about 15 wt. percent, the solution becomes capable of detonation by a strong meteoritic impact. An explosion of Ganymede's ice envelope about 0.5 By ago could account for the formation of the Trojans and irregular satellites, all known differences between Ganymede and Callisto, and many other things. The explosion of a small icy planet with M approx less than 0.5 Moon created the asteroid belt. Two to three explosions occurred on Io, and two on Europa. The specific features of the longperiod comets close to Saturn's orbit permit dating Titan's envelope explosion as 10,000 yr ago, which produced its thick atmosphere, young Saturn's rings, as well as a reservoir of ice fragments saturated by 2H2 + O2, i.e., cometary nuclei between the orbits of Jupiter and Saturn. Thus these nuclei should contain, besides organic matter, also 2H2 + O2, which could be used for their transportation as well as for fuel for spaceships. Ices of such composition can reside deep inside Deimos, the Trojans, C-asteroids, etc. The danger of a future explosion of Callisto's electrolyzed ices, which would result in a catastrophic bombardment of the Earth by comets, may be high enough to warrant a revision of the priorities and strategy of space exploration.

Drobyshevski, E. M.↗

NASA NTRS2003

New ISTP Solar Max: A Multi-Spacecraft Study of the Flow of Ionospheric Plasma

The unique instrumentation on the Polar satellite combined with the simultaneous measurement of different parts of the magnetosphere with multiple satellites make possible the study of magnetospheric processes in a special way. In particular, the study of the ionospheric supply of plasma to the magnetosphere can by accomplished to give important results on the plasmas which drive the dynamics of the magnetosphere. This study concentrated on the period of September to December, 2001 in which the Polar orbit had precessed to the point that the line of apsides was near the equatorial plane. This unique orbital configuration enabled the TIDE instrument to measure outflowing ions across the polar cap and then transit the magnetotail lobes and observe the dramatic change in plasma characteristics as the satellite entered the plasma sheet. Contact was made with investigators on the Cluster and Geotail satellite missions and corresponding time frames were studied in the data. There were two approximate conjunctions between Polar and Geotail and data were compared to look for features which might be related. The higher energy concentration of the Geotail instrument made direct comparisons with TIDE difficult, and the Cluster measurements did not surface any cases that corresponded closely in space and time. There were, however, many interesting aspects of the Polar orbits which permitted the observation of the changing ionospheric outflowing plasma characteristics. As in earlier measurements, the ionospheric plasma could be seen flowing up the magnetic field lines out of the northern and southern polar caps. Its energy suggested a polar wind origin energized by the centrifugal acceleration of flow through the polar cusp. The roughly 10eV ions then moved out into the lobes of the magnetotail where they could be seen flowing toward the plasma sheet in both the northern and southern magnetotail lobes. There was also a double field-aligned region of warm ions observed just outside the plasmasphere, stretching toward the auroral zone and inner plasma sheet boundary. Upon entering the plasma sheet, the plasma energy jumped from 10 s of eV to greater than 1 keV. The single field aligned flows transitioned to highly variable spatially choppy energized ion distributions with a variety of pitch angle configurations. This pattern was quite repeatable in all of the Polar orbits that were examined and are compatible with the source of ions being the polar wind which is then energized to 10 s of eV by the centrifugal acceleration. These modestly energized polar wind ions are then carried to the magnetotail where they are substantially energized by the curvature drift-induced movement across the cross-tail potential of the magnetotail. This latter drift energizes the ions to the energies typically found in the plasma sheet. Subsequent drift and energization can cause the ions to become part of the ring current. The results of this study were presented at the Spring AGU meeting in 2002 and the GEM meeting in June 2003. They are the foundation for a paper that has been submitted by Matthew Huddleston to the Journal of Geophysical Research in December 2003. This work was part of the thesis that Matthew completed in finishing his Ph.D. in Physics at Vanderbilt University.

Chappell, Charles R.↗

DOE OSTI2023

Nuclear fusion powered Titan aircraft

This paper discusses a system for Titan exploration enabled by nuclear fusion power. Titan is one of the most interesting locations in the solar system with a thick atmosphere, surface oceans, under-ice oceans and complex terrain. This paper provides a conceptual design of a fusion-powered system to explore many parts of Titan and enable the use of high-power instruments. The design includes a fusion-powered orbital transfer vehicle and an electric Titan science aircraft. A Direct Fusion Drive (DFD) propulsive engine could bring a sizable spacecraft to Titan orbit in less than two years. A second fusion reactor, configured as a closed-loop power generator, would be used for an electric Titan science aircraft. Both reactors are based on the Princeton Field-Reversed Configuration (PFRC) concept which combines an FRC with a magnetic mirror. PFRC uses a novel radio-frequency plasma heating system and deuterium-helium-3 fuel. A lower temperature plasma flows around the closed-field FRC region removing the fusion products. In the DFD propulsive configuration, this secondary flow permits direct and variable thrust and exhaust velocity. The science aircraft would do a powered entry to Titan and then have the capability to fly anywhere on the moon at subsonic speeds. The DFD-powered transfer vehicle would allow the in-orbit transfer stage to change inclination as needed to cover different areas of the surface.

33 ADVANCED PROPULSION SYSTEMS↗

DOE OSTI2023

The Physical and Engineering Limits of Coupled In situ TEM Experiments

Almost all future energy systems (advanced nuclear reactors, fusion energy system, concentrating solar-thermal power (CSP), and wind technologies) are limited by degradation of key material systems exposed to multiple environmental stressors. The degradation during exposure to high temperatures, radiation, mechanical loading, and chemical attack is often dictated by mechanisms active at the microstructural level. The nature of these mechanisms and the associated variations between sequential and concurrent interplay can be explored if the transmission electron microscope (TEM) is utilized as a toolbox for exploration [1]. One such tool developed at Sandia National Laboratories to couple several of these environments is the In situ Ion Irradiation TEM (I3TEM) [2]. Several studies over the last decade utilizing this tool have shown that the scientific intuition developed over decades of sequential experiments is not always a good indicator of concurrent mechanisms or failure routes. This presentation will highlight the recent and planned additions into the I3TEM facility of a Waviks gas injection system and Raman system, respectively, as can be seen in Fig. 1, permitting environmental degradation from gas species leaked into the pole piece region during quantitative mechanical loading (indentation, monotonic loading, high temperature creep, irradiation induced creep, and high-cycle fatigue); multi-beam ion irradiation (energies ranging from 1 keV to 48 MeV and species from H to Au); laser exposure (20 W and 1064 nm), or various combinations thereof that are already possible [3]. This addition permits the facility to explore both sequential or concurrently the four axes of stressors: thermal, mechanical, radiation, and chemical. This information can be directly coupled to modeling, expediting the refinement and validation of both atomistic and mesoscale models.

degradation↗

NASA NTRS2007

Ground Clutter as a Monitor of Radar Stability at Kwajalein,RMI

There are many applications in which the absolute and day-to-day calibration of radar sensitivity is necessary. This is particularly so in the case of quantitative radar measurements of precipitation. While absolute calibrations can be done periodically using solar radiation, variations that occur between such absolute checks are required to maintain the accuracy of the data. The authors have developed a method for h s purpose using the radar on Kwajalein Atoll, which has been used to provide a baseline calibration for control of measurements of rainfall made by the Tropical Rainfall Measuring Mission 0T.he method u ses echoes from a multiplicity of ground targets. The average clutter echoes at the lowest elevation scan have been found to be remarkably stable from hour to hour, day to day, and month to month within better than +1 dB. They vary significantly only after either deliberate system modifications, equipment failure or unknown causes. A cumulative probability distribution of echo reflectivities (Ze in dBZ) is obtained on a daily basis. This CDF includes both the precipitation and clutter echoes. Because the precipitation echoes at Kwajalein rarely exceed 45 dBZ, selecting an upper percentile of the CDF associated with intense clutter reflectivities permits monitoring of radar stability. The reflectivity level at which the CDF attains 95% is our reference. Daily measurements of the CDFs have been made since August 1999 and have been used to correct the 7 M years of measurements and thus enhance the integrity of the global record of precipitation observed by TRMM. The method also has potential applicability to other pound radar sites.

Silberstein, David S.↗

NASA NTRS1994

Phytoplankton production in the Sargasso Sea as determined using optical mooring data

Optical measurements from an untended mooring provide high-frequency observations of in-water optical properties and permit the estimation of important biological parameters continuously as a function of time. A 9-month time series, composed of three separate deployments, of optical data from the BIOWATT 1987 deep-sea mooring located in the oligotrophic waters of the Sargasso Sea at 34 deg N, 70 deg W are presented. These data have been tested using several bio-optical models for the purpose of providing a continuous estimate of phytoplankton productivity. The data are discussed in the context of contemporaneous shipboard observations and for future ocean color satellite observations. We present a continuous estimation of phytoplankton productivity for the 9-month time series. Results from the first 70-day deployment are emphasized to demonstrate the utility of optical observations as proxy measures of biological parameters, to present preliminary analysis, and to compare our bio-optical observations with concurrent physical observations. The bio-optical features show variation in response to physical forcings including diel variations of incident solar irradiance, episodic changes corresponding to wind forcing, variability caused by advective mesoscale eddy events in the vicinity of the mooring, and seasonal variability corresponding to changes in solar radiation, shoaling of the mixed layer depth, and succession of phytoplankton populations.

Waters, K. J.↗

NASA NTRS1961

Flight Performance Handbook for Orbital Operations: Orbital Mechanics and Astrodynamics Formulae, Theorems, Techniques, and Applications

This handbook provides parametric data useful both to the space vehicle designer and mission analyst. It provides numerical and analytical relationships between missions and gross vehicle characteristics as a function of performance parameters. The effects of missile constraints and gross guidance limitations plus operational constraints such as launch site location, tracking net location, orbit visibility and mission on trajectory and orbit design parameters are exhibited. The influence of state-of- the-art applications of solar power as compared to future applications of nuclear power on orbit design parameters, such as eclipse time, are among the parameters included in the study. The principal aim, however, is in providing the analyst with useful parametric design information to cover the general area of earth satellite missions in the region of near-earth to cislunar space and beyond and from injection to atmospheric entry and controlled descent. The chapters are organized around the central idea of orbital operations in the 1961-1969 era with emphasis on parametric flight mechanics studies for ascent phase and parking orbits, transfer maneuvers, rendezvous maneuver, operational orbit considerations, and operational orbit control. The results are based almost entirely on the principles of flight and celestial mechanics. Numerous practical examples have been worked out in detail. This is especially important where it has been difficult or impossible to represent all possible variations of the parameters. The handbook contains analytical formulae and sufficient textual material to permit their proper use. The analytic methods consist of both exact and rapid, approximate methods. Scores of tables, working graphs and illustrations amplify the mathematical models which, together with important facts and data, cover the engineering and scientific applications of orbital mechanics. Each of the five major chapters are arranged to provide a rapid review of an entire astrodynamic subject. By the use of compact graphical and tabular presentation the full scope of the material is made available in an easy-to-use style. Throughout the volume the analyst is shown, by means of suitable introductions, notes, authoritative examples, and cross-references the vital interrelation of the various orbital mechanics topics in the general field of earth satellites and satellite rendezvous. The handbook is designed to give the analyst rapid, reliable access to the mathematics of orbital mechanics needed for virtually any working requirements.

Ambrosio, Alphonso↗

NASA NTRS1980

Impulsive phase of solar flares

The present understanding of the impulsive phase of a solar flare, characterized by short-duration bursts of impulsive hard X-ray, EUV, optical and radio emission indicating the release of energetic electrons is reviewed. Observations of the spectral distribution of impulsive hard X-ray bursts and of Type III and radio continuum bursts are presented and interpreted in terms of energetic electron distributions, and impulsive EUV, XUV, soft X-ray and optical observations, which provide a lower limit to total energy release during the impulsive phase, are discussed. The role of energetic electrons in exciting the hard X-ray, EUV and microwave emissions is considered, and thin-target, thick-target, partial-precipitation and thermal models of impulsive phase electron acceleration are evaluated in light of the observations. It is noted that available data do not allow discrimination between a thermal or a nonthermal electron distribution, on which depends the proportion of flare energy supplied by the energetic electrons, and that data favors models which permit at least partial electron precipitation. Future observational and theoretical work is indicated.

Kane, S. R.↗