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NASA NTRS2019

The Ability of GeoCarb to Constrain the Interannual Variability of Carbon Gases over the Amazon

We perform a number of idealized assimilation experiments with the GEOS constituent data assimilation system to test the ability of GeoCarb retrievals of CO, CO2, and CH4 to constrain the interannual variability of these gases over the Amazon. Retrievals for instruments on other satellites which observe in similar channels (e.g. MOPITT, GOSAT, and OCO-2) are limited due to persistent cloud coverage. Given its ability to sample the same location multiple times in one day, the expectation is that GeoCarb retrievals will return more soundings than those from previous missions. The goal of the assimilation experiments is to understand which scanning strategies lead to the best sounding densities and thus have the best chance of constraining interannual variability in the carbon species. The experiments each begin by picking a given year at random from a nature run (i.e., a model simulation meant to represent the truth). The model fields are sampled according to a given strategy and then screened to account for cloud coverage. Next, we pick another year at random and assimilate the synthetic GeoCarb samples into the GEOS model for that year. The output of the assimilation, 6-hourly, 3D fields of each constituent, is then directly comparable to the nature run. This comparison allows us to evaluate the ability of GeoCarb measurements to constrain the interannual variability of each gas.

Weir, B.↗

NASA NTRS1995

Reflectance spectroscopy of ferric sulfate-bearing montmorillonites as Mars soil analog materials

Spectroscopic analyses have shown that smectites enhanced in the laboratory with additional ferric species exhibit important similarities to those of the soils on Mars. Ferrihydrite in these chemically treated smectites has features in the visible to near-infrared region that resemble the energies and band strengths of features in reflectance spectra observed for several bright regions on Mars. New samples have been prepared with sulfate as well, because S was found by Viking to be a major component in the surface material on Mars. A suite of ferrihydrite-bearing and ferric sulfate-bearing montmorillonites, prepared with variable Fe3+ and S concentrations and variable pH conditions, has been analyzed using reflectance spectroscopy in the visible and infrared regions, Mossbauer spectroscopy at room temperature and 4 K, differential thermal analysis, and X-ray diffraction. These analyses support the formation of ferrihydrite of variable crystallinity in the ferrihydrite-bearing montmorillonites and a combination of schwertmannite and ferrihydrite in the ferric sulfate-bearing montmorillonites. Small quantities of poorly crystalline or nanophase forms of other ferric materials may also be present in these samples. The chemical formation conditions of the ferrihydrite-bearing and ferric sulfate-bearing montmorillonites influence the character of the low temperature Mossbauer sextets and the visible reflectance spectra. An absorption minimum is observed at 0.88-0.89 micrometers in spectra of the ferric sulfate-bearing samples, and at 0.89-0.92 micrometers in spectra of the ferrihydrate-bearing montmorillonites. Mossbauer spectra of the ferric sulfate-bearing montmorillonites indicate variable concentrations of ferrihydrite and schwertmannite in the interlaminar spaces and along grain surfaces. Dehydration under reduced atmospheric pressure conditions induces a greater effect on the adsorbed and interlayer water in ferrihydrite-bearing montmorillonite than on the water in ferric sulfate-bearing montmorillonite. Reflectance spectra of ferric sulfate-bearing montmorillonite include a strong 3-micrometers band that is more resistant to dry atmospheric conditions than the 3-micrometers band in spectra of similarly prepared ferrihydrite-bearing montmorillonites.

NASA Discipline Exobiology↗

NASA NTRS2011

Non-Stationary Internal Tides Observed with Satellite Altimetry

Temporal variability of the internal tide is inferred from a 17-year combined record of Topex/Poseidon and Jason satellite altimeters. A global sampling of along-track sea-surface height wavenumber spectra finds that non-stationary variance is generally 25% or less of the average variance at wavenumbers characteristic of mode-l tidal internal waves. With some exceptions the non-stationary variance does not exceed 0.25 sq cm. The mode-2 signal, where detectable, contains a larger fraction of non-stationary variance, typically 50% or more. Temporal subsetting of the data reveals interannual variability barely significant compared with tidal estimation error from 3-year records. Comparison of summer vs. winter conditions shows only one region of noteworthy seasonal changes, the northern South China Sea. Implications for the anticipated SWOT altimeter mission are briefly discussed.

Ray, Richard D.↗

NASA NTRSDate not supplied

Lidar-Polarimeter Retrieval OSSEs using a Nature Run in Support of NASA's Aerosols, Clouds, Convection and Precipitation (ACCP) Study

The 2017 Decadal Survey (DS) highlighted Earth System Science themes, science and application questions, and several high priority objectives that have led to the inclusion of Aerosols (A) and Clouds-Convection-Precipitation (CCP) as Designated Observables (DOs). On June 1, 2018, several NASA centers (GSFC, LaRC, JPL, MSFC, GRC and ARC) submitted a joint Study Plan to the NASA Earth Science Division for the Aerosol (A) and Cloud, Convection, and Precipitation (CCP) Pre-formulation Study (ACCP). The DS and the ACCP team recognized the science merit in combining the A and CCP DOs for both enhancing the ability to address a number of science objectives and also to provide an expanded capability to address additional objectives beyond those addressed by individual DOs. A critical element of the ACCP observing strategy is to make extensive use of new passive and active sensors as well as of the so-called Program-of-Record (PoR), complemented by a fully integrated sub-orbital component. Central to this observing system design is the adoption of a Value Framework in which quantitative assessment of the science benefits of space- and air-borne assets is a key element. Given pre-defined ACCP science objectives and geophysical variables with desired accuracies, ACCP relies on a spectrum of Observing System Simulation Experiments (OSSEs) aimed at addressing pixel level retrieval uncertainties and sampling trade-offs. In this talk we will discuss a subset of Retrieval OSSEs being considered for ACCP, namely, synergistic lidar-polarimeter retrievals based on observation simulations from the GEOS-5 Nature Run (G5NR). Starting with aerosol states from the GEOS-5 Nature Run (G5NR) sampled along specific satellite orbits, we simulate polarized radiances at the desired polarimeter wavelengths with the Vector Linearized Direct Ordinate Radiative Transfer (VLIDORT) model, alongside the lidar signal for the relevant lidars with realistic error characterization. Next, inversions are performed with the Generalized Retrieval of Aerosol and Surface Properties (GRASP) system and the accuracy of the retrieved geophysical variables are assessed. In this presentation we will highlight results for key architectures being considered for ACCP with emphasis on geophysical variables of particular relevance to ACCP’s aerosol science objectives.

A Da Silva↗

NASA NTRS2003

Characterization of the Effects of Precursor Mineralogy on Hematite Spectra: Application to Martian Hematite Mineralization

The Thermal Emission Spectrometer (TES) instrument aboard Mars Global Surveyor discovered several isolated deposits of gray, crystalline hematite in Sinus Meridiani, Aram Chaos, and Valles Marineris. A variety of formation mechanisms has been proposed for the martian hematite deposits, including aqueous and nonaqueous processes. Comparison of the average Sinus Meridiani hematite spectrum measured by TES to laboratory emissivity spectra for a variety of naturally occurring hematites shows small but potentially important differences. In particular, the emissivity minimum at 300 and 445/cm in the Sinus Meridiani (SM) spectrum is displaced 10-25/cm to lower frequencies compared to some natural hematite samples. In addition, these bands in the TES data are narrower than the broad bands seen in many natural hematite spectra. These differences may imply that the natural variability of hematite spectra has not been fully characterized, especially with respect to the reaction pathway (precursor mineralogy and temperature of hematite formation) and crystal morphology. Here, we describe the thermal infrared spectral characteristics of several series of synthetic hematite samples derived by direct precipitation, dehydroxylation of fine-grained goethite and the oxidation of magnetite. Several natural hematite sample spectra are also presented for comparison. Transmission electron microscopy (TEM) and Mossbauer spectral analyses of selected samples were performed in order to help determine the causes of the changes seen in the infrared spectra.

Glotch, Timothy D.↗

NASA NTRS2009

Circuit for Driving Piezoelectric Transducers

The figure schematically depicts an oscillator circuit for driving a piezoelectric transducer to excite vibrations in a mechanical structure. The circuit was designed and built to satisfy application-specific requirements to drive a selected one of 16 such transducers at a regulated amplitude and frequency chosen to optimize the amount of work performed by the transducer and to compensate for both (1) temporal variations of the resonance frequency and damping time of each transducer and (2) initially unknown differences among the resonance frequencies and damping times of different transducers. In other words, the circuit is designed to adjust itself to optimize the performance of whichever transducer is selected at any given time. The basic design concept may be adaptable to other applications that involve the use of piezoelectric transducers in ultrasonic cleaners and other apparatuses in which high-frequency mechanical drives are utilized. This circuit includes three resistor-capacitor networks that, together with the selected piezoelectric transducer, constitute a band-pass filter having a peak response at a frequency of about 2 kHz, which is approximately the resonance frequency of the piezoelectric transducers. Gain for generating oscillations is provided by a power hybrid operational amplifier (U1). A junction field-effect transistor (Q1) in combination with a resistor (R4) is used as a voltage-variable resistor to control the magnitude of the oscillation. The voltage-variable resistor is part of a feedback control loop: Part of the output of the oscillator is rectified and filtered for use as a slow negative feedback to the gate of Q1 to keep the output amplitude constant. The response of this control loop is much slower than 2 kHz and, therefore, does not introduce significant distortion of the oscillator output, which is a fairly clean sine wave. The positive AC feedback needed to sustain oscillations is derived from sampling the current through the piezoelectric transducer. This positive AC feedback, in combination with the slow feedback to the voltage-variable resistors, causes the overall loop gain to be just large enough to keep the oscillator running. The positive feedback loop includes two 16-channel multiplexers, which are not shown in the figure. One multiplexer is used to select the desired piezoelectric transducer. The other multiplexer, which is provided for use in the event that there are significant differences among the damping times of the 16 piezoelectric transducers, facilitates changing the value of one of the resistors in the positive-feedback loop to accommodate the damping time of the selected transducer.

Randall, David P.↗

NASA NTRS1991

Preliminary results for LDEF/HEPP thermal control samples

Sixty-five one inch by twelve inch strips of Kapton coated with various black paints, clear coatings, and thin film oxides were placed at three locations on the Long Duration Exposure Facility. Two sets were flown in the ram direction on top of the MLI blanket of the Cascade Variable Conductance Heat Pipe Experiment. Two other sets were flown on top of the MLI blanket of the Low Temperature Heat Pipe Experiment perpendicular to the ram direction. The last thirteen samples were taped to the perimeter of the HEPP power tray on the space end of the satellite. The solar absorptance and normal emittance measurements made on the 52 remaining samples are presented, as well as data on the above mentioned samples.

Kauder, Lon↗

NASA NTRS1973

Eigenvalue uncertainty in stressed structures.

A method is presented for calculating the statistics of the natural frequencies and mode shapes of vibration for a structure acted upon by an external static loading which results in the structure being stressed for eigenvalue analysis. The analytical tools presented apply to the probabilistic eigenvalue problem, and it is apparent that structural parameter uncertainty will significantly influence all aspects of the structure's response. The treatment of a sample problem serves the purpose of furthering understanding for the importance of considering structural parameters as random variables.

Hart, G. C.↗

NASA NTRS1975

Light element geochemistry of the Apollo 16 site

The abundance and isotopic composition of carbon, sulfur, and nitrogen, the abundance of helium and hydrogen, and the content of metallic iron are reported for lunar surface samples from the Apollo 16 landing site at Cayley-Descartes. The light elements show marked interstation variability at the site. The abundances in soils of C, N, He, and H are apparently controlled mainly by exposure to the solar wind, through implantation or stripping processes. Carbon abundances (but not observed isotopic distributions) are compatible with a model in which equilibrium is established after 10,000-100,000 yr between solar wind input and loss by proton stripping. Sulfur abundances in soils are apparently controlled by abundances in local country rocks, but the lunar S cycle is quite complex. A metallic iron component may have originated by solar wind reduction of lunar Fe(2+).

Kerridge, J. F.↗

NASA NTRS1975

Ride-quality testing under controlled flight conditions

As part of a NASA program to develop the technology of ride quality, a flight-test program has been conducted to obtain subjective reactions of a significant number of test passengers to a variety of controlled and repeatable flight conditions. For these experiments, the computer of a variable-stability research aircraft was programmed to precisely control the aircraft's in-flight motions as specified by motion command signals prerecorded on magnetic tape. Problems initially encountered derived primarily from the quality of the motion command signals and tape playback device, plus the aircraft motion response in degrees of freedom other than that desired. Problem solutions were obtained through the use of filtering and compensating networks. The variable-stability-system modifications, problems encountered, and their solutions are described. The test procedure is described and sample results are presented which illustrate the usefulness of this technique for ride-quality research.

Schoonover, W. E., Jr.↗

NASA NTRS1976

A computer program for anisotropic shallow-shell finite elements using symbolic integration

A FORTRAN computer program for anisotropic shallow-shell finite elements with variable curvature is described. A listing of the program is presented together with printed output for a sample case. Computation times and central memory requirements are given for several different elements. The program is based on a stiffness (displacement) finite-element model in which the fundamental unknowns consist of both the displacement and the rotation components of the reference surface of the shell. Two triangular and four quadrilateral elements are implemented in the program. The triangular elements have 6 or 10 nodes, and the quadrilateral elements have 4 or 8 nodes. Two of the quadrilateral elements have internal degrees of freedom associated with displacement modes which vanish along the edges of the elements (bubble modes). The triangular elements and the remaining two quadrilateral elements do not have bubble modes. The output from the program consists of arrays corresponding to the stiffness, the geometric stiffness, the consistent mass, and the consistent load matrices for individual elements. The integrals required for the generation of these arrays are evaluated by using symbolic (or analytic) integration in conjunction with certain group-theoretic techniques. The analytic expressions for the integrals are exact and were developed using the symbolic and algebraic manipulation language.

Andersen, C. M.↗

NASA NTRS1980

Laboratory verification of the lunar orbital X-ray fluorescence experiment - Initial results

The combined use of remote sensing and returned sample chemical data in lunar studies presumes a direct link between the two types of data. Laboratory experiments have demonstrated that within the precision of the lunar orbital X-ray fluorescence data there is a direct relationship between the fluorescence K-series X-radiation emitted from Mg, Al and Si in the surfaces of lunar soil samples and the concentrations of these elements in the bulk soil samples. This relationship encompasses both mare and terra soils. The degree of maturity is not an important variable for the existing orbital X-ray data. It is argued that these results are directly applicable to the lunar surface analyzed by the Apollo orbital X-ray fluorescence experiment.

Hubbard, N.↗

NASA NTRS1982

Implementation of a C-1 triangular element based on the P-version of the finite element method

The implementation of a computer code CONE (for C(1) continuity) based on the p-version of the finite element method is described. A hierarchic family of triangular finite elements of degree p 5 is used. This family enforces C(1)-continuity across interelement boundaries, and the code is applicable to fourth order partial differential equations in two independent variables, in particular to the biharmonic equation. Applications to several benchmark problems in plate bending are presented. Sample results are examined and compared with theoretical predictions. In particular the analysis of the bending of a rhombic plate shows a significant improvement over othr published results.

Wang, D. W.↗

NASA NTRS1987

Simultaneous field measurements of biogenic emissions of nitric oxide and nitrous oxide

Seasonal and diurnal emissions of NO and N2O from agricultural sites in Jamestown, Virginia and Boulder, Colorado are estimated in terms of soil temperature; percent moisture; and exchangeable nitrate, nitrite, and ammonium concentrations. The techniques and procedures used to analyze the soil parameters are described. The spatial and temporal variability of the NO and N2O emissions is studied. A correlation between NO fluxes in the Virginia sample and nitrate concentration, temperature, and percent moisture is detected, and NO fluxes for the Colorado site correspond with temperature and moisture. It is observed that the N2O emissions are only present when percent moisture approaches or exceeds the field capacity of the soil. The data suggest that NO is produced primarily by nitrification in aerobic soils, and N2O is formed by denitrification in anaerobic soils.

Anderson, Iris Cofman↗

NASA NTRS1988

The geology and petrogenesis of the southern closepet granite

The Archaean Closepet Granite is a polyphase body intruding the Peninsular Gneiss Complex and the associated supracrustal rocks. The granite out-crop runs for nearly 500 km with an approximate width of 20 to 25 km and cut across the regional metamorphic structure passing from granulite facies in the South and green schist facies in the north. In the amphibolite-granulite facies transition zone the granite is intimately mixed with migmatites and charnockite. Field observations suggests that anatexis of Peninsular gneisses led to the formation of granite melt, and there is a space relationship between migmatite formation, charnockite development and production and emplacement of granite magma. Based on texture and cross cutting relationships four major granite phases are recognized: (1) Pyroxene bearing dark grey granite; (2) Porphyritec granite; (3) Equigranular grey granite; and (4) Equigranular pink granite. The granite is medium to coarse grained and exhibit hypidiomorphic granular to porphyritic texture. The modal composition varies from granite granodiorite to quartz monzonite. Geochemical variation of the granite suite is consistent with either fractional crystallization or partial melting, but in both the cases biotite plus feldspar must be involved as fractionating or residual phases during melting to account trace element chemistry. The trace element data has been plotted on discriminant diagrams, where majority of samples plot in volcanic arc and within plate, tectonic environments. The granite show distinct REE patterns with variable total REE content. The REE patterns and overall abundances suggests that the granite suite represents a product of partial melting of crustal source in which fractional crystallization operated in a limited number of cases.

Jayananda, M.↗

NASA NTRS1990

Photometry of variable AFGL sources

Results of infrared photometric observations of 63 AFGL sources over the past 9 years are presented. Using these data together with previous measurements of these stars, pulsation periods and mean photometric characteristics are determined. These stars are found to lie midway between optically identified Mira variables and the radio-luminous OH/IR stars in their period distribution and photometric properties. For the sample as a whole, there is no evidence for sudden or transient behavior such as a switch in pulsation mode. Rather, these stars suggest rapid, but continuous, evolution from shorter period Miras with weak mass loss to longer periods and larger mass-loss rates. The carbon-rich stars in the sample have the same period distribution as the oxygen-rich stars. None of the carbon stars have periods as long as those of the very long period radio-luminous OH/IR stars.

Jones, Terry Jay↗

NASA NTRS1993

Improving the chi-squared approximation for bivariate normal tolerance regions

Let X be a two-dimensional random variable distributed according to N2(mu,Sigma) and let bar-X and S be the respective sample mean and covariance matrix calculated from N observations of X. Given a containment probability beta and a level of confidence gamma, we seek a number c, depending only on N, beta, and gamma such that the ellipsoid R = (x: (x - bar-X)'S(exp -1) (x - bar-X) less than or = c) is a tolerance region of content beta and level gamma; i.e., R has probability gamma of containing at least 100 beta percent of the distribution of X. Various approximations for c exist in the literature, but one of the simplest to compute -- a multiple of the ratio of certain chi-squared percentage points -- is badly biased for small N. For the bivariate normal case, most of the bias can be removed by simple adjustment using a factor A which depends on beta and gamma. This paper provides values of A for various beta and gamma so that the simple approximation for c can be made viable for any reasonable sample size. The methodology provides an illustrative example of how a combination of Monte-Carlo simulation and simple regression modelling can be used to improve an existing approximation.

Feiveson, Alan H.↗

NASA NTRS2001

The Oxidation Kinetics of Continuous Carbon Fibers in a Cracked Ceramic Matrix Composite

Experimental observations and results suggest two primary regimes as a function of temperature, i.e., diffusion and reaction controlled kinetics. Thermogravimetric analysis of carbon fiber in flowing oxygen gave an activation energy of 64.1 kJ/mol in the temperature range of 500 to 600 C and an apparent activation energy of 7.6 kJ/mol for temperatures from 600 to 1400 C. When C/SiC composite material was unstressed, matrix effects at temperatures from 900 to 1400 C protected the internal fibers. When under stress, self-protection was not observed. Increasing the stress from 10 to 25 ksi caused a 67 to 82 percent reduction in times to failure at temperatures from 750 to 1500 C. Based on experimental results, observation, and theory, a finite difference model was developed, which simulates the diffusion of oxygen into a matrix crack that is bridged by carbon fibers. The model allows the influence of important variables on oxidation kinetics to be studied systematically, i.e., temperature, reaction rate constant, diffusion coefficient, environment, and sample geometry.

Halbig, Michael C.↗