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At least 703 records · Page 39
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Root water uptake of biofuel crops revealed by coupled electrical resistivity and soil water content measurements

Abstract Biofuel crops, including annuals such as maize ( Zea mays L.), soybean [ Glycine max (L.) Merr.], and canola ( Brassica napus L.), as well as high‐biomass perennial grasses such as miscanthus ( Miscanthus × giganteus J.M. Greef & Deuter ex Hodkinson & Renvoiz), are candidates for sustainable alternative energy sources. However, large‐scale conversion of croplands to perennial biofuel crops could have substantial impacts on regional water, nutrient, and C cycles due to the longer growing seasons and differences in rooting systems compared with most annual crops. However, due to the limited tools available to nondestructively study the spatiotemporal patterns of root water uptake in situ at field scales, these differences in crop water use are not well known. Geophysical imaging tools such as electrical resistivity (ER) reveal changes in water content in the soil profile. In this study, we demonstrate the use of a novel coupled hydrogeophysical approach with both time domain reflectometry soil water content and ER measurements to compare root water uptake and soil properties of an annual crop rotation with the perennial grass miscanthus, across three growing seasons (2009–2011) in southwest Michigan, USA. We estimated maximum root depths to be between 1.2 and 2.2 m, with the vertical distribution of roots being notably deeper in 2009 relative to 2010 and 2011, likely due to the drought conditions during that first year. Modeled cumulative ET of both crops was underestimated (2–34%) relative to estimates obtained from soil water drawdown in prior studies but was found to be greater in the perennial grass than the annual crops, despite shallower modeled rooting depths in 2010 and 2011.

Kuhl, Alexandria S.↗
DOE OSTI2023

Wetting of a Hydrophobic Surface: Far-IR Action Spectroscopy and Dynamics of Microhydrated Naphthalene

The interaction of water and polycyclic aromatic hydrocarbons is of fundamental importance in areas as diverse as materials science and atmospheric and interstellar chemistry. The interplay between hydrogen bonding and dipole–π interactions results in subtle dynamics that are challenging to describe from first principles. Here, we employ far-IR action vibrational spectroscopy with the infrared free-electron laser FELIX to investigate naphthalene with one to three water molecules. We observe diffuse bands associated with intermolecular vibrational modes that serve as direct probes of the loose binding of water to the naphthalene surface. These signatures are poorly reproduced by static DFT or Møller–Plesset computations. Instead, a rationalization is achieved through Born–Oppenheimer Molecular Dynamics simulations, revealing the active mobility of water over the surface, even at low temperatures. Therefore, our work provides direct insights into the wetting interactions associated with shallow potential energy surfaces while simultaneously demonstrating a solid experimental–computational framework for their investigation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Intensification of Hurricane Sally (2020) over the Mississippi River Plume

Abstract Tropical Cyclone (TC) Sally formed on 11 September 2020, traveled through the Gulf of Mexico (GMX), and intensified rapidly before making landfall on the Alabama coast as a devastating category-2 TC with extensive coastal and inland flooding. In this study, using a combination of observations and idealized numerical model experiments, we demonstrate that the Mississippi River plume played a key role in the intensification of Sally near the northern Gulf Coast. As the storm intensified and its translation slowed before landfall, sea surface cooling was reduced along its track, coincident with a pronounced increase in SSS. Further analysis reveals that TC Sally encountered a warm Loop Current eddy in the northern GMX close to the Mississippi River plume. Besides deepening the thermocline, the eddy advected low-salinity Mississippi River plume water into the storm’s path. This resulted in the development of strong upper-ocean salinity stratification, with a shallow layer of freshwater lying above a deep, warm “barrier layer.” Consequently, TC-induced mixing and the associated sea surface cooling were reduced, aiding Sally’s intensification. These results suggest that the Mississippi River plume and freshwater advection by the Loop Current eddies can play an important role in TC intensification near the U.S. Gulf Coast.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Cold-Air Outbreaks in the Marine Boundary Layer Experiment (COMBLE) Field Campaign Report

The Cold-Air Outbreaks in the Marine Boundary Layer Experiment (COMBLE) was conducted successfully between 1 December 2019 and 31 May 2020 around the Norwegian Sea. COMBLE deployed the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) first Mobile Facility (AMF1) along the coast of northern Scandinavia, at an arctic latitude (70°N), and an array of additional instruments on Bear Island (75°N) in the Norwegian Sea. The instruments deployed at these two sites collected a large array of in situ and remote-sensing observations of atmospheric conditions, clouds, precipitation, and aerosol. The main objective of COMBLE is to quantify the properties of shallow convective clouds that develop as part of an air-mass transformation process when cold air blows over open water. The two COMBLE sites are located at ~1,200 km and ~500 km from the cold source, i.e., arctic ice edge, respectively.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1973

Preliminary study of Lake Pontchartrain and vicinity using remotely sensed data from the ERTS-A satellite

The author has identified the following significant results. During the summer of 1972, huge mats of duckweeds (Lemnaceae) appeared on Lake Pontchartrain, a shallow estuary in southeastern Louisiana. In color infrared photography, duckweeds show a characteristic light lavender color, unlike algal mats or water hyacinth, as observed in low level aerial photography. Although at least five species are present in the area, most water coverage is by Lemna minor and Spirodela oligorrhiza. ERTS-1 imagery shows many areas of bayous, swamps, and marginal waters of Lake Pontchartrain covered with duckweeds. Subsequent passes show a seasonal decreases in duckweeds.

Hidalgo, J. U.↗
NASA NTRS1981

Application of the NASA airborne oceanographic lidar to the mapping of chlorophyll and other organic pigments

Laser fluorosensing techniques used for the airborne measurement of chlorophyll a and other naturally occurring waterborne pigments are reviewed. Previous experiments demonstrating the utility of the airborne oceanographic lidar (AOL) for assessment of various marine parameters are briefly discussed. The configuration of the AOL during the NOAA/NASA Superflux experiments is described. The participation of the AOL in these experiments is presented and the preliminary results are discussed. The importance of multispectral receiving capability in a laser fluorosensing system for providing reproducible measurements over wide areas having spatial variations in water column transmittance properties is addressed. This capability minimizes the number of truthing points required and is usable even in shallow estuarine areas where resuspension of bottom sediment is common. Finally, problems encountered on the Superflux missions and the resulting limitations on the AOL data sets are addressed and feasible solutions to these problems are provided.

Hoge, F. E.↗
DOE OSTI2025

Behaviour of cadmium isotopes in sulfidic waters and sediments of the Black Sea: Implications for global cadmium cycling and the application of cadmium isotopes as a paleo-oceanographic proxy

The cadmium isotope system has found use as a tracer for biological productivity, redox and organic carbon burial in the oceans. There are, however, very few observational constraints on Cd isotopic behaviour in modern sulfidic marine conditions, limiting our understanding of the modern Cd cycle, and our ability to use Cd isotope measurements of ancient sedimentary deposits as a paleoceanographic proxy. Here we study the behaviour of dissolved Cd in the water column of the Black Sea and its incorporation into sediments on the basin floor. The isotopic composition of dissolved Cd in the upper ∼50 m of the Black Sea water column is controlled by a combination of biological uptake and regeneration along with mixing of river water and Mediterranean seawater. Cadmium declines to <2 % of its peak subsurface concentration within the zone of nitrate-reduction but above the sulfide chemocline. The isotopic composition of dissolved Cd below the sulfide chemocline evolves in a manner that is consistent with experimental Cd sulfide fractionation factors, providing field-based support for these earlier studies. In contrast, the stability of the dissolved Cd isotopic signature above the chemocline, despite a large reduction in dissolved Cd concentrations, is explained by diffusion towards the Cd-sulfide sink below the chemocline. Sediments accumulating in the deep Black Sea below the sulfide chemocline have isotopic compositions that are similar to dissolved Cd in its near-surface aqueous concentration maximum. Sediments accumulating at shallower depths have lighter isotopic compositions that are likely affected by non-sulfidic burial pathways mediated by macrofaunal mixing and diagenesis of shallow burial phases. Our study shows that the isotopic composition of bulk sediments accumulating under sulfidic conditions is similar to dissolved Cd in the upper water column, supporting its use as a paleo-chemical proxy for ancient seawater as long as basin-scale controls on open ocean seawater sources are considered. We show that Cd burial in the deep Black Sea, predominantly as CdS, accounts for ∼0.5–15 % of total annual Cd burial in the global ocean.

Biogeochemical cycles↗
NASA NTRS1984

An upper ocean current jet and internal waves in a Gulf Stream warm core ring

On June 22, 1982, the R/V Endeavor, while participating in a multi-ship study of a warm core ring 82B, encountered a strong front in the core of the ring. The vessel was headed on a radial section outward from ring center while a CTD was repeatedly raised and lowered between 10 and 300 m. Current profiles in the upper 100 m were obtained continuously with a Doppler acoustic profiling system. Above the shallow 45 m seasonal thermocline, a current jet of 4 km width was encountered having a central core of relatively light water and a maximum current of 1.1 m/s. This jet was both highly nonlinear and totally unexpected. A high frequency packet of directional internal waves was acoustically observed in the seasonal thermocline at the outer edge of the jet. Vertical velocities were large enough (6 cm/s) as to be directly observable in the Doppler returns. The waves were propagating from the northeast, parallel to the ship track, and orthogonal to the jet toward the center of the warm core ring. While a nonlinear, centrifugal term was required for the force balance of the jet, the high-frequency internal wave packet could be explained with linear, gravest-mode wave dynamics.

Joyce, T. M.↗
NASA NTRS1993

Estimating chlorophyll content and bathymetry of Lake Tahoe using AVIRIS data

Data on chlorophyll content and bathymetry of Lake Tahoe obtained on August 9, 1990 by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) are compared to concurrent in situ surface and in-water measurements. Measured parameters included profiles of percent transmission of monochromatic light, stimulated chlorophyll fluorescence, photosynthetically available radiation, spectral upwelling and downwelling irradiance, and upwelling radiance. Several analyses were performed illustrating the utility of the AVIRIS over a dark water scene. Image-derived chlorophyll concentration compared extremely well with that measured with bottle samples. A bathymetry map of the shallow parts of the lake was constructed which compares favorably with published lake soundings.

Hamilton, Michael K.↗
DOE OSTI2021

The Relationship Between Topography, Bedrock Weathering, and Water Storage Across a Sequence of Ridges and Valleys

Abstract Bedrock weathering regulates nutrient mobilization, water storage, and soil production. Relative to the mobile soil layer, little is known about the relationship between topography and bedrock weathering. Here, we identify a common pattern of weathering and water storage across a sequence of three ridges and valleys in the sedimentary Great Valley Sequence in Northern California that share a tectonic and climate history. Deep drilling, downhole logging, and characterization of chemistry and porosity reveal two weathering fronts. The shallower front is ∼7 m deep at the ridge of all three hillslopes, and marks the extent of pervasive fracturing and oxidation of pyrite and organic carbon. A deeper weathering front marks the extent of open fractures and discoloration. This front is 11 m deep under two ridges of similar ridge‐valley spacing, but 17.5 m deep under a ridge with nearly twice the ridge‐valley spacing. Hence, at ridge tops, the fraction of the hillslope relief that is weathered scales with hillslope length. In all three hillslopes, below this second weathering front, closed fractures and unweathered bedrock extend about one‐half the hilltop elevation above the adjacent channels. Neutron probe surveys reveal that seasonally dynamic moisture is stored to approximately the same depth as the shallow weathering front. Under the channels that bound our study hillslopes, the two weathering fronts coincide and occur within centimeters of the ground surface. Our findings provide evidence for feedbacks between erosion and weathering in mountainous landscapes that result in systematic subsurface structuring and water routing.

58 GEOSCIENCES↗
DOE OSTI2023

Quantifying the Impact of Vertical Resolution on the Representation of Marine Boundary Layer Physics for Global-Scale Models

Abstract While GCM horizontal resolution has received the majority of scale improvements in recent years, ample evidence suggests that a model’s vertical resolution exerts a strong control on its ability to accurately simulate the physics of the marine boundary layer. Here we show that, regardless of parameter tuning, the ability of a single-column model (SCM) to simulate the subtropical marine boundary layer improves when its vertical resolution is improved. We introduce a novel objective tuning technique to optimize the parameters of an SCM against profiles of temperature and moisture and their turbulent fluxes, horizontal winds, cloud water, and rainwater from large-eddy simulations (LES). We use this method to identify optimal parameters for simulating marine stratocumulus and shallow cumulus. The novel tuning method utilizes an objective performance metric that accounts for the uncertainty in the LES output, including the covariability between model variables. Optimization is performed independently for different vertical grid spacings and value of time step, ranging from coarse scales often used in current global models (120 m, 180 s) to fine scales often used in parameterization development and large-eddy simulations (10 m, 15 s). Uncertainty-weighted disagreement between the SCM and LES decreases by a factor of ∼5 when vertical grid spacing is improved from 120 to 10 m, with time step reductions being of secondary importance. Model performance is shown to converge at a vertical grid spacing of 20 m, with further refinements to 10 m leading to little further improvement. Significance Statement In successive generations of computer models that simulate Earth’s atmosphere, improvements have been mainly accomplished by reducing the horizontal sizes of discretized grid boxes, while the vertical grid spacing has seen comparatively lesser refinements. Here we advocate for additional attention to be paid to the number of vertical layers in these models, especially in the model layers closest to Earth’s surface where climatologically important marine stratocumulus and shallow cumulus clouds reside. Our experiments show that the ability of a one-dimensional model to represent physical processes important to these clouds is strongly dependent on the model’s vertical grid spacing.

Meteorology & Atmospheric Sciences↗
NASA NTRS1977

Overall evaluation of LANDSAT (ERTS) follow on imagery for cartographic application

The author has identified the following significant results. LANDSAT imagery can be operationally applied to the revision of nautical charts. The imagery depicts shallow seas in a form that permits accurate planimetric image mapping of features to 20 meters of depth where the conditions of water clarity and bottom reflection are suitable. LANDSAT data also provide an excellent simulation of the earth's surface, for such applications as aeronautical charting and radar image correlation in aircraft and aircraft simulators. Radiometric enhancement, particularly edge enhancement, a technique only marginally successful with aerial photographs has proved to be high value when applied to LANDSAT data.

Colvocoresses, A. P.↗
NASA NTRS1992

A southwest monsoon hydrographic climatology for the Northwestern Arabian Sea

This paper provides a detailed hydrographic climatology for the shallow northwestern Arabian Sea prior to and during the southwest monsoon, presented as multiple-year composite vertical hydrographic sections based on National Oceanographic Data Center historical ocean station data. Temperature and salinity measurements are used to infer the water masses present in the upper 500 m. The hydrographic evolution depicted on bimonthly sections is inferred to result from wind-driven physical processes. In the northwestern Arabian Sea the water mass in the upper 50 m is the Arabian Sea Surface Water. Waters from 50 to 500 m are formed by mixing of Arabian Sea Surface Water with Antarctic and Indonesian intermediate waters. The inflow of Persian Gulf Water does not significantly influence the hydrography of the northwestern Arabian Sea along the Omani coast. Nitrate has a high inverse correlation with temperature and oxygen in the premonsoon thermocline in the depth interval 50-150 m. During the southwest monsoon, coastal upwelling off Oman and adjacent offshore upward Ekman pumping alter the shallow hydrography.

Brock, John C.↗
DOE OSTI2022

Effects of Cone Penetrometer Testing on Shallow Hydrogeology at a Contaminated Site

Penetration testing is a popular and instantaneous technique for subsurface mapping, contaminant tracking, and the determination of soil characteristics. While the small footprint and reproducibility of cone penetrometer testing makes it an ideal method for in-situ subsurface investigations at contaminated sites, the effects to local shallow groundwater wells and measurable influence on monitoring networks common at contaminated sites is unknown. Physical and geochemical parameters associated with cone penetrometer testing were measured from a transect of shallow groundwater monitoring wells adjacent to penetrometer testing. For wells screened above the depth of cone refusal, the physical advancement and retraction of the cone had a significant effect ( p < 0.01) on water level for several pushes within 10 meters of a monitoring well, and a measured increase in specific conductivity. No effect on geochemistry or water level was observed in continuous monitoring data from wells screened below the depth of cone refusal, but variability in specific conductivity from these wells during penetration testing was only a fraction of the natural variation measured during precipitation events. Continuous measurements of specific conductivity and water level demonstrated that the effects of penetration testing have limited spatial and temporal distributions with a null effect post-testing.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Analysis of bipolar membranes for electrochemical CO 2 capture from air and oceanwater

Carbon dioxide (CO 2 ) must be removed from the atmosphere to mitigate the negative effects of climate change. However, the most scalable methods for removing CO 2 from the air require heat from fossil-fuel combustion to produce pure CO 2 and continuously regenerate the sorbent. Bipolar-membrane electrodialysis (BPM-ED) is a promising technology that uses renewable electricity to dissociate water into acid and base to regenerate bicarbonate-based CO 2 capture solutions, such as those used in chemical loops of direct-air-capture (DAC) processes, and in direct-ocean capture (DOC) to promote atmospheric CO 2 drawdown via decarbonization of the shallow ocean. In this study, we develop an experimentally validated 1D model for the electrochemical regeneration of CO 2 from bicarbonate-based carbon capture solutions and seawater using BPM-ED. For DAC, our experimental and computational results demonstrate that pH swings induced by BPM water dissociation drive the formation of CO 2 at the cation-exchange layer|catholyte interface with energy-intensities of less than 150 kJ mol -1 . However, high rates of bubble formation increase energy intensity at current densities >100 mA cm -2 . Correspondingly, accelerating water dissociation catalysis and enacting bubble removal could enable CO 2 recovery at energy intensities <100 kJ mol -1 and current densities >100 mA cm -2 . For DOC, mass transport limitations associated with low carbon concentrations in oceanwater suggest that DOC is best suited for clean production of acid and base usable in downstream processes. Further, these results provide design principles for industrial-scale CO 2 recovery using BPM-ED.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2011

Improving Simulated Soil Moisture Fields Through Assimilation of AMSR-E Soil Moisture Retrievals with an Ensemble Kalman Filter and a Mass Conservation Constraint

Model simulated soil moisture fields are often biased due to errors in input parameters and deficiencies in model physics. Satellite derived soil moisture estimates, if retrieved appropriately, represent the spatial mean of soil moisture in a footprint area, and can be used to reduce model bias (at locations near the surface) through data assimilation techniques. While assimilating the retrievals can reduce model bias, it can also destroy the mass balance enforced by the model governing equation because water is removed from or added to the soil by the assimilation algorithm. In addition, studies have shown that assimilation of surface observations can adversely impact soil moisture estimates in the lower soil layers due to imperfect model physics, even though the bias near the surface is decreased. In this study, an ensemble Kalman filter (EnKF) with a mass conservation updating scheme was developed to assimilate the actual value of Advanced Microwave Scanning Radiometer (AMSR-E) soil moisture retrievals to improve the mean of simulated soil moisture fields by the Noah land surface model. Assimilation results using the conventional and the mass conservation updating scheme in the Little Washita watershed of Oklahoma showed that, while both updating schemes reduced the bias in the shallow root zone, the mass conservation scheme provided better estimates in the deeper profile. The mass conservation scheme also yielded physically consistent estimates of fluxes and maintained the water budget. Impacts of model physics on the assimilation results are discussed.

Li, Bailing↗
DOE OSTI2022

Experimental performance analysis of a dual source heat pump integrated with thermal energy storage

To mitigate disturbances to the electric grid resulting from the growing penetration of intermittent and decentralized renewable generation, a dual-source (air source and ground source) heat pump (DSHP) integrated with thermal energy storage (TES) was developed. The DSHP can use either ambient air or the shallow subsurface of the ground to provide space heating or space cooling to the building as the conventional heat pump and produce hot/cold water for charging TES. Using dual sources (air and ground) can reduce the required size of the expensive ground heat exchangers while retaining high energy efficiency. During the off-peak period, the DSHP cools/heats the TES with low-cost electricity or overproduced renewable power. The stored cooling/heating energy in the TES is released during peak hours of the electric grid to meet the thermal demands of the building without consuming electricity to run the DSHP. A 2-ton (7 kW) prototype DSHP was developed and integrated with a 50-gallon (189 L) TES tank filled with a phase change material. Field tests were conducted to characterize the performance of the integrated system operating in various operation modes.

Wang, Lingshi↗
NASA NTRS1991

Tidal and atmospheric forcing of the upper ocean in the Gulf of California. I - Sea surface temperature variability

SST variability in the northern Gulf of California is examined on the basis of findings of two years of satellite infrared imagery (1984-1986). Empirical orthogonal functions of the temporal and spatial SST variance for 20 monthly mean images show that the dominant SST patterns are generated by spatially varying tidal mixing in the presence of seasonal heating and cooling. Atmospheric forcing of the northern gulf appears to occur over large spatial scales. Area-averaged SSTs for the Guaymas Basin, island region, and northern basin exhibit significant fluctuations which are highly correlated. These fluctuations in SST correspond to similar fluctuations in the air temperature which are related to synoptic weather events over the gulf. A regression analysis of the SST relative to the fortnightly tidal range shows that tidal mixing occurs over the sills in the island region as well as on the shallow northern shelf. Mixing over the sills occurs as a result of large breaking internal waves of internal hydraulic jumps which mix over water in the upper 300-500 m.

Paden, Cynthia A.↗